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1.

QUESTION 1

Dalton's Atomic Theory included all of the ideas listed below except:

a All
.

atoms of a given element have properties that differ from those of


other elements.
b All atoms of a given element have identical properties.
.
c Atoms cannot be created or destroyed.
.
d Compounds are formed when atoms of
.

different elements combine with


one another in small whole-number ratios.
e An element is composed of very small particles called protons, neutrons
.
and electrons.
1 points

QUESTION 2

1.

Atoms consist of three fundamental particles. What are these particles


and their charges?
a.
b.
c.
d.
e.

proton
proton
proton
proton
proton

(+1), neutron (neutral) and electron (-1)


(-1), neutron (+1) and electron (neutral)
(+1), neutron (-1) and electron (neutral)
(-1), neutron (neutral) and electron (+1)
(neutral), neutron (+1) and electron (-1)
1 points

1.

QUESTION 3

One of the following does not describe gases. Which one is it?
a.
b.
c.
d.
e.

Particles far apart.


Expands infinitely.
Relatively low densities.
Easily compressed.
Rigid shape.
1 points

QUESTION 4

1.

All of the following are properties of oxygen. Which one is


a physical property?
It supports combustion.
b. It condenses to a liquid at 219C and atmospheric pressure.
c. It causes iron to rust.
d. It reacts with calcium to produce calcium oxide, CaO.
e. All of these are physical properties.
a.

1 points

1.

QUESTION 5

Which of the following is an extensive property of matter?


a.
b.
c.
d.
e.

weight
density
specific gravity
melting point
color
1 points

QUESTION 6

1.

Which of the following changes in water represents chemical a change?


a.
b.
c.
d.
e.

Heating water from 25C to 60C.


Boiling water.
Calcium reacting with water to produce calcium hydroxide.
Melting of ice.
Sublimation of solid ice directly to gaseous water.
1 points

1.

QUESTION 7

Which of the following is not a mixture?


a.
b.
c.
d.
e.

oxygen
gasoline
air
seawater
steel
1 points

QUESTION 8

1.

Which statement is false?


a Different
.

mixtures of the same two substances can have different


compositions.
b All samples of a particular pure substance have the same composition
.
and properties.
c An example of a homogeneous mixture is one prepared by mixing two
.
liquids, ethyl alcohol (grain alcohol) and water.
d A compound is a substance that can be decomposed by chemical
.
means into simpler substances.
e An example of a heterogeneous mixture is one prepared by dissolving
.
the solid, sodium chloride (table salt), in the liquid, water.
1 points

QUESTION 9

1.

Which element/symbol pair is incorrect?


a.
b.
c.
d.
e.

Ag / gold
O / oxygen
Pb / lead
Fe / iron
Ca / calcium
1 points

1.

QUESTION 10

Which symbol name combination is incorrect?


a.
Zn zinc
b.
Pd lead
c.
Mn manganese
d.
Sn tin
e.
Sr strontium
1 points

1.

QUESTION 11

In the Rutherford gold foil experiment, the fact that most of the alpha
particles were not deflected as they passed through the gold foil indicates
that
the nucleus is positively charged.
the atom is mostly empty space.
c. atoms are solid spheres touching each other in the solid state.
d. gold is very dense.
e. none of the above is correct.
a.

b.

1 points

QUESTION 12

1.

The Rutherford "gold foil experiment" suggested ____.


a
.
b
.
c
.
d
.

that atoms have a tiny, positively charged, massive center


the existence of canal rays
the ratio of the mass of an electron to the charge of the electron

that protons have charges equal in magnitude but opposite in sign to


those of electrons
e that electrons have negative charges
.

1 points

QUESTION 13

1.

The atomic number of a certain element is 19, and its atomic weight is
39. An atom of the element contains ____ protons, ____ neutrons, and the
chemical symbol for the element is ____.
a.
b.
c.
d.
e.

19, 19, F
19, 20, F
19, 20, K
20, 19, K
none of these
1 points

1.

QUESTION 14

Give the number of protons, neutrons, and electrons in the

ion.
a.
b.
c.
d.
e.

16
16
16
34
16

p,
p,
p,
p,
p,

18
16
18
16
18

n,
n,
n,
n,
n,

18 e
19 e
16 e
18 e
14e
1 points

QUESTION 15

1.

