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# 2004 Institution of Chemical Engineers
Trans IChemE, Part B, July 2004
Process Safety and Environmental Protection, 82(B4): 291300
www.ingentaselect.com=titles=09575820.htm
Centre for the Application of Science and Technology to Rural Areas (ASTRA), Indian Institute of Science, Bangalore, India
2
Department of Chemical and Process Engineering, University of Moratuwa, Moratuwa, Sri Lanka
INTRODUCTION
291
292
Angola
Benin
Bolivia
Brazil
Burundi
Cameroon
Central African Republic
Cote dIvoire
Colombia
Congo, Republic of Congo
Democratic Republic of
Costa Rica
Cuba
Dominican Republic
Ecuador
El Salvador
Equatorial Guinea
Ethiopia
Gabon
Ghana
Guatemala
Guinea
Haiti
Honduras
India
Indonesia
Jamaica
Kenya
Liberia
Madagascar
Malawi
Mexico
Nicaragua
Nigeria
Panama
Papua New Guinea
Paraguay
Peru
Philippines
Rwanda
Sierra Leone
Sri Lanka
Tanzania
Thailand
Togo
Trinidad and
Tobago
Uganda
Vietnam
Zambia
Zimbabwe
Country
Finland
Sweden
Denmark
Norway
Netherlands
Belgium=
Luxembourg
Germany
Switzerland
France
Austria
USA
Canada
Italy
Hungary
Israel
Cyprus
Spain
Yugoslavia
Greece
UK
Australia
New Zealand
Japan
Portugal
Ireland
Hong Kong
Per
capita,
kg year1
Roasting
Roasting and
grinding
12.4
11.45
11.03
9.71
7.7
7.26
Light
Light
Medium
Light
Light
Medium
6.42
5.69
5.67
5.67
4.8
4.34
3.7
3.2
2.58
2.49
2.46
2.25
2.23
2.19
2.06
1.78
1.48
1.25
1
0.61
Light
Medium
Dark
Dark
Light
Light
Dark
Dark
Dark
Dark
Dark
Dark
Dark
Medium
Medium
Medium
Light
Dark
Medium
Medium
Soluble=
instant
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B4): 291300
COFFEE PROCESSING
the wastewater. There is little control over the use of pesticides,
as most primary producers are developing countries. In addition to complex organic products, heavy metals could also find
their way into the wastewater. Coffee wastes, for example,
contain copper, which comes from the application of copperbased fungicide used in the control of coffee diseases.
Cenicafe in Colombia has introduced the use of agricultural
biotechnology practices to coffee processing. It introduced
integrated pest management (IPM) practices by releasing tiny
wasps that eat the Broca (coffee berry borer) instead of using
insecticides. This reduces crop damage to less than 5%. This,
carried out with the International Institute of Biological
Control, had been a pioneering plant biotechnology project
(www.cabi.org). Herbicide and synthetic pesticide use in
Indian coffee is minimal.
Processing coffee
The processing steps in coffee may be grouped into primary,
secondary and tertiary steps. Primary coffee processing refers
to the processing of coffee fruit to obtain coffee beans (also
called green beans). The next stage refers to hulling, roasting
and grinding. Tertiary processing involves making of instant
coffee and=or other value addition operations.
Primary processing
Primary coffee processing is carried out within coffee
plantations. Primary processing produces green beans from
the coffee fruit. The coffee fruit consists of coloured exocarp
(skin), fleshy yellowish-white mesocarp (pulp), mucilage layers
(covering the two beans joined together along the flat sides and
made up mainly of pectin) and two coats (first a thin fibrous
textured parchment and second a fine membrane, silver skin).
Primary processing is done in two major waysthe dry
and wet methods. In the dry method, the fruits are picked
and laid out to dry in the sun for 34 weeks. A hulling
machine then strips away the outer skin and pulp. The beans
are not always consistent in quality and producing highquality coffee with the dry method is challenging because
the beans are exposed to climatic conditions during the
drying process. The product is known as the dry natural
cherry. Most robusta and very little arabica is processed in
this way. Value added is usually low. Solid wastes are
generated and they are used as fuel for thermal applications.
