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CHEMWATCH 4753-61
Version No:4
CD 2011/4 Page 1 of 12
Min/Nil=0
Low=1
Moderate=2
High=3
Extreme=4
Risk Phrases
Flammable.
May cause SENSITISATION by skin contact.
Harmful to aquatic organisms, may cause long- term adverse
effects in the aquatic environment.
Safety Phrases
Do not breathe dust.
continued...
S24
S25
S37
S39
S51
S09
S53
S401
S26
S46
S60
CHEMWATCH 4753-61
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Section 2 - HAZARDS IDENTIFICATION
CAS RN
94-36-0
5444-75-7
%
1-10
1-10
1-5
1-5
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Section 4 - FIRST AID MEASURES
- Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask
device, or pocket mask as trained. Perform CPR if necessary.
- Transport to hospital, or doctor.
NOTES TO PHYSICIAN
For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:
- Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.
- Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea,
intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor
arterial blood gases (pO2 50 mm Hg) should be intubated.
- Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of
myocardial injury has been reported; intravenous lines and cardiac monitors should be established in
obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves
clearance.
- A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document
aspiration and detect the presence of pneumothorax.
- Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial
sensitisation to catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the
preferred agents, with aminophylline a second choice.
- Lavage is indicated in patients who require decontamination; ensure use of cuffed endotracheal tube in
adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Do not use a water jet to fight fire.
FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.
- If safe, switch off electrical equipment until vapour fire hazard removed.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- Avoid spraying water onto liquid pools.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 500 metres in all directions.
FIRE/EXPLOSION HAZARD
- Liquid and vapour are flammable.
- Moderate fire hazard when exposed to heat or flame.
- Vapour forms an explosive mixture with air.
- Moderate explosion hazard when exposed to heat or flame.
- Vapour may travel a considerable distance to source of ignition.
- Heating may cause expansion or decomposition leading to violent rupture of containers.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), other pyrolysis products typical of
burning organic material.
FIRE INCOMPATIBILITY
- Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool
chlorine etc. as ignition may result.
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CHEMWATCH 4753-61
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Section 5 - FIRE FIGHTING MEASURES
HAZCHEM
2YE
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Remove all ignition sources.
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb small quantities with vermiculite or other absorbent material.
- Wipe up.
- Collect residues in a flammable waste container.
MAJOR SPILLS
- Clear area of personnel and move upwind.
- Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.
- Consider evacuation (or protect in place).
- No smoking, naked lights or ignition sources.
- Increase ventilation.
- Stop leak if safe to do so.
- Water spray or fog may be used to disperse /absorb vapour.
- Contain spill with sand, earth or vermiculite.
- Use only spark-free shovels and explosion proof equipment.
- Collect recoverable product into labelled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite.
- Collect solid residues and seal in labelled drums for disposal.
- Wash area and prevent runoff into drains.
- If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Containers, even those that have been emptied, may contain explosive vapours.
- Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of overexposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- Avoid smoking, naked lights or ignition sources.
- Avoid generation of static electricity.
- DO NOT use plastic buckets.
- Earth all lines and equipment.
- Use spark-free tools when handling.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
continued...
CHEMWATCH 4753-61
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Section 7 - HANDLING AND STORAGE
CHEMWATCH 4753-61
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Section 7 - HANDLING AND STORAGE
Material
___________
dibenzoyl peroxide (Benzoyl peroxide)
TWA mg/m
_______
5
CAS:5444- 75- 7
IDLH
MATERIAL DATA
CHEMSET 101 PLUS:
DIBENZOYL PEROXIDE:
For benzoyl peroxide:
The recommendation for the TLV-TWA is based on the absence of subjective symptoms of irritation of the
nose and throat in humans exposed to 5.25 mg/m3. Whether this is sufficiently low to prevent cumulative
effects in man is not known.
CHEMSET 101 PLUS:
as vinyl toluene
IDLH Level: 5000 ppm
The toxicological properties of vinyltoluene are similar to those of styrene and
the TLV- TWA and STEL are analogous. The limits are thought to be protective
against mucous membrane and ocular irritation and should reduce the complaints
of objectionable odour. Given that axonal degeneration found in rats inhaling
vinyltoluene is more significant than in rats inhaling comparable concentrations
of styrene, and that neurological changes are more prominent, the limits are the
subject of review.
Human subjects show ocular and upper respiratory tract irritation at 400 ppm, complain of a strong
objectionable odour at 300 ppm and a strong but tolerable odour at 200 ppm.. At 50 ppm, the odour is
detectable and may become disagreeable, but does not produce irritation of the mucous membranes.
2-ETHYLHEXYLBENZOATE:
No exposure limits set by NOHSC or ACGIH.
PERSONAL PROTECTION
EYE
- Safety glasses with side shields.
- Chemical goggles.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A
continued...
CHEMWATCH 4753-61
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
written policy document, describing the wearing of lens or restrictions on use, should be created for each
workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals
in use and an account of injury experience. Medical and first-aid personnel should be trained in their
removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye
irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first
signs of eye redness or irritation - lens should be removed in a clean environment only after workers have
washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].
HANDS/FEET
- Wear chemical protective gloves, eg. PVC.
- Wear safety footwear or safety gumboots, eg. Rubber.
NOTE:
- The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing
gloves and other protective equipment, to avoid all possible skin contact.
- Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
OTHER
- Overalls.
- PVC Apron.
- PVC protective suit may be required if exposure severe.
- Eyewash unit.
- Ensure there is ready access to a safety shower.
- Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as
they may produce static electricity.
- For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or
pockets), non sparking safety footwear.
RESPIRATOR
Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national
equivalent)
The local concentration of material, quantity and conditions of use determine the type of personal protective
equipment required. For further information consult site specific CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Welldesigned engineering controls can be highly effective in protecting workers and will typically be independent
of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker
and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove
or dilute an air contaminant if designed properly. The design of a ventilation system must match the
particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.
For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation
system may be required. Ventilation equipment should be explosion-resistant.
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CHEMWATCH 4753-61
Version No:4
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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Does not mix with water.
Sinks in water.
State
Melting Range (C)
Boiling Range (C)
Flash Point (C)
Decomposition Temp (C)
Autoignition Temp (C)
Upper Explosive Limit (%)
Lower Explosive Limit (%)
Not Available
Molecular Weight
Viscosity
Solubility in water (g/L)
pH (1% solution)
pH (as supplied)
Vapour Pressure (kPa)
Specific Gravity (water=1)
Relative Vapour Density
(air=1)
Evaporation Rate
Not Applicable
Not Available
Immiscibl e
Not Available
Not A vailable
Not Available
1.7
Not Available
Not Available
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Section 11 - TOXICOLOGICAL INFORMATION
make an assessment.
Substance accumulation, in the human body, may occur and may cause some concern following repeated or longterm occupational exposure.
There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some
persons compared to the general population.
Based on experience with animal studies, there is a possibility that exposure to the material may result in
toxic effects to the development of the foetus, at levels which do not cause significant toxic effects to the
mother.
Prolonged or repeated skin contact with benzoyl peroxide may result in allergic skin reactions even at
diluted concentrations. Ingestion results in abdominal pain, low body oxygen and severe depression. Chronic
effects of exposure include allergic reactions characterised by redness, itching, oozing, crusting, and
scaling of the skin and asthmatic wheezing. Although it does not exhibit complete carcinogenic or tumourinitiating activity, it has been associated with certain tumours of like papillomas and squamous cell
carcinomas.
There is inadequate evidence in humans for the carcinogenicity of vinyl toluene. There is evidence suggesting
lack of carcinogenicity of vinyl toluene in experimental animals.
TOXICITY AND IRRITATION
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
2-ETHYLHEXYLBENZOATE:
CHEMSET 101 PLUS:
No significant acute toxicological data identified in literature search.
DIBENZOYL PEROXIDE:
CHEMSET 101 PLUS:
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's
oedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the
delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immune
reactions. The significance of the contact allergen is not simply determined by its sensitisation potential:
the distribution of the substance and the opportunities for contact with it are equally important. A weakly
sensitising substance which is widely distributed can be a more important allergen than one with stronger
sensitising potential with which few individuals come into contact. From a clinical point of view, substances
are noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.
DIBENZOYL PEROXIDE:
TOXICITY
IRRITATION
Oral (rat) LD50: 7710 mg/kg
Eye (rabbit): 500 mg/24h - Mild
Inhalation (human) TCLo: 12 mg/m
Skin effects (MAK): very weak
Subcutaneous (Rat) LD: 40 mg/kg (@ 50%)
Intraperitoneal (Mouse) LD50: 440 mg/kg
Intravenous (Rabbit) LD: 16 mg/kg
The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or
prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin
redness, swelling, the production of vesicles, scaling and thickening of the skin.
Benzoyl peroxide may cause double vision, breathing problems, excess saliva and tear formation, redness of
the skin and changes in motor activity. It did not produce blood or biochemical adverse effects, gene
mutation or evidence of cancer. Repeated oral administration may result in decreased weights of testes and
the newborn.
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
continued...
CARCINOGEN
Benzoyl peroxide
International Agency
for Research on Cancer
(IARC) - Agents
Reviewed by the IARC
Monographs
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Section 11 - TOXICOLOGICAL INFORMATION
Group
Persistence:
Water/Soil
LOW
LOW
Persistence: Air
Bioaccumulation
Mobility
HIGH
No Data
Available
LOW
LOW
MED
MED
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Section 13 - DISPOSAL CONSIDERATIONS
- Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical
wastes or Incineration in a licenced apparatus (after admixture with suitable combustible material).
- Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE LIQUID
HAZCHEM:
2YE (ADG7)
ADG7:
Class or Division:
UN No.:
Special Provision:
Portable Tanks & Bulk
Containers Instruction:
Packagings & IBCs Packing Instruction:
3
3269
236
None
Subsidiary Risk:
Packing Group:
Limited Quantity:
Portable Tanks & Bulk
Containers - Special
Provision:
Packagings & IBCs Special Packing
Provision:
None
III
5L
None
Subsidiary risk:
UN packing group:
None
III
3
3269
A66
ICAO/IATA Subrisk:
Packing Group:
None
III
370
Maximum Qty/Pack:
Passenger and Cargo
Maximum Qty/Pack:
Passenger and Cargo
Limited Quantity
Maximum Qty/Pack:
5 kg
IMDG Subrisk:
Packing Group:
Special provisions:
None
III
236 340
None
P302
370
Y370
5 kg
1 kg
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CHEMWATCH 4753-61
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Section 15 - REGULATORY INFORMATION