Txy Diagram for Binary Feed mixture of Acetone and Isopropanol at 101.

3 kPa

System Pressure=

101.3 kPa

Antoine Coefficient for Acetone

A=
7.11714
B=
1210.595
C=
229.664

759.81248458
*Coefficients are obtained from ANCHEM book.

Isopropanol Coefficient for Isopropanol

A=
7.74021
B=
1359.517
C=
197.527

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27

Boiling point of pure Acetone at System Pressure=

Boiling point of pure Isopropanol at System Pressure=

56.094050642
82.237584814

Bubble Point Calculations:

*SEbp means Squared Error of bubble points

Xacetone
Xisopropanol
1.00
0.00
0.99
0.01
0.98
0.02
0.97
0.03
0.96
0.04
0.95
0.05
0.94
0.06
0.93
0.07
0.92
0.08
0.91
0.09
0.90
0.10
0.89
0.11
0.88
0.12
0.87
0.13
0.86
0.14
0.85
0.15
0.84
0.16
0.83
0.17
0.82
0.18
0.81
0.19
0.80
0.20
0.79
0.21
0.78
0.22
0.77
0.23
0.76
0.24
0.75
0.25
0.74
0.26

Tbubble
56.09402
56.2951
56.4973
56.70062
56.90508
57.11068
57.31742
57.52532
57.73438
57.9446
58.15599
58.36857
58.58232
58.79727
59.01341
59.23076
59.44931
59.66907
59.89005
60.11226
60.33569
60.56036
60.78627
61.01342
61.24182
61.47148
61.70239

Pacetone*
759.8118
765.0414
770.3289
775.6752
781.081
786.5471
792.0742
797.6633
803.315
809.0302
814.8098
820.6546
826.5654
832.5432
838.5887
844.7028
850.8865
857.1406
863.4661
869.8639
876.3348
882.8798
889.4999
896.1961
902.9692
909.8202
916.7502

PIsopropanol*
239.76341216
242.1192976
244.50784065
246.92957348
249.38503699
251.87478098
254.39936423
256.9593546
259.55532915
262.18787421
264.85758552
267.56506829
270.31093731
273.09581706
275.92034175
278.78515546
281.69091221
284.638276
287.62792095
290.66053133
293.73680165
296.8574367
300.02315164
303.23467203
306.4927339
309.79808377
313.15147871

SEbp
9.16205E-013
1.99903E-013
1.05435E-015
2.31935E-013
8.10606E-013
1.66090E-012
2.71245E-012
3.90060E-012
5.16643E-012
6.45675E-012
7.72401E-012
8.92625E-012
1.00272E-011
1.09959E-011
1.18072E-011
1.24410E-011
1.28830E-011
1.31238E-011
1.31594E-011
1.29907E-011
1.26240E-011
1.20700E-011
1.13443E-011
1.04669E-011
9.46213E-012
8.35804E-012
7.18652E-012

28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77

0.73
0.72
0.71
0.70
0.69
0.68
0.67
0.66
0.65
0.64
0.63
0.62
0.61
0.60
0.59
0.58
0.57
0.56
0.55
0.54
0.53
0.52
0.51
0.50
0.49
0.48
0.47
0.46
0.45
0.44
0.43
0.42
0.41
0.40
0.39
0.38
0.37
0.36
0.35
0.34
0.33
0.32
0.31
0.30
0.29
0.28
0.27
0.26
0.25
0.24

0.27
0.28
0.29
0.30
0.31
0.32
0.33
0.34
0.35
0.36
0.37
0.38
0.39
0.40
0.41
0.42
0.43
0.44
0.45
0.46
0.47
0.48
0.49
0.50
0.51
0.52
0.53
0.54
0.55
0.56
0.57
0.58
0.59
0.60
0.61
0.62
0.63
0.64
0.65
0.66
0.67
0.68
0.69
0.70
0.71
0.72
0.73
0.74
0.75
0.76

61.93456
62.168
62.40272
62.6387
62.87596
63.11451
63.35434
63.59546
63.83786
64.08157
64.32656
64.57286
64.82045
65.06934
65.31954
65.57104
65.82385
66.07796
66.33338
66.5901
66.84813
67.10747
67.3681
67.63004
67.89329
68.15783
68.42366
68.6908
68.95922
69.22893
69.49993
69.7722
70.04575
70.32057
70.59666
70.874
71.1526
71.43244
71.71351
71.99582
72.27935
72.56409
72.85004
73.13718
73.4255
73.71499
74.00564
74.29744
74.59038
74.88444

923.7601
930.8508
938.0235
945.2791
952.6187
960.0432
967.5536
975.1511
982.8367
990.6114
998.4762
1006.432
1014.481
1022.623
1030.859
1039.191
1047.619
1056.145
1064.77
1073.495
1082.321
1091.249
1100.28
1109.415
1118.656
1128.003
1137.458
1147.022
1156.695
1166.479
1176.375
1186.384
1196.507
1206.746
1217.1
1227.572
1238.162
1248.872
1259.702
1270.653
1281.726
1292.923
1304.244
1315.69
1327.262
1338.961
1350.789
1362.745
1374.83
1387.046

316.55368638
320.00548501
323.50766347
327.06102123
330.66636842
334.32452577
338.03632465
341.80260699
345.62422528
349.50204254
353.43693221
357.42977817
361.48147458
365.59292585
369.76504651
373.99876109
378.29500403
382.65471948
387.07886118
391.56839228
396.12428512
400.74752105
405.43909018
410.19999113
415.03123077
419.9338239
424.90879296
429.9571677
435.07998475
440.27828731
445.55312469
450.90555185
456.33662897
461.84742091
467.43899673
473.11242906
478.86879363
484.70916852
490.63463368
496.64627013
502.74515941
508.93238285
515.20902086
521.57615222
528.03485347
534.58619813
541.2312561
547.97109297
554.80676949
561.73934099

5.98265E-012
4.78428E-012
3.63148E-012
2.56610E-012
1.63100E-012
8.69340E-013
3.23752E-013
3.54639E-014
4.33102E-014
3.82705E-013
1.08453E-012
2.17402E-012
3.66950E-012
5.58141E-012
7.91099E-012
1.06492E-011
1.37761E-011
1.72596E-011
2.10552E-011
2.51057E-011
2.93414E-011
3.36801E-011
3.80286E-011
4.22841E-011
4.63364E-011
5.00699E-011
5.33681E-011
5.61167E-011
5.82080E-011
5.95468E-011
6.00539E-011
5.96731E-011
5.83750E-011
5.61616E-011
5.30701E-011
4.91751E-011
4.45883E-011
3.94578E-011
3.39626E-011
2.83066E-011
2.27078E-011
1.73869E-011
1.25519E-011
8.38266E-012
5.01483E-012
2.52558E-012
9.22201E-013
1.36634E-013
2.71490E-014
3.89523E-013

78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101

0.23
0.22
0.21
0.20
0.19
0.18
0.17
0.16
0.15
0.14
0.13
0.12
0.11
0.10
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0.00

0.77
0.78
0.79
0.80
0.81
0.82
0.83
0.84
0.85
0.86
0.87
0.88
0.89
0.90
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99
1.00

75.17961
75.47587
75.77321
76.07162
76.37108
76.67157
76.97309
77.2756
77.5791
77.88356
78.18898
78.49533
78.80259
79.11075
79.41979
79.72969
80.04043
80.352
80.66436
80.97752
81.29143
81.60609
81.92147
82.23754

1399.393 568.76985685
1411.872 575.89936016
1424.484 583.12888731
1437.23 590.45946774
1450.109 597.89212376
1463.124 605.42787048
1476.273 613.06771574
1489.559 620.81266019
1502.982 628.66369739
1516.542 636.62181388
1530.24 644.68798931
1544.077 652.86319644
1558.052 661.14840099
1572.168 669.54456131
1586.423 678.0526277
1600.818 686.67354131
1615.355 695.4082325
1630.033 704.25761853
1644.852 713.22260034
1659.814 722.30405855
1674.918 731.50284821
1690.165 740.81979256
1705.555 750.25567548
1721.088 759.81123286
Average Value of SEbp=

Root Mean Square of Average Value of SE bp=

Taking out the bubble and dew point temperature
Xacetone
1.00
0.99
0.98
0.97
0.96
0.95
0.94
0.93
0.92
0.91
0.90
0.89
0.88
0.87
0.86
0.85
0.84
0.83
0.82
0.81

Tbubble
56.09402
56.2951
56.4973
56.70062
56.90508
57.11068
57.31742
57.52532
57.73438
57.9446
58.15599
58.36857
58.58232
58.79727
59.01341
59.23076
59.44931
59.66907
59.89005
60.11226

