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Abstract:
The performance of a lithium ion cell is strongly related to the temperature. Therefore it is important to understand the process of heat generation and dissipation inside a single cell but also in battery packs since this is also
closely coupled to safety issues.
In this study, commercial 18650 lithium ion cells with LiMn2O4 cathodes as well as 20Ah pouch cells with
LiFePO4 cathodes were tested under isoperibolic and adiabatic conditions in an accelerating rate calorimeter
(THT Company) to investigate the heat effects during cycling.
Isoperibolic investigations in the range from 25 to 60C show that the applied environmental temperature does
not largely influence the battery thermal behavior. At 1C rate the maximum temperature increase over three
cycles was 4C almost independent of the environmental temperature. Additionally, the heat capacity and calorimeter constant were measured after calibration using cylindrical dummy cells made of AlMgSi0.5 with the cell
dimensions. By integrating over the heat dissipation rate and the enthalpy accumulation rate the total generated
heat was determined in dependence of discharge C-rate. Tests under adiabatic conditions, i.e. under negligible
heat loss, more accurately simulate a battery pack where several cells are closely packed and the neighboring
cells prevent the heat transfer to the ambient. The cell temperature was largely increasing at 1C rate over three
cycles by more than 40C rate before reaching the safety limit temperature of 75C.
This work presents also a short overview of some ECMs followed by a first implementation of an extended ECM
with a simplified thermal model in Matlab/Simulink/Simscape. The identification problem of the structure
and the parameters of an ECM are discussed in terms of the Current Interruption Technique (CIT).
In addition to the calorimetric measurements the distribution of the surface temperature was determined on the
pouch cell during charging and discharging using a thermographic camera system (FLIR, X6540sc) which
allows temperature measurements with spatial resolution. The resulting information from the IR images could be
correlated to the results of measurements with the calorimeter. It could be also used to identify temperature
gradients and hot spots on the surface of the cell.
1 Electrochemical-calorimetric measurements
Lithium ion batteries used in electric vehicles are getting more and more attention. Therefore it is important to
understand the heat generation and dissipation of single lithium ion cells and packs during operation, since this is
closely related to battery performance and safety issues.
!"#
"
$$
'()* !"#
$$
% &
"
% &
!1&
where
is the total heat generation rate,
the enthalpy accumulation rate,
the heat dissipation rate,
m the mass of the cell,
the measured heat capacity of the cell, h a heat transfer coefficient, A the battery area
exposed to the environment, T and T the cell surface and environment temperatures, respectively, ARC the
calorimeter constant [1]. The heat capacity of the cell and the calorimeter constant were determined to calculate
the total generated heat during cycling. For the calibration of the setup a dummy cell made of AlMgSi0.5 with the
cell dimensions was used.
enthalpy accumulation
heat dissipation
Chemistries (cathode//
LiMn2O4//
LiFePO4//
NMC//
anode)
graphite
graphite
graphite
1.6
20
40
3.7
3.3
3.7
2.5 4.2
2.0 3.6
2.7 4.2
Dimensions(mm)
Pouch 2271607.25
Pouch 22021510.7
23*
>6
)- */
BC D C
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/
5,
*4 6
>3*
)-
1*- /
5
123* *4 6
TE &
DC
Q,
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"9 &
*8
:;<= >
/
5,
*- 6
i=1, , n
(2)
(3)
(4)
56 HI
L/ > .
(5)
where Ri, Ci, Ui, Ii, i=1,n denotes the corresponding resistors, capacitors, voltages and currents of each RCbranch. UOC is the open circuit voltage, IL the load current and UL the terminal voltage, R0 is the ohmic resistance
of the battery. T, Ta are the temperature and ambient temperature, RT, CT the convection resistance and heat
capacitance respectively, Q the power dissipated inside the cell and SOC the dimensionless state of charge and
CQ the total charge of the battery. This system of equations can be rewritten in more general form using the state
space approach:
M
T!O, P, Q&
OI
(6)
(7)
,U
HV
,W
(8)
a)
b)
Figure 9: a) One pulse from the test and b) Impedance as a function of DOD.
