CODE
PAPER  1
Date : 04032016
Duration : 3 Hours
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
INSTRUCTIONS
2.
The question paper CODE is printed on the right hand top corner on this sheet of this booklet.
3.
4.
Blank paper, clipboard, log tables, slide rules, calculators, cellular phones, pagers and electronic gadgets
in any form are not allowed.
5.
The answer sheet, a machinegradable Objective Response Sheet (ORS), is provided separately.
6.
7.
Do not break the seals of the questionpaper booklet before instructed to do so by the invigilators.
8.
Write your Name, Roll No. in the space provide on this page of booklet.
Write your Roll no. in the boxes given at the top left corner of your ORS with black ball point pen. Also, darken
the corresponding bubbles with Black ball point pen only. Also fill your roll no on the back side of your ORS
in the space provided (if the ORS is both side printed).
10. Fill your Paper Code as mentioned on the Test Paper and darken the corresponding bubble with Black ball
point pen.
11. If student does not fill his/her roll no. and paper code correctly and properly, then his/her marks will not be
displayed and 5 marks will be deducted (paper wise) from the total.
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darken the bubble corresponding to your answer.
13. Neither try to erase / rub / scratch the option nor make the Cross (X) mark on the option once filled. Do not
scribble, smudge, cut, tear, or wrinkle the ORS. Do not put any stray marks or whitener anywhere on the
ORS.
14. If there is any discrepancy between the written data and the bubbled data in your ORS, the bubbled data will
be taken as final.
C. Question paper format and Marking scheme :
15. The question paper consists of 3 parts (Chemistry, Physics & Mathematics). Each part consists of Four
Sections.
16. For each question in SectionI , you will be awarded 3 marks if you darken the bubble corresponding to the
correct answer and zero marks if no bubble is darkened. In case of bubbling of incorrect answer, minus
one (1) mark will be awarded.
A. General :
1. This Question Paper contains 81 questions.
17. For each question in SectionII , you will be awarded 4 marks if you darken the bubble(s) corresponding
to the correct choice(s) for the answer and zero mark if no bubbled is darkened. There is no negative
marking for incorrect answer(s) for this section.
18. For each question in SectionIII , you will be awarded 3 marks if you darken the bubble corresponding to
the correct answer and zero marks if no bubble is darkened. In case of bubbling of incorrect answer, minus
one (1) mark will be awarded.
19. For each question in SectionIV, you will be awarded 2 marks if you darken only the bubble corresponding
to the correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer,
minus one (1) mark will be awarded.
Roll Number
PARTI
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION  I
1.
Zn metal reduces SO32 ions into H2S in presence of concentrated H2SO4. What weight of Zn is required for
reduction of 6.3 g Na2SO3 in presence of concentrated acid.
(A) 9.75 g
(B) 13 g
(C) 130 g
(D) 23 g
2.
3.
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4.
Which of the following reactions of potassium superoxide supply oxygen gas in the breathing equipments
used in space and submarines ?
(1) Reaction of superoxide with nitrogen in the exhaled air.
(2) Reaction of superoxide with moisture in the exhaled air.
(3) Reaction of superoxide with carbon dioxide in the exhaled air.
(A) (1), (2) and (3)
(B) (2) and (3) only
(C) (2) only
(D) (1) and (2) only
5.
6.
7.
An ionic compound XY forms a crystal structure in which 'Y' atoms form ccp lattice and 'X' atoms are so
positioned that each 'X'atom touches 6'Y'atoms. If the nearest distance between two 'X'atoms is 2 2 ,
then the density (g/cm3) of XY crystal is :
(Given : At. mass of X = 14, At. Mass of Y = 50, Avogadros number = 6 1023)
(A) 5 6
8.
(B)
20
3
(C)
5
6
(D)
5
3
In which of the following species, the configuration at the starred atom is changed if any change in configuration
of neighbour atom is carried out.
(A)
(B)
(C)
(D)
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9.
CH3 S N a
DMSO
(A)
10.
(B)
(C)
(D)
Which of the following compound does not gives positve tollens test :
(A)
(B)
(C)
(D)
SECTION  II
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11.
Which of the following is/are correct about critical conditions of real gas following Vander Waal's equation of
state.
(A) At critical point, there is no distinction between liquid and vapour state hence density of liquid become
equal to density of vapour.
2P
T
V T
(C) Z = 3/8 for every gas at critical point, and gases are more compressible than ideal gas
(D) For the temperature less than TC, volume has three imaginary roots.