How many neutrons does the phosphorus isotope

a.
b.
c.
d.
e.

contain?

17
8
15
32
2
1 points

1.

QUESTION 16

Consider the following statements about atomic structure. Which


is true?
a The
.

volume occupied by the nucleus of an atom represents a large


percentage of the total volume of the atom.
b The mass number of an atom is the sum of the number of protons plus
.
electrons in the atom.

c The number of protons in an atom is its atomic number.


.
d Isotopes of an element differ only in the number of protons.
.
e The atomic number is the same as the mass number for most
.

elements.
1 points

1.

QUESTION 17

What is the atomic weight of a hypothetical element consisting of two


isotopes, one with mass 64.23 amu (26.00%), and one with mass 65.32
amu?
a.
64.80 amu
b.
65.16 amu
c.
64.37 amu
d.
64.96 amu
e.
65.04 amu
1 points

1.

QUESTION 18

Chapter 5 Values

Some of the following values may be useful for solving some of the
problems.
speed of light 3.00 108 m/s
Planck's constant 6.63 1034 Js

1 joule 1 kgm2/s2
1 ngstrom 1 1010 m

2.
What is the wavelength of yellow light having a frequency of 5.17 1014 Hz?
a.
5.80 107 m
b.
2.72 106 m
c.
1.55 1023 m
d.
3.60 1010 m
e.
6.45 1028 m
1 points

QUESTION 19

1.

When an electron of an excited hydrogen atom falls from level n 2 to


level n 1, what wavelength of light is emitted? R 1.097 107 m1
a.
1215
b.
1820
c.
18.2

d.
e.

970
4800
1 points

1.

QUESTION 20

Which match is incorrect?

a de Broglie
.
b Millikan
.
c Thomson
.
d Faraday
.

predicted that electrons have wave-like properties


determined the magnitude of the charge on an electron
demonstrated the existence of the neutron

proposed that the elements of a chemical compound are


held together
by
electrical forces
e Rutherford
showed that most of the mass of an atom is in its nucleus
.

1 points

QUESTION 21

1.

The general shape of the region in space occupied by electrons is


described by which quantum number?

c.

n
ms
ml

d.

e.

a.
b.

1 points

1.

QUESTION 22

No two electrons in the same atom can have the same set of four
quantum numbers is a statement of ____.
a.
b.
c.
d.
e.

the Heisenberg Uncertainty Principle


the Aufbau Principle
the Pauli Exclusion Principle
Dalton's Theory
Hund's Rule
1 points

QUESTION 23

1.

Which element has the electron configuration below?


1s22s22p63s23p63d104s24p3

Se
Ca
V
As
P

a.
b.
c.
d.
e.

1 points

1.

QUESTION 24

Which one of the following electron configurations is incorrect?


a.
b.
c.
d.
e.

C
[He]2s22p4
Sc [Ar]3d14s2
Cl 1s22s22p63s23p6
Ge [Ar]3d104s23p3
N3 1s22s22p6
1 points

QUESTION 25

1.

Which of the following sets of quantum numbers could represent the


"last" electron added to complete the electron configuration for a ground
state atom of Br according to the Aufbau Principle.
n

ml

ms

a. 4

b. 3

c. 4

d. 4

e. 4

1 points

QUESTION 26

1.

Which Lewis Dot Formula is incorrect?


a.
b.
c.
d.
e.
1 points

1.

QUESTION 27

How many valence electrons does a phosphorus atom have?


a.
b.
c.
d.
e.

6
5
3
4
2
1 points

QUESTION 28

1.

How many unpaired electrons are shown in a Lewis Dot Formula for
silicon?
a.
b.
c.
d.
e.

1
3
0
2
4
1 points

1.

QUESTION 29

Which Lewis dot notation for atoms and ions is correct for the reaction
for the formation of aluminum oxide?
a.
b.
c.
d.
e.

1 points

QUESTION 30

1.

What is the formula for the binary compound of gallium and chlorine?
Ga3Cl2
Ga2Cl3
GaCl
GaCl3
GaCl2

a.
b.
c.
d.
e.

1 points

1.

QUESTION 31

What is the formula for the binary ionic compound of aluminum and
sulfur?
a.