The wet method or washed coffee methods are used in
locations with plentiful supplies of fresh water. It is carried
out in two steps, pulping and washing. One can note the
following distribution of wet and dry processing in the
producing countries, although many countries follow both
methods and the rest aspire to change to wet processing if
possible (www.ico.org).
wet processingBolivia, Burundi, Cameroon, Colombia,
Costa Rica, Cuba, Dominican Republic, East Timor,
Equador, El Salvador, Equatorial Guinea, Ethiopia,
Guatemala, Honduras, India, Indonesia, Jamaica, Kenya,
Malawi, Mexico, Nicaragua, Papua New Guinea,
Rwanda, Tanzania, Uganda, Venezuela, Vietnam,
Zambia, Zimbabwe;
dry processingAngola, Benin, Brazil, Central African
Republic, Congo, Congo Democratic Republic, Cote
dIvoire, Gabon, Ghana, Guinea, Haiti, Madagascar,
Nigeria, Paraguay, Philippines, Sri Lanka, Thailand, Togo.
293
Pulping
The coffee fruit is squeezed between two serrated metal
plates and the skin and the pulp are detached from the seed.
The mucilage-coated seeds and fruit skins (with pulp) are
separated into different streams. The skin and pulp are
carried away in a stream of flowing water. In the receiving
tank the skin with the pulp is separated out (solid waste)
from the waste water (pulp water). The pulp water most
often joins the wastewater stream. However, wherever there
is an acute shortage of fresh water (as in many plantations
today), this water is recovered and recycled for 25 days in
the pulping process. In India three main types of pulpers are
usedthe drum, disc and slotted types (Chellamuthu et al.,
2000). At a few locations, modified designs use screw
conveyers to carry the skin and pulp and therefore do not
have a significant pulp water stream. The seeds at this stage
carry a mucilage layer that is removed in the next step.
Washing (removal of mucilage)
Freshly pulped coffee seeds are covered with a highly
slippery mucilaginous layer approximately 1.5 mm thick and
translucent. There are five methods of removing this mucilage (Ranganna, 2002) namely, natural fermentation, chemical methods, warm water soaking, enzymatic fermentation
and attrition. The most popular methods combine fermentation and attrition. The beans, still enclosed in a sticky inner
mucilage and parchment wrapper, are soaked for 472 h in
fermentation tanks. This fermentation loosens the remaining
mucilage through a series of enzymatic reactions. It is then
washed away in a combination of the processes of washing
and attrition (mostly by a machine called a washer).
Fermentation time is controlled to achieve the right quality
of beans. The resultant coffee is termed parchment coffee.
Sometimes coffee fruits are washed and sorted as in the
washed method, but are not placed in fermentation tanks.
Instead they are set out to dry. This also results in parchment
coffee called semi-washed coffee. The washed coffee, with a
moisture content of 55%, is dried in the sun to a moisture
content of 15%. The dried coffee is later hulled to remove
the parchment and the silver skin. The overall sequence of
operations typical for a South Indian plantation is given in
Figure 2. Note that for robusta most Indian plantations
follow the dry processing method.
Secondary processing
Dried green beans are subjected to mechanical removal of
the parchment layer from the bean. The beans are then
graded according to size, shape, weight, colour and uniformity. The beans are then roasted to give them a dark brown
colour and the strong aroma and taste that are usually
associated with coffee. Roasting represents the largest fraction of value addition. Secondary processing has less
environmental impact and near zero impact on water
resources. The air emissions perhaps are the only aspect
that needs to be considered. Very little secondary processing
is carried out in producer countries except for internal
consumption or bulk soluble coffee.
Tertiary processing
Coffee powder may be subjected to different processes to
develop product varieties. Instant coffee manufacture and
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B4): 291300
294
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B4): 291300
COFFEE PROCESSING
Table 4. Physico-chemical characteristics of coffee effluents (range,
ASTRA, 2002a).
Parameter
Units
Wash water
(semi-washed
coffee)
Pulp
water
Secondary
wash water
46.3
16.470
N.A.
N.A.
g l1
g l1
2.625.8
0.370.97
2.323
0.86
15.565
0.50.9
14.353
5.330
N.A.
N.A.
N.A.
