Beruflich Dokumente
Kultur Dokumente
INDUSTRY DOCUMENT
SERIES: COINDS/18/1984-85
EMISSION REGULATIONS
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'1IP,
CQJX@
CENTRAL POLLUTION CONTROL BOARD
(Ministry of Environment & Forests, Government of India)
Published By: Member Secretary, Central Pollution Control Board, Delhi; and
Printed at:
Mis Sharma Printers and Stationers, Delhi - 110 093, Phone: 2297265,
~.
(NILAY CHAUDHURI)
CHAIRMAN
(Phosphatid.
Oil Refineries
in the
Air (Prevention
ana Control
of Pollution)
Act,
1981
Section 17(l)(g), the emission standards for the air polluting industrial operations,
as mentioned
above,
Pollution
Control Boards.
in the Schedule
will be evolved
subsequently.
The rationale
for evolving
standards
are
again in January,
data
obtained
applicable
till
December,
The stack
monitoring
shall be done as
standards
area.
area
of its proximity
are
more stringent
of the industries
than those
and specially
if it
is one that
location.
that
is already
A protected
to national
parks, forests,
historical
area because
monuments
and health
resorts.
While measuring
the
emission
in- a stack,
the
temperature,
pressure,
and
termed
of pollutants
as Standard
moisture.
for Standard
Air for
reporting
compliance
to
For example,
ed by the
if the volume
dry
mrn Hg and
gas
meter,
is Vm cubic
a temperature
where
Pbar
is the
calibration
collected
is the
metres
of TmoC;
then
Pbar
298
Vm Y
(273+ Tm)
barometric
factor
dry
the emission
the
the sampling
under
train,
a negatl\'e
standard
as measur-
pressure
voiume,
Vstd
site,
in mm
of Pm
is given by
- Pm
760
pressure,
of the
through
gas
at
the
sampling
metre.
Thus,
concentration
if the
is V~?d
total
mg/Nm3
Hg and
particulates
250 mg/Nm3
150 mg/Nm3
2.
for particulate
matter
and oxides
of sulphur
150. mg/Nm3
matter
for
particulate
Off-gases
must go for H 50
Z
manufacture
: No release
o
52/53
shall be permitted
from
ter.
New Plants
(Built and Commissioned
after January
I, 1985)
the
smelter
150 mg/Nm3
or conver-
Existing Plants
250 mg/Nm3
(t
ill
December
31,
1986)
150 mg/Nm3
(from January 1, 1987)
4.
matter
of particulate
each process
Distillation
(Atmospheric plus Vacuum~
2.5 kg/Te of feed
120 kg/Te
the feed
of
Sulphur
In
*Feed Indicates the feed for that part of the proce:;s under consideratLon
only .
250 mg/Nm3
of
1 kg (P-)/Te
produced
of
particulate
alUminIUm
and
pO
mg/Nm3
matter
of
particulate
Status in respect
of evolving
Emission
Regulations
Cement
and cement
products
Ceramic
and ceramic
Chemical
and allied
industries
products
Prepared
industries
chemical
Prepared
acid*
for
Sulphuric
Prepared
for Nitric
Acid*
Prepared
for Calcium
industries
metallurgical
UP
industr ies
Prepared
and Steel*
Prepared
Prepared
Fertilizer**
9.
Foundries
10.
11.
Mining industries
12.
Non-ferrous
Carbide**
UP
industry*
UP
industries
based
for cement
for
Integrated
Iron
for Urea*
for
Phosphat
ic
UP
products
metallurgical
industries
UP
UP
industries
Ores/mineral
processing
industries
benef iciation,
pelletization,
etc.
Prepared
for
Aluminium**
Prepared
for Copper**
Prepared
for Lead**
Prepared
for Zinc**
including
UP
Power'(coal,
petroleum
and their
products) generating
plants and boiler
plants
Paper and pulp (including
industries
16.
Textile
17.
Petroleum
refineries
18.