Al

b.
c.

AlS
Al

d.

Al

e.

AlS

1 points

QUESTION 32

1.

A chemical bond formed by two atoms sharing one or more pairs of


electrons is called a (or an) ____ bond.
a.
b.
c.
d.
e.

covalent
coordinate covalent
ionic
nonpolar
polar
1 points

1.

QUESTION 33

Draw the Lewis dot formula for CO

. The number of unshared

pairs of electrons in the outer shell of the central atom is ____.


a.

zero

b.
c.
d.
e.

two
one
four
three
1 points

1.

QUESTION 34

The Lewis structure for the carbonate ion, CO32-, shows ____ doubles
bond(s), ____ single bond(s) and ____ lone pair(s) on the central atom.
a.
2, 1, 2
b.
2, 1, 1
c.
3, 1, 2
d.
2, 2, 1
e.
1, 2, 0
1 points

1.

QUESTION 35

Which one of the following Lewis dot formulas is incorrect?


a.
b.

c.
d.
e.
1 points

QUESTION 36

1.

Which Lewis dot formula is incorrect?


a.

b.

c.

d.

e.

1 points

QUESTION 37

1.

Assign a formal charge to each atom of

a.
b.
c.
d.
e.

As
As
As
As
As

=
=
=
=
=

5+, Cl = 10, Cl = 0
4+, Cl = 16+, Cl = 25-, Cl = 7+
1 points

1.

QUESTION 38

How many resonance structures does the bicarbonate ion, HCO

-,

have?
a.
b.
c.
d.
e.

1
2
3
0
4
1 points

QUESTION 39

1.

What is the electronic geometry for 5 regions of high electron density


on a central atom?
a.
b.
c.

trigonal planar
tetrahedral
trigonal bipyramidal

octahedral
square planar

d.
e.

1 points

1.

QUESTION 40

What is the electronic geometry for 6 regions of high electron density


on a central atom?
octahedral
square planar
tetrahedral
trigonal bipyramidal
trigonal planar

a.
b.
c.
d.
e.

1 points

QUESTION 41

1.

What angle(s) are associated with a central atom that has


octahedral electronic geometry?
a.
b.
c.
d.
e.

120
90 and 180
120 and 180
109.5
90 and 120
1 points

1.

QUESTION 42

Which one of the following molecules is polar?


a.
b.
c.
d.
e.

P4
CO2
N2
Cl2
H2O
1 points

QUESTION 43

1.

Which one of the following molecules is nonpolar?


a.
b.
c.
d.
e.

CSO
NH3
CO2
H 2O
NF3

1 points

QUESTION 44

1.

The O-N-O bond angles associated with the nitrate ion, NO3-, are all
120. The hybridization at the nitrogen atom is ____.
a.
sp3
b.
sp3d
c.
sp
d.
sp3d2
e.
sp2
1 points

QUESTION 45

1.

Which one of the following molecules has sp hybridization at the


central atom?
a.
b.
c.
d.
e.

PF5
SeF6
BF3
CF4
BeBr2
1 points

1.

QUESTION 46

What kind of hybrid orbitals are utilized by the boron atom in


BF3 molecules?
a.
sp
b.
sp3
c.
sp3d2
d.
sp2
e.
sp3d
1 points

1.

QUESTION 47

For AsF3, the electronic geometry is ____ and the molecular geometry is

____.
a.
b.
c.
d.
e.

tetrahedral, trigonal planar


trigonal planar, linear
trigonal planar, trigonal planar
trigonal planar, tetrahedral
tetrahedral, tetrahedral
1 points

QUESTION 48

1.

The electronic geometry of the central atom in PCl3 is ____.


a.
tetrahedral
b.
octahedral
c.
trigonal bipyramidal
d.
pyramidal
e.
trigonal planar
1 points

QUESTION 49

1.

The molecular geometry of the hydrogen sulfide molecule is ____.


a.
b.
c.
d.
e.

linear
pyramidal
trigonal planar
trigonal bipyramidal
angular
1 points

1.

QUESTION 50

Which of the following molecules is sp3 hybridized at the central atom


and has bent molecular geometry?
a.
CH2Cl2
b.
OF2
c.
CO2
d.
NH3
e.
SO2
1 points

1.