12.
13.
A reaction takes place in three steps. The rate constant of the three steps are K1, K2 and K3 respectively.
K 1K 3
The overall rate constant K = K
.
2
The energy of activation for the three steps are 40, 30 and 20 KJ respectively. Therefore :
(A) Overall energy of activation is 10 KJ
(B) Overall energy of activation is 30 KJ
K1
(C) The reaction mechanism is 2A
K2
K
A* + A ; A *
3
1
2 C ; C
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aq. NaOH /
(X) + 3 CH3COONa
14.
(B) CH3CHO
(C) CO2
(D) HCOOH
15.
PhCOOH + CHI3
yellow ppt.
(A)
(B)
(C)
(D) PhCCPh
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SECTION  III
Comprehension Type
This section contains 3 paragraphs. Based open each paragraph, there are 2 questions. Each question has
4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
17.
Which one of the following molecular geometries (i.e. shapes) is not possible for the sp3d2 hybridisation ?
(A) Trigonal bipyramidal
(B) Octahedral
CO32,
ClO3 ,
(II)
(III)
SO3,
(IV)
(C) (III) and (IV)
XeO3
(V)
(D) (IV) and (V)
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18.
Minimum concentration of Ag+ ion at which precipitation of atleast one anion starts.
(A) 108
19.
(C) 2 106
(D) 2 1010
The percentage of one of the anion precipitated when another anion starts precipitation is (Given
(A) 98.7%
(B) 99.3%
(C) 97.6%
1
2
= 0.7)
(D) 92.7%
OHC
20.
CHO
+ CH2O (1 eq.)
(x)
NaBH4
(y)
excess
SOCl 2
(z)
1) KCN
2) OH (partial hydriolysis)
3 ) KOBr /
(w)
(A)
21.
1) base
2) heat
(B)
(C)
(D)
(B)
(C)
(D)
(A)
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SECTION  IV
22.
Mn(II) salt on fusion with potassium chlorate and sodium carbonate yields pink colour permangnate ions.
23.
G for the change, H2O (, 0.9 atm, 373 K) H2O (g, 0.9 atm, 373 K) is negative.
24.
H2O2 solutions are stored in dark coloured plastic or wax coated glass vessels often with negative catalysts
such as urea or sodium stannate added as stabilizers.
25.
[Ni(CO)4] > [Co(CO)4] > [Fe(CO)4]2 With respect to strength of M C, bond. (M = Ni, Co or Fe)
26.
CH3

CH2=CHCH2Br is more reactive than CH2 CH C Br towards SN2 reaction.

CH3
27.
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PART II
SECTION  I
Straight Objective Type
This section contains 10 multiple choice questions. Each question has choices (A), (B), (C) and (D),
out of which ONLY ONE is correct.
28.
Ultraviolet light of wavelength 1 and 2 ( 2 1 ) when allowed to fall on hydrogen atoms in their ground
state is found to liberate electrons with kinetic energies E1 and E2 respectively. The value of planck's constant
can be found from the relation.
(A) h
1
2 1 E1 E 2
c
(B) h
1
1 2 E1 E 2
c
(C) h
E1 E 2 1 2
c 2 1
(D) h
E1 E 2 1 2
c 1 2
29.
The ratio of total acceleration of the electron in singly ionized helium atom and hydrogen atom according to
bohr model (both in ground state) is:
(A) 1
(B) 8
(C) 4
(D) 16
30.
A man can swim in still water with a velocity 5m/s. He wants to reach at directly opposite point on the other
bank of a river which is flowing at a rate of 4m/s. River is 15m wide and the man can run with twice the velocity
as compared with velocity of swimmer with respect to river. If he swims perpendicular to river flow and then
run along the bank, then time taken by him to reach the opposite point is :
(A) 3 sec
(B) less than 3 sec
(C) 5 sec
(D) 4.2 sec
31.
A man throws a packet from a tower directly aiming at his friend who is standing at a certain distance from
the base which is same as a height of the tower. If packet is thrown with a speed of 4m/s and it hits the
ground midway between the tower base & his friend than height of the tower is (g = 10m/s2)
(A) 5m
(B) 8m
(C) 3.2m
(D) 13m
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32.
If distance is measured in kilometer scale then the maximum permissible error will be :
(A) 103 on mm scale
(B) 106 on mm scale
3
(C) 10 on mm scale
(D) 107 on mm scale
33.
