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QUESTION BASED ON IMPORTANT TOPICS OF CHEMISTRY FOR AIPMT

6.
1.

CH 3

its K(sp) is :

CH 3 C CH CH 3

(a) 4.00 10 6 M 3
6

2.

3.

4.

5.

The compound

If pH of a saturated solution of Ba (OH)2 is 12, the value of

(b) 4.00 107 M3

7

on reaction with NaIO4 in the presence of KMnO4 gives

(a) CH3CHO + CO2
(b) CH3COCH3
(c) CH3COCH3 + CH3COOH
(d) CH3COCH3 + CH3CHO

(c) 5.00 10 M
(d) 5.00 10 M
In qualitative analysis, the metals of Group I can be separated
from other ions by precipitating them as chloride salts. A
solution initially contains Ag+ and Pb2+ at a concentration
of 0.10 M. Aqueous HCl is added to this solution until the
Cl concentration is 0.10 M. What will the concentrations of
Ag+ and Pb2+ be at equilibrium?
(Ksp for AgCl = 1.8 1010,
Ksp for PbCl2 = 1.7 105)
(a) [Ag+] = 1.8 107 M ; [Pb2+] = 1.7 106 M
(b) [Ag+] = 1.8 1011 M ; [Pb2+] = 8.5 105 M
(c) [Ag+] = 1.8 109 M ; [Pb2+] = 1.7 103 M
(d) [Ag+] = 1.8 1011 M ; [Pb2+] = 8.5 104 M
Which one of the following molecular hydrides acts as a
Lewis acid?
(a) NH3
(b) H2O
(c) B2H6
(d) CH4
The values of K sp of CaCO 3 and CaC 2 O 4 are
4.7 109 and 1.3 109 respectively at 25C. If the mixture
of these two is washed with water, what is the concentration
of Ca2+ ions in water?
(a) 7.746 105 M
(b) 5.831 105 M
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(c) 6.856 10 M
(d) 3.606 105 M
In the presence of platinum catalyst, hydrocarbon A adds
hydrogen to form n-hexane. When hydrogen bromide is
added to A instead of hydrogen, only a single bromo
compound is formed. Which of the following is A?
(a) CH 3 CH 2 CH CH CH 2 CH 3

7.

H 3 C CH CH
|

(d) CH 2

HBr

CH 3

A(predominantly) is :
(a) CH 3 CH CH 2 CH 2 Br
|

CH 3

(b) CH3

Br
|
C CH 2 CH3
|
CH3

(c) CH3 CH CH CH 3
|
|
Br CH3
(d) CH 3

8.

CH CH CH 3
|
|
CH 3 Br

Which one of the following alkenes will react faster with

H2 under catalytic hydrogenation conditions?
(R = Alkyl Substituent)

R
(a)

(b) CH 3 CH 2 CH 2 CH CH CH 3
(c) CH 3 CH CH CH 2 CH 2 CH 3

CH 2

(c)

(b)

(d)

CH CH 2 CH 2 CH 2 CH 3

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9.

Cuprous compounds such as CuCl, CuCN and CuSCN are

the only salts stable in water due to
(a) high hydration energy of Cu+ ions
(b) their inherent tendency not do disproportionate
(c) diamagnetic nature
(d) insolubility in water
10. CrO3 dissolves in aqueous NaOH to give
(b) CrO42
(a) Cr2O72
(c) Cr(OH)3
(d) Cr(OH)2
11. The basic character of the transition metal monoxides follows
the order
(Atomic Nos.,Ti = 22, V = 23, Cr = 24, Fe = 26)
(a) TiO > VO > CrO > FeO
(b) VO > CrO > TiO > FeO
(c) CrO > VO > FeO > TiO
(d) TiO > FeO > VO > CrO
12. Among the following series of transition metal ions, the one
where all metal ions have 3d2 electronic configuration is(At.
nos. Ti = 22; V = 23; Cr = 24; Mn = 25)
(a) Ti 3 , V 2 , Cr 3 , Mn 4
(b) Ti , V 4 , Cr 6 , Mn 7

15. Schotten-Baumann reaction is a reaction of phenols with

(a) Benzoyl chloride and sodium hydroxide
(b) Acetyl chloride and sodium hydroxide
(c) Salicylic acid and conc. H2SO4
(d) Acetyl chloride and conc H2SO4
16. Acetaldehyde reacts with semicarbazide and forms
semicarbazone. Its structure is
(a) CH3CH = NNHCON = CHCH3
(b) CH3CH = NNHCONH2
(c) CH 3CH

(d) CH3CH = NCONHNH2

17. A solution containing 10 g per dm3 of urea (molecular mass
= 60 g mol1) is isotonic with a 5% solution of a non-volatile
solute. The molecular mass of this nonvolatile solute is
(a) 300 g mol1
(b) 350 g mol1
1
(c) 200 g mol
(d) 250 g mol1
18. The freezing point depression constant for water is 1.86C
m1. If 5.00 g Na2SO4 is dissolved in 45.0 g H2O, the freezing
point is changed by 3.82C. Calculate the vant Hoff factor
for Na2SO4.

19.

HCl

13.

3CH 3COCH 3

3H 2O

(a) 2.05

(b) 2.63

(c) 3.11

(d) 0.381

The vant Hoff factor i for a compound which undergoes

dissociation in one solvent and association in other solvent
is respectively :
(a) less than one and greater than one.

(A)
(CH 3 )2 C CH CO CH

OH

(c) Ti 4 , V 3 , Cr 2 , Mn 3
(d) Ti 2 , V 3 , Cr 4 , Mn 5

N N CONH 2

(b) less than one and less than one.

C(CH 3 ) 2

(B)
This polymer (B) is obtained when acetone is saturated with
hydrogen chloride gas, B can be
(a) phorone
(b) formose
(c) diacetone alcohol
(d) mesityl oxide.
14. Th e reagent (s) which can be used to distin guish
acetophenone from benzophenone is (are)
(a) 2,4- Dinitrophenylhydrazine
(b) Aqueous solution of NaHSO3
(c) Benedict reagent
(d) I2and NaOH.

(c) greater than one and less than one.

(d) greater than one and greater than one.
20.

Which one of the following salts will have the same value
of vant Hoff factor (i) as that of K4[Fe (CN)6].
(a) Al2(SO4)3
(b) NaCl
(c) Al (NO3)3
(d) Na2SO4.

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