Tdew
56.09402
56.71584
57.31203
57.88493
58.43655
58.96863
59.48271
59.98014
60.46209
60.92963
61.38369
61.82513
62.2547
62.6731
63.08095
63.47883
63.86726
64.24672
64.61767
64.98051

9.78641E-013
1.54088E-012
1.85584E-012
1.78454E-012
1.31856E-012
6.23142E-013
6.43435E-014
2.10344E-013
1.79617E-012
5.64376E-012
1.25337E-011
2.30328E-011
3.72920E-011
5.48427E-011
7.44337E-011
9.39638E-011
1.10574E-010
1.20959E-010
1.21945E-010
1.11335E-010
8.89739E-011
5.78802E-011
2.52119E-011
2.71396E-012
2.28467E-011 Average(ab)=
4.77983E-006

60.33569
60.56036
60.78627
61.01342
61.24182
61.47148
61.70239
61.93456
62.168
62.40272
62.6387
62.87596
63.11451
63.35434
63.59546
63.83786
64.08157
64.32656
64.57286
64.82045
65.06934
65.31954
65.57104
65.82385
66.07796
66.33338
66.5901
66.84813
67.10747
67.3681
67.63004
67.89329
68.15783
68.42366
68.6908
68.95922
69.22893
69.49993
69.7722
70.04575
70.32057
70.59666
70.874
71.1526
71.43244
71.71351
71.99582
72.27935
72.56409
72.85004

65.33563
65.68337
66.02408
66.35805
66.68558
67.00692
67.32234
67.63208
67.93634
68.23534
68.52929
68.81835
69.10271
69.38253
69.65798
69.92919
70.19631
70.45947
70.7188
70.97442
71.22645
71.47499
71.72014
71.96201
72.20069
72.43628
72.66885
72.89849
73.12529
73.34931
73.57063
73.78932
74.00545
74.21908
74.43027
74.63909
74.84558
75.04981
75.25183
75.45169
75.64944
75.84512
76.03878
76.23047
76.42023
76.60811
76.79413
76.97834
77.16078
77.34148

Temperature (C)

0.80
0.79
0.78
0.77
0.76
0.75
0.74
0.73
0.72
0.71
0.70
0.69
0.68
0.67
0.66
0.65
0.64
0.63
0.62
0.61
0.60
0.59
0.58
0.57
0.56
0.55
0.54
0.53
0.52
0.51
0.50
0.49
0.48
0.47
0.46
0.45
0.44
0.43
0.42
0.41
0.40
0.39
0.38
0.37
0.36
0.35
0.34
0.33
0.32
0.31

TXY Diagram - Temperatu

85
80
75
70
65

Temp

85
80

0.30
0.29
0.28
0.27
0.26
0.25
0.24
0.23
0.22
0.21
0.20
0.19
0.18
0.17
0.16
0.15
0.14
0.13
0.12
0.11
0.10
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0.00

73.13718
73.4255
73.71499
74.00564
74.29744
74.59038
74.88444
75.17961
75.47587
75.77321
76.07162
76.37108
76.67157
76.97309
77.2756
77.5791
77.88356
78.18898
78.49533
78.80259
79.11075
79.41979
79.72969
80.04043
80.352
80.66436
80.97752
81.29143
81.60609
81.92147
82.23754

77.52048
77.69781
77.87351
78.04761
78.22013
78.39112
78.56059
78.72857
78.89511
79.06021
79.2239
79.38622
79.54719
79.70683
79.86515
80.0222
80.17798
80.33253
80.48585
80.63798
80.78892
80.93871
81.08735
81.23487
81.38129
81.52662
81.67088
81.81409
81.95625
82.0974
82.23754

75
70
65
60
55
0.00

0.10

0.20

0.30

0.40

Mole Fraction of A

mm Hg

btained from ANCHEM book.

C
C

ared Error of bubble points

ab
3.169006
3.15977
3.150529
3.141281
3.132028
3.12277
3.113507
3.104239
3.094966
3.085689
3.076407
3.067122
3.057832
3.048539
3.039242
3.029942
3.020639
3.011333
3.002025
2.992714
2.983401
2.974087
2.964771
2.955454
2.946136
2.936817
2.927498

Yacetone
Yisopropanol
1.00
0.00
0.99
0.01
0.98
0.02
0.97
0.03
0.96
0.04
0.95
0.05
0.94
0.06
0.93
0.07
0.92
0.08
0.91
0.09
0.90
0.10
0.89
0.11
0.88
0.12
0.87
0.13
0.86
0.14
0.85
0.15
0.84
0.16
0.83
0.17
0.82
0.18
0.81
0.19
0.80
0.20
0.79
0.21
0.78
0.22
0.77
0.23
0.76
0.24
0.75
0.25
0.74
0.26

Tdew
56.09402259
56.71583538
57.31203132
57.88493167
58.43654821
58.96863165
59.48271256
59.98013576
60.46208914
60.92962763
61.3836931
61.82513081
62.25470303
62.67310028
63.08095079
63.47882823
63.86725832
64.24672436
64.61767192
64.98051288
65.33562889
65.68337436
66.02407906
66.35805044
66.68557561
67.00692317
67.32234472

Pacetone*
759.8118
776.0765
791.9297
807.4048
822.5308
837.3333
851.8349
866.0553
880.0122
893.7213
907.1966
920.4508
933.4953
946.3405
958.9959
971.4704
983.7719
995.9079
1007.885
1019.711
1031.39
1042.929
1054.333
1065.606
1076.754
1087.78
1098.69

PIsopropanol*
239.763412
247.1116046
254.3332781
261.438413
268.4357992
275.3331626
282.1372924
288.8541655
295.4890613
302.0466645
308.5311549
314.9462836
321.2954377
327.5816931
333.8078596
339.976516
346.0900412
352.150638
358.1603538
364.1210979
370.0346553
375.9026993
381.7268015
387.5084408
393.2490114
398.9498294
404.6121391

SEbp
9.17102E-013
3.82352E-013
2.28765E-011
1.40903E-010
4.14378E-010
8.40158E-010
1.35737E-009
1.87857E-009
2.32150E-009
2.62914E-009
2.77633E-009
2.76658E-009
2.62378E-009
2.38272E-009
2.08102E-009
1.75326E-009
1.42763E-009
1.12463E-009
8.57160E-010
6.31575E-010
4.49085E-010
3.07261E-010
2.01410E-010
1.25698E-010
7.40220E-011
4.05998E-011
2.03394E-011

2.918178
2.908859
2.89954
2.890223
2.880906
2.871591
2.862277
2.852966
2.843657
2.834351
2.825048
2.815748
2.806453
2.797162
2.787875
2.778594
2.769317
2.760047
2.750783
2.741526
2.732275
2.723033
2.713798
2.704571
2.695354
2.686145
2.676946
2.667758
2.65858
2.649413
2.640258
2.631115
2.621984
2.612867
2.603763
2.594673
2.585598
2.576538
2.567494
2.558466
2.549455
2.540461
2.531485
2.522527
2.513588
2.504669
2.49577
2.486891
2.478034
2.469199

0.73
0.72
0.71
0.70
0.69
0.68
0.67
0.66
0.65
0.64
0.63
0.62
0.61
0.60
0.59
0.58
0.57
0.56
0.55
0.54
0.53
0.52
0.51
0.50
0.49
0.48
0.47
0.46
0.45
0.44
0.43
0.42
0.41
0.40
0.39
0.38
0.37
0.36
0.35
0.34
0.33
0.32
0.31
0.30
0.29
0.28
0.27
0.26
0.25
0.24

0.27
0.28
0.29
0.30
0.31
0.32
0.33
0.34
0.35
0.36
0.37
0.38
0.39
0.40
0.41
0.42
0.43
0.44
0.45
0.46
0.47
0.48
0.49
0.50
0.51
0.52
0.53
0.54
0.55
0.56
0.57
0.58
0.59
0.60
0.61
0.62
0.63
0.64
0.65
0.66
0.67
0.68
0.69
0.70
0.71
0.72
0.73
0.74
0.75
0.76

67.63207637
67.93633992
68.23534405
68.52928533
68.81834915
69.10271053
69.38253492
69.65797889
69.92919073
70.196311026
70.45947324
70.71880412
70.9744242
71.22644817
71.47498526
71.7201396
71.96201052
72.20069283
72.43627715
72.66885007
72.89849447
73.12528969
73.34931174
73.57063349
73.78932484
74.00545289
74.21908208
74.43027433
74.63908919
74.84558396
75.04981378
75.25183177
75.4516891
75.64943513
75.84511746
76.03878202
76.23047316
76.42023374
76.60810514
76.79412742
76.97833928
77.16077819
77.34148043
77.52048113
77.69781432
77.87351297
78.04760908
78.22013365
78.39111679
78.5605877