Figure 10: Simulation of Artemis Road (Top) and Artemis Urban (Bottom) in Simulink/ Simscape.
3 Thermography
Accelerating Rate Calorimeters (ARC) are reliable and very useful for spot temperature measurement, but for
scanning large areas or components, its easy to miss critical effects. A thermal imaging camera can scan entire
components at once never missing any overheating hazards. In our work, a thermal camera was used to investigate the heat effects and the local temperature distribution during cycling in more details.
Every object emits radiation in the infrared region. Infrared radiation (IR) is not detectable by the human eye, but
an IR thermography camera can convert it to a visual image that depicts thermal variations across an object [8].
From Stefan-Bolzmann law, the radiated energy from a blackbody is
X
Y" Z !X/
&,
(9)
where is the Stefan-Bolzmanns constant (5.6710-8 W/m2K4). Since there is no perfect blackbody, the emissivity was used to calculate the temperature of a normal object [8]:
]
X ^_ X^^ ,
(10)
where Wbb is the emitted energy from a blackbody and Wobj is the emitted energy of a normal object at the same
temperature. So emissivity is a number between 0 and 1. Thus, the emissive power of a normal object is [8]
X
]Y" Z !X/
).
(11)
As shown in Figure 11, the radiation that impings on the IR camera lens comes from three different sources [8].
The camera receives radiation from the target object, puls radiation from its surroundings that has been reflected
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onto the objects surface. Both of these radiation components become attenuated when they pass through the
atmosphere. Since the atmosphere absorbs parts of the radiation, it will also emit radiation. [8]
] b X ^_
!1
]& b XV
c$
!1
b& X9
(12)
where is the object emissivity, is the transmission through the atmosphere, Trefl is the reflected ambient
temperature, and Tatm is the temperature of the atmosphere. To calculate the correct target object temperature, IR
camera software requires inputs for the emissivity of the object, atmosphere transmission and temperature, and
the temperature of the ambient surroundings. These factor can be measured, assumed, or found from look-up
tables [8].
The thermal imaging setup for a prismatic format of the lithium iron phosphat pouch cell was performed using
FLIR X6540sc IR camera (Figure 12). The camera has a maximal resolution of 640 by 512 pixels and the wavelength range is between 3.5 and 5 m. The camera is connected to a computer to save the thermal imaging using
software (FLIR Research IR, FLIR Systems). The cell was oriented in a vertical configuration and connected to
the Digatron MCT Cell Tester. The aluminum packaging of the cells provides a too low emissivity (=0.09) for
accurate IR imaging. Therefore, the surface of the cell was coated with graphite that has an emissivity of approximately 1.0 to ensure a uniform emissivity. A high emissivity surface effectively eliminates reflections from
the object being imaged [9].
charge rate C/2. The heterogeneity of the temperature distribution on the surface of the cell with increasing
discharge rate will be studied.
Figure 13: Thermal imaging at the beginning and the end of discharge
The local temperature on the surface of the cell was captured, as shown in Figure 14. It is evident that in horizontal and vertical direction no obvious temperature heterogeneity was observed.
Figure 14 : Temperature Comparison in different direction on the surface of the cell at a C/2 discharge rate
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Bibliography
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[7] http://www.mathworks.de/de/help/physmod/simscape/examples/lithium-battery-cell-two-rc-branch-equivalentcircuit.html?searchHighlight=lithium%20battery.
[8] FLIR: The Ultimate Infrared Handbook for R&D Professionals.
[9] Matthew A. Keyser, Ahmad Pesaran, Mark Mihalic, Ji-Sang Yu, Soo-Ryung Kim, Mohamed Alamgir, Daniel Rivers,
Thermal Characterization of Advanced Lithium-Ion Polymer Cells, Third Advanced Automotive Battery Conference, June
2003.
Acknowledgement
This R&D project is partially funded by the Federal Ministry for Education and Research (BMBF) within the
framework IKT 2020 Research for Innovations under the grant 16N12515 and is supervised by the Project
Management Agency VDIVDEIT.
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