Beruflich Dokumente
Kultur Dokumente
Prepared For:
Acme-Rockford Group
Prepared By:
MWH Americas, Inc.
175 West Jackson Blvd., Suite 1900
Chicago, Illinois 60604
TABLE OF CONTENTS
1.0
1.1
1.2
1.3
1.4
INTRODUCTION ................................................................................................... 4
Purpose....................................................................................................................... 4
Objectives .................................................................................................................. 4
Project Organization .................................................................................................. 5
Project Team Work Responsibilities ......................................................................... 5
2.0
2.1
2.2
2.3
2.4
2.5
2.6
3.0
REFERENCES ...................................................................................................... 15
LIST OF TABLES
Table 1
LIST OF FIGURES
Figure 1
LIST OF APPENDICES
Appendix A
Photographic Log
Appendix B
As-built Drawings
B1 MWHs Construction As-Built Drawings
B2 Maple Leaf Environmental Equipments As-Built Drawings
B3 Intellishares As-Built Drawings
Appendix C
Appendix D
Analytical Data
D1 - Air Sampling Analytical Results
D2 - Soil Sampling Analytical Results
D3 - Purge Water Sampling Analytical Results
Page 2
Air Sparge
Ballard Companies, Inc.
Below Ground surface
Construction Completion Report
First Environmental Laboratories, Inc.
Granular Activated Carbon
Gallons Per Minute
Health and Safety Plan
Hand/off/auto
Horsepower
Illinois Environmental Protection Agency
Intellishare Environmental Clean Air Solutions
Joint Utility Locating Information for Excavators
Kilovolt-Ampere
Midwest Mechanical Works, Inc.
Missman Stanley & Associates, P.C.
Maple Leaf Environmental Equipment Inc.
MWH Americas, Inc.
Nicor, Inc.
Programmable Logic Controller
Polyvinyl chloride
Remedial Action Plan
Remedial Action Work Plan
Remedial Design Report
Remedial Design Work Plan
Remedial Objectives Report
Revolutions Per Minute
Standard cubic feet per minute
Site Investigation Report
Acme Solvent Reclaiming, Inc. Site in Rockford, Illinois
Site Remediation Objectives
Soil Vapor Extraction
Tiered Approach to Corrective Action Objectives
Testing Service Corporation
United States Environmental Protection Agency
Voltage Alternating Current
Vapor Liquid Separator
Vapor Monitoring Points
Volatile organic compounds
Page 3
1.0
1.1
INTRODUCTION
PURPOSE
1.2
OBJECTIVES
The objectives of the remedial activities for the Site, as outlined in the ROR are to:
Prevent potential human contact with contaminated groundwater through the institution
of a municipal ordinance to prohibit usage of groundwater in or from the groundwater
contaminant plume beneath and downgradient from the Site;
Remediate contaminated soil to below Site specific Tier 2 Soil Remediation Objectives
(SROs) for the soil component of the groundwater ingestion exposure route;
Remediate contaminated soil to below the TACO Tier 1 values for the inhalation
exposure route;
Page 4
Monitor remedial progress by measuring total mass removed by the SVE/AS system;
and
SROs for the chemicals of potential concern at the Site are listed in Table 8 of the ROR. Soil
confirmation samples will be collected by geoprobe at eight locations shown on Figure 9 of
the ROR and will be analyzed for VOCs. All of the objectives listed above are defined in
greater detail in Section 3.2 of the ROR.
1.3
PROJECT ORGANIZATION
MWH was retained by the Acme Rockford Group as the general remediation contractor for
this project. MWH retained the following subcontractors:
Company:
JB Lawn Care
Missman Stanley & Associates, P.C. (Missman Stanley)
Testing Service Corporation (TSC)
Midwest Mechanical Works, Inc. (Midwest)
Ballard Companies, Inc. (Ballard)
First Environmental Laboratories, Inc.
Stat Analysis Corporation
Role:
Landscaping
Surveyors
Drillers
Mechanical
Electrical
Soil/Water Laboratory
Air Laboratory
The following personnel were involved in the Acme remediation project to date:
Name:
Andrew Frierdich
Peter Vagt
Chris Daly
Robert Larrabee
Justin Finger
Denise Garcia
Title:
Project Manager
Project Manager
Licensed Project Engineer
Construction Project Manager
Field Technician
Field Engineer
Organization:
IEPA
MWH
MWH
MWH
MWH
MWH
Page 5
that was engineered and manufactured by Intellishare Environmental Clean Air Solutions out
of Menomonie, Wisconsin. The oxidizer was assembled on Site and integrated electrically
and mechanically with the equipment building and utilities.
The mechanical contractor, Midwest of Byron, Illinois and electrical contractor, Ballard of
Rockford, Illinois assisted with placement and assembly of the equipment building and
oxidizer. Ballard installed the electrical wiring for all the oxidizers sensor switches,
thermocouples, temperature and pressure gauges and installed conduit and electrical cable to
the control panel located inside the equipment building. Midwest installed the equipment
building and installed the vapor conveyance piping, natural gas piping, and SVE extraction
conveyance hosing.
MLEE performed system
October 18 to 21, 2010.
integration
Page 6
and
commissioning
activities
from
2.0
This section describes the tasks conducted by MWH and its subcontractors as part of the
construction activities associated with the installation of the SVE/AS systems at the Site.
Construction began on September 10, 2010 and was completed on October 18, 2010.
Commissioning of the SVE system occurred during October 18 thru 21, 2010. The system
formally began operations on October 21, 2010.
A photographic log is included in Appendix A and the as-built record drawings are included
in Appendix B.
2.1
The Health and Safety Plan (HASP) associated with the construction activities for the
SVE/AS remedial systems is provided in the RAWP (MWH, December 2009).
2.2
SITE SECURITY
A chain-link fence was installed along the perimeter of the Site during pilot study activities
in 2009. An informational sign was posted at the northwest and east sides of the fence that
directed the public to the Rockford Public Library and the ACMEcleanup.com website for
more information.
2.3
SITE PREPARATION
To allow access to the locations of SVE/AS wells, the equipment building, and the oxidizer,
the Site was prepared by removing oversized brush and mowing grassy areas. This task was
performed on September 10, 2010.
Prior to drilling activities, a Joint Utility Locating Information for Excavators (JULIE)
request provided utility location information.
2.4
AIR PERMIT
The IEPA air permit was issued October 12, 2010 for 12-month operation of the full scale
SVE system controlled by an oxidizer. Guidelines and compliance sampling requirements
outlined in the permit were followed during the system commissioning and monthly
monitoring activities.
2.5
SITE SURVEYS
On September 13, 2010, Missman Stanley of Rockford, Illinois was at the Site to conduct
surveying activities. Missman Stanley surveyed the proposed locations and grade elevations
for the SVE wells, AS wells, vapor monitoring points (VMPs), the equipment building, and
the oxidizer.
On January 5, 2011, Missman Stanley returned to the Site and surveyed as-built locations
and grades of the SVE wells, AS wells, VMPs, equipment building, and oxidizer.
Construction Completion Report
SVE/AS System
Page 7
2.6
WELL INSTALLATION
The SVE wells, AS wells and VMPs were installed from September 22, 2010 to
October 1, 2010 by TSC. The well installation activities were overseen by a MWH field
technician.
2.6.1 SVE Wells
The SVE well locations are shown on Sheet 4 of Appendix B-1. Well construction diagrams
are provided in Appendix C. Two wells, SVE-01S and SVE-02D, were installed during the
pilot study in 2009 and have been incorporated into the full-scale SVE system. A total of 21
SVE wells are utilized for vapor extraction in this SVE/AS system.
In 2010, 19 SVE wells (SVE-03S through SVE-22D) were installed with a 4-inch (inner
diameter) hollow-stem auger resulting in an eight-inch borehole. The wells were constructed
with three-inch diameter polyvinyl chloride (PVC) pipe with three-inch diameter PVC
screens placed at the bottom of each SVE boring. The screens were ten-feet in length with a
slot size of 0.010-inches. The annular space within the borehole was filled from the bottom
to one foot above the top of the screen with silica sand. A one-foot thick seal of 3/8-inch
bentonite chips was installed above the sand pack, and the remainder of the annular space
above the bentonite seal to the ground surface was filled with 20 percent solids bentonite
grout.
The following nine SVE wells (SVE-03S, SVE-04S, SVE-05S, SVE-06S, SVE-07S,
SVE-08S, SVE-09S, SVE-10S and SVE-11S) are screened in the shallow sandy layer with
total well depths between 19 and 21 feet below ground surface (bgs), and are defined as
shallow wells.
The following ten SVE wells (SVE-12D, SVE-13D, SVE-14D, SVE-15D, SVE-16D,
SVE-17D, SVE-18D, SVE-19D, SVE-20D and SVE-21D) are screened in the deep sandy
layer with total well depths between 33 and 35 feet bgs, and are defined as deep wells.
2.6.2 Air Sparge Points
AS well locations are shown on Sheet 4 of Appendix B-1. Well construction diagrams are
provided in Appendix C. One AS well, AS-01, was installed during the pilot study in 2009 at
an approximate depth of 42 feet bgs and has been incorporated into the full-scale system. A
total of four AS wells are utilized for air sparging locations in this SVE/AS system.
In 2010, three AS wells (AS-02, AS-03 and AS-04) were constructed with two-inch diameter
PVC pipe to a depth of approximately 42 feet bgs. A four-foot screen with a slot size of
0.010-inches was installed at the bottom of each well. The AS points were installed with a
4-inch (inner diameter) hollow-stem auger resulting in an eight-inch borehole. The annular
space within the borehole was filled from the bottom to one foot above the top of the screen
with silica sand. A one-foot thick seal of 3/8-inch bentonite chips was installed above the
sand pack, and the remainder of the annular space above the bentonite seal to the ground
surface was filled with 20 percent solids bentonite grout.
Page 8
EQUIPMENT INSTALLATION
On October 4, 2010, the equipment building and oxidizer were delivered to the Site. A crane
was utilized to lift and place the building and the oxidizer chamber component into the
permanent location. Mechanical contractor, Midwest and electrical contractor, Ballard
assisted with placement and assembly of the building and oxidizer. MWH reviewed the
system components to verify that all system components were constructed in accordance
with the approved designs.
Page 9
Page 10
The equipment building was shipped by flatbed truck to the Site. The load was lifted by
crane into the designated location. The building was then shimmed and leveled.
Once the building was positioned, packaging that protected the equipment during shipping
was removed. Exterior hoods insulated for noise were installed over the exhaust fans and
louvers. Silencer filters were installed on the exterior of the building. Three fire
extinguishers and a spill kit were placed inside the building.
2.8.2 Oxidizer
The oxidizer unit, manufactured by Intellishare, is a 500 SCFM chlorinated thermal oxidizer
with a heat exchanger (Model TO500). The oxidizer is designed to destroy the organic vapor
contaminants by operating at a temperature of 1,550 degrees Fahrenheit. The oxidizer unit
was delivered to the Site on October 4, 2010 and lifted by crane into the designated location.
The base and chamber of the oxidizer were placed in the designated locations and the
oxidizers heat exchanger and the stack were assembled on Site as directed by an Intellishare
technician.
After the oxidizer was placed on Site, Midwest installed the vapor conveyance piping
(five-inch carbon steel) connecting the SVE blower (in the equipment building) to the
oxidizer.
The natural gas supply pipe (1 -inch carbon steel piping) was installed
connecting the gas meter (located at the north side of the Site) to the oxidizer.
Ballard installed the electrical wiring for all the oxidizers sensor switches, thermocouples,
temperature and pressure gauges and installed conduit and electrical cable to the control
panel located inside the equipment building. These activities were completed on
October 8, 2010.