QUESTION 51

Of the following, which element does not match its designation?


a.

Th

f-transition metal

b.

Sr

representative metal

c.

In

representative nonmetal

d.

Si

metalloid

e.

d-transition metal

1 points

QUESTION 52

1.

What would be the outer electron configuration of group VIA (O, S, Se, .
. .)?
a.

ns

np

b.

np

c.

ns

np

d.

ns

np

e.

ns

np
1 points

1.

QUESTION 53

Choose the term that best describes all members of this series of
elements:
Xe, Rn, He, Ne, Kr
a.
metalloids
b.
alkali metals
c.
noble gases
d.
representative elements
e.
alkaline earth metals
1 points

1.

QUESTION 54

Which element has the largest atomic radius?


Al
Si
S
Cl
P

a.
b.
c.
d.
e.

1 points

QUESTION 55

1.

Which element has the smallest radius?


a.
b.
c.

Na
Mg
P

Si
Al

d.
e.

1 points

1.

QUESTION 56

The minimum energy required to remove the most loosely held


electron is
a.
b.
c.
d.
e.

electron affinity
first ionization energy.
electronegativity.
kinetic energy
potential energy
1 points

QUESTION 57

1.

Which element has the lowest first ionization energy?


a.
b.
c.
d.
e.

I
F
At
Cl
Br
1 points

1.

QUESTION 58

Which of the following elements has the most negative electron


affinity?
a.
b.
c.
d.
e.

Te
Se
P
S
Si
1 points

QUESTION 59

1.

Which one of the following species is not isoelectronic with neon?


a.

b.

Cl

c.

Na

d.

Mg

e.

Al
1 points

1.

QUESTION 60

Which ion has the largest radius?


a.

Te

b.

c.

Po

d.

e.

Se
1 points

QUESTION 61

1.

Name the molecular compound, HNO3.


a.
nitric oxide
b.
nitric acid
c.
ammonia
d.
methane
e.
nitrous acid
1 points

QUESTION 62

1.

What is the molecular formula for hydrogen chloride?


a.
b.
c.
d.
e.

HClO
HClO3
HCl
HClO4
HClO2
1 points

1.

QUESTION 63

Each response below lists an ion by name and by chemical symbol or


formula. Also each ion is classified as monatomic or polyatomic and as a
cation or anion. Which response contains an error?

a.
b.
c.
d.
e.

magnesium
sulfite
carbonate
ammonium
hydroxide

Mg2
SO32
CO32
NH4
OH

monatomic
polyatomic
polyatomic
polyatomic
monatomic

cation
anion
anion
cation
anion
1 points

1.

QUESTION 64

What is the formula for aluminum fluoride?


Al2F3
AlF
Al3F
Al3F2
AlF3

a.
b.
c.
d.
e.

1 points

QUESTION 65

1.

What is the formula for manganese(III) oxide?


a.
b.
c.
d.
e.

Mn2O3
MgO
MnO
Mg2O3
MnO4
1 points

1.

QUESTION 66

What is the name of Fe(OH)3?


a.
iron hydroxide
b.
iron trihydroxide
c.
iron (III) hydroxide
d.
iron (II) hydroxide
e.
none of these
1 points

1.

QUESTION 67

From the following ionic compounds, choose the name-formula pair


that is not correctly matched.
a.
b.
c.

ammonium nitrate
zinc hydroxide
calcium oxide

NH4NO3
Zn(OH)2
CaO

d.
e.

sodium sulfate
sodium sulfide

Na2SO3
Na2S
1 points

1.

QUESTION 68

From the following compounds choose the name-formula pair that is


incorrectly matched.
a.
b.
c.
d.
e.

cuprous sulfide
sodium sulfite
ammonium fluoride
ferric chloride
copper(II) carbonate

Co2S
Na2SO3
NH4F
FeCl3
CuCO3
1 points

QUESTION 69

1.

Calculate the number of moles of oxygen atoms in 35.2 grams of


oxygen.
a.
b.
c.
d.
e.

2.20
4.42
0.54
1.13
2.57

moles
moles
moles
moles
moles
1 points

1.

QUESTION 70

Determine the number of sulfur atoms in 27.1 g of molecular sulfur

(S8).
a.
b.
c.
d.
e.