Petroleum
industries
products
processing
paper
products)
industries
and petro-chemical
from
and disposal
Incinerators
*Printed
in Emission
**Printed
in Emission
.Regulations
Re uIatlOns
- Part
- Pai't
II
Prepared
Prepared
for Carbon
Black
Calcium
There
the
carbide
are,
at
country
Calcium
with
is
the
present,
with
oxide
a total
the
decomposition
lump
fine
formed.
These
can
be
and
feed
in arc
control
arresting
of calcium
control.
furnaces.
equipment.
are
at
of
usually
by
High
can easily
tonnes
less
than
that
shaft
250
type
and
carbide
per
is made
graphite
to react
electrodes.
oxide
and carbo:,
IS
matter
collectf'd
scrubbers
or
of
idters
150 mg/Nrn3.
Standard
250 mg!Nm3
150 mg/Nm-
tlw
dioxide
emissIon'>
operation
is generated
in a suitable
bdg
in
annum.
decomposition
of particulate
this
efficiency
This
acetylene.
vertical
control
1,00,000
to calcium
attrition
EnOrrTIOllS quantities
It is reqlJired
calcium
in kilns.
carbonate
be carried
levels
over
producing
of
SODERBERG
is generated
kilns
for
manufacturers
limestone
with
This could
maintained
devices
from
furnaces
powder
limestone.
major
required
production
is obtained
in arC
dioxide,
material
eight
carbon
During
basic
pollution
Wi1h
:,p"irl<
Ther~
will also
considered
for
be emissions
the present.
from
mining
Emission
and
regulations
dealt
Part -I",.
Comprehensive
Document
The ore
is ground
The
final
In the
concentrate
operation
Industry
after
mills
absence
of any
is
data
which
sulphuric
bearing
from
are
gases.
the
off-gases
assumed.
formed
Further
refining
converter
travel
from
smelter
the
These
gases
in the
sent
for
filtered.
froth
During
at
it is considered
is done
from
the
crossing
floatation.
Ie crushing
of dust is generated.
smelter,
through
ferti-
rational
products
not
(July 1984)
the achievability
Three
are
acid,
Regulations
Series:
and then
amount
monitoring
from
in "Emission
thickening
ore handling,
namely,
slag,
crossing
tower
and
join
tower
finally
and
The
the
main
where
enter
an emission
metal
in a converter.
cyclones
to go by
S02
off-gases
stream
built-in
of
ESP
the
sulphuric
should
be
IS
acid
plant.
Under
normal
prIOr to the
less
hence
than
4.7
needs
operating
conditions
suiphuric
acid
percent
502
venting.
This
plant.
is not
no
s.ulphurdioxide
It is claimed
suitable
is considered
for
that
off-gases
production
extremely
of
emitted
containing
H S04
2
undesirable
for
and
the
protection
of vegetativ~
the
should
plant
sulphuric
attached
acid
and human
be maintained
No 50/503 emission
is generally
cover
plant
so that
is' permitted
in dosed
there
from
to the crossing
circuit
health.
are
no fugitive
the duct/stack
tower.
reason,
emissions.
of smelter
which
even
if the
concentration
of 502
ACID
IF NECESSARY
CONTENT
PLANT
SHOULD
BY OXIDIZING
BE
MADE
SULPHUR
OPERATIVE
TO MAKE
ALL
UP
THE
THE S02
IN THE OFF-GASES.
150 mg/Nm3
for particulate
matter
Off-gases
H S04
2
release
must
go
for
manufacture.
No
of 50/503
shall be
permitted
or converter
from
the
smelter
The process
reducing
consists
conditions.
process
conditions,
Carbon
black,
devices
from getting
vessel
aromatic
The normal
product
there
is' a large
as particulate
hydrocarbons
is carbon
amount
matter,
black.
of carbon
is attempted
in reactors
under
Owing to the
monoxide
produced.
to be saved by control
lhrough
bag filters
vented
maintained
bag filters
pass
Properly
in burning
can control
the emissions
before
being
to
the
atmosphere.
with reverse
to within
older plants
go upto
have bag filters of the shaker type, where the emissions can
250 mg/Nm3
Guided by the control efficiency
of bag filters
installed
The vent
gas is usually
very rich
in carbon
in the ambient
air which may cause harm to the people living in the neigh-
or oxidized
this,
it is required
in an after-combustor
prior
that
build-up
adverse
conditions
To minimize
excessive
and under
meteorological
bourhood.
could cause
monoxide
in concentration
to venting.
recycled
The height
of the
30 metres.