1109.486
1120.173
1130.754
1141.232
1151.61
1161.892
1172.08
1182.177
1192.186
1202.108
1211.947
1221.704
1231.381
1240.982
1250.506
1259.958
1269.337
1278.646
1287.887
1297.061
1306.17
1315.215
1324.197
1333.118
1341.979
1350.781
1359.526
1368.214
1376.848
1385.427
1393.953
1402.428
1410.851
1419.224
1427.547
1435.823
1444.051
1452.232
1460.367
1468.457
1476.503
1484.506
1492.465
1500.382
1508.258
1516.093
1523.888
1531.643
1539.359
1547.037

410.2371179
415.8258817
421.379489
426.8989446
432.3852038
437.8391751
443.2617236
448.6536734
454.0158107
459.3488855
464.6536142
469.9306814
475.180742
480.4044226
485.6023234
490.7750196
495.9230627
501.0469818
506.1472851
511.2244607
516.2789778
521.3112877
526.3218248
531.3110072
536.2792379
541.2269053
546.1543842
551.0620361
555.9502101
560.8192435
565.6694625
570.5011823
575.3147081
580.1103354
584.8883501
589.6490298
594.3926432
599.1194513
603.8297073
608.5236569
613.201539
617.8635859
622.5100233
627.1410707
631.756942
636.3578452
640.9439832
645.5155534
650.0727485
654.6157563

9.02574E-012
3.36900E-012
9.60386E-013
1.69390E-013
1.04538E-014
5.42730E-016
2.12896E-014
1.95181E-013
7.80643E-013
2.08820E-012
4.41718E-012
8.01212E-012
1.30355E-011
1.95548E-011
2.75411E-011
3.68752E-011
4.73605E-011
5.87398E-011
7.07114E-011
8.29497E-011
9.51212E-011
1.06901E-010
1.17984E-010
1.28100E-010
1.37020E-010
1.44558E-010
1.50580E-010
1.55001E-010
1.57783E-010
1.58937E-010
1.58511E-010
1.56592E-010
1.53294E-010
1.48759E-010
1.43141E-010
1.36611E-010
1.29340E-010
1.21503E-010
1.13270E-010
1.04802E-010
9.62483E-011
8.77442E-011
7.94100E-011
7.13479E-011
6.36436E-011
5.63647E-011
4.95625E-011
4.32721E-011
3.75139E-011
3.22953E-011

2.460386
2.451596
2.442829
2.434087
2.425369
2.416677
2.40801
2.39937
2.390757
2.382171
2.373614
2.365085
2.356585
2.348115
2.339675
2.331265
2.322887
2.31454
2.306226
2.297944
2.289695
2.28148
2.273298
2.265152
2.708637

0.23
0.22
0.21
0.20
0.19
0.18
0.17
0.16
0.15
0.14
0.13
0.12
0.11
0.10
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0.00

0.77
0.78
0.79
0.80
0.81
0.82
0.83
0.84
0.85
0.86
0.87
0.88
0.89
0.90
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99
1.00

78.72857474
78.89510546
79.06020662
79.22390422
79.38622355
79.54718918
79.70682504
79.86515439
80.02219987
80.17798352
80.33252682
80.48585065
80.6379754
80.78892089
80.93870648
81.08735102
81.23487289
81.38129002
81.5266199
81.6708796
81.81408577
81.95625466
82.09740214
82.23754369

1554.677 659.1447599
1562.28 663.6599384
1569.846 668.1614661
1577.375 672.6495137
1584.869 677.1242476
1592.328 681.5858306
1599.753 686.0344217
1607.143 690.4701765
1614.499 694.8932471
1621.822 699.3037821
1629.113 703.7019271
1636.37 708.0878246
1643.596 712.4616139
1650.791 716.8234315
1657.954 721.1734109
1665.087 725.5116831
1672.189 729.838376
1679.262 734.1536152
1686.304 738.4575237
1693.318 742.7502218
1700.303 747.0318275
1707.259 751.3024564
1714.187 755.5622219
1721.088 759.811235
Average Value of SEbp=

Root Mean Square of Average Value of SE bp=

2.76119E-011
2.34496E-011
1.97865E-011
1.65937E-011
1.38382E-011
1.14836E-011
9.49168E-012
7.82393E-012
6.44233E-012
5.31043E-012
4.39402E-012
3.66172E-012
3.08548E-012
2.64079E-012
2.30691E-012
2.06689E-012
1.90761E-012
1.81969E-012
1.79737E-012
1.83837E-012
1.94375E-012
2.11781E-012
2.36799E-012
2.70477E-012
3.28186E-010
1.81159E-005

Diagram - Temperature (C) vs. Mole Fraction of Acetone in Binary Mixture

Tbubbl
e

Tbubbl
e

0.20

0.30

0.40

0.50

0.60

0.70

Mole Fraction of Acetone in Binary Mixture

0.80

0.90

1.00

56.09405
56.35549
56.61692
56.87836
57.13979
57.40123
57.66266
57.9241
58.18553
58.44697
58.7084
58.96984
59.23127
59.49271
59.75415
60.01558
60.27702
60.53845
60.79989
61.06132
61.32276

56.09405
56.35549
56.61692
56.87836
57.13979
57.40123
57.66266
57.9241
58.18553
58.44697
58.7084
58.96984
59.23127
59.49271
59.75415
60.01558
60.27702
60.53845
60.79989
61.06132
61.32276

61.58419 61.58419
61.84563 61.84563
62.10706 62.10706
62.3685 62.3685
62.62993 62.62993
62.89137
63.1528
63.41424
63.67568
63.93711
64.19855
64.45998
64.72142
64.98285
65.24429
65.50572
65.76716
66.02859
66.29003
66.55146
66.8129
67.07433
67.33577
67.59721
67.85864
68.12008

62.89137
63.1528
63.41424
63.67568
63.93711
64.19855
64.45998
64.72142
64.98285
65.24429
65.50572
65.76716
66.02859
66.29003
66.55146
66.8129
67.07433
67.33577
67.59721
67.85864
68.12008

n Binary Mixture

Tbubbl
e

68.38151
68.64295
68.90438
69.16582
69.42725
69.68869
69.95012
70.21156
70.47299
70.73443
70.99587
71.2573
71.51874
71.78017
72.04161
72.30304
72.56448
72.82591
73.08735
73.34878
73.61022
73.87165
74.13309
74.39452
74.65596
74.9174
75.17883
75.44027
75.7017
75.96314
76.22457
76.48601
76.74744
77.00888
77.27031
77.53175
77.79318
78.05462
78.31605
78.57749
78.83893
79.10036
79.3618
79.62323
79.88467
80.1461
80.40754
80.66897
80.93041
81.19184

68.38151
68.64295
68.90438
69.16582
69.42725
69.68869
69.95012
70.21156
70.47299
70.73443
70.99587
71.2573
71.51874
71.78017
72.04161
72.30304
72.56448
72.82591
73.08735
73.34878
73.61022
73.87165
74.13309
74.39452
74.65596
74.9174
75.17883
75.44027
75.7017
75.96314
76.22457
76.48601
76.74744
77.00888
77.27031
77.53175
77.79318
78.05462
78.31605
78.57749
78.83893
79.10036
79.3618
79.62323
79.88467
80.1461
80.40754
80.66897
80.93041
81.19184

Tbubbl
e

81.45328
81.71471
81.97615
82.23758

81.45328
81.71471
81.97615
82.23758

Equilibrium Diagram for Mixture of Acetone and Isopropanol at 101.3 kPa

Xacetone
1.00
0.99
0.98
0.97
0.96
0.95
0.94
0.93
0.92
0.91
0.90
0.89
0.88
0.87
0.86
0.85
0.84
0.83
0.82
0.81
0.80
0.79
0.78
0.77
0.76
0.75
0.74
0.73
0.72
0.71
0.70
0.69
0.68
0.67
0.66
0.65
0.64
0.63
0.62
0.61
0.60
0.59

Tbubble
56.09402
56.2951
56.4973
56.70062
56.90508
57.11068
57.31742
57.52532
57.73438
57.9446
58.15599
58.36857
58.58232
58.79727
59.01341
59.23076
59.44931
59.66907
59.89005
60.11226
60.33569
60.56036
60.78627
61.01342
61.24182
61.47148
61.70239
61.93456
62.168
62.40272
62.6387
62.87596
63.11451
63.35434
63.59546
63.83786
64.08157
64.32656
64.57286
64.82045
65.06934
65.31954