2.07 1023
0.845
5.09 1023
0.106
5.27 1023
1 points

1.

QUESTION 71

Calculate the formula weight of Na2SO4.


a.
215 amu
b.
142 amu
c.
185 amu
d.
193 amu
e.
119 amu

1 points

QUESTION 72

1.

What is the mass of 2.2 109 CO2 molecules?


a.
9.7 1010 g
b.
4.4 1014 g
c.
1.0 1012 g
d.
1.6 1013 g
e.
1.2 106 g
1 points

QUESTION 73

1.

How many molecules are contained in 5.00 grams of NH3?


a.
3.00 1024
b.
3.40 1022
c.
1.77 1023
d.
9.45 1022
e.
5.42 1022
1 points

QUESTION 74

1.

What is the percent by mass of sulfur in Al2(SO4)3?


a.
28.1%
b.
18.8%
c.
9.38%
d.
24.6%
e.
35.4%
1 points

QUESTION 75

1.

Analysis of a sample of a covalent compound showed that it contained


14.4% hydrogen and 85.6% carbon by mass. What is the empirical formula
for this compound?
a.
b.
c.
d.
e.

C2H3
CH3
C2H5
CH
CH2
1 points

1.

QUESTION 76

Glucose has a molecular weight of 180.2 g and an empirical formula


CH2O. What is its molecular formula?

a.
b.
c.
d.
e.

C10H12O3
C6H12O6
C8H4O5
C12H22O11
CH2O
1 points

1.

QUESTION 77

A compound contains, by mass, 87.5% nitrogen and 12.5% hydrogen.


Its molecular weight is found to be 32 g/mol. What is its molecular formula?
a.
b.
c.
d.
e.

N 2H 4
NH2
NH3
N 2H 5
N 2H 6
1 points

QUESTION 78

1.

Classify the following reaction.


2 H2O(l) 2 H2(g) + O2(g)
a.
b.
c.
d.

combination
decompositio
double displacement
combustion
1 points

1.

QUESTION 79

Classify the following reaction.


a.
b.
c.
d.

C6H12O6(s) + 6 O2(g) 6 CO2(g) + 6 H2O(g)


decompositio
combustion
combination
double displacement
1 points

1.

QUESTION 80

Classify the following reaction.


2 Al(s) + 3 CuSO4 (aq) Al2(SO4)3(aq) + 3 Cu(s)

a.
b.
c.
d.

decompositio
single displacement
combination
combustion
1 points

1.

QUESTION 81

Classify the following reaction.


3 MgCl2 (aq) + 2 K3PO4(aq) Mg3(PO4)2(s) + 6 KCl(aq)
a.
double displacement
b.
combination
c.
decompositio
d.
combustion
1 points

QUESTION 82

1.

Classify the following reaction.

a.
b.
c.
d.

2 Al(s) + 3 Cl2(g) 2 AlCl3(s)


combination
combustion
decompositio
double displacement
1 points

1.

QUESTION 83

What is the coefficient of H2Owhenthefollowingequationisproperlybalanced


withthesmallestsetofwholenumbers?
___Na+___H2O___NaOH+___H2
a.
b.
c.
d.

3
2
1
4
1 points

1.

QUESTION 84

When balanced with the smallest set of whole numbers, the coefficient
of O2inthefollowingequationis:
__C2H4+__O2__CO2+__H2O

a.
b.
c.
d.

6
3
12
4
1 points

1.

QUESTION 85

What is the coefficient of H2SO4whenthefollowingequationisproperlybalanced


withthesmallestsetofwholenumbers
___Ca3(PO4)2+___H2SO4___CaSO4+___H3PO4
a.
3
b.
11
c.
10
d.
8
1 points

1.

QUESTION 86

How many moles of O2 are required to react with 23.5 moles of


methanol?
2CH3OH 3O2 2CO2 4H2O
a.
40
b.
23.5
c.
47.0
d.
11.8
e.
35.3
1 points

1.

QUESTION 87

How many moles of H2O will be produced from the complete


combustion of 2.4 grams of CH4?
CH4 2O2 CO2 2H2O
a.
0.15
b.
0.30
c.
3.0
d.
1.5
e.
6.0
1 points

1.