In the circuit shown in the figure C1 = C, C2 = 2C, C3 = 3C, C4 = 4C. Then select incorrect alternate :
C3
C1
C2
C4
Which of the following graph is correct between heat supplied and temperature for phase transformation of
water :
(A)
(B)
(C)
(D)
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35.
(A) 7P0V0
36.
(C) 9P0V0
(D) 9P0V0
A particle is projected from ground as shown in figure. Particle and wedge starts moving simultaneously.
Maximum height of inclined so that particle will not hit the inclined is : (g = 10 m/s 2)
(A)
37.
(B) 7P0V0
28
m
9
(B)
21
m
9
(C)
28
m
12
(D)
21
m
12
A small ring of mass m is connected with a particle of same mass by an ideal string & the whole
system in released as shown in figure.
friction between ring A and wire is 3/5, ring A
(SPACECoefficient
FOR ROUGH of
WORK)
will starts sliding when connecting string will make an angle with the vertical, then will be : (particle
is free to move and ring can slide only)
(A) 30
(B) 45
(C) 60
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SECTION  II
Multiple Correct Answers Type
This section contains 5 multiple correct answer(s) type questions. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE OR MORE is/are correct.
38.
A wire shaped as a semicircle of radius a, is rotating about an axis PQ with a constant angular velocity
, with the help of an external agent. A uniform magnetic field B exists in space and is directed
LC
into the plane of the figure. (circuit part remains at rest) (left part is at rest)
Ba 2
R 2LC
Ba 2
(B) The rms value of current in the circuit is
2R 2LC
2 B2 a 4
(C) The maximum energy stored in the capacitor is
8R 2C
2B2a 4
(D) The maximum power delivered by the external agent is
4LCR
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39.
AB is a light rigid rod, which is rotating about a vertical axis passing through A. A spring of force constant K
and natural length is attached at A and its other end is attached to a small bead of mass m. The bead can
slide without friction on the rod. At the initial moment the bead is at rest (w.r.t. the rod) and the spring is
unstrecthed. Select correct options :
K, l
m
B
Bead
(A) The maximum velocity attained by the bead w.r.t the rod is given by Vmax
m4 2
K m 2
m 4 K 2 2
(B) The maximum velocity attained by the bead w.r.t the rod is given by Vmax
2
m K
(C) The maximum extension in the spring is given by X max
2m 2
K m 2
(D) The maximum value of contact force between the bead and the rod is greater than mg
40.
Two refracting media are separated by a spherical interface as shown in figure. PP' is the principle axis. 1
and 2 are the refractive indices of medium of incidence and medium of refraction respectively. Then:
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41.
then:
x
(B) 1m
(A)
x
(C)
(D)
t
42.
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SECTION  III
Comprehension Type
This section contains 3 paragraphs. Based upon each paragraph, 2 multiple choice questions have to
be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
44.
25
Jmol1K1.
3
(C) 3 105 J
(C) 35kJ
(D) 15kJ
(B) 3.2kJ
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Assume that a voltmeter reads V E.d between its terminals. A time varying magnetic field B(t)
exists in a circular region of radius a and it is directed into the plane of the figure B(t) = B0t where B0 is a
positive constant of proper dimensions and t is the time
B
b
b
v1
R1
R2
v2
B (t )
A
45.
(A) 2 a B0
46.
a 2 B0
(C )
2
(B)
a B0
(B)
a 2 B0 R1
R2
(D)
a 2 B0
2
The reading of V1 is :
(A)
a B0
(C)
a 2 B0 R1
R1 R2
a 2 B0 R1
(D)
R1 R2
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48.
4
R 3 ( A BR )
3
(B) 4 R 3 ( A BR )
(C)
4
3
R 3 A BR
3
4
(D)
4
3
R 3 A BR
3
2
4
Gr ( A Br )
3
(B) 4 Gr ( A Br )
(C)
4
3
Gr A Br
3
4
(D)
4
3
Gr A Br
3
2
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SECTION  IV
49.
When an electron in a hydrogen atom makes a transition from an excited state to the ground state, its
kinetic energy increases, its potential energy decreases and its total energy remains constant.
50.
A nucleus at rest split into two nuclear parts having radii in ratio 1 : 2. Their velocity will be in the ratio 8:1.
51.
A sphere is rolling up on a rough incline plane. If suddenly the friciton becomes zero, the retardation of the
COM of the spehre will increase.
52.
A man is standing on a circular platform which is free to rotate about a fixed vertical axis. If the man starts
moving on the peripheri of the platform, the COM of the system (man + platform), Starts moving w.r.t. ground.