Total System Pressure=

Pacetone* Yacetone 45 Line

759.8118
1.00
1.00
765.0414
1.00
0.99
770.3289
0.99
0.98
775.6752
0.99
0.97
781.081
0.99
0.96
786.5471
0.98
0.95
792.0742
0.98
0.94
797.6633
0.98
0.93
803.315
0.97
0.92
809.0302
0.97
0.91
814.8098
0.97
0.90
820.6546
0.96
0.89
826.5654
0.96
0.88
832.5432
0.95
0.87
838.5887
0.95
0.86
844.7028
0.94
0.85
850.8865
0.94
0.84
857.1406
0.94
0.83
863.4661
0.93
0.82
869.8639
0.93
0.81
876.3348
0.92
0.80
882.8798
0.92
0.79
889.4999
0.91
0.78
896.1961
0.91
0.77
902.9692
0.90
0.76
909.8202
0.90
0.75
916.7502
0.89
0.74
923.7601
0.89
0.73
930.8508
0.88
0.72
938.0235
0.88
0.71
945.2791
0.87
0.70
952.6187
0.87
0.69
960.0432
0.86
0.68
967.5536
0.85
0.67
975.1511
0.85
0.66
982.8367
0.84
0.65
990.6114
0.83
0.64
998.4762
0.83
0.63
1006.432
0.82
0.62
1014.481
0.81
0.61
1022.623
0.81
0.60
1030.859
0.80
0.59

le F r a c t io n o f A c e t o n e in V a p o u r, Y a c e t o n e

Using Raoult's Law,

PA=YAP=XAPA*

101.3

Equilibrium Diagram for

65.57104
65.82385
66.07796
66.33338
66.5901
66.84813
67.10747
67.3681
67.63004
67.89329
68.15783
68.42366
68.6908
68.95922
69.22893
69.49993
69.7722
70.04575
70.32057
70.59666
70.874
71.1526
71.43244
71.71351
71.99582
72.27935
72.56409
72.85004
73.13718
73.4255
73.71499
74.00564
74.29744
74.59038
74.88444
75.17961
75.47587
75.77321
76.07162
76.37108
76.67157
76.97309
77.2756
77.5791
77.88356
78.18898
78.49533
78.80259
79.11075
79.41979

1039.191
1047.619
1056.145
1064.77
1073.495
1082.321
1091.249
1100.28
1109.415
1118.656
1128.003
1137.458
1147.022
1156.695
1166.479
1176.375
1186.384
1196.507
1206.746
1217.1
1227.572
1238.162
1248.872
1259.702
1270.653
1281.726
1292.923
1304.244
1315.69
1327.262
1338.961
1350.789
1362.745
1374.83
1387.046
1399.393
1411.872
1424.484
1437.23
1450.109
1463.124
1476.273
1489.559
1502.982
1516.542
1530.24
1544.077
1558.052
1572.168
1586.423

0.79
0.79
0.78
0.77
0.76
0.75
0.75
0.74
0.73
0.72
0.71
0.70
0.69
0.69
0.68
0.67
0.66
0.65
0.64
0.62
0.61
0.60
0.59
0.58
0.57
0.56
0.54
0.53
0.52
0.51
0.49
0.48
0.47
0.45
0.44
0.42
0.41
0.39
0.38
0.36
0.35
0.33
0.31
0.30
0.28
0.26
0.24
0.23
0.21
0.19

0.58
0.57
0.56
0.55
0.54
0.53
0.52
0.51
0.50
0.49
0.48
0.47
0.46
0.45
0.44
0.43
0.42
0.41
0.40
0.39
0.38
0.37
0.36
0.35
0.34
0.33
0.32
0.31
0.30
0.29
0.28
0.27
0.26
0.25
0.24
0.23
0.22
0.21
0.20
0.19
0.18
0.17
0.16
0.15
0.14
0.13
0.12
0.11
0.10
0.09

M o le F r a c t io n o f A c e t o n

0.58
0.57
0.56
0.55
0.54
0.53
0.52
0.51
0.50
0.49
0.48
0.47
0.46
0.45
0.44
0.43
0.42
0.41
0.40
0.39
0.38
0.37
0.36
0.35
0.34
0.33
0.32
0.31
0.30
0.29
0.28
0.27
0.26
0.25
0.24
0.23
0.22
0.21
0.20
0.19
0.18
0.17
0.16
0.15
0.14
0.13
0.12
0.11
0.10
0.09

Equilibrium Diagram for

f(x) = 0.5787049595x^3 - 1.
Equilibrium Line

Polynomial (Equil
Line)

0.00

0.10

0.20

0.30

Mole Fraction

0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0.00

79.72969
80.04043
80.352
80.66436
80.97752
81.29143
81.60609
81.92147
82.23754

1600.818
1615.355
1630.033
1644.852
1659.814
1674.918
1690.165
1705.555
1721.088

0.17
0.15
0.13
0.11
0.09
0.07
0.04
0.02
0.00

0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0.00

kPa

759.8125 mm Hg

ium Diagram for the Acetone and Isopropanol System at 101.3kPa

ium Diagram for the Acetone and Isopropanol System at 101.3kPa

.5787049595x^3 - 1.7814359975x^2 + 2.2026508424x + 0.0030314695

Equilibrium Line

Polynomial (Equilibrium
Line)

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

Mole Fraction of Acetone in Liquid, Xacetone

0.90

1.00

Mole Fraction of Acetone Bubble Point Temp. Dew Point Temp.

1.00
56.06
56.06
0.95
57.07
58.93
0.90
58.12
61.34
0.85
59.19
63.44
0.80
60.29
65.3
0.75
61.43
66.97
0.70
62.6
68.49
0.65
63.8
69.9
0.60
65.03
71.2
0.55
66.29
72.41
0.50
67.59
73.55
0.45
68.92
74.62
0.40
70.28
75.63
0.35
71.68
76.59
0.30
73.11
77.51
0.25
74.56
78.38
0.20
76.05
79.22
0.15
77.56
80.02
0.10
79.1
80.79
0.05
80.66
81.53
0.00
82.24
82.25

Temperature (C)

TXY Diagram - Temperature (C) vs. Mole Fraction of A

85
80
75

Bubble P
Dew Poin

70
65
60
55
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
Mole Fraction of Acetone in Binary Mixture

ole Fraction of Acetone in Binary Mixture at 101.32kPa

0 1.00

Bubble Point Temp.

Dew Point Temp.

Density of Feed @ 40C

Density of Acetone=
Density of Isopropanol=
Density of Feed=
Mr Acetone=
Mr Isopropanol=
1 k mole of Acetone=
1 k mole of Isopropanol=
1 k mole of Feed=
900 k mole of Feed=

0.7678829247 g/cm3
0.7678375116 g/cm3
0.767880654 g/cm3

=
=
=

767.88292466
767.83751159
767.88065401

58.08 g/mole
60.096 g/mole
58.08 kg
60.096 kg
58.1808 kg
52362.72 kg

Feed Volumetric Flowrate=

68.191221809 m3/hr

=
=

68191.221809
18.942006058

Density of Distillate @ 28C

Density of Acetone=
Density of Isopropanol=
Density of Distillate=

0.7821028306 g/cm3
0.7797398331 g/cm3
0.7821025943 g/cm3

=
=
=

782.10283059
779.73983306
782.10259429

Mr Acetone=
Mr Isopropanol=

58.08 g/mole
60.096 g/mole

1 k mole of Acetone=
1 k mole of Isopropanol=
1 k mole of Distillate=
837.9838 k mole of Distillate=

58.08
60.096
58.0802016
48670.268042

Distillate Volumetric Flowrate=

62.230030173 m3/hr

=
=

62230.030173
17.286119493

Density of Bottoms @ 73.83997C

Density of Acetone=
Density of Isopropanol=
Density of Bottoms=

0.7257604241 g/cm3
0.732127436 g/cm3
0.7303720508 g/cm3

=
=
=

725.76042409
732.12743596
730.37205079

=
=

5055.8271955
1.4043964432

Mr Acetone=
Mr Isopropanol=

kg
kg
kg
kg

58.08 g/mole
60.096 g/mole

1 k mole of Acetone=
1 k mole of Isopropanol=
1 k mole of Bottoms=
62.0162 k mole of Bottoms=