N.A.
g l1
0.11.6
0.21.9
N.A.
g l1
g l1
295
Parameter
Units
pH
Total Solids
Total dissolved solids=total solids
COD
BOD
Total alkalinity
mg l1
%
mg l1
mg l1
g l1
With
recirculation
Without
recirculation
45
19504800
45
22004600
5.4 (0.74)
16502800
12003000
8501750
14003900
5090
2480 (1158)
1443 (483)
0.039 (0.027)
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B4): 291300
296
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B4): 291300
COFFEE PROCESSING
297
Table 6. Treatment needs and costs of a typical 1tonne fruit per day lagoon.
Values based on NEERI, 1978 design; capacity based on processing of
1.0 tonnes fruit per day; 12,000 l per tonne of fruit processed (Shanmukappa et al., 1998; US$1 Rs 50, 2002).
No.
1
2
3
4
5
Treatment
tank
Period of storage
(days)
Equalization tank
1
Anaerobic tank
21
Aerobic tank
7
Settling tank
1
Total
30
Total cost (@Rs 2.5 l1) Rs 1 million
Volume
stored (l)
12,000
252,000
84,000
12,000
360,000
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B4): 291300
298
These technologies carry varying investment costs, operating skills, operating costs and environmental branding.
These also lead to different strategies in environment
management by coffee producers. For a long time in
India, anaerobicaerobic lagoons have been the only technology accepted by most stakeholders. As argued earlier in
the text, due to the poor water situation and the number of
estates involved in pulping, this technology needs to be
gradually phased out. This technology in its current form
solves only the earlier kind of environmental problems.
Further, this end-of-pipe approach is not conducive for
backward integration of best practices and environmental
consciousness. On the other hand large numbers of existing
biogas=anaerobic digester technologies are being adapted to
coffee effluents as primary feedstock. Many of them function well and would require operation and management
strategies just like those followed in industrial wastewater
treatment systems. The high initial investment costs, the
minimum economic size-based bottom-line, high skills
needed for operators, etc., are conducive for adoption by
large plantations but not small and medium size plantations
that dominate the Indian coffee cultivation scenario. This
also is an end-of-the pipe solution and is unlikely to
significantly influence the backward integration of best
practices. The majority of Indian coffee plantations fall
in the small and medium categories processing under
10 tonnes fruit per day, and the strategy must accommodate
the seasonal nature of the process.
This situation is conducive for a third kind of anaerobic
reactors that can function with multiple feed stockboth
solid and liquid wastes generated on the coffee plantation
throughout the year. A variant of downflow whole cell
immobilized reactor (Chanakya et al., 1998; currently
called the ASTRA bioreactor) has been functioning in
15 locations for periods of up to 4 years (see for example
www.ginimao.com). The reactor functions like a plug-flow
reactor using various biomass feed stocks found on the
coffee plantation. In this mode it is made to accumulate
partially digested herbaceous biomass on which high populations of methanogens remain adhered. During the pulping
season, biomass feeding is stopped and coffee effluents
(COD >25 g l1) is passed horizontally through the methanogen rich biomass bed. Over 90% COD is removed (Table
7). As this system can accept a high concentration effluent,
reactors built are small, occupying only 5% of the space
originally allocated to anaerobic lagoons, and plantations
also reduce their water needs for processing by about 90%.
The bioreactors are built as 60 m3 modules by plantations
using largely local materials and skills. It costs US$1200
per module. Each module has a peak overall loading rate
(OLR) of 2 kg BOD m3 day1 arising from pulping 12
tonnes of fruit per day when operated at 1520 C. The
resource recovery concept embodies the extraction of useful
energy, trapping of excess dissolved and suspended plant
nutrients and re-use of the wastewater on-farm for irrigation.
The digested biomass support is extracted as compost (soil
conditioner) for the plantation. The bioreactor treated effluent has 0.61.0 g l1 BOD and requires a short stay in an
aerobic lagoon before reuse on land for irrigation. In the
future, as more, of the small plantations take to wet processing, there will be need to use even more best practices
integrated resource recovery systemsavoiding environmental stresses with process modifications rather than
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B4): 291300
Gas m3 kg1
COD or fruit
Remarks,
limitations etc.