QUESTION 88

Acrylonitrile, C3H3N, is a molecule used to produce a plastic called


Orlon. How many grams of acrylonitrile could be produced by reacting 583 g

of propene, C3H6 with excess ammonia, NH3 and oxygen?


2C3H6 2NH3 3O2 C3H3N 6H2O
a.
735 g
b.
583 g
c.
368 g
d.
1470 g
e.
462 g
1 points

QUESTION 89

1.

What mass of phosphoric acid, H3PO4, would actually react with 7.17
grams of LiOH?
3LiOH H3PO4 Li3PO4 3H2O
a.
19.6 g
b.
9.80 g
c.
3.27 g
d.
29.4 g
e.
6.53 g
1 points

QUESTION 90

1.

How many moles of carbon dioxide could be produced if 10 moles of


octane, C8H18, are combined with 20 moles of oxygen?
C8H18 25O2 16CO2 18H2O
a.
40 mol
b.
12.8 mol
c.
8.0 mol
d.
20 mol
e.
62.5 mol
1 points

QUESTION 91

1.

If 58 moles of NH3 are combined with 32 moles of sulfuric acid, what is


the limiting reactant and how much of the excess reactant is left over?
2NH3 H2SO4 (NH4)2SO4
a.
NH3, 1.0 mol
b.
H2SO4, 3.0 mol
c.
NH3, 29 mol
d.
H2SO4, 29 mol
e.
NH3, 3.0 mol
1 points

1.

QUESTION 92

If 25 grams of methane, CH4, and 30 g of ammonia, NH3, are combined


w/ excess oxygen, how much methane or ammonia will be left when the
reaction is finished?
CH4 NH3 O2 2HCN 6H2O
a.
0.10 mol CH4
b.
0.10 g CH4
c.
10 g NH3
d.
0.10g NH3
e.
0.10 mol NH3
1 points

1.

QUESTION 93

The thermite reaction is performed using 8.6 g Fe2O3 and 1.8 g


powdered Al metal. Which reactant is in excess and by how much?
Fe2O3 2Al Al2O3 2Fe
a.
Al, 0.3 g
b.
Al, 2.1 g
c.
Al, 1.1 g
d.
Fe2O3, 2.0 g
e.
Fe2O3, 3.3 g
1 points

1.

QUESTION 94

What is the percent yield of CO2 if the reaction of 10.0 grams of CO


with excess O2 produces 12.8 grams of CO2?
2CO(g) O2(g) 2CO2(g)
a.
76.4%
b.
78.1%
c.
88.9%
d.
84.4%
e.
81.5%
1 points

1.

QUESTION 95

If 6.6 g of fluorine reacts with 5.6 g chlorine to produce 8.5 g of


chlorine trifluoride, what is the limiting reactant and the percent yield of
chlorine trifluoride?
Cl2 3F2 2ClF3
a.
F2, 79%
b.
F2, 45%
c.
F2, 69%

d.
e.

Cl2, 53%
Cl2, 58%
1 points

1.

QUESTION 96

In interpreting the results of his "oil drop" experiment in 1909, Robert


Millikan was able to determine ____.
a
.

that electrically neutral particles (neutrons) are present in the nuclei of


atoms
the charge on an electron

b
.
c. the
d
.
e
.

charge on a proton
that the masses of protons and neutrons are nearly identical
the extremely dense nature of the nuclei of atoms
1 points

QUESTION 97

1.

Ernest Rutherford's model of the atom did not specifically include the
____.
neutron
proton
nucleus
electron
electron or the proton

a.
b.
c.
d.
e.

1 points

1.

QUESTION 98

Which of the following particles has the smallest mass?


a.
b.
c.
d.
e.

a hydrogen nucleus
a neutron
a proton
a hydrogen atom
an electron
1 points

QUESTION 99

1.

Which two subatomic particles have approximately the same mass?


a.
b.
c.
d.

neutrons and electrons


protons and electrons
electrons and nuclei
protons and neutrons

e.

protons and alpha particles


1 points

1.

QUESTION 100

Isotopes are atoms of the same element that


a.
b.
c.
d.
e.

have
have
have
have
have

different
different
different
different
different

atomic numbers.
nuclear charges.
numbers of electrons.
numbers of protons.
numbers of neutrons.

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