58.08
60.096
59.5401888
3692.6348772

kg
kg
kg
kg

Bottoms Volumetric Flowrate=

5.0558271955 m3/hr

Density of Overhead Vapor @ 56.09603C

External reflux ratio=
Overhead distillate molar flow rate=

0.8120258617
837.9838 kmole/hr

Given that the the R:D ~ 0.8120:1, overhead vapor molar flow rate can be found
Overhead vapor molar flow rate=
Overhead vapor mass flow rate=

1518.4483173 kmole/hr
88191.784388 kg/hr

Ideal gas law, PV=nRT is used to find V, the volumetric flow rate of the overhead vapor
P=
101300 Pa
n=
1518.448317301 kmole/hr
R=
8314 m3.Pa/(kmole.K)
T=
329.24603 K
Rearranging the Ideal Gas eqn, V=(nRT/P)
V=
V=

41031.8535937305 m3/hr
11.3977371094 m3/s

n (m/M)=
m=
m=

1518.448317301 kmole/hr
88191.7843880213 kg/hr
24.4977178856 kg/s

Density of Overhead Vapor (m/V)=

2.1493492656 kg/m3

NOTE: External reflux mass flow rate is therefore=

39521.516346 kg/hr

Viscosity of Feed (Liquid) @ 40C

Viscosity of Acetone=
Viscosity of Isopropanol=
Viscosity of Feed=

0.2498357692 cP
0.9732527699 cP
0.2860066193 cP

=
=
=

0.0002498358
0.0009732528
0.0002860066

Viscosity of Distillate (Liquid) @ 28C

Viscosity of Acetone=
Viscosity of Isopropanol=
Viscosity of Feed=

0.2998292659 cP
1.7941643727 cP
0.2999786994 cP

=
=
=

0.0002998293
0.0017941644
0.0002999787

Viscosity of Bottoms (Liquid) @ 73.83997C

Viscosity of Acetone=
0.2083496074 cP
Viscosity of Isopropanol=
0.5453462731 cP
Viscosity of Feed=
0.4524362923 cP

=
=
=

0.0002083496
0.0005453463
0.0004524363

Viscosity of Overhead Vapor (Gas) @ 56.09603C

Viscosity of Acetone=
83.08832627 P
Viscosity of Isopropanol=
85.575161836 P
Viscosity of Feed=
83.088574954 P

=
=
=

8.30883E-006
8.55752E-006
8.30886E-006

Calculations for Overhead Vapor Temperature

Overhead Vapor Tempeature of 0.9999 Acetone

sd

56.096033363

Calculations for Feed @ 40C

Heat Capacity for Feed
CpL of Acetone=
CpL of Isopropanol=
CpL of Feed=

132.36781449 J/mol.K
177.81043103 J/mol.K
134.63994532 J/mol.K

Heat Capacity for Distillate

CpL of Acetone=
CpL of Isopropanol=
CpL of Feed=

128.06642112 J/mol.K
172.99081998 J/mol.K
128.07091356 J/mol.K

Heat Capacity for Bottoms

CpL of Acetone=
CpL of Isopropanol=
CpL of Feed=

137.90022719 J/mol.K
184.0298008 J/mol.K
171.31187735 J/mol.K

Heat of Vaporization for Feed

of Acetone=
of Isopropanol=
of Feed=

30.291215651 kJ/mol
42.436731978 kJ/mol
30.898491468 kJ/mol

=
=
=

30291.215651
42436.731978
30898.491468

Heat of Vaporization for Overhead Vapor

of Acetone (@ 329.246K)=
29.807066338 kJ/mol
of Isopropanol (@ 329.246K)=
41.976113919 kJ/mol
of Feed (@ 329.246K)=
29.808283243 kJ/mol

=
=
=

29807.066338
41976.113919
29808.283243

Given that q=1+(((CpL*(Tb-Tf))/)

q=
1.030984719

Equilibrium Diagram for Mixture of Acetone and Isopropanol at 101.3 kPa

Using Raoult's Law,
PA=YAP=XAPA*
Xacetone

Total System Pressure=

Tbubble
1.00
0.99
0.98
0.97
0.96
0.95
0.94
0.93
0.92
0.91
0.90
0.89
0.88
0.87
0.86
0.85
0.84
0.83
0.82
0.81
0.80
0.79
0.78
0.77
0.76
0.75
0.74

56.0940226016
56.2950987829
56.4972957274
56.7006199772
56.905078034
57.1106763552
57.3174213504
57.5253193775
57.7343767381
57.9445996748
58.1559943653
58.3685669189
58.5823233723
58.7972696842
59.0134117315
59.2307553035
59.4493060978
59.6690697146
59.8900516518
60.1122572996
60.3356919354
60.5603607176
60.7862686801
61.0134207266
61.2418216252
61.4714760009
61.7023883308

Pacetone*
Yacetone
45 Line
759.8117573
1.00
1.00
765.04136554
1.00
0.99
770.32893106
0.99
0.98
775.67521989
0.99
0.97
781.08100749
0.99
0.96
786.54707868
0.98
0.95
792.07422777
0.98
0.94
797.66325848
0.98
0.93
803.314984
0.97
0.92
809.03022703
0.97
0.91
814.80981967
0.97
0.90
820.65460353
0.96
0.89
826.56542966
0.96
0.88
832.54315851
0.95
0.87
838.58865996
0.95
0.86
844.70281325
0.94
0.85
850.88650692
0.94
0.84
857.14063881
0.94
0.83
863.46611597
0.93
0.82
869.86385456
0.93
0.81
876.33477985
0.92
0.80
882.87982609
0.92
0.79
889.49993637
0.91
0.78
896.19606261
0.91
0.77
902.96916536
0.90
0.76
909.8202137
0.90
0.75
916.75018513
0.89
0.74

Feedline
2.6136986752
2.2809589402
1.9482192051
1.6154794701
1.282739735
0.95

0.73
0.72
0.71
0.70
0.69
0.68
0.67
0.66
0.65
0.64
0.63
0.62
0.61
0.60
0.59
0.58
0.57
0.56
0.55
0.54
0.53
0.52
0.51
0.50
0.49
0.48
0.47
0.46
0.45
0.44
0.43
0.42
0.41
0.40
0.39
0.38
0.37
0.36
0.35
0.34
0.33
0.32
0.31
0.30
0.29
0.28
0.27
0.26
0.25
0.24

61.9345629376
62.1680039825
62.4027154587
62.6387011857
62.8759648017
63.1145097572
63.3543393073
63.5954565052
63.837864195
64.0815650038
64.3265613351
64.5728553601
64.8204490118
65.0693439748
65.3195416796
65.5710432935
65.8238497123
66.0779615526
66.3333791437
66.5901025175
66.8481314018
67.1074652102
67.3681030338
67.6300436315
67.8932854211
68.1578264707
68.423664487
68.6907968081
68.9592203917
69.2289318056
69.4999272185
69.772202388
70.0457526512
70.3205729148
70.5966576433
70.8740008495
71.1525960843
71.4324364259
71.7135144716
71.9958223261
72.2793515962
72.5640933804
72.8500382635
73.1371763102
73.425497063
73.7149895374
74.0056422242
74.29744309
74.5903795826
74.884438639

923.76006536
930.85084821
938.02353536
945.27913623
952.61866772
960.04315407
967.55362652
975.15112317
982.83668862
990.61137378
998.47623553
1006.4323364
1014.4807443
1022.622532
1030.858777
1039.1905611
1047.6189697
1056.1450918
1064.7700192
1073.4948464
1082.3206695
1091.2485864
1100.2796957
1109.4150965
1118.6558873
1128.0031661
1137.458029
1147.02157
1156.6948801
1166.4790465
1176.375152
1186.384274
1196.5074835
1206.7458448
1217.1004138
1227.5722378
1238.162354
1248.8717887
1259.7015563
1270.6526582
1281.726082
1292.9228
1304.2437686
1315.6899272
1327.2621969
1338.9614801
1350.7886592
1362.7445959
1374.8301306
1387.0460818

0.89
0.88
0.88
0.87
0.87
0.86
0.85
0.85
0.84
0.83
0.83
0.82
0.81
0.81
0.80
0.79
0.79
0.78
0.77
0.76
0.75
0.75
0.74
0.73
0.72
0.71
0.70
0.69
0.69
0.68
0.67
0.66
0.65
0.64
0.62
0.61
0.60
0.59
0.58
0.57
0.56
0.54
0.53
0.52
0.51
0.49
0.48
0.47
0.45
0.44

