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  • Table of The Simple Relationships Between The Basic Values Within An Electrolytic and Galvaic Cells in Respect To The Redox Half Equations

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    Mark Riley
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    This is handy because the knowledge that you should have from 1st semester redox chemistry should allow you to review the table and not have to much trouble at all thinking about why the values are on which side and correspond with other values below and above and why the values change for electyrolytic cells. And in senior chem where I made the table it helped me to first understand.

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    Table of the simple relationships between the basic values within an electrolytic and galvaic cells in respect to the redox half equations

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    This is handy because the knowledge that you should have from 1st semester redox chemistry should allow you to review the table and not have to much trouble at all thinking about why the values are on which side and correspond with other values below and above and why the values change for electyrolytic cells. And in senior chem where I made the table it helped me to first understand.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Als PDF, TXT herunterladen oder online auf Scribd lesen
    Markieren Sie unangemessene Inhalte
    1K Ansichten1 Seite

    Table of The Simple Relationships Between The Basic Values Within An Electrolytic and Galvaic Cells in Respect To The Redox Half Equations

    Hochgeladen von

    Mark Riley
    This is handy because the knowledge that you should have from 1st semester redox chemistry should allow you to review the table and not have to much trouble at all thinking about why the values are on which side and correspond with other values below and above and why the values change for electyrolytic cells. And in senior chem where I made the table it helped me to first understand.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Als PDF, TXT herunterladen oder online auf Scribd lesen
    Markieren Sie unangemessene Inhalte
    von 1

    Annode Oxidation REDuction

    Gain of oxygen CAThode


    Loss of hydrogen Loss of oxygen
    Loss of 𝒆 Gain of hydrogen
    +𝑒 in products Gain of 𝒆
    Oxidation +𝑒 in reactants
    StrongestReductant Reduction
    Anode StrongestOxident
    Corrodes Faster Cathode
    𝒆 →→
    Voltaic Cell Spontaneous
    Negative Electrode Positive Electrode
    HASLower E0 HASHigest E0
    E0 x-1
    Solid forms (plating)
    ←← 𝑃𝑜𝑠𝑖𝑡𝑖𝑣𝑒 𝐼𝑜𝑛𝑠 (𝐶𝑎𝑡𝑖𝑜𝑛𝑠) 𝐴+
    𝐴−𝑁𝑒𝑔𝑎𝑡𝑖𝑣𝑒 𝐼𝑜𝑛𝑠 (𝐴𝑛𝑖𝑜𝑛𝑠) →→
    Zn s |Zn(NO3 )2 aq ||Cu(NO3 )2 aq |Cu(s)
    Electrolytic Cells Non Spontaneous
    Positive Electrode Negative
    0
    Highest E Electrode
    E0 x-1 Lowest E0
    Becomes basic 𝑝𝐻 ↑ GOES AS PREDICTED
    Becomes acidic 𝑝𝐻 ↓
    Solid forms on electrode
    +
    𝐴 𝑃𝑜𝑠𝑖𝑡𝑖𝑣𝑒 𝐼𝑜𝑛𝑠 (𝐶𝑎𝑡𝑖𝑜𝑛𝑠) →→
    ←← 𝑁𝑒𝑔𝑎𝑡𝑖𝑣𝑒 𝐼𝑜𝑛𝑠 (𝐴𝑛𝑖𝑜𝑛𝑠) 𝐴−
    Cl=-1 Br=-1 H=+1 O=-2 Ag=+1
    H2 O2 ∶ O = −1 CuH2 : H = −1
    K Na Li Ba Ca Mg Al Zn Fe Ni Sn Pb H2 Cu Ag Hg
    ←strongest REDUCTANT weakest→
    𝑤𝑜𝑛𝑡 𝑟𝑒𝑎𝑐𝑡 𝑤𝑖𝑡ℎ 𝑎𝑐𝑖𝑑 ← 𝐻2 → will react

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