53.
A charged particle is kept at rest in a uniform magnetic field. If now the magnetic field starts increasing with
time, the particle may start moving.
54.
On charging a soap bubble, its radius increases because the excess pressure inside the bubble increases.
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PART III
SECTION  I
1 x 2 a 2 1 sin 1 sin 3 2 x cos 1 cos 2 a 2 1 0 .Find the set of values of a so that above
(B) [1 , 1]
(D)
L1 : r cos 3 i
2 sin j cos 3 k
L 2 : r a i b j c k ,
Where
and are scalars and is the acute angle between L1 and L2 . If the angle ' 'is independent of
(B)
(C)
(D)
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57.
2
conjugate complex numbers, then
(A) 0
58.
0 is
1
(B) real
x 2 y2
59.
(B) 4
(C) 5
(D) 6
x2 1
If I x
dx , then I equals
x2 1
(A)
1 4
1 4
x 1
x 1 c
2
2
(B)
(C)
x 4 1 sin 1 x 2 c
(D)
1 4
1
x 1 n x 2 x 4 1 c
2
2
x 4 1 2sin 1 x 2 c
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sec 2 x
60.
lim
x
(A)
61.
f t dt
2
x
16
equals
8
f 2
If 1 x 2
(A) 4
(B)
2
f 2
(C)
2 1
f
2
(D)
4f 2
dy
4
8
x 1 y , y 0 , then the value of y 8 is
dx
3
9
(B) 2
(C) 3
(D) 5
62.
Let P be any point in the first quadrant of a curve . Normal drawn to the curve at P meet xaxis at Q so that
PQ = 5.Also the curve passes through (0 ,5) .Then locus of P is
(A) A circle of radius 5
(B) An ellipse with eccentricity 1/5
(C) A hyperbola with coordinate axes as asymptotes
(D) none of these
63.
64.
3
, then the number of points, where f(x) is nondifferentiable
2 2
(B) 3
(C) 4
(D) 5
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SECTION  II
A hyperbola has focus at origin , its eccentricity is 2 & corresponding directrix is x + y + 1 = 0. The
equation of its asymptotes is/are:
(A) x + 1 = 0
66.
If f(x) =
(B)
x 1 0
(C) y 1 0
(D) y 1 0
 x 1
then f(x) is
x2
(A) One  One in (2, )
(C) One  One in (, 0)
67.
If tangents at points A(x1, y1) & B(x2, y2) to the parabola y2 = 4x intersect at C(x3, y3), & 1, 2, 3 are
length of perpendicular on any tangent of given parabola from A, B, C respectively then(A) x1, x3, x2 are in G.P.
(B) y1, y3, y2 are in A.P.
(C) 1, 3, 2 are in H.P..
(D) 1, 3, 2 are in G.P.
.P.
68.
69.
A circle centred at 'O' has radius 1 and contains the point A. Segment AB is tangent to the circle at A and
AOB = .If point C lies on OA and BC bisect the angle ABO then OC equal
(A) 1 sin
(B)
cos2
1 sin
(C)
1
1 sin
(D)
1 sin
cos 2
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SECTION  III
Comprehension Type
This section contains 3 paragraphs. Based upon each paragraph, there are 2 questions. Each question has
4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
70.
If 6 persons are selected, the probability that there will be two trio's in which exactly one trio is of the same
family is
(A)
71.
125
1547
(B)
25
221
(C)
30
1547
(D)
60
1547
If 3 persons are selected, the probability that there will be exactly 2 persons of the same family will be
(A)
45
68
(B)
45
136
(C)
27
91
(D)
18
119
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In a ABC ,P,Q,R are the feet of angle bisectors from the vertices to their opposite sides as shown in above
figure. PQR is constructed.
72.
73.
(B) 90
(C) 120
(D) 150
28
3
(B)
88
3
(C)
78
3
(D)
84
3
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74.
The greatest integral value of m for which the point of intersection of L1 and L2 has integral coordinate, is
(A) 5
75.
(B) 9
(C) 47
(D) 51
Square of the distance between the integral points of intersection of L1 and L2 for the greatest and the least
integral values of m is
(A) 5
(B) 20
(C) 25
(D) 30
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SECTION  IV
77.
Let
rn
r r 1 be a root of ax
r 1
irrational.
78.
66
79.
If
y2
b
80.
81.
x
y
cos+ sin = 1.
a
b
C1n C 5 n C 2 n C 6 .... n C n 4 n C n 2 n C n 4
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