0.73
0.72
0.71
0.70
0.69
0.68
0.67
0.66
0.65
0.64
0.63
0.62
0.61
0.60
0.59
0.58
0.57
0.56
0.55
0.54
0.53
0.52
0.51
0.50
0.49
0.48
0.47
0.46
0.45
0.44
0.43
0.42
0.41
0.40
0.39
0.38
0.37
0.36
0.35
0.34
0.33
0.32
0.31
0.30
0.29
0.28
0.27
0.26
0.25
0.24

0.23
0.22
0.21
0.20
0.19
0.18
0.17
0.16
0.15
0.14
0.13
0.12
0.11
0.10
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0.00

75.1796066949
75.4758696997
75.7732131331
76.0716220252
76.3710809806
76.6715742049
76.973085533
77.2755984598
77.5790961717
77.8835615769
78.1889773347
78.4953258796
78.8025894405
79.110750051
79.4197895472
79.7296895524
80.0404314421
80.3519962899
80.6643647868
80.9775171353
81.2914329146
81.6060909153
81.921468948
82.2375436247

1399.3932455
1411.8723947
1424.4842795
1437.229627
1450.1091411
1463.1235032
1476.2733721
1489.5593846
1502.9821566
1516.5422828
1530.2403378
1544.0768765
1558.052434
1572.1675254
1586.4226455
1600.8182667
1615.3548372
1630.0327773
1644.852475
1659.8142794
1674.9184936
1690.1653646
1705.5550725
1721.0877173

0.42
0.41
0.39
0.38
0.36
0.35
0.33
0.31
0.30
0.28
0.26
0.24
0.23
0.21
0.19
0.17
0.15
0.13
0.11
0.09
0.07
0.04
0.02
0.00

0.23
0.22
0.21
0.20
0.19
0.18
0.17
0.16
0.15
0.14
0.13
0.12
0.11
0.10
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0.00

Minimum External Reflux Ratio & External Reflux Ratio Calculation

Coefficients for equation of Yacetone/Xacetone curve in the Equilibrium Diagram
x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
0.003
Coefficients for equation of Feed Line curve
x^3
x^2
x^1
C
0
0 33.273973504 -30.66027483
Coefficients of overall equation to find the roots of the Yacetone/Xacetone and Feed Line curves
x^3
x^2
x^1
C
0.5787
-1.7814 -31.0712735 30.663274829
Solving for the roots of the overall equation
x
f(x)=0
0.951034206 1.6330438512569E-007
When the value of x is at

0.951034206 , the value of y is at

Finding the minimum external reflux equation and ratio

Coordinates
X
Y
1st min. ext. reflux coordinate=
0.9999
0.9999
2nd min. ext. reflux coordinate=
0.951034206 0.9844121437

0.9844121437

Gradient of the minimum reflux line=

Coefficients for minimum reflux line
x^3
x^2
0

0.3169467857

x^1
C
0 0.3169467857 0.682984909

Minimum reflux ratio is therefore=

Finding the reflux ratio
Reflux ratio multiplier=
Reflux ratio=

0.4640147781

1.75
0.8120258617

Calculations for operating line, internal reflux ratio, enriching line, and the number of total theoretical numb
External reflux ratio=
0.8120258617
Y-intercept of this reflux ratio=
0.5518133163
Finding the equation for the operating line and internal reflux ratio
Coordinates
X
Y
1st operating line coordinate=
0.9999
0.9999
2nd operating line coordinate=
0 0.5518133163
Gradient of operating line=

0.4481314968

Equation of operating line=

y=(0.4481)*x+0.5518

Internal reflux ratio (slope of operating line, L/V)=

0.4481314968

Finding the Intersection point of the feed line and the operating line
Coefficients of the feed line
x^3
x^2
x^1
C
0
0 33.273973504 -30.66027483
Coefficients of the operating line
x^3
x^2
0

x^1
C
0 0.4481314968 0.5518133163

Coefficients of the overall equation to find the intersection point

x^3
x^2
x^1
C
0
0 32.825842007 -31.21208814
Solving for the roots of the overall equation
x
f(x)=0
0.9508389195
0
When x=0.9508, (overall eqn) Y=(32.8258)*x-31.2121=0
x-coordinate of the intersection point is therefore=
y-coordinate of the intersection point is therefore=

0.950839
0.977914

Finding the equation of the enriching line

Coordinates
X
Y
1st enriching line coordinate=
0.2757
0.2757
2nd enriching line coordinate=
0.9508389195 0.9779141846
Gradient of enriching line=
Y-intercept, C, of enriching line=
Equation of enriching line=

1.0401032503
-0.011056466
y=(1.0401)*x-0.0111

Finding the theoretical number of trays required

1st Tray
Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram
x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
0.003
Coefficients for the 1st tray horizontal line
x^3
x^2
x^1
0
0

C
0

0.9999

Coefficients for overall equation to find 1st tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
-0.9969
Solving for the roots of the overall equation to find 1st tray intersection point
x
f(x)=0
0.9938796097
0.0007969037
2nd Tray
Coefficients of the operating line
x^3
x^2
0

x^1
C
0 0.4481314968 0.5518133163

Substituting x=0.9939 into the coefficients above,

y=
0.9972020735

Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
0.003
Coefficients for the 2nd tray horizontal line
x^3
x^2
x^1
0
0

C
0 0.9972020735

Coefficients for overall equation to find 2nd tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
-0.9942
Solving for the roots of the overall equation to find 2nd tray intersection point
x
f(x)=0
0.9845881741 -9.798311597309E-006
3rd Tray
Coefficients of the operating line
x^3
x^2
0

x^1
C
0 0.4481314968 0.5518133163

Substituting x=0.9846 into the coefficients above,

y=
0.9930382885
Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram
x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
0.003
Coefficients for the 3rd tray horizontal line
x^3
x^2
x^1
0
0

C
0

0.9930

Coefficients for overall equation to find 3rd tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
-0.9900
Solving for the roots of the overall equation to find 3rd tray intersection point
x
f(x)=0
0.9735788483
-0.000014938
4th Tray
Coefficients of the operating line
x^3
x^2
0

x^1
C
0 0.4481314968 0.5518133163

Substituting x=0.9736 into the coefficients above,

y=
0.9881046629
Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram
x^3
x^2
x^1
C

0.5787

-1.7814

Coefficients for the 4th tray horizontal line

x^3
x^2
x^1
0
0

2.2027

0.003

C
0 0.9881046629

Coefficients for overall equation to find 4th tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027 -0.985104663
Solving for the roots of the overall equation to find 4th tray intersection point
x
f(x)=0
0.9612015475
0.0002051295
5th Tray
Coefficients of the operating line
x^3
x^2
0

x^1
C
0 0.4481314968 0.5518133163

Substituting x=0.9612 into the coefficients above,

y=
0.9825580045
Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram
x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
0.003
Coefficients for the 5th tray horizontal line
x^3
x^2
x^1
0
0

C
0 0.9825580045

Coefficients for overall equation to find 5th tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027 -0.979558005
Solving for the roots of the overall equation to find 5th tray intersection point
x
f(x)=0
0.9462510464 1.1660072616881E-005
x-coordinate threshold for transition from operating line to enriching line=
Hence the enriching line eqn will be used to find the horizontal line for the next tray
6th Tray
Coefficients of the enriching line
x^3
x^2
0

x^1
C
0 1.0401032503 -0.011056466

Substituting x=0.9463 into the coefficients above,

y=
0.9731423228
Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram

0.9508389195

x^3

x^2
0.5787

x^1
-1.7814

Coefficients for the 6th tray horizontal line

x^3
x^2
x^1
0
0

C
2.2027

0.003

C
0 0.9731423228

Coefficients for overall equation to find 6th tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027 -0.970142323
Solving for the roots of the overall equation to find 6th tray intersection point
x
f(x)=0
0.9213553045
-0.0002743976
7th Tray
Coefficients of the enriching line
x^3
x^2
0

x^1
C
0 1.0401032503 -0.011056466

Substituting x=0.9214 into the coefficients above,

y=
0.9472481807
Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram
x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
0.003
Coefficients for the 7th tray horizontal line
x^3
x^2
x^1
0
0

C
0 0.9472481807

Coefficients for overall equation to find 7th tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027 -0.944248181
Solving for the roots of the overall equation to find 7th tray intersection point
x
f(x)=0
0.8561725367
-0.0009861832
8th Tray
Coefficients of the enriching line
x^3
x^2
0

x^1
C
0 1.0401032503 -0.011056466

Substituting x=0.8562 into the coefficients above,

y=
0.8794513721
Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram
x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
0.003