2.8.3 Control System
A PLC provides supervisory control and data acquisition for the system equipment. The
PLC is housed in the electrical/control room of the equipment building. Further details
regarding system controls are provided in the process and instrumentation diagrams included
with the as-built drawings (Appendix B).
2.8.4 Telemetry System
The telemetry system allows remote access via the internet to monitor and control the
SVE/AS system. The telemetry module is a MLEE Model SL-WP wireless remote access
system.
Through the program interface, installed on the MWH project engineers computers, users
can remotely control equipment by selecting hand, off or auto control, shut down or restart
the system, review system operating parameters and diagnose system alarms. The telemetry
system records critical operating data including equipment operating hours, oxidizer
temperatures, and vapor flow rate.
Page 11
Page 12
WASTE DISPOSAL
Soil cuttings collected during drilling activities and used personnel protective equipment
were containerized in a roll-off box on Site. A composite sample of soil from each well
location was collected and submitted to First Environmental Laboratories, Inc. (First
Environmental) of Naperville, Illinois to be analyzed for waste characterization parameters.
The soil was analyzed for the following parameters by the following analytical methods.
Parameters
Analytical Method
Flash point
Paint filter
pH
Phenols
Reactive cyanide
Reactive sulfide
TCLP herbicides
TCLP pesticides
TCLP metals
TCLP semi-volatile organic compounds
TCLP VOCs
Total sulfide
1010M
9095A
4500H+B
420.1
7.3.3.2
7.3.4.2
1311/8321A
1311/8081A
1311/6010B and 1311/7470A
1311/8270C
1311/8260B
4500S2,C,D
Soil waste analytical results are attached in Appendix D-2. The results confirm that the
waste is categorized as Illinois special waste (i.e. not hazardous).
The roll-off box
containing the soil waste and the disposable personal protective gear was hauled to
Winnebago Landfill Company located at 8403 Lindenwood Road in Rockford, Illinois for
disposal on November 24th, 2010. The manifest was signed by Gary Letcher, Attorney Chair
of Acme Rockford Group, and filed in MWHs records.
Water generated during well development and decontamination activities was containerized
in four 55-gallon drums. Samples of the contents of each drum were collected to determine
if the water could be discharged to the sanitary sewer under the Sites wastewater discharge
permit. The samples were submitted to First Environmental for analysis of VOCs by method
5030B/8260B. Purge water analytical results are attached in Appendix D-3. The results
indicated that concentrations of ethylbenzene, toluene and trichloroethane exceeded
permitted discharge limits.
Therefore, the purge water was hauled off Site as
environmentally hazardous waste, for treatment and disposal, by Badger Disposal of WI, Inc
Page 13
located at 5611 West Hemlock Street in Milwaukee, Wisconsin on November 24, 2010. The
manifest was signed by Gary Letcher, Attorney Chair of Acme Rockford Group,
and filed in MWHs records.
A minimal amount of construction debris was generated during the construction activities.
Disposal of this waste was managed by MWHs subcontractors at their facilities.
2.12 AS-BUILT DRAWINGS
As-built drawings are provided in Appendix B.
Page 14
3.0
REFERENCES
MWH, 2007. Site Investigation Report, Soil Vapor Extraction & Air Sparge System, Acme
Solvent Reclaiming, Inc. Site, Rockford, Illinois.
MWH, 2007. Remedial Objectives Report, Soil Vapor Extraction & Air Sparge System, Acme
Solvent Reclaiming, Inc. Site, Rockford, Illinois.
MWH, 2008. Remedial Action Plan, Soil Vapor Extraction & Air Sparge System, Acme
Solvent Reclaiming, Inc. Site, Rockford, Illinois.
MWH, 2009. Remedial Design Work Plan, Pilot Test, Soil Vapor Extraction/Air Sparge
System, Acme Solvent Reclaiming, Inc. Site, Rockford, Illinois.
MWH, 2009. Remedial Design Report, Soil Vapor Extraction & Air Sparge System, Acme
Solvent Reclaiming, Inc. Site, Rockford, Illinois.
MWH, 2009. Remedial Action Work Plan, Soil Vapor Extraction & Air Sparge System, Acme
Solvent Reclaiming, Inc. Site, Rockford, Illinois.
DLG/CAD/CRS/JEF/PJV
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Page 15
TABLE
Table 1
Thermal Oxidizer Results for Method TO-15 (VOCs)
ACME Site
Rockford, Illinois
Compounds
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,4-Trimethylbenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
2-Butanone (Methyl Ethyl Ketone)
2-Hexanone
4-Ethyltoluene
4-Methyl-2-pentanone
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Ethanol
Ethyl Benzene
Heptane
m,p-Xylene
Methylene Chloride
o-Xylene
Propylbenzene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Vinyl Chloride
Total
Total
Units
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
lb/hr
10/20/10
Oxidizer
Influent
Effluent
700
ND
ND
U
ND
ND
U
ND
65
ND
ND
U
ND
79
15.00
ND
U
ND
ND
U
ND
39
ND
ND
U
ND
ND
U
ND
110
ND
ND
U
ND
ND
U
560.00
ND
U
ND
ND
U
ND
ND
U
ND
ND
U
ND
ND
U
ND
ND
U
ND
ND
U
ND
ND
U
ND
ND
U
ND
ND
U
ND
440
ND
ND
U
ND
ND
U
ND
ND
U
31.00
1,400
ND
540
ND
4,400
8.30
55
ND
970
3.20
30
ND
ND
U
ND
140
5.90
17,000
4.30
ND
U
ND
ND
U
ND
87
ND
ND
U
ND
627.7
26,055
0.316
0.002
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
Destruction
Efficiency
100.00%
NC
NC
100.00%
NC
81.01%
NC
NC
100.00%
NC
NC
100.00%
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
100.00%
NC
NC
NC
100.00%
100.00%
99.81%
100.00%
99.67%
100.00%
NC
95.79%
99.97%
NC
NC
100.00%
NC
97.59%
99.37%
Qualifiers:
Notes:
NC - Not calculated
U - Below reported quantitation limit
ND - Not detected
J - Result is estimated
ppbv - Parts per billion volume
lb/hr - Pounds per hour
VOC - Volatile organic compounds
Destruction efficiencies were not calculated if either the influent or effluent samples were estimated.
Destruction efficiencies were also not calculated if the effluent result exceeded either influent result.
Total destruction efficiencies that include the estimated results of any individual compound will be considered an estimated valu
System
Date
Temp
Flow
(F)
(scfm)
Oxidizer Inlet
10/20/10
57
778
Oxidizer Effluent
10/20/10
978
778
Temperatures and flow rates reported correspond to instantaneous readings.
ACB\DLG
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Page 1 of 1
FIGURE
SITE
APPENDICES
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
ACME-Rockford Group
Project Name:
Site Name:
ACME
Site Location:
224.12
49.50
27.00
D
69.99
Pictorial View
78.72
207.00
Top View
14.15
249.79
No Loss Stack
72.00
Combustion
Air Filter
Flame Arrestor
Combustion
Air Blower
177.79
12.15
152.79
134.91
Heat
Exchanger
Air Sparge
Blower
Air Sparge
Control Valve
Left View
Shipping Break
Junction
Box
Heat Exchanger
Module
Insulated
Duct
B
101.54
Balancing
Damper
Oxidizer Skid
101.54
Fuel Train
With Enclosure
6.00
0
1" FNPT
Right View
DRAWING NO.
CHECKED
DATE
APPROVED
DATE
LAST DRAWN BY
DATE
7/28/2010
Henry A
DATE
8/2/2006
SCALE
NTS
CUSTOMER
REV.
ACME - Rockford, IL
PAGE
SOURCE
LAST PLOTTED BY
XXX
DATE
OF
XXX
FILE PATH
DRAWN
N-10-0965-002
Analyte
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Butadiene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
2-Butanone
2-Hexanone
4-Ethyltoluene
4-Methyl-2-pentanone
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Cyclohexane
Dibromochloromethane
Dichlorodifluoromethane
Ethanol
Ethyl acetate
Ethylbenzene
alpha-Chlorotoluene
Cumene
2-Propanol
Freon 12
cis-1,3-Dichloropropene
Freon 11
Freon-113
Freon-114
Heptane
Hexachlorobutadiene
Sample ID :
Date Collected :
Test Method Units
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-16
ppbv
TO-17
ppbv
TO-18
ppbv
TO-19
ppbv
TO-20
ppbv
TO-21
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
TO-15
ppbv
5600
ND
ND
360
52
ND
23000
ND
260
ND
130
9900
14
ND
ND
ND
42
ND
8700
ND
150
120
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1800
ND
120
ND
ND
NA
ND
140000
NA
NA
NA
NA
NA
NA
18
ND
5100
ND
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Outlet TO 0965
10/20/2010
ACME-TOXEFF-102110
10/21/2010 16:16
ACME-TOXEFF-102210
10/22/2010 12:21
ND
ND
ND
ND
ND
ND
15
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
560
ND
NA
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NA
31 J
NA
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.2
ND
ND
ND
ND
1
ND
ND
ND
ND
10
ND
0.96
ND
1800
0.53
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NA
ND
9.1
NA
NA
NA
NA
NA
NA
ND
ND
0.44
ND
3.5
ND
ND
ND
ND
ND
46
ND
1.2
ND
ND
18
ND
ND
ND
ND
ND
ND
13
3.1
350
0.55
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.37
ND
ND
ND
ND
NA
ND
140
NA
NA
NA
NA
NA
NA
ND
ND
5.6
ND
Page 1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
48
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NA
ND
0.55
NA
NA
NA
NA
NA
NA
ND
ND
ND
ND
ACME-TOXEFF-110210
11/02/2010 14:30
ACME-TOXEFF-110910
11/09/2010 10:00
ND
ND
ND
ND
ND
ND
0.9
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
520
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NA
ND
0.55
NA
NA
NA
NA
NA
NA
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.72
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
870
0.55
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NA
ND
1.2
NA
NA
NA
NA
NA
NA
ND
ND
ND
ND
Sample ID :
Date Collected :
Analyte
Test Method Units
Hexane
TO-15
ppbv
Isopropyl Alcohol
TO-15
ppbv
m,p-Xylene
TO-15
ppbv
Methyl tert-butyl ether
TO-15
ppbv
Methylene chloride
TO-15
ppbv
o-Xylene
TO-15
ppbv
Propene
TO-15
ppbv
Propylbenzene
TO-15
ppbv
Styrene
TO-15
ppbv
Tetrachloroethene
TO-15
ppbv
Tetrahydrofuran
TO-15
ppbv
Toluene
TO-15
ppbv
trans-1,2-Dichloroethene
TO-15
ppbv
trans-1,3-Dichloropropene
TO-15
ppbv
Trichloroethene
TO-15
ppbv
Trichlorofluoromethane
TO-15
ppbv
Vinyl acetate
TO-15
ppbv
Vinyl chloride
TO-15
ppbv
Xylenes, Total
TO-15
ppbv
Total
ppbv
110
ND
760000
ND
ND
210000
ND
NA
3800
6900
ND
450000
ND
ND
1100
ND
ND
ND
970000
1,627,276.00
Outlet TO 0965
10/20/2010
ACME-TOXEFF-102110
10/21/2010 16:16
ACME-TOXEFF-102210
10/22/2010 12:21
ND
NA
8.3
ND
ND
3.2
NA
ND
ND
5.9
ND
4.3
ND
ND
ND
NA
NA
ND
11.5
627.70
ND
ND
27
ND
ND
7
ND
NA
ND
ND
2.7
19
ND
ND
ND
ND
ND
ND
34
1,880.93
ND
ND
460
ND
ND
150
ND
NA
2.1
7.9
ND
350
ND
ND
ND
ND
ND
ND
610
1,551.32
Notes:
ppbv - Parts per billion volume
ND - Not detected
NA - Not Analyzed
Qualifiers:
J - Result is estimated
DLG/JEF
O:\1009100-1009199\1009103 Acme Design-Build\4.0 Execution (Project Deliverables)\4.4 Analtyical Data\Air Sampling\Summary Air Sampling Results.xls
Page 2
ND
ND
2.4
ND
ND
0.48
ND
NA
ND
ND
ND
0.7
ND
ND
ND
ND
ND
ND
2.9
52.13
ACME-TOXEFF-110210
11/02/2010 14:30
ACME-TOXEFF-110910
11/09/2010 10:00
ND
ND
2.4
ND
ND
0.66
ND
NA
ND
ND
ND
0.36
ND
ND
ND
ND
ND
ND
3.1
524.87
ND
ND
5.3
ND
ND
1.6
ND
NA
ND
ND
ND
2.3
ND
ND
ND
ND
ND
ND
6.9
881.67
10/25/2010
Mr. Gary Wolf
Intellishare Environmental
1422 Indian Head Drive East
Menomonie WI 54751
Project Name: Rockford, IL
Project #: N-10-0965
Workorder #: 1010482
Dear Mr. Gary Wolf
The following report includes the data for the above referenced project for sample(s)
received on 10/22/2010 at Air Toxics Ltd.