New plants
(Built and Commis:>ioned
after January 1, 198.5.)
150 mg/Nm3
Existing PlantS
(Built and Commissioned
before December 31, 1984)
250 mg/Nm3
(t ill December
150 mg/Nm3
31,
1986)
To
install
for
reactor
after-burners
December 1987.
off-gas,
by
there
are fifty
one companies
manutacturing
fertilizers.
The annual
production
of SSP in India
is 1.2 million tonnes compared to 2.2 million tonnes of the total production
of phosphatIC fertilizers,
(Source
Fertilizer
Statistics,
Fertilizer
Association
(DAP), Nitro-phQsphate,
Captive production
phoric acid from rock phosphate and sulphuric acid also exists;
directly
purchase.
of phos-
some units
and
during acidification
in the concentration
desired,
sulphuric,
Fluoride
is emitted
dust
of phosphoric acid.
phosphoric
from
or nitric
rock phosphate
Fluoride
in digestors
and
becomes
or as vapour (Fluorine,
Hydrofluoric
the digesting
during dig~stion,
acid
or Silicon
acid.
either
as
Tetrafluoride)
Forty kilogram me (kg) of Fluoride (as F-) is the most that can be emitted
per tonne
of rock phosphate
medium is demonstrated
processed.
Scrubbing
to perform at an efficiency
The controlled
of rock phosphate
processed.
Fluoride
3.6 mg/Nm
emission
3
3
164,000 N m /hr
Phosphoric
production
165 Te/day
acid
Rock phosphate
ptocessed
3.6 x 164000 x 24
1000 x 1000 x 520
Efficiency
control
Tqking
99.5
percent
is 0.2 kg/Te
for total
fluoride
can De easily
of
of
as the
stable
of mixed
De used
of rock phosphate
efficiency,
the
processed.
fertilizers,
granuldtion
in these
achieved.
150 mg/Nm3
cases
care
and mixing.
whereby
Similarly,
shall
shall
also
processed
total
Consequently,
should be less than 25 mg/Nm3
a limit
.03 kg/Te
rock phosphate
In the case
would
be taken
fluoride
emission
the measured
emission
so that
in the case
limit
of grinding
be achieved.
of
the
product
techniques
150 mg/Nm3
of rock phosphate
The following
limits
"dopted:
Acidification
of rock phosphate
Granulation,
of Jock phosphate
25 mg/Nm3
as total
F-
maHer
are
The spectrum
distillation
of operations
of refineries
and blending.
reforming
on the emissions.
basic
30 percent
between
for polymerization,
in India ranges
India
The sulphur
while that
with a greater
are converted
by crack-
in oil refineries
is sulphur dioxide.
and
Atmospheri'c Distillation
ii)
Vacuum Distillation
iii)
iv)
Cokirg ullit
v)
vi)
Reformer Heater
Fluid catalytic
cracker (FCC)
In cases
where
the process
kg/Te
distillation,
of feed
units
(atmospheric
feed.
In those
cases
The
emissions
and
particul~te
of
The sulphur
feed
the
at
the
CO boiler
the
recommended
dioxide
emission
Mathura
in the fuel.
Amine
shall
off
SRU.
kept
gas,
The
above
Mathura
conven~ion
the
required
outlet
areas.