Authors
Year
Country
Scale of
operation
Type of
reactor
Feed rate
kg m3 d1
Calle
1957
Spain
Laboratory
Batch
Maheswaran
1988
Kenya
Calzada et al.
(diphasic)
1984
Guatemala
Laboratory
Calzada et al.
(packed bed
reactor)
Gathuo (pulp)
Gathuo et al.
(wastewater)
BTG
(www.btgworld.com)
1984
Guatemala
Laboratory
PBR (PUF)
1995
1991
Kenya
Kenya
Bench
Bench
NA
NA
NA
60
350 l
Coffee pulp with cow
60 kg of pulp and
5 kg of cow dung
dung Mixed
in 182 l of water
conditions
Review of work in Kenyathe only successful biogas installation reported uses 50=50 mixture of cow dung and
coffee pulp (uses a masticated mixture)
22 kg COD
5771 % COD
2
4 v=v
Neutralized to pH 7
reduction
This high-rate
system has shown
HRT reduction from
10 to 2 days
4047% conversion
15
3 v=v
Coffee pulp as
922 kg VS
of sugars
substrate Isothermal
m3 day 7 1
conditions at 35 C
7.2 kg DM
90
410
0.25d
6.5 kg COD
90
410
0.30c
1999
Costa Rica=
Netherlands
Demonstration
and 250 m3
UASB
20003000 kg COD
7580% COD
Calvert
1997
PNG
Bench
UASB
80% BOD
removal
Bello-Mendoza
and Castillo-Rivera
Boopathy et al.
(1986)
Boopathy
1988
Mexico
Pilot
UASB-filter
1.89 kg COD
77%
1986
India
Laboratory
Bottle
C:N ration study for satisfactory AD of coffee pulp30:1 with 25% TS found to be the optimum condition
1988
India=Italy
Laboratory
2.5 l batch
Boopathy
1987
India=UK
Laboratory
Metabolism of protein, carbohydrates and lipid of coffee pulp during AD process. Enzyme activity of coffee pulp
was found to be higher compared with a cow dung digester
Cow dung was identified as the best innoculum material for the start-up of anaerobic digestion using coffee pulp as
substrate
Boopathy
Boopathy and
Mariappan
Chanakya et al.
ASTRA
1987
1984
India
India
Laboratory
Laboratory
CSTR
CSTR
1998
2002b
India
India
Laboratory
Field
BIBR
BIBR
810 kg TS
23 kg COD
Batch
Conversion
(% or kg m3 day1
85%
90%
HRT (day)
12.5
0.9
0.7
710
COFFEE PROCESSING
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B4): 291300
Table 7. Summary of R&D and field trials on anaerobic digestion of coffee waste water.
0.026c
0.5d
0.5d
Down-flow mode
Horizontal flow mode
CSTR, completely strirred tank reactor (often unstirred); PBR, packed bed reactor; UASB, upflow anaerobic sludge blanket; PUF, polyurethane foam; BIBR, biomass immobilized-bed reactor; c, COD basis; d, dry matter
basis; DM, dry matter; VS, volatile solids.
299
300
CONCLUSIONS
The review shows that there are significant problems
facing the producer countries and the situation is steadily
deteriorating further. The additional environmental burden is
perceived to be high. There is no one solution, although a
solution which will bring in environmental protection
with resource-recovery will help significantly. Cenicafes
pulping system, ASTRAs plug flow type bioreactor
system, composting and vermi-composting methods appear
to significantly benefit in impact reduction in primary processing. ASTRAs design overcomes the limitations listed by the
review of Adams and Dougan. The significance is that it can
handle both the solid and liquid waste streams together in
addition to being a system of lower operating and maintenance cost. Financing appears to be a major hurdle in
implementing wastewater treatment in primary producing
countries. In India external subsidy via an international donor
programme has sparked the ASTRA implementation of a
technology that had been pursued for a while. In Costa Rica it
appears that climate change convention had found a partner
in implementing a government directive on pollution control.
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ACKNOWLEDGEMENT
The authors would like to express their gratitude to Indo-Norwegian
Environment Program (INEP) for the financial support, which provided the
foundation for this work.
The manuscript was received 23 July 2003 and accepted for publication
22 March 2004.
Trans IChemE, Part B, Process Safety and Environmental Protection, 2004, 82(B4): 291300