Coefficients for the 8th tray horizontal line

x^3
x^2
x^1
0
0

C
0 0.8794513721

Coefficients for overall equation to find 8th tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027 -0.876451372
Solving for the roots of the overall equation to find 8th tray intersection point
x
f(x)=0
0.7164116924 7.7979130353345E-005
9th Tray
Coefficients of the enriching line
x^3
x^2
0

x^1
C
0 1.0401032503 -0.011056466

Substituting x=0.7164 into the coefficients above,

y=
0.7340856637
Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram
x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
0.003
Coefficients for the 9th tray horizontal line
x^3
x^2
x^1
0
0

C
0 0.7340856637

Coefficients for overall equation to find 9th tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027 -0.731085664
Solving for the roots of the overall equation to find 9th tray intersection point
x
f(x)=0
0.5032281892 3.4884676310965E-006
10th Tray
Coefficients of the enriching line
x^3
x^2
0

x^1
C
0 1.0401032503 -0.011056466

Substituting x=0.5032 into the coefficients above,

y=
0.5123528091
Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram
x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
0.003
Coefficients for the 10th tray horizontal line

x^3

x^2

x^1

C
0 0.5123528091

Coefficients for overall equation to find 10th tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027 -0.509352809
Solving for the roots of the overall equation to find 10th tray intersection point
x
f(x)=0
0.2946523357
-0.0001791166
11th Tray
Coefficients of the enriching line
x^3
x^2
0

x^1
C
0 1.0401032503 -0.011056466

Substituting x=0.2947 into the coefficients above,

y=
0.295412386
Coefficients for the equation of Yacetone/Xacetone curve in the Equilibrium Diagram
x^3
x^2
x^1
C
0.5787
-1.7814
2.2027
0.003
Coefficients for the 11th tray horizontal line
x^3
x^2
x^1
0
0

C
0.295412386

Coefficients for overall equation to find 11th tray intersection point

x^3
x^2
x^1
C
0.5787
-1.7814
2.2027 -0.292412386
Solving for the roots of the overall equation to find 11th tray intersection point
x
f(x)=0
0.1502870453
0.0003541859

Number of total theoretical stages=

Number of completed theoretical stages
Number of unfinished theoretical stages=
Number of total theoretical stages=

10
0.1312804184
10.131280418

Calculations for the number of actual trays needed for the distillation
Using O'Connell Correlation to estimate overall column efficiency
Eoc=0.492(L)^-0.245
where uL is the visosity of the feed of in cP
a is the average relative volatility
Eoc=

0.5237559902

Relative Volatility=

Eoc=

52.375599019 %

Therefore total actual trays required is found.

Number of total actual trays required=
Number of total actual trays required (rounded up)=

19.343512262
20

The O'Connell correlation was based on data for bubble-cap trays.

For sieve and valve trays, its prediction are likely to be slightly conservative.
Which means it is good, because you are overdesigning the column.
It is needed to account for heat losses, pressure drops, and other factors which are not taken into account for this i

Estimating the gas velocity for column entrainment flood prediction

Assumptions made:
System is low or nonfoaming.
Weir height is less than 15% of tray spacing.
Sieve perforations are 13mm or less in diameter.
Ratio of slot (bubble cap), perforation (sieve), or full valve opening (valve plate) area Ah to active area Aa is 0.1 or g
First of all, dimensionless flow parameter FLG needs to be found.
FLG=

(L/G)*(G/L)^0.5

*Values of L, G, G, L are taken under the conditions of the top tray.

To ensure that the distillation column is not under-designed, values will be slightly modified.
Considering that the liquid flow at the top tray is only the external reflux coming in,
L=
Mass flow rate of external reflux
L=
39521.5163464872 kg/hr
Considering that the vapor mass flow rate at top tray is of the same mass flow rate going into the condensor,,
G=
Mass flow rate of overhead vapor
G=
88191.7843880213 kg/hr
From previous calculations, G & L are already known.
G=
2.1493492656 kg/m3
L=
730.3720507883 kg/m3
FLG is then calculated and derived.
FLG=
FLG=

(L/G)*(G/L)^0.5
0.0243101083

FLG is linked to Csbf (capacity parameter corrected for surface tension, m/s) via the following equation
Csbf=

0.0105+8.127(10^-4)(TS^0.755)exp[-1.463FLG^0.842]

where

TS is plate/tray spacing, mm

Usually, tray spacing is 24inches for columns with greater than 1.5m and lesser than 6m diameter(REFERENCE N
Assuming that tray spacing is 24inches,
Tray spacing=
Tray spacing=

24 inches
609.6012192 mm

39.37

With tray spacing derived, Csbf can be calculated

0.0105+8.127(10^-4)(TS^0.755)exp[-1.463FLG^0.842]
Csbf=
Csbf=

0.1070720852 m/s

Csbf is related to Unf (gas velocity through net area at flood, m/s) by the following equation
Unf=
Csbf((/20)^0.2)*((L-G)/G)^0.5
where

is surface tension of liquid at the top tray, dynes/cm

Calculating the surface tension of liquid at the top tray

Surface Tension of Top Tray Liquid @ 56.09603C
Surface Tension of Pure Acetone=
19.24370494 dynes/cm
Surface Tension of Pure Isopropanol=
18.419560699 dynes/cm
Surface Tension of Top Tray Liquid=
19.243622525 dynes/cm
Unf=
Unf=

Csbf((/20)^0.2)*((L-G)/G)^0.5
1.9557180196 m/s

CSB(corrected with surface tension)

CSB (corrected)=

0.1062496791 m/s

From Perry's Chemical Engineer's Handbook, 14-38,

C=[G/(3600*G*AN)]*[G/(L-G)]^0.5
Given that column should operate at approximately 80% of flooding point,
C=
0.0856576682 m/s
A N=
[G/(3600*G*C)]*[G/(L-G)]^0.5
A N=

7.228925985 m2

Assuming that the downcomer area is 0.3m2,

Column Cross Section area=
downcomer area + net area
Column Cross Section area=
7.528925985
Plotting a table
Flow rate of feed

18.942006058 L/s
0.0189420061 m3/s

Volume of feed for 5minutes

17.047805452

I. Column DiamI. Column Radius

X-area
Height of columVelocity for overhead vapor
0.05
0.025 0.0019634954 391079.56216 J742
0.1
0.05 0.0078539816 97769.89054
0
0.15
0.075 0.0176714587 43453.284685
0

0.2
0.25
0.3
0.35
0.4
0.45
0.5
0.55
0.6
0.65
0.7
0.75
0.8
0.85
0.9
0.95
1
1.05
1.1
1.15
1.2
1.25
1.3
1.35
1.4
1.45
1.5
1.55
1.6
1.65
1.7
1.75
1.8
1.85
1.9
1.95
2
2.05
2.1
2.15
2.2
2.25
2.3
2.35
2.4
2.45
2.5
2.55
2.6
2.65

0.1
0.125
0.15
0.175
0.2
0.225
0.25
0.275
0.3
0.325
0.35
0.375
0.4
0.425
0.45
0.475
0.5
0.525
0.55
0.575
0.6
0.625
0.65
0.675
0.7
0.725
0.75
0.775
0.8
0.825
0.85
0.875
0.9
0.925
0.95
0.975
1
1.025
1.05
1.075
1.1
1.125
1.15
1.175
1.2
1.225
1.25
1.275
1.3
1.325

0.0314159265
0.0490873852
0.0706858347
0.096211275
0.1256637061
0.1590431281
0.1963495408
0.2375829444
0.2827433388
0.331830724
0.3848451001
0.4417864669
0.5026548246
0.5674501731
0.6361725124
0.7088218425
0.7853981634
0.8659014751
0.9503317777
1.0386890711
1.1309733553
1.2271846303
1.3273228961
1.4313881528
1.5393804003
1.6512996385
1.7671458676
1.8869190876
2.0106192983
2.1382464998
2.2698006922
2.4052818754
2.5446900494
2.6880252142
2.8352873699
2.9864765163
3.1415926536
3.3006357817
3.4636059006
3.6305030103
3.8013271108
3.9760782022
4.1547562844
4.3373613574
4.5238934212
4.7143524758
4.9087385212
5.1070515575
5.3092915846
5.5154586025

24442.472635
15643.182486
10863.321171
7981.2155543
6110.6181588
4828.1427427
3910.7956216
3232.0624972
2715.8302928
2314.0802495
1995.3038886
1738.1313874
1527.6545397
1353.2164781
1207.0356857
1083.3228869
977.6989054
886.80172826
808.0156243
739.28083584
678.9575732
625.72729946
578.52006237
536.46030475
498.82597214
465.01731529
434.53284685
406.950637
381.91363492
359.11805524
338.30411952
319.24862217
301.75892142
285.66805125
270.83072172
257.12002772
244.42472635
232.64697333
221.70043206
211.50868695
202.00390608
193.12570971
184.82020896
177.03918613
169.7393933
162.88195009
156.43182486
150.35738645
144.63001559
139.22376723

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

2.7
2.75
2.8
2.85
2.9
2.95
3
3.05
3.1
3.15
3.2
3.25
3.3
3.35
3.4
3.45
3.5
3.55
3.6
3.65
3.7
3.75
3.8
3.85
3.9
3.95
4
4.05
4.1
4.15
4.2
4.25
4.3
4.35
4.4
4.45
4.5
4.55
4.6
4.65
4.7
4.75
4.8
4.85
4.9
4.95
5

1.35
1.375
1.4
1.425
1.45
1.475
1.5
1.525
1.55
1.575
1.6
1.625
1.65
1.675
1.7
1.725
1.75
1.775
1.8
1.825
1.85
1.875
1.9
1.925
1.95
1.975
2
2.025
2.05
2.075
2.1
2.125
2.15
2.175
2.2
2.225
2.25
2.275
2.3
2.325
2.35
2.375
2.4
2.425
2.45
2.475
2.5

5.7255526112
5.9395736107
6.157521601
6.3793965822
6.6051985542
6.834927517
7.0685834706
7.306166415
7.5476763502
7.7931132763
8.0424771932
8.2957681009
8.5529859994
8.8141308887
9.0792027689
9.3482016398
9.6211275016
9.8979803542
10.178760198
10.463467032
10.752100857
11.044661673
11.341149479
11.641564277
11.945906065
12.254174844
12.566370614
12.882493375
13.202543127
13.526519869
13.854423602
14.186254326
14.522012041
14.861696747
15.205308443
15.552847131
15.904312809
16.259705478
16.619025137
16.982271788
17.349445429
17.720546062
18.095573685
18.474528299
18.857409903
19.244218499
19.634954085

134.11507619
129.28249989
124.70649304
120.36920965
116.25432882
112.34690094
108.63321171
105.10066169
101.73765925
98.533525362
95.478408731
92.563209979
89.779513811
87.119528216
84.576029879
82.142315094
79.812155543
77.579758413
75.439730355
73.387044879
71.417012813
69.525255495
67.70768043
65.960459127
64.28000693
62.662964615
61.106181588
59.606700528
58.161743332
56.768698238
55.425108016
54.128659123
52.877171736
51.668590588
50.500976519
49.372498695
48.281427427
47.22612754
46.20505224
45.216737445
44.259796533
43.332915475
42.434848325
41.564413026
40.720487522
39.902006138
39.107956216

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

Calculations for volume accumulated after 20minutes of feed flow rate

Volume accumulated after 20minutes of feed flow rate=
477.3386 m3
Diameter of Feed Tank=
pi=
Height

6
3.1415926536
16.882397819

5.9236483575

kg/m3
kg/m3
kg/m3

L/hr
L/s

kg/m3
kg/m3
kg/m3

Feed Properties
Feed is @

40 C

313.15 K

Liquid density regression coefficients for Feed

Given that liquid density eqn is (g/cm3)=A*B^-(1-(T/Tc))^n
Acetone
A=
0.27728
B=
0.2576
Yacetone
Yisopropanol
n=
0.29903
Tc=
508.2
1.00
0.00
0.99
0.01
Isopropanol
0.9999
0.0001
A=
0.26785
B=
0.26475
n=
0.243
Tc=
508.31

Tdew
56.09402
56.71584
56.10024

Distillate Properties
Distillate is @

28 C

301.15 K

Bottoms Properties
Bottoms is @

73.83997019 C

346.99 K

L/hr
L/s

kg/m3
kg/m3
kg/m3

Xacetone

L/hr
L/s

Tbubble
0.28 73.71498954
0.27 74.00564222
0.2757 73.83997019

Overhead Properties
Overhead Vapor is @

56.09603 C

1kmole of Acetone=
1kmole of Isopropanol=
1kmole of Overhead Vapor=

329.246

58.08 kg
60.096 kg
58.0802016 kg

m= mass flow rate

M= molar mass of the vapor

Pa.s
Pa.s
Pa.s

Pa.s
Pa.s
Pa.s

Feed Properties
Feed is @
Distillate Properties
Distillate is @
Bottoms Properites
Botoms is @
Overhead Properties
Overhead Vapor is @

50 C

323.15 K

28 C

301.15 K

73.83997 C

346.99 K

56.09603 C

329.246 K

Viscosity of Liquid, , regression coefficients for Feed

Given that Vicosity of Liquid, liquid (centipoise)=10^(A+(B/T)+(C*T)+(D*T^2))
Pa.s
Pa.s
Pa.s

Acetone
A=
B=
C=
D=

Pa.s
Pa.s
Pa.s

Isopropanol
A=
B=

-7.2126
903.05
0.018385
-2.0353E-005

-0.7009
841.5

C=
D=

J/mol
J/mol
J/mol

Viscosity of Gas, , regression coefficients for Feed

Given that Vicosity of Gas, gas (micropoise)=A+(B*T)+(C*T^2)
Acetone
A=
B=
C=

-4.055
0.26655
-5.6936E-006

Isopropanol
A=
B=
C=

-10.859
0.30873
-4.8098E-005

Feed Properties
Feed is @

50 C

323.15 K

Distillate Properties
Distillate is @

28 C

301.15 K

Bottoms Properties
Bottoms is @

73.83997019 C

346.99 K

56.09603 C

Overhead Properties
Overhead is @

When Feed is at above stated temperature, bubble point is

Tb=
57.11067636 C
=
330.2607

J/mol
J/mol
J/mol

Liquid Heat Capacity, CpL, regression coefficients for Feed

Given that Liquid Heat Capacity, CpL(J/mol.K)= A+B*T+C*T^2+D*T^3
Acetone
A=
46.878
B=
0.62652
C=
-0.0020761
D=
2.9583E-006
Isopropanol
A=
B=

72.525
0.79553

329.246

M o le F r a c t io n o f A c e t o n e in V a p o u r , Y a c e t o n e

-0.0086068
8.2964E-006

M ol
C=
D=

-0.002633
3.6498E-006

Enthalpy of Vaporization, , regression coefficients for Feed

Given that Enthalpy of Vaporization, (kJ/mol)=A*(1-(T/Tc))^n
Acetone
A=
49.244
Tc=
508.2
n=
0.481
Isopropanol
A=
Tc=
n=

101.3 kPa

Op. Line
0.9999
0.995419
0.990938
0.986457
0.981976
0.977495

58.982
508.31
0.326

Operating Line is y=(0.4481)*x+0.5518

Enriching Line is y=(1.0401)*x-0.0111
Enriching Line

0.987396
0.976995
0.966594
0.956193
0.945792
0.935391
0.92499
0.914589
0.904188
0.893787
0.883386
0.872985
0.862584
0.852183
0.841782
0.831381
0.82098
0.810579
0.800178
0.789777
0.779376
0.768975
0.758574

759.8125 mm Hg

0.748173
0.737772
0.727371
0.71697
0.706569
0.696168
0.685767
0.675366
0.664965
0.654564
0.644163
0.633762
0.623361
0.61296
0.602559
0.592158
0.581757
0.571356
0.560955
0.550554
0.540153
0.529752
0.519351
0.50895
0.498549
0.488148
0.477747
0.467346
0.456945
0.446544
0.436143
0.425742
0.415341
0.40494
0.394539
0.384138
0.373737
0.363336
0.352935
0.342534
0.332133
0.321732
0.311331
0.30093
0.290529
0.280128
0.269727

Note that: C=y-mx

Note that: Rm=(XD/y)-1

ra ctio n o f Ace to n e in Vap o u r, Yac eto n e

r of total theoretical number of stages required

Molar fraction of acetone at bottoms=

0.2757

Equilibrium Diagram for the Acetone and Isopropanol System

M o le F ra ctio n o f Ace to n e in Vap o u r, Yac eto

y=m*x+C
C=y-(m*x)

Equilibrium Diagram for the Acetone and Isopropanol System

f(x) = 0.5787049595x^3 - 1.7814359975x^2 + 2.2026508424x + 0.0030314695

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

Mole Fraction of Acetone in Liquid, Xacetone

0.90

1.00

0.950839

x-coordinate threshold for termination of calculations for theoretical trays=

ative Volatility=

2.708637291

0.2757

taken into account for this ideal distillation column design.

to active area Aa is 0.1 or greater. Otherwise the value of Unf obtained from Fig. 14