One
is, therefore,
high
kg/Te
of
it -is required
carbon
containing
efficiency
cyclones.
py having
an after
control
cleaning
of
shall
sulphur
from
sulphur
this
dioxide
the
the
dioxide
as the
shall
data
standard,
through
unit
is
be
by the
90 kg/nr
efficiency
in the feed.
recovery
in
the
shall
maintained
concentration
of sulphur
combus-
sulphide
pass
recovery
The
be reduction
hydrogen
then
spent
or 0.25 kg/Te
monoxide
chiefly
Adopting
sulphide
of
feed.
or an emission
ar~ twelve
for
hydrogen
There
dioxide,
matter,
sulphur
As revealed
of sulphur
distillation
as 0.25
efficiency
98 percent.
or 17.5 Te/day
of 94 percent
be
The scrubped
Refinery,
sulphur
Refinery.
for
of sl,Jlphur content
the
atmos-
is 198 kg/hr
for
high sulphur,
shall be controlled
procedure
scrubbing
are
by installing
monoxide
FCC
adopted
contains
The particulate
be controlled
carbon
fuel
from
emission
The standard
is, therefor~,
the
stack
is reduced.
matter.
shall
particulate
tQr.
from
uncontrolled
Refinery).
vacuum)
where
of having a common
the normal
(Mathura
plus
that
catalyst,
ccnsists
Using
unit is adopted
in the feed.
refineries
in India.
Three of these
of these
is in Mathura
and
applicable
to these
refineries.
three
two
are located
in Bombay.
in sensitive
This standard
The ambient
determine
air quality
should
be studied
applicable
Boards
by the
refineries
for
format
published
on
Monitoring
document
industrialisation
Applicable
of
emission
the monitoring
a)
by the
Baroda,
standards
three
year,
refineries.
to
This
State PolJution
beginning
Pollution
Control
This is relevant
Haldia,
for these
years
April
1986.
Central
Cochin,
next
one
Regulations.
the
in the other
to the Central
for
Madras
refineries
and
Board,
considering
in its
the
Visakhapatnam.
will be evovled
after
(Part-I),
17/1983-84.
Comprehensive
Industry Document
should be calculated
Distilldtl.:-n
(Atmospherk
plus Vacuum)
2.
Catalytic
Cracker
3.
Sulphur Recovery
120 kg/Te
ppm
Vis Breaker
Unit
FCC
Charge Heater
FCC
CO
kg/hr
90250
42198
175200
3540
3060
23
194-
6501250
355
750020000
3090
Boiler
'Sulphur
Recovery
Unit
which
for aluminium
has to be purified
can be extracted
There
'Two
are
of
six
these
through
into
control
The
an
use
VERTICAL
aluminium
kiln.
plants.
at
draw
before
exhaust
aluminium
Hall-Heroult
process.
in the
method
it is possible
it through
hydroxide
Similar
steps
manufacturers
SODERBERG
the
This is aluminium
whil~
country.
the
others
gases,
through
a pollution
the stack.
that
is precipitated
are collected
to cement
is calcined
by electrostatic
industries
in
precipitators
producing
200 tonnes
Aluminium
or for
in
aluminium
as in cement
Part
and
distinct
by the classical
In all cases,
prior to releasing
purified
rotary
ANODES.
enclosure
device
electrolysis
primary
the
is bauxite.
in several
existing
use PREBAKED
cell
manufacture
plants
power
'Emission
Document
generally
generation.
Regulations
Series:
have captive
Stack
(July
height
1984)
COIDS/ 17/1983-84'.
boilers
for their
and emission
Part
One,'
steam
requirement
standards
Comprehensive
are
given
Industry
2~3
Baking Furnace
Pre-baked
anodes
in order
process
generally
to Improve
their
utilize
a fuel
dry strength.
for baking
the
The emission
"
(Reference
In the
anodes
green
manufacture
fluorspar
of aluminium
and aluminium
fluoride
by electrolysis
are added.
of
in the carbon
control
alkaline
liner.
(as
A negligible amount
The standard
methods 0.1
reactor
Consequently,
followed
prior to release
cryolite,
alumina;
from
efficiency
the
efficiency
of the control
device
would be adequate
250
mg/Nm3
1 kg (F-)!Te
duced
of
particulates
of aluminium
150 mg/N m 3
matter
of
pr.o-
particulate
2.
3.
as Q(kg/hr)
14 (Q)0.3
4.
is estimated
IS
estimated as Q(tonnes/hr)
74 (Q)0.27
In no case should the height of the stack be less than 30 m, for plants
~iven in the Schedule of the Air (Prevention and Control of Pollution)
Act, 1981, and located in industrial areas of cities.