The data and associated QC analyzed by Modified TO-15 are compliant with the
project requirements or laboratory criteria with the exception of the deviations noted in
the attached case narrative.
Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is
committed to providing accurate data of the highest quality. Please feel free to contact
the Project Manager: Jacquelyn Luta at 916-985-1000 if you have any questions
regarding the data in this report.
Regards,
Jacquelyn Luta
Project Manager
WORK ORDER #:
1010482
PHONE:
715-233-6115 x115
BILL TO:
P.O. #
FAX:
DATE RECEIVED:
DATE COMPLETED:
10/22/2010
10/15/2010
PROJECT #
N-10-0965 Rockford, IL
CONTACT:
Jacquelyn Luta
FRACTION #
NAME
TEST
01A
02A
03A
03B
04A
04B
05A
05AA
05B
05BB
OUTLET TO 0965
INLET TO 0965
Lab Blank
Lab Blank
CCV
CCV
LCS
LCSD
LCS
LCSD
Modified TO-15
Modified TO-15
Modified TO-15
Modified TO-15
Modified TO-15
Modified TO-15
Modified TO-15
Modified TO-15
Modified TO-15
Modified TO-15
CERTIFIED BY:
DATE:
RECEIPT
VAC./PRES.
FINAL
PRESSURE
5.2 "Hg
6.0 "Hg
NA
NA
NA
NA
NA
NA
NA
NA
15 psi
15 psi
NA
NA
NA
NA
NA
NA
NA
NA
10/25/10
Laboratory Director
LABORATORY NARRATIVE
EPA Method TO-15
Intellishare Environmental
Workorder# 1010482
Two 1 Liter Summa Canister samples were received on October 22, 2010. The laboratory performed
analysis via modified EPA Method TO-15 using GC/MS in the full scan mode.
This workorder was independently validated prior to submittal using 'USEPA National Functional
Guidelines' as generally applied to the analysis of volatile organic compounds in air. A rules-based, logic
driven, independent validation engine was employed to assess completeness, evaluate pass/fail of relevant
project quality control requirements and verification of all quantified amounts.
Receiving Notes
There were no receiving discrepancies.
Analytical Notes
All Quality Control Limit exceedences and affected sample results are noted by flags. Each flag is defined
at the bottom of this Case Narrative and on each Sample Result Summary page. Target compound
non-detects in the samples that are associated with high bias in QC analyses have not been flagged.
Dilutions were performed on samples OUTLET TO 0965 and INLET TO 0965 due to the presence of
high level target species.
Definition of Data Qualifying Flags
Eight qualifiers may have been used on the data analysis sheets and indicates as follows:
B - Compound present in laboratory blank greater than reporting limit (background subtraction not
performed).
J - Estimated value.
E - Exceeds instrument calibration range.
S - Saturated peak.
Q - Exceeds quality control limits.
U - Compound analyzed for but not detected above the reporting limit.
UJ- Non-detected compound associated with low bias in the CCV
N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates
as follows:
a-File was requantified
b-File was quantified by a second column and detector
r1-File was requantified for the purpose of reissue
Page 3 of 24
Amount
(ppbv)
Rpt. Limit
(ug/m3)
Ethanol
12
31 J
23
59 J
Acetone
12
560
29
1300
Toluene
3.0
4.3
11
16
Tetrachloroethene
3.0
5.9
21
40
m,p-Xylene
3.0
8.3
13
36
o-Xylene
3.0
3.2
13
14
1,2,4-Trimethylbenzene
3.0
15
15
74
Rpt. Limit
(ppbv)
Amount
(ppbv)
Rpt. Limit
(ug/m3)
Amount
(ug/m3)
Methylene Chloride
29
55
99
190
1,1-Dichloroethane
29
65
120
260
cis-1,2-Dichloroethene
29
440
110
1700
1,1,1-Trichloroethane
29
700
160
3800
Heptane
29
540
120
2200
Trichloroethene
29
87
150
470
Toluene
29
17000
110
64000
Tetrachloroethene
29
140
190
960
Ethyl Benzene
29
1400
120
5900
m,p-Xylene
29
4400
120
19000
o-Xylene
29
970
120
4200
Propylbenzene
29
30
140
150
4-Ethyltoluene
29
110
140
560
1,3,5-Trimethylbenzene
29
39
140
190
1,2,4-Trimethylbenzene
29
79
140
390
Rpt. Limit
Compound
Amount
(ug/m3)
Page 4 of 24
p102241
6.10
(ppbv)
Amount
(ppbv)
Rpt. Limit
(ug/m3)
Amount
(ug/m3)
3.0
3.0
12
3.0
3.0
3.0
3.0
3.0
12
3.0
3.0
12
12
3.0
12
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
12
3.0
3.0
3.0
3.0
3.0
3.0
3.0
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
31 J
Not Detected
Not Detected
560
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
4.3
Not Detected
Not Detected
5.9
15
21
25
7.8
6.7
12
8.0
17
23
23
12
29
30
9.5
38
10
11
12
11
12
9.0
12
9.0
15
17
10
19
14
9.7
12
12
16
14
44
20
14
12
11
14
17
21
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
59 J
Not Detected
Not Detected
1300
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
16
Not Detected
Not Detected
40
Rpt. Limit
Compound
Freon 12
Freon 114
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Freon 11
Ethanol
Freon 113
1,1-Dichloroethene
Acetone
2-Propanol
Carbon Disulfide
3-Chloropropene
Methylene Chloride
Methyl tert-butyl ether
trans-1,2-Dichloroethene
Hexane
1,1-Dichloroethane
2-Butanone (Methyl Ethyl Ketone)
cis-1,2-Dichloroethene
Tetrahydrofuran
Chloroform
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
2,2,4-Trimethylpentane
Benzene
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Page 5 of 24
p102241
6.10
(ppbv)
Amount
(ppbv)
Rpt. Limit
(ug/m3)
Amount
(ug/m3)
12
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
12
12
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
8.3
3.2
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
15
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
50
26
23
14
13
13
13
13
32
15
21
15
15
15
15
18
18
16
18
90
130
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
36
14
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
74
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Rpt. Limit
Compound
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethyl Benzene
m,p-Xylene
o-Xylene
Styrene
Bromoform
Cumene
1,1,2,2-Tetrachloroethane
Propylbenzene
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
alpha-Chlorotoluene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobutadiene
J = Estimated value due to bias in the CCV.
Container Type: 1 Liter Summa Canister
Surrogates
%Recovery
Method
Limits
100
96
99
70-130
70-130
70-130
Toluene-d8
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Page 6 of 24
w102512
5.72
(ppbv)
Amount
(ppbv)
Rpt. Limit
(ug/m3)
Amount
(ug/m3)
29
29
110
29
29
29
29
29
110
29
29
110
110
29
110
29
29
29
29
29
29
29
29
29
29
29
29
29
29
29
29
29
29
110
29
29
29
29
29
29
29
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
55
Not Detected
Not Detected
Not Detected
65
Not Detected
440
Not Detected
Not Detected
700
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
540
87
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
17000
Not Detected
Not Detected
140
140
200
240
73
63
110
75
160
220
220
110
270
280
89
360
99
100
110
100
120
84
110
84
140
160
98
180
130
91
120
120
150
130
410
190
130
120
110
130
160
190
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
190
Not Detected
Not Detected
Not Detected
260
Not Detected
1700
Not Detected
Not Detected
3800
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
2200
470
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
64000
Not Detected
Not Detected
960
Rpt. Limit
Compound
Freon 12
Freon 114
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Freon 11
Ethanol
Freon 113
1,1-Dichloroethene
Acetone
2-Propanol
Carbon Disulfide
3-Chloropropene
Methylene Chloride
Methyl tert-butyl ether
trans-1,2-Dichloroethene
Hexane
1,1-Dichloroethane
2-Butanone (Methyl Ethyl Ketone)
cis-1,2-Dichloroethene
Tetrahydrofuran
Chloroform
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
2,2,4-Trimethylpentane
Benzene
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Page 7 of 24
w102512
5.72
(ppbv)
Amount
(ppbv)
Rpt. Limit
(ug/m3)
Amount
(ug/m3)
110
29
29
29
29
29
29
29
29
29
29
29
29
29
29
29
29
29
29
110
110
Not Detected
Not Detected
Not Detected
Not Detected
1400
4400
970
Not Detected
Not Detected
Not Detected
Not Detected
30
110
39
79
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
470
240
220
130
120
120
120
120
300
140
200
140
140
140
140
170
170
150
170
850
1200
Not Detected
Not Detected
Not Detected
Not Detected
5900
19000
4200
Not Detected
Not Detected
Not Detected
Not Detected
150
560
190
390
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Rpt. Limit
Compound
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethyl Benzene
m,p-Xylene
o-Xylene
Styrene
Bromoform
Cumene
1,1,2,2-Tetrachloroethane
Propylbenzene
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
alpha-Chlorotoluene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Container Type: 1 Liter Summa Canister
Surrogates
%Recovery
Method
Limits
98
98
102
70-130
70-130
70-130
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
Page 8 of 24
p102222
1.00
Date of Collection: NA
Date of Analysis: 10/22/10 11:40 PM
(ppbv)
Amount
(ppbv)
Rpt. Limit
(ug/m3)
Amount
(ug/m3)
0.50
0.50
2.0
0.50
0.50
0.50
0.50
0.50
2.0
0.50
0.50
2.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
2.5
3.5
4.1
1.3
1.1
1.9
1.3
2.8
3.8
3.8
2.0
4.8
4.9
1.6
6.3
1.7
1.8
2.0
1.8
2.0
1.5
2.0
1.5
2.4
2.7
1.7
3.1
2.3
1.6
2.0
2.0
2.7
2.3
7.2
3.4
2.3
2.0
1.9
2.3
2.7
3.4
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Rpt. Limit
Compound
Freon 12
Freon 114
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Freon 11
Ethanol
Freon 113
1,1-Dichloroethene
Acetone
2-Propanol
Carbon Disulfide
3-Chloropropene
Methylene Chloride
Methyl tert-butyl ether
trans-1,2-Dichloroethene
Hexane
1,1-Dichloroethane
2-Butanone (Methyl Ethyl Ketone)
cis-1,2-Dichloroethene
Tetrahydrofuran
Chloroform
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
2,2,4-Trimethylpentane
Benzene
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Page 9 of 24
p102222
1.00
Date of Collection: NA
Date of Analysis: 10/22/10 11:40 PM
(ppbv)
Amount
(ppbv)
Rpt. Limit
(ug/m3)
Amount
(ug/m3)
2.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
8.2
4.2
3.8
2.3
2.2
2.2
2.2
2.1
5.2
2.4
3.4
2.4
2.4
2.4
2.4
3.0
3.0
2.6
3.0
15
21
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Rpt. Limit
Compound
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethyl Benzene
m,p-Xylene
o-Xylene
Styrene
Bromoform
Cumene
1,1,2,2-Tetrachloroethane
Propylbenzene
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
alpha-Chlorotoluene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Container Type: NA - Not Applicable
Surrogates
%Recovery
Method
Limits
96
92
92
70-130
70-130
70-130
Toluene-d8
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Page 10 of 24
w102506
1.00
Date of Collection: NA
Date of Analysis: 10/25/10 10:49 AM
(ppbv)
Amount
(ppbv)
Rpt. Limit
(ug/m3)
Amount
(ug/m3)
0.50
0.50
2.0
0.50
0.50
0.50
0.50
0.50
2.0
0.50
0.50
2.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
2.5
3.5
4.1
1.3
1.1
1.9
1.3
2.8
3.8
3.8
2.0
4.8
4.9
1.6
6.3
1.7
1.8
2.0
1.8
2.0
1.5
2.0
1.5
2.4
2.7
1.7
3.1
2.3
1.6
2.0
2.0
2.7
2.3
7.2
3.4
2.3
2.0
1.9
2.3
2.7
3.4
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Rpt. Limit
Compound
Freon 12
Freon 114
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Freon 11
Ethanol
Freon 113
1,1-Dichloroethene
Acetone
2-Propanol
Carbon Disulfide
3-Chloropropene
Methylene Chloride
Methyl tert-butyl ether
trans-1,2-Dichloroethene
Hexane
1,1-Dichloroethane
2-Butanone (Methyl Ethyl Ketone)
cis-1,2-Dichloroethene
Tetrahydrofuran
Chloroform
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
2,2,4-Trimethylpentane
Benzene
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Page 11 of 24
w102506
1.00
Date of Collection: NA
Date of Analysis: 10/25/10 10:49 AM
(ppbv)
Amount
(ppbv)
Rpt. Limit
(ug/m3)
Amount
(ug/m3)
2.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
8.2
4.2
3.8
2.3
2.2
2.2
2.2
2.1
5.2
2.4
3.4
2.4
2.4
2.4
2.4
3.0
3.0
2.6
3.0
15
21
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Rpt. Limit
Compound
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethyl Benzene
m,p-Xylene
o-Xylene
Styrene
Bromoform
Cumene
1,1,2,2-Tetrachloroethane
Propylbenzene
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
alpha-Chlorotoluene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Container Type: NA - Not Applicable
Surrogates
%Recovery
Method
Limits
98
99
100
70-130
70-130
70-130
Toluene-d8
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Page 12 of 24
p102216
1.00
Date of Collection: NA
Date of Analysis: 10/22/10 06:51 PM
Compound
%Recovery
97
101
90
98
94
99
87
92
132 Q
99
96
90
94
85
97
91
110
94
100
92
101
96
95
96
98
101
96
98
100
95
108
98
97
104
97
101
101
98
107
100
100
Freon 12
Freon 114
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Freon 11
Ethanol
Freon 113
1,1-Dichloroethene
Acetone
2-Propanol
Carbon Disulfide
3-Chloropropene
Methylene Chloride
Methyl tert-butyl ether
trans-1,2-Dichloroethene
Hexane
1,1-Dichloroethane
2-Butanone (Methyl Ethyl Ketone)
cis-1,2-Dichloroethene
Tetrahydrofuran
Chloroform
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
2,2,4-Trimethylpentane
Benzene
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Page 13 of 24
p102216
1.00
Date of Collection: NA
Date of Analysis: 10/22/10 06:51 PM
Compound
%Recovery
107
104
101
100
105
110
109
114
103
116
98
112
111
118
121
105
105
111
106
100
99
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethyl Benzene
m,p-Xylene
o-Xylene
Styrene
Bromoform
Cumene
1,1,2,2-Tetrachloroethane
Propylbenzene
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
alpha-Chlorotoluene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Q = Exceeds Quality Control limits.
Container Type: NA - Not Applicable
Surrogates
%Recovery
Method
Limits
101
95
104
70-130
70-130
70-130
Toluene-d8
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Page 14 of 24
w102502
1.00
Date of Collection: NA
Date of Analysis: 10/25/10 08:23 AM
Compound
%Recovery
127
124
129
123
125
108
122
117
116
115
115
114
118
117
115
109
123
112
119
115
113
116
118
112
114
107
117
120
109
118
110
110
115
115
114
108
91
110
109
113
108
Freon 12
Freon 114
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Freon 11
Ethanol
Freon 113
1,1-Dichloroethene
Acetone
2-Propanol
Carbon Disulfide
3-Chloropropene
Methylene Chloride
Methyl tert-butyl ether
trans-1,2-Dichloroethene
Hexane
1,1-Dichloroethane
2-Butanone (Methyl Ethyl Ketone)
cis-1,2-Dichloroethene
Tetrahydrofuran
Chloroform
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
2,2,4-Trimethylpentane
Benzene
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Page 15 of 24
w102502
1.00
Date of Collection: NA
Date of Analysis: 10/25/10 08:23 AM
Compound
%Recovery
115
115
112
107
106
110
108
109
114
109
107
108
109
111
107
99
99
109
99
90
93
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethyl Benzene
m,p-Xylene
o-Xylene
Styrene
Bromoform
Cumene
1,1,2,2-Tetrachloroethane
Propylbenzene
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
alpha-Chlorotoluene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Container Type: NA - Not Applicable
Surrogates
%Recovery
Method
Limits
104
105
100
70-130
70-130
70-130
Toluene-d8
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Page 16 of 24
p102217
1.00
Date of Collection: NA
Date of Analysis: 10/22/10 08:58 PM
Compound
%Recovery
109
112
89
109
107
107
100
106
106
98
95
96
100
93
103
89
110
103
109
97
108
104
100
102
105
110
104
112
108
100
119
106
105
117
104
111
110
102
120
110
110
Freon 12
Freon 114
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Freon 11
Ethanol
Freon 113
1,1-Dichloroethene
Acetone
2-Propanol
Carbon Disulfide
3-Chloropropene
Methylene Chloride
Methyl tert-butyl ether
trans-1,2-Dichloroethene
Hexane
1,1-Dichloroethane
2-Butanone (Methyl Ethyl Ketone)
cis-1,2-Dichloroethene
Tetrahydrofuran
Chloroform
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
2,2,4-Trimethylpentane
Benzene
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Page 17 of 24
p102217
1.00
Date of Collection: NA
Date of Analysis: 10/22/10 08:58 PM
Compound
%Recovery
122
114
116
112
118
124
121
128
113
127
111
123
124
133 Q
136 Q
116
121
128
120
115
109
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethyl Benzene
m,p-Xylene
o-Xylene
Styrene
Bromoform
Cumene
1,1,2,2-Tetrachloroethane
Propylbenzene
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
alpha-Chlorotoluene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Q = Exceeds Quality Control limits.
Container Type: NA - Not Applicable
Surrogates
%Recovery
Method
Limits
101
94
98
70-130
70-130
70-130
Toluene-d8
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Page 18 of 24
p102218
1.00
Date of Collection: NA
Date of Analysis: 10/22/10 09:32 PM
Compound
%Recovery
103
107
92
104
103
105
94
101
117
95
92
92
100
91
103
90
108
103
109
96
108
102
103
100
103
111
101
109
105
98
118
105
104
115
102
111
111
101
118
111
109
Freon 12
Freon 114
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Freon 11
Ethanol
Freon 113
1,1-Dichloroethene
Acetone
2-Propanol
Carbon Disulfide
3-Chloropropene
Methylene Chloride
Methyl tert-butyl ether
trans-1,2-Dichloroethene
Hexane
1,1-Dichloroethane
2-Butanone (Methyl Ethyl Ketone)
cis-1,2-Dichloroethene
Tetrahydrofuran
Chloroform
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
2,2,4-Trimethylpentane
Benzene
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Page 19 of 24
p102218
1.00
Date of Collection: NA
Date of Analysis: 10/22/10 09:32 PM
Compound
%Recovery
124
113
116
112
116
125
121
127
113
126
110
122
124
131 Q
135 Q
118
121
128
119
118
112
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethyl Benzene
m,p-Xylene
o-Xylene
Styrene
Bromoform
Cumene
1,1,2,2-Tetrachloroethane
Propylbenzene
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
alpha-Chlorotoluene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Q = Exceeds Quality Control limits.
Container Type: NA - Not Applicable
Surrogates
%Recovery
Method
Limits
100
92
100
70-130
70-130
70-130
Toluene-d8
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Page 20 of 24
w102503
1.00
Date of Collection: NA
Date of Analysis: 10/25/10 09:05 AM
Compound
%Recovery
112
109
118
112
120
104
114
111
101
94
98
102
107
105
111
96
111
111
111
108
119
111
115
107
108
106
108
113
104
108
110
104
109
112
107
106
90
100
112
113
107
Freon 12
Freon 114
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Freon 11
Ethanol
Freon 113
1,1-Dichloroethene
Acetone
2-Propanol
Carbon Disulfide
3-Chloropropene
Methylene Chloride
Methyl tert-butyl ether
trans-1,2-Dichloroethene
Hexane
1,1-Dichloroethane
2-Butanone (Methyl Ethyl Ketone)
cis-1,2-Dichloroethene
Tetrahydrofuran
Chloroform
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
2,2,4-Trimethylpentane
Benzene
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Page 21 of 24
w102503
1.00
Date of Collection: NA
Date of Analysis: 10/25/10 09:05 AM
Compound
%Recovery
119
116
116
103
106
107
106
110
109
100
95
94
98
99
97
90
90
94
89
81
88
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethyl Benzene
m,p-Xylene
o-Xylene
Styrene
Bromoform
Cumene
1,1,2,2-Tetrachloroethane
Propylbenzene
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
alpha-Chlorotoluene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Container Type: NA - Not Applicable
Surrogates
%Recovery
Method
Limits
100
99
96
70-130
70-130
70-130
Toluene-d8
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Page 22 of 24
w102504
1.00
Date of Collection: NA
Date of Analysis: 10/25/10 09:42 AM
Compound
%Recovery
137 Q
132 Q
143 Q
128
136
116
127
133 Q
120
115
116
122
126
122
118
109
121
123
125
115
117
116
124
116
121
111
125
127
105
119
110
113
116
121
117
116
90
107
122
120
117
Freon 12
Freon 114
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroethane
Freon 11
Ethanol
Freon 113
1,1-Dichloroethene
Acetone
2-Propanol
Carbon Disulfide
3-Chloropropene
Methylene Chloride
Methyl tert-butyl ether
trans-1,2-Dichloroethene
Hexane
1,1-Dichloroethane
2-Butanone (Methyl Ethyl Ketone)
cis-1,2-Dichloroethene
Tetrahydrofuran
Chloroform
1,1,1-Trichloroethane
Cyclohexane
Carbon Tetrachloride
2,2,4-Trimethylpentane
Benzene
1,2-Dichloroethane
Heptane
Trichloroethene
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Page 23 of 24
w102504
1.00
Date of Collection: NA
Date of Analysis: 10/25/10 09:42 AM
Compound
%Recovery
130
124
122
105
108
109
108
116
117
105
103
102
106
108
107
98
99
103
98
89
94
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethyl Benzene
m,p-Xylene
o-Xylene
Styrene
Bromoform
Cumene
1,1,2,2-Tetrachloroethane
Propylbenzene
4-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
alpha-Chlorotoluene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Q = Exceeds Quality Control limits.
Container Type: NA - Not Applicable
Surrogates
%Recovery
Method
Limits
103
111
103
70-130
70-130
70-130
Toluene-d8
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Page 24 of 24
Page 1 of 14
Client:
Project:
Lab Order:
Lab Sample ID
Client Sample ID
10100784-001A ACME-TOXEFF-102110
10100784-002A ACME-TOXEFF-102210
Tag Number
Date Received
10/21/2010 4:16:00 PM
10/22/2010 12:21:00 PM
10/22/2010
10/22/2010
Page 2 of 14
Lab Order:
10100784
Project:
Lab ID:
10100784-001A
Analyses
RL Qualifier Units
DF
Date Analyzed
TO-15
1,1,1-Trichloroethane
ND
0.3
ppbv
10/26/2010
1,1,2,2-Tetrachloroethane
ND
0.3
ppbv
10/26/2010
1,1,2-Trichloroethane
ND
0.3
ppbv
10/26/2010
1,1-Dichloroethane
ND
0.74
ppbv
10/26/2010
1,1-Dichloroethene
ND
0.3
ppbv
10/26/2010
1,2,4-Trichlorobenzene
ND
0.74
ppbv
10/26/2010
1,2,4-Trimethylbenzene
3.2
0.3
ppbv
10/26/2010
1,2-Dibromoethane
ND
0.3
ppbv
10/26/2010
1,2-Dichlorobenzene
ND
0.3
ppbv
10/26/2010
1,2-Dichloroethane
ND
0.3
ppbv
10/26/2010
1,2-Dichloropropane
ND
0.3
ppbv
10/26/2010
0.3
ppbv
10/26/2010
1,3-Butadiene
ND
0.3
ppbv
10/26/2010
1,3-Dichlorobenzene
ND
0.3
ppbv
10/26/2010
1,4-Dichlorobenzene
ND
0.3
ppbv
10/26/2010
1,4-Dioxane
ND
1.5
ppbv
10/26/2010
2-Butanone
10
0.74
ppbv
10/26/2010
2-Hexanone
ND
ppbv
10/26/2010
0.96
0.3
ppbv
10/26/2010
ND
1.5
ppbv
10/26/2010
1,3,5-Trimethylbenzene
4-Ethyltoluene
4-Methyl-2-pentanone
Acetone
1800
74
ppbv
25
10/27/2010
Benzene
0.53
0.3
ppbv
10/26/2010
Benzyl chloride
ND
1.5
ppbv
10/26/2010
Bromodichloromethane
ND
0.3
ppbv
10/26/2010
Bromoform
ND
1.5
ppbv
10/26/2010
Bromomethane
ND
1.5
ppbv
10/26/2010
Carbon disulfide
ND
1.5
ppbv
10/26/2010
Carbon tetrachloride
ND
0.3
ppbv
10/26/2010
Chlorobenzene
ND
0.3
ppbv
10/26/2010
Chloroethane
ND
0.3
ppbv
10/26/2010
Chloroform
ND
0.3
ppbv
10/26/2010
Chloromethane
ND
1.5
ppbv
10/26/2010
cis-1,2-Dichloroethene
ND
0.3
ppbv
10/26/2010
cis-1,3-Dichloropropene
ND
0.3
ppbv
10/26/2010
Cyclohexane
ND
0.3
ppbv
10/26/2010
Dibromochloromethane
ND
0.3
ppbv
10/26/2010
Dichlorodifluoromethane
ND
0.3
ppbv
10/26/2010
Ethyl acetate
ND
0.3
ppbv
10/26/2010
Qualifiers:
* - Non-accredited parameter
Page 3 of 14
Lab Order:
10100784
Project:
Lab ID:
10100784-001A
Analyses
RL Qualifier Units
DF
Date Analyzed
TO-15
Ethylbenzene
9.1
0.3
ppbv
10/26/2010
Freon-113
ND
0.3
ppbv
10/26/2010
Freon-114
ND
0.3
ppbv
10/26/2010
0.44
0.3
ppbv
10/26/2010
Hexachlorobutadiene
ND
0.3
ppbv
10/26/2010
Hexane
ND
1.5
ppbv
10/26/2010
Isopropyl Alcohol
ND
1.5
ppbv
10/26/2010
27
0.59
ppbv
10/26/2010
ND
0.3
ppbv
10/26/2010
Methylene chloride
ND
ppbv
10/26/2010
o-Xylene
0.3
ppbv
10/26/2010
Propene
ND
ppbv
10/26/2010
Styrene
ND
0.3
ppbv
10/26/2010
Tetrachloroethene
ND
0.3
ppbv
10/26/2010
Tetrahydrofuran
2.7
0.74
ppbv
10/26/2010
19
0.3
ppbv
10/26/2010
Heptane
m,p-Xylene
Toluene
trans-1,2-Dichloroethene
ND
0.3
ppbv
10/26/2010
trans-1,3-Dichloropropene
ND
0.74
ppbv
10/26/2010
Trichloroethene
ND
0.74
ppbv
10/26/2010
Trichlorofluoromethane
ND
0.3
ppbv
10/26/2010
Vinyl acetate
ND
ppbv
10/26/2010
Vinyl chloride
ND
0.3
ppbv
10/26/2010
Xylenes, Total
34
0.89
ppbv
10/26/2010
Qualifiers:
* - Non-accredited parameter
Page 4 of 14
Lab Order:
10100784
Project:
Lab ID:
10100784-002A
Analyses
RL Qualifier Units
DF
Date Analyzed
TO-15
1,1,1-Trichloroethane
3.5
0.3
ppbv
10/26/2010
1,1,2,2-Tetrachloroethane
ND
0.3
ppbv
10/26/2010
1,1,2-Trichloroethane
ND
0.3
ppbv
10/26/2010
1,1-Dichloroethane
ND
0.75
ppbv
10/26/2010
1,1-Dichloroethene
ND
0.3
ppbv
10/26/2010
1,2,4-Trichlorobenzene
ND
0.75
ppbv
10/26/2010
1,2,4-Trimethylbenzene
46
0.3
ppbv
10/26/2010
1,2-Dibromoethane
ND
0.3
ppbv
10/26/2010
1,2-Dichlorobenzene
1.2
0.3
ppbv
10/26/2010
1,2-Dichloroethane
ND
0.3
ppbv
10/26/2010
1,2-Dichloropropane
ND
0.3
ppbv
10/26/2010
18
0.3
ppbv
10/26/2010
1,3-Butadiene
ND
0.3
ppbv
10/26/2010
1,3-Dichlorobenzene
ND
0.3
ppbv
10/26/2010
1,4-Dichlorobenzene
ND
0.3
ppbv
10/26/2010
1,4-Dioxane
ND
1.5
ppbv
10/26/2010
2-Butanone
ND
0.75
ppbv
10/26/2010
2-Hexanone
ND
ppbv
10/26/2010
13
0.3
ppbv
10/26/2010
4-Methyl-2-pentanone
3.1
1.5
ppbv
10/26/2010
Acetone
350
75
ppbv
25
10/27/2010
Benzene
1,3,5-Trimethylbenzene
4-Ethyltoluene
0.55
0.3
ppbv
10/26/2010
Benzyl chloride
ND
1.5
ppbv
10/26/2010
Bromodichloromethane
ND
0.3
ppbv
10/26/2010
Bromoform
ND
1.5
ppbv
10/26/2010
Bromomethane
ND
1.5
ppbv
10/26/2010
Carbon disulfide
ND
1.5
ppbv
10/26/2010
Carbon tetrachloride
ND
0.3
ppbv
10/26/2010
Chlorobenzene
ND
0.3
ppbv
10/26/2010
Chloroethane
ND
0.3
ppbv
10/26/2010
Chloroform
ND
0.3
ppbv
10/26/2010
Chloromethane
ND
1.5
ppbv
10/26/2010
cis-1,2-Dichloroethene
0.37
0.3
ppbv
10/26/2010
cis-1,3-Dichloropropene
ND
0.3
ppbv
10/26/2010
Cyclohexane
ND
0.3
ppbv
10/26/2010
Dibromochloromethane
ND
0.3
ppbv
10/26/2010
Dichlorodifluoromethane
ND
0.3
ppbv
10/26/2010
Ethyl acetate
ND
0.3
ppbv
10/26/2010
Qualifiers:
* - Non-accredited parameter
Page 5 of 14
Lab Order:
10100784
Project:
Lab ID:
10100784-002A
Analyses
RL Qualifier Units
DF
Date Analyzed
TO-15
Ethylbenzene
140
7.5
ppbv
25
10/27/2010
Freon-113
ND
0.3
ppbv
10/26/2010
Freon-114
ND
0.3
ppbv
10/26/2010
Heptane
5.6
0.3
ppbv
10/26/2010
Hexachlorobutadiene
ND
0.3
ppbv
10/26/2010
Hexane
ND
1.5
ppbv
10/26/2010
Isopropyl Alcohol
ND
1.5
ppbv
10/26/2010
m,p-Xylene
460
15
ppbv
25
10/27/2010
ND
0.3
ppbv
10/26/2010
10/26/2010
Methylene chloride
ND
ppbv
o-Xylene
150
7.5
ppbv
25
10/27/2010
Propene
ND
ppbv
10/26/2010
Styrene
2.1
0.3
ppbv
10/26/2010
Tetrachloroethene
7.9
0.3
ppbv
10/26/2010
Tetrahydrofuran
ND
0.75
ppbv
10/26/2010
Toluene
350
7.5
ppbv
25
10/27/2010
trans-1,2-Dichloroethene
ND
0.3
ppbv
10/26/2010
trans-1,3-Dichloropropene
ND
0.75
ppbv
10/26/2010
Trichloroethene
ND
0.75
ppbv
10/26/2010
Trichlorofluoromethane
ND
0.3
ppbv
10/26/2010
Vinyl acetate
ND
ppbv
10/26/2010
Vinyl chloride
ND
0.3
ppbv
10/26/2010
Xylenes, Total
610
22
ppbv
25
10/27/2010
Qualifiers:
* - Non-accredited parameter
Page 6 of 14
Page 7 of 14
Page 8 of 14
CLIENT:
Work Order:
Project:
ZZZZZ
Analyte
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Butadiene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
2-Butanone
2-Hexanone
4-Ethyltoluene
4-Methyl-2-pentanone
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Qualifiers:
SampType: MBLK
BatchID:
TestCode: TO_15A+
Units: ppbv
Prep Date:
TestNo: TO-15
Result
PQL
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.20
0.20
0.20
0.50
0.20
0.50
0.20
0.20
0.20
0.20
0.20
0.20
ND
ND
ND
ND
ND
ND
ND
ND
0.12
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.20
0.20
0.20
1.0
0.50
2.0
0.20
1.0
2.0
0.20
1.0
0.20
1.0
1.0
1.0
0.20
0.20
0.20
SPK value
%REC
LowLimit
HighLimit
R67083
SeqNo: 1784388
%RPD
RPDLimit
Qual
J*
Page 9 of 14
CLIENT:
Work Order:
Project:
SampType: MBLK
Batch ID: R67083
ZZZZZ
Analyte
Units: ppbv
Prep Date:
TestNo: TO-15
PQL
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Cyclohexane
Dibromochloromethane
Dichlorodifluoromethane
Ethyl acetate
Ethylbenzene
Freon-113
Freon-114
Heptane
Hexachlorobutadiene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.20
1.0
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
Hexane
Isopropyl Alcohol
m,p-Xylene
Methyl tert-butyl ether
Methylene chloride
o-Xylene
Propene
Styrene
Tetrachloroethene
Tetrahydrofuran
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylenes, Total
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.0
1.0
0.40
0.20
2.0
0.20
2.0
0.20
0.20
0.50
0.20
0.20
0.50
0.50
0.20
2.0
0.20
0.60
BatchID:
TestCode: TO_15A+
Result
Qualifiers:
SPK value
%REC
LowLimit
Page 10 of 14
HighLimit
R67083
SeqNo: 1784388
%RPD
RPDLimit
Qual
CLIENT:
Work Order:
Project:
SampType: LCS
Batch ID: R67083
ZZZZZ
Analyte
TestCode: TO_15A+
Units: ppbv
R67083
Prep Date:
TestNo: TO-15
SeqNo: 1784389
Result
PQL
SPK value
%REC
LowLimit
HighLimit
%RPD
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Butadiene
4.51
4.7
4.7
4.72
4.58
4.83
4.82
4.82
4.75
4.31
4.63
4.83
4.62
0.20
0.20
0.20
0.50
0.20
0.50
0.20
0.20
0.20
0.20
0.20
0.20
0.20
5
5
5
5
5
5
5
5
5
5
5
5
5
0
0
0
0
0
0
0
0
0
0
0
0
0
90.2
94
94
94.4
91.6
96.6
96.4
96.4
95
86.2
92.6
96.6
92.4
70
70
70
70
70
70
70
70
70
70
70
70
70
130
130
130
130
130
130
130
130
130
130
130
130
130
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
2-Butanone
2-Hexanone
4-Ethyltoluene
4-Methyl-2-pentanone
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
4.88
4.83
4.26
4.67
4.53
4.9
4.58
4.03
4.6
4.91
4.7
5.24
4.66
4.97
4.5
4.86
4.76
4.44
0.20
0.20
1.0
0.50
2.0
0.20
1.0
2.0
0.20
1.0
0.20
1.0
1.0
1.0
0.20
0.20
0.20
0.20
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
0
0
0
0
0
0
0
0.12
0
0
0
0
0
0
0
0
0
0
97.6
96.6
85.2
93.4
90.6
98
91.6
78.2
92
98.2
94
105
93.2
99.4
90
97.2
95.2
88.8
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Qualifiers:
Page 11 of 14
RPDLimit
Qual
CLIENT:
Work Order:
Project:
ZZZZZ
Analyte
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Cyclohexane
Dibromochloromethane
Dichlorodifluoromethane
Ethyl acetate
Ethylbenzene
Freon-113
Freon-114
Heptane
Hexachlorobutadiene
Hexane
Isopropyl Alcohol
m,p-Xylene
Methyl tert-butyl ether
Methylene chloride
o-Xylene
Propene
Styrene
Tetrachloroethene
Tetrahydrofuran
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylenes, Total
Qualifiers:
SampType: LCS
TestCode: TO_15A+
Units: ppbv
R67083
Prep Date:
TestNo: TO-15
SeqNo: 1784389
Result
PQL
SPK value
%REC
LowLimit
HighLimit
%RPD
5.09
4.71
4.8
4.52
4.99
4.74
4.35
4.86
4.76
5.37
4.5
5.04
4.5
1.0
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
1.0
5
5
5
5
5
5
5
5
5
5
5
5
5
0
0
0
0
0
0
0
0
0
0
0
0
0
102
94.2
96
90.4
99.8
94.8
87
97.2
95.2
107
90
101
90
70
70
70
70
70
70
70
70
70
70
70
70
70
130
130
130
130
130
130
130
130
130
130
130
130
130
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4.1
9.65
4.63
4.03
4.8
4.87
4.89
4.85
4.14
4.69
4.54
5.15
4.74
4.73
4.54
4.69
14.45
1.0
0.40
0.20
2.0
0.20
2.0
0.20
0.20
0.50
0.20
0.20
0.50
0.50
0.20
2.0
0.20
0.60
5
10
5
5
5
5
5
5
5
5
5
5
5
5
5
5
15
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
82
96.5
92.6
80.6
96
97.4
97.8
97
82.8
93.8
90.8
103
94.8
94.6
90.8
93.8
96.3
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Page 12 of 14
RPDLimit
Qual
CLIENT:
Work Order:
Project:
SampType: LCSD
Batch ID: R67083
ZZZZZ
Analyte
TestCode: TO_15A+
Units: ppbv
Prep Date:
TestNo: TO-15
R67083
Run ID: VOA-6_101026A
SeqNo: 1784390
Result
PQL
SPK value
%REC
LowLimit
HighLimit
%RPD
RPDLimit
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Butadiene
4.53
4.7
4.77
4.76
4.56
4.82
4.82
4.89
4.78
4.34
4.66
4.89
4.68
0.20
0.20
0.20
0.50
0.20
0.50
0.20
0.20
0.20
0.20
0.20
0.20
0.20
5
5
5
5
5
5
5
5
5
5
5
5
5
0
0
0
0
0
0
0
0
0
0
0
0
0
90.6
94
95.4
95.2
91.2
96.4
96.4
97.8
95.6
86.8
93.2
97.8
93.6
70
70
70
70
70
70
70
70
70
70
70
70
70
130
130
130
130
130
130
130
130
130
130
130
130
130
4.51
4.7
4.7
4.72
4.58
4.83
4.82
4.82
4.75
4.31
4.63
4.83
4.62
0.442
0
1.48
0.844
0.438
0.207
0
1.44
0.630
0.694
0.646
1.23
1.29
25
25
25
25
25
25
25
25
25
25
25
25
25
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
2-Butanone
2-Hexanone
4-Ethyltoluene
4-Methyl-2-pentanone
Acetone
Benzene
Benzyl chloride
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
4.86
4.82
4.44
4.87
4.78
5.06
4.77
4.06
4.64
5.05
4.75
5.26
4.76
4.93
4.5
4.86
4.74
4.49
0.20
0.20
1.0
0.50
2.0
0.20
1.0
2.0
0.20
1.0
0.20
1.0
1.0
1.0
0.20
0.20
0.20
0.20
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
0
0
0
0
0
0
0
0.12
0
0
0
0
0
0
0
0
0
0
97.2
96.4
88.8
97.4
95.6
101
95.4
78.8
92.8
101
95
105
95.2
98.6
90
97.2
94.8
89.8
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
4.88
4.83
4.26
4.67
4.53
4.9
4.58
4.03
4.6
4.91
4.7
5.24
4.66
4.97
4.5
4.86
4.76
4.44
0.411
0.207
4.14
4.19
5.37
3.21
4.06
0.742
0.866
2.81
1.06
0.381
2.12
0.808
0
0
0.421
1.12
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
Qualifiers:
Page 13 of 14
Qual
CLIENT:
Work Order:
Project:
ZZZZZ
Analyte
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Cyclohexane
Dibromochloromethane
Dichlorodifluoromethane
Ethyl acetate
Ethylbenzene
Freon-113
Freon-114
Heptane
Hexachlorobutadiene
Hexane
Isopropyl Alcohol
m,p-Xylene
Methyl tert-butyl ether
Methylene chloride
o-Xylene
Propene
Styrene
Tetrachloroethene
Tetrahydrofuran
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylenes, Total
Qualifiers:
SampType: LCSD
TestCode: TO_15A+
Units: ppbv
Prep Date:
TestNo: TO-15
R67083
Run ID: VOA-6_101026A
SeqNo: 1784390
Result
PQL
SPK value
%REC
LowLimit
HighLimit
%RPD
RPDLimit
4.88
4.72
4.87
4.53
5.04
4.75
4.5
4.87
4.75
5.45
4.5
4.96
4.51
1.0
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
1.0
5
5
5
5
5
5
5
5
5
5
5
5
5
0
0
0
0
0
0
0
0
0
0
0
0
0
97.6
94.4
97.4
90.6
101
95
90
97.4
95
109
90
99.2
90.2
70
70
70
70
70
70
70
70
70
70
70
70
70
130
130
130
130
130
130
130
130
130
130
130
130
130
5.09
4.71
4.8
4.52
4.99
4.74
4.35
4.86
4.76
5.37
4.5
5.04
4.5
4.21
0.212
1.45
0.221
0.997
0.211
3.39
0.206
0.210
1.48
0
1.60
0.222
25
25
25
25
25
25
25
25
25
25
25
25
25
4.15
9.67
4.72
4.03
4.82
4.81
4.97
4.89
4.31
4.75
4.55
5.21
4.8
4.75
4.6
4.83
14.49
1.0
0.40
0.20
2.0
0.20
2.0
0.20
0.20
0.50
0.20
0.20
0.50
0.50
0.20
2.0
0.20
0.60
5
10
5
5
5
5
5
5
5
5
5
5
5
5
5
5
15
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
83
96.7
94.4
80.6
96.4
96.2
99.4
97.8
86.2
95
91
104
96
95
92
96.6
96.6
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
4.1
9.65
4.63
4.03
4.8
4.87
4.89
4.85
4.14
4.69
4.54
5.15
4.74
4.73
4.54
4.69
14.45
1.21
0.207
1.93
0
0.416
1.24
1.62
0.821
4.02
1.27
0.220
1.16
1.26
0.422
1.31
2.94
0.276
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
Page 14 of 14
Qual
Page 1 of 8
Client:
Project:
Lab Order:
Lab Sample ID
Client Sample ID
10100926-001A ACME-TOXEFF-102510
10100926-002A ACME-TOXEFF-102810
Tag Number
Date Received
10/25/2010 2:30:00 PM
10/28/2010 1:00:00 PM
10/28/2010
10/28/2010
Page 2 of 8
Lab Order:
10100926
Project:
Lab ID:
10100926-001A
Analyses
RL Qualifier Units
DF
TO-15
Date Analyzed
Analyst: VP
1,1,1-Trichloroethane
ND
0.31
ppbv
1,1,2,2-Tetrachloroethane
ND
0.31
ppbv
11/3/2010
1,1,2-Trichloroethane
ND
0.31
ppbv
11/3/2010
1,1-Dichloroethane
ND
0.78
ppbv
11/3/2010
1,1-Dichloroethene
ND
0.31
ppbv
11/3/2010
1,2,4-Trichlorobenzene
ND
0.78
ppbv
11/3/2010
1,2,4-Trimethylbenzene
0.58
0.31
ppbv
11/3/2010
1,2-Dibromoethane
ND
0.31
ppbv
11/3/2010
1,2-Dichlorobenzene
ND
0.31
ppbv
11/3/2010
1,2-Dichloroethane
ND
0.31
ppbv
11/3/2010
1,2-Dichloropropane
ND
0.31
ppbv
11/3/2010
1,3,5-Trimethylbenzene
ND
0.31
ppbv
11/3/2010
1,3-Butadiene
ND
0.31
ppbv
11/3/2010
1,3-Dichlorobenzene
ND
0.31
ppbv
11/3/2010
1,4-Dichlorobenzene
ND
0.31
ppbv
11/3/2010
1,4-Dioxane
ND
1.6
ppbv
11/3/2010
2-Butanone
ND
0.78
ppbv
11/3/2010
2-Hexanone
ND
3.1
ppbv
11/3/2010
4-Ethyltoluene
ND
0.31
ppbv
11/3/2010
4-Methyl-2-pentanone
ND
1.6
ppbv
11/3/2010
Acetone
420
31
ppbv
10
11/4/2010
Benzene
ND
0.31
ppbv
11/3/2010
Benzyl chloride
ND
1.6
ppbv
11/3/2010
Bromodichloromethane
ND
0.31
ppbv
11/3/2010
Bromoform
ND
1.6
ppbv
11/3/2010
Bromomethane
ND
1.6
ppbv
11/3/2010
Carbon disulfide
ND
1.6
ppbv
11/3/2010
Carbon tetrachloride
ND
0.31
ppbv
11/3/2010
Chlorobenzene
ND
0.31
ppbv
11/3/2010
Chloroethane
ND
0.31
ppbv
11/3/2010
Chloroform
ND
0.31
ppbv
11/3/2010
Chloromethane
ND
1.6
ppbv
11/3/2010
cis-1,2-Dichloroethene
ND
0.31
ppbv
11/3/2010
cis-1,3-Dichloropropene
ND
0.31
ppbv
11/3/2010
Cyclohexane
ND
0.31
ppbv
11/3/2010
Dibromochloromethane
ND
0.31
ppbv
11/3/2010
Dichlorodifluoromethane
ND
0.31
ppbv
11/3/2010
Ethyl acetate
ND
0.31
ppbv
11/3/2010
Qualifiers:
11/3/2010
* - Non-accredited parameter
Page 3 of 8
Lab Order:
10100926
Project:
Lab ID:
10100926-001A
Analyses
RL Qualifier Units
DF
TO-15
Date Analyzed
Analyst: VP
0.42
0.31
ppbv
Freon-113
ND
0.31
ppbv
11/3/2010
Freon-114
ND
0.31
ppbv
11/3/2010
Heptane
ND
0.31
ppbv
11/3/2010
Hexachlorobutadiene
ND
0.31
ppbv
11/3/2010
Hexane
ND
1.6
ppbv
11/3/2010
Isopropyl Alcohol
ND
1.6
ppbv
11/3/2010
m,p-Xylene
1.6
0.63
ppbv
11/3/2010
ND
0.31
ppbv
11/3/2010
11/3/2010
Methylene chloride
11/3/2010
ND
3.1
ppbv
o-Xylene
0.47
0.31
ppbv
11/3/2010
Propene
ND
3.1
ppbv
11/3/2010
Styrene
ND
0.31
ppbv
11/3/2010
Tetrachloroethene
ND
0.31
ppbv
11/3/2010
Tetrahydrofuran
ND
0.78
ppbv
11/3/2010
Toluene
0.5
0.31
ppbv
11/3/2010
trans-1,2-Dichloroethene
ND
0.31
ppbv
11/3/2010
trans-1,3-Dichloropropene
ND
0.78
ppbv
11/3/2010
Trichloroethene
ND
0.78
ppbv
11/3/2010
Trichlorofluoromethane
ND
0.31
ppbv
11/3/2010
Vinyl acetate
ND
3.1
ppbv
11/3/2010
Vinyl chloride
ND
0.31
ppbv
11/3/2010
Xylenes, Total
2.1
0.94
ppbv
11/3/2010
Qualifiers:
* - Non-accredited parameter
Page 4 of 8
Lab Order:
10100926
Project:
Lab ID:
10100926-002A
Analyses
RL Qualifier Units
DF
TO-15
Date Analyzed
Analyst: VP
1,1,1-Trichloroethane
ND
0.29
ppbv
1,1,2,2-Tetrachloroethane
ND
0.29
ppbv
11/3/2010
1,1,2-Trichloroethane
ND
0.29
ppbv
11/3/2010
1,1-Dichloroethane
ND
0.73
ppbv
11/3/2010
1,1-Dichloroethene
ND
0.29
ppbv
11/3/2010
1,2,4-Trichlorobenzene
ND
0.73
ppbv
11/3/2010
1,2,4-Trimethylbenzene
ND
0.29
ppbv
11/3/2010
1,2-Dibromoethane
ND
0.29
ppbv
11/3/2010
1,2-Dichlorobenzene
ND
0.29
ppbv
11/3/2010
1,2-Dichloroethane
ND
0.29
ppbv
11/3/2010
1,2-Dichloropropane
ND
0.29
ppbv
11/3/2010
1,3,5-Trimethylbenzene
ND
0.29
ppbv
11/3/2010
1,3-Butadiene
ND
0.29
ppbv
11/3/2010
1,3-Dichlorobenzene
ND
0.29
ppbv
11/3/2010
1,4-Dichlorobenzene
ND
0.29
ppbv
11/3/2010
1,4-Dioxane
ND
1.5
ppbv
11/3/2010
2-Butanone
ND
0.73
ppbv
11/3/2010
2-Hexanone
ND
2.9
ppbv
11/3/2010
4-Ethyltoluene
ND
0.29
ppbv
11/3/2010
4-Methyl-2-pentanone
ND
1.5
ppbv
11/3/2010
Acetone
48
2.9
ppbv
11/3/2010
Benzene
ND
0.29
ppbv
11/3/2010
Benzyl chloride
ND
1.5
ppbv
11/3/2010
Bromodichloromethane
ND
0.29
ppbv
11/3/2010
Bromoform
ND
1.5
ppbv
11/3/2010
Bromomethane
ND
1.5
ppbv
11/3/2010
Carbon disulfide
ND
1.5
ppbv
11/3/2010
Carbon tetrachloride
ND
0.29
ppbv
11/3/2010
Chlorobenzene
ND
0.29
ppbv
11/3/2010
Chloroethane
ND
0.29
ppbv
11/3/2010
Chloroform
ND
0.29
ppbv
11/3/2010
Chloromethane
ND
1.5
ppbv
11/3/2010
cis-1,2-Dichloroethene
ND
0.29
ppbv
11/3/2010
cis-1,3-Dichloropropene
ND
0.29
ppbv
11/3/2010
Cyclohexane
ND
0.29
ppbv
11/3/2010
Dibromochloromethane
ND
0.29
ppbv
11/3/2010
Dichlorodifluoromethane
ND
0.29
ppbv
11/3/2010
Ethyl acetate
ND
0.29
ppbv
11/3/2010
Qualifiers:
11/3/2010
* - Non-accredited parameter
Page 5 of 8
Lab Order:
10100926
Project:
Lab ID:
10100926-002A
Analyses
RL Qualifier Units
DF
TO-15
Date Analyzed
Analyst: VP
0.55
0.29
ppbv
Freon-113
ND
0.29
ppbv
11/3/2010
Freon-114
ND
0.29
ppbv
11/3/2010
Heptane
ND
0.29
ppbv
11/3/2010
Hexachlorobutadiene
ND
0.29
ppbv
11/3/2010
Hexane
ND
1.5
ppbv
11/3/2010
Isopropyl Alcohol
ND
1.5
ppbv
11/3/2010
m,p-Xylene
2.4
0.58
ppbv
11/3/2010
ND
0.29
ppbv
11/3/2010
11/3/2010
Methylene chloride
11/3/2010
ND
2.9
ppbv
o-Xylene
0.48
0.29
ppbv
11/3/2010
Propene
ND
2.9
ppbv
11/3/2010
Styrene
ND
0.29
ppbv
11/3/2010
Tetrachloroethene
ND
0.29
ppbv
11/3/2010
Tetrahydrofuran
ND
0.73
ppbv
11/3/2010
Toluene
0.7
0.29
ppbv
11/3/2010
trans-1,2-Dichloroethene
ND
0.29
ppbv
11/3/2010
trans-1,3-Dichloropropene
ND
0.73
ppbv
11/3/2010
Trichloroethene
ND
0.73
ppbv
11/3/2010
Trichlorofluoromethane
ND
0.29
ppbv
11/3/2010
Vinyl acetate
ND
2.9
ppbv
11/3/2010
Vinyl chloride
ND
0.29
ppbv
11/3/2010
Xylenes, Total
2.9
0.88
ppbv
11/3/2010
Qualifiers:
* - Non-accredited parameter
Page 6 of 8
Page 7 of 8
Page 8 of 8
Page 1 of 6
Client:
Project:
Lab Order:
Lab Sample ID
Client Sample ID
10110145-001A ACME-TOXEFF-110210
Tag Number
Date Received
11/2/2010 2:30:00 PM
11/4/2010
Page 2 of 6
Lab Order:
10110145
Project:
Lab ID:
10110145-001A
Analyses
RL Qualifier Units
DF
TO-15
Date Analyzed
Analyst: VP
1,1,1-Trichloroethane
ND
0.31
ppbv
1,1,2,2-Tetrachloroethane
ND
0.31
ppbv
11/4/2010
1,1,2-Trichloroethane
ND
0.31
ppbv
11/4/2010
1,1-Dichloroethane
ND
0.79
ppbv
11/4/2010
1,1-Dichloroethene
ND
0.31
ppbv
11/4/2010
1,2,4-Trichlorobenzene
ND
0.79
ppbv
11/4/2010
1,2,4-Trimethylbenzene
0.9
0.31
ppbv
11/4/2010
1,2-Dibromoethane
ND
0.31
ppbv
11/4/2010
1,2-Dichlorobenzene
ND
0.31
ppbv
11/4/2010
1,2-Dichloroethane
ND
0.31
ppbv
11/4/2010
1,2-Dichloropropane
ND
0.31
ppbv
11/4/2010
1,3,5-Trimethylbenzene
ND
0.31
ppbv
11/4/2010
1,3-Butadiene
ND
0.31
ppbv
11/4/2010
1,3-Dichlorobenzene
ND
0.31
ppbv
11/4/2010
1,4-Dichlorobenzene
ND
0.31
ppbv
11/4/2010
1,4-Dioxane
ND
1.6
ppbv
11/4/2010
2-Butanone
ND
0.79
ppbv
11/4/2010
2-Hexanone
ND
3.1
ppbv
11/4/2010
4-Ethyltoluene
ND
0.31
ppbv
11/4/2010
4-Methyl-2-pentanone
ND
1.6
ppbv
11/4/2010
Acetone
520
31
ppbv
10
11/4/2010
Benzene
ND
0.31
ppbv
11/4/2010
Benzyl chloride
ND
1.6
ppbv
11/4/2010
Bromodichloromethane
ND
0.31
ppbv
11/4/2010
Bromoform
ND
1.6
ppbv
11/4/2010
Bromomethane
ND
1.6
ppbv
11/4/2010
Carbon disulfide
ND
1.6
ppbv
11/4/2010
Carbon tetrachloride
ND
0.31
ppbv
11/4/2010
Chlorobenzene
ND
0.31
ppbv
11/4/2010
Chloroethane
ND
0.31
ppbv
11/4/2010
Chloroform
ND
0.31
ppbv
11/4/2010
Chloromethane
ND
1.6
ppbv
11/4/2010
cis-1,2-Dichloroethene
ND
0.31
ppbv
11/4/2010
cis-1,3-Dichloropropene
ND
0.31
ppbv
11/4/2010
Cyclohexane
ND
0.31
ppbv
11/4/2010
Dibromochloromethane
ND
0.31
ppbv
11/4/2010
Dichlorodifluoromethane
ND
0.31
ppbv
11/4/2010
Ethyl acetate
ND
0.31
ppbv
11/4/2010
Qualifiers:
11/4/2010
* - Non-accredited parameter
Page 3 of 6
Lab Order:
10110145
Project:
Lab ID:
10110145-001A
Analyses
RL Qualifier Units
DF
TO-15
Date Analyzed
Analyst: VP
0.55
0.31
ppbv
Freon-113
ND
0.31
ppbv
11/4/2010
Freon-114
ND
0.31
ppbv
11/4/2010
Heptane
ND
0.31
ppbv
11/4/2010
Hexachlorobutadiene
ND
0.31
ppbv
11/4/2010
Hexane
ND
1.6
ppbv
11/4/2010
Isopropyl Alcohol
ND
1.6
ppbv
11/4/2010
m,p-Xylene
2.4
0.63
ppbv
11/4/2010
ND
0.31
ppbv
11/4/2010
11/4/2010
Methylene chloride
11/4/2010
ND
3.1
ppbv
o-Xylene
0.66
0.31
ppbv
11/4/2010
Propene
ND
3.1
ppbv
11/4/2010
Styrene
ND
0.31
ppbv
11/4/2010
Tetrachloroethene
ND
0.31
ppbv
11/4/2010
Tetrahydrofuran
ND
0.79
ppbv
11/4/2010
0.36
0.31
ppbv
11/4/2010
trans-1,2-Dichloroethene
ND
0.31
ppbv
11/4/2010
trans-1,3-Dichloropropene
ND
0.79
ppbv
11/4/2010
Trichloroethene
ND
0.79
ppbv
11/4/2010
Trichlorofluoromethane
ND
0.31
ppbv
11/4/2010
Vinyl acetate
ND
3.1
ppbv
11/4/2010
Vinyl chloride
ND
0.31
ppbv
11/4/2010
Xylenes, Total
3.1
0.94
ppbv
11/4/2010
Toluene
Qualifiers:
* - Non-accredited parameter
Page 4 of 6
Page 5 of 6
Page 6 of 6
Page 1 of 8
Client:
Project:
Lab Order:
Lab Sample ID
Client Sample ID
10110279-001A ACME-TOXEFF-110910
10110279-002A ACME-TOXINF-110910
Tag Number
Date Received
11/9/2010 10:00:00 AM
11/9/2010 10:10:00 AM
11/9/2010
11/9/2010
Page 2 of 8
Lab Order:
10110279
Project:
Lab ID:
10110279-001A
Analyses
RL Qualifier Units
DF
Date Analyzed
TO-15
1,1,1-Trichloroethane
ND
0.31
ppbv
11/10/2010
1,1,2,2-Tetrachloroethane
ND
0.31
ppbv
11/10/2010
1,1,2-Trichloroethane
ND
0.31
ppbv
11/10/2010
1,1-Dichloroethane
ND
0.77
ppbv
11/10/2010
1,1-Dichloroethene
ND
0.31
ppbv
11/10/2010
1,2,4-Trichlorobenzene
ND
0.77
ppbv
11/10/2010
1,2,4-Trimethylbenzene
0.72
0.31
ppbv
11/10/2010
1,2-Dibromoethane
ND
0.31
ppbv
11/10/2010
1,2-Dichlorobenzene
ND
0.31
ppbv
11/10/2010
1,2-Dichloroethane
ND
0.31
ppbv
11/10/2010
1,2-Dichloropropane
ND
0.31
ppbv
11/10/2010
1,3,5-Trimethylbenzene
ND
0.31
ppbv
11/10/2010
1,3-Butadiene
ND
0.31
ppbv
11/10/2010
1,3-Dichlorobenzene
ND
0.31
ppbv
11/10/2010
1,4-Dichlorobenzene
ND
0.31
ppbv
11/10/2010
1,4-Dioxane
ND
1.5
ppbv
11/10/2010
2-Butanone
ND
0.77
ppbv
11/10/2010
2-Hexanone
ND
3.1
ppbv
11/10/2010
4-Ethyltoluene
ND
0.31
ppbv
11/10/2010
4-Methyl-2-pentanone
ND
1.5
ppbv
11/10/2010
Acetone
870
62
ppbv
20
11/11/2010
Benzene
0.55
0.31
ppbv
11/10/2010
Benzyl chloride
ND
1.5
ppbv
11/10/2010
Bromodichloromethane
ND
0.31
ppbv
11/10/2010
Bromoform
ND
1.5
ppbv
11/10/2010
Bromomethane
ND
1.5
ppbv
11/10/2010
Carbon disulfide
ND
1.5
ppbv
11/10/2010
Carbon tetrachloride
ND
0.31
ppbv
11/10/2010
Chlorobenzene
ND
0.31
ppbv
11/10/2010
Chloroethane
ND
0.31
ppbv
11/10/2010
Chloroform
ND
0.31
ppbv
11/10/2010
Chloromethane
ND
1.5
ppbv
11/10/2010
cis-1,2-Dichloroethene
ND
0.31
ppbv
11/10/2010
cis-1,3-Dichloropropene
ND
0.31
ppbv
11/10/2010
Cyclohexane
ND
0.31
ppbv
11/10/2010
Dibromochloromethane
ND
0.31
ppbv
11/10/2010
Dichlorodifluoromethane
ND
0.31
ppbv
11/10/2010
Ethyl acetate
ND
0.31
ppbv
11/10/2010
Qualifiers:
* - Non-accredited parameter
Page 3 of 8
Lab Order:
10110279
Project:
Lab ID:
10110279-001A
Analyses
RL Qualifier Units
DF
Date Analyzed
TO-15
Ethylbenzene
1.2
0.31
ppbv
11/10/2010
Freon-113
ND
0.31
ppbv
11/10/2010
Freon-114
ND
0.31
ppbv
11/10/2010
Heptane
ND
0.31
ppbv
11/10/2010
Hexachlorobutadiene
ND
0.31
ppbv
11/10/2010
Hexane
ND
1.5
ppbv
11/10/2010
Isopropyl Alcohol
ND
1.5
ppbv
11/10/2010
m,p-Xylene
5.3
0.62
ppbv
11/10/2010
ND
0.31
ppbv
11/10/2010
Methylene chloride
ND
3.1
ppbv
11/10/2010
o-Xylene
1.6
0.31
ppbv
11/10/2010
Propene
ND
3.1
ppbv
11/10/2010
Styrene
ND
0.31
ppbv
11/10/2010
Tetrachloroethene
ND
0.31
ppbv
11/10/2010
Tetrahydrofuran
ND
0.77
ppbv
11/10/2010
Toluene
2.3
0.31
ppbv
11/10/2010
trans-1,2-Dichloroethene
ND
0.31
ppbv
11/10/2010
trans-1,3-Dichloropropene
ND
0.77
ppbv
11/10/2010
Trichloroethene
ND
0.77
ppbv
11/10/2010
Trichlorofluoromethane
ND
0.31
ppbv
11/10/2010
Vinyl acetate
ND
3.1
ppbv
11/10/2010
Vinyl chloride
ND
0.31
ppbv
11/10/2010
Xylenes, Total
6.9
0.92
ppbv
11/10/2010
Qualifiers:
* - Non-accredited parameter
Page 4 of 8
Lab Order:
10110279
Project:
Lab ID:
10110279-002A
Analyses
RL Qualifier Units
DF
Date Analyzed
TO-15
5600
170
ppbv
500
11/11/2010
1,1,2,2-Tetrachloroethane
ND
170
ppbv
500
11/11/2010
1,1,2-Trichloroethane
ND
8.5
ppbv
25
11/10/2010
1,1-Dichloroethane
360
21
ppbv
25
11/10/2010
1,1-Dichloroethene
52
8.5
ppbv
25
11/10/2010
1,2,4-Trichlorobenzene
ND
420
ppbv
500
11/11/2010
1,2,4-Trimethylbenzene
23000
170
ppbv
500
11/11/2010
1,2-Dibromoethane
ND
8.5
ppbv
25
11/10/2010
1,2-Dichlorobenzene
260
170
ppbv
500
11/11/2010
1,2-Dichloroethane
ND
8.5
ppbv
25
11/10/2010
130
8.5
ppbv
25
11/10/2010
9900
170
ppbv
500
11/11/2010
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Butadiene
14
8.5
ppbv
25
11/10/2010
1,3-Dichlorobenzene
ND
170
ppbv
500
11/11/2010
1,4-Dichlorobenzene
ND
170
ppbv
500
11/11/2010
1,4-Dioxane
ND
42
ppbv
25
11/10/2010
2-Butanone
42
21
ppbv
25
11/10/2010
2-Hexanone
ND
85
ppbv
25
11/10/2010
8700
170
ppbv
500
11/11/2010
4-Methyl-2-pentanone
ND
42
ppbv
25
11/10/2010
4-Ethyltoluene
Acetone
150
85
ppbv
25
11/10/2010
Benzene
120
8.5
ppbv
25
11/10/2010
Benzyl chloride
ND
850
ppbv
500
11/11/2010
Bromodichloromethane
ND
8.5
ppbv
25
11/10/2010
Bromoform
ND
850
ppbv
500
11/11/2010
Bromomethane
ND
42
ppbv
25
11/10/2010
Carbon disulfide
ND
42
ppbv
25
11/10/2010
Carbon tetrachloride
ND
8.5
ppbv
25
11/10/2010
Chlorobenzene
ND
170
ppbv
500
11/11/2010
Chloroethane
ND
8.5
ppbv
25
11/10/2010
Chloroform
ND
8.5
ppbv
25
11/10/2010
Chloromethane
ND
42
ppbv
25
11/10/2010
1800
8.5
ppbv
25
11/10/2010
cis-1,3-Dichloropropene
ND
8.5
ppbv
25
11/10/2010
cis-1,2-Dichloroethene
Cyclohexane
120
8.5
ppbv
25
11/10/2010
Dibromochloromethane
ND
8.5
ppbv
25
11/10/2010
Dichlorodifluoromethane
ND
8.5
ppbv
25
11/10/2010
Ethyl acetate
ND
8.5
ppbv
25
11/10/2010
Qualifiers:
* - Non-accredited parameter
Page 5 of 8
Lab Order:
10110279
Project:
Lab ID:
10110279-002A
Tag Number:
Matrix: Air
Analyses
Result
RL Qualifier Units
DF
Date Analyzed
TO-15
140000
34000
ppbv
100000
11/11/2010
Freon-113
18
8.5
ppbv
25
11/10/2010
Freon-114
ND
8.5
ppbv
25
11/10/2010
5100
170
ppbv
500
11/11/2010
Hexachlorobutadiene
ND
170
ppbv
500
11/11/2010
Hexane
110
42
ppbv
25
11/10/2010
Isopropyl Alcohol
ND
42
ppbv
25
11/10/2010
760000
68000
ppbv
100000
11/11/2010
ND
8.5
ppbv
25
11/10/2010
11/10/2010
Heptane
m,p-Xylene
Methyl tert-butyl ether
Methylene chloride
ND
85
ppbv
25
o-Xylene
210000
34000
ppbv
100000
11/11/2010
Propene
ND
85
ppbv
25
11/10/2010
Styrene
3800
170
ppbv
500
11/11/2010
Tetrachloroethene
6900
170
ppbv
500
11/11/2010
11/10/2010
Tetrahydrofuran
Toluene
ND
21
ppbv
25
450000
34000
ppbv
100000
11/11/2010
ND
8.5
ppbv
25
11/10/2010
11/10/2010
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
ND
21
ppbv
25
1100
21
ppbv
25
11/10/2010
Trichlorofluoromethane
ND
8.5
ppbv
25
11/10/2010
Vinyl acetate
ND
85
ppbv
25
11/10/2010
Vinyl chloride
ND
8.5
ppbv
25
11/10/2010
Xylenes, Total
970000
100000
ppbv
100000
11/11/2010
Trichloroethene
Qualifiers:
* - Non-accredited parameter
Page 6 of 8
Page 7 of 8
Page 8 of 8