Beruflich Dokumente
Kultur Dokumente
1. I n t r o d u c t i o n
Several transition metal oxides when heated with
glass-forming substances such as PzOs, TeO2 and
GeO 2, etc., form glasses on quenching the melt. The
loss of oxygen from the melt produces a proportion of
lower valency transition metal ions, and electrical
conduction in these glasses occurs by electron hopping
from an ion in the low valency state (e.g. Cu +) transition metal to a n ion in the higher valency state
2. E x p e r i m e n t a l w o r k
Six glasses in the CuO-TeO 2 system with 15, 25, 30,
35, 40, and 50 mol % CuO were prepared by melting
the oxides in alumina crucibles for 30min at 700 to
900 ~C. The electrical measurements were made by
standard techniques. Evaporated gold electrodes were
found to give ohmic contacts for fields up to at least
103 V cm-~ and were used in all the electrical measurements. Thin glass films, which are necessary for optical
absorption measurements, were obtained by blowing
techniques. Specimens in the thickness range 2.5 to
6.25#m were obtained as measured using a Sigma
comparator. All thin films were unannealed when
used for optical'measurements. The optical absorption measurements were made on thin blown films at
room temperature in the wavelength range 200 to
900 nm.
15 nlol % CuO
25 m01% Cu0
2500
CuO
(moi %)
Endothermal
temp (~
Exothermal
temp (~
- AH
(jg-l)
CuO
(mol %)
W
(eV)
Ee,(= 2W)
(eV)
Eop~
(eV)
Eo
(eV)
15
356
436
352
428
410
472
396
476
88.26
45.30
14.79
54.24
15
25
30
35
40
50
0.8
0.74
0.69
0.66
0.60
0.53
1.60
1.48
1.38
1.32
1.20
1.06
2.75
2.68
2.62
2.55
2.30
0.33
0.34
0.37
0.49
0.75
25
(1)
~(c~) =
1 I0
~ tn 7
(2)
~o exp (hco/Eo)
~(co)
A(hco -
Eopt)2/hco
(3)
40-
30- .d
E
g
20
10-
100
300
Temperature ( o C)
s~o
2501
(o) (b)
100 /
"
=0.5,
r,a
.._I 9
>o
'E 80
~
.~
iI
/ /
6O
/ /
o
.a
1.0
'
/,
/,'/"
,/
/
I
2.0
I.
I /
2.5
I.
I
3.0
Photon energy (eV)
I
3,5
Figure 5 (c~hc@/2plotted against he) for two samples of coppertellurium oxide glassesof the same thickness, 6.25 fire. (a) 40 tool %
1.5.
400
500
600
Wavelength (nrn)
700
Inl
3.4. D.c. c o n d u c t i v i t y
The d.c. electrical conductivity of CuO-TeO2 glasses
was measured in the temperature range 293 to 453 K.
All measurements were taken more than once. The
180
(e)
~
(a).
160
(c)
9.0
5140
3
'E
120
r
v
a/ ~ J
100
1oi
/
/
2.0
~/
I
2.5
i
t
3.0
3.5
8.0
2.0
I
I
2.5
3.0
Photon energy (eV)
I
3.5
0.~
(b)
8~0.6
>=
JE
//
0.4
0.2
I
2.0
2.5
3.0
Photon energy (eV)
3.5
a0 exp
25
(4)
35
45
CuO content {tool o/o)
I0-6 -
E10-7
2.8
2.6
10-a
8
~o
2.4
10-9
2.2
25
35
Cu0 content ( mot %}
45
10-10
2.0
I
2.5
~
3.0
1000/T(K -1)
t
3.5
2503
1.0
1011
20 ~ C
--
50 ~ C
1010
~-
--
_-
05
15
25
35
CuO content (rno[ O/o)
~5
c~
. . . . .
80 ~ C
109
4. Discussion
(d)
_ _ (c)
(b)
10-9
(a)
120~
10 8
I
1
I
3
l
2
Time(h)
10-10
References
10-!1
10-12 I
10-13 [
1o
1oo
1ooo
2504
Received 7 July
and accepted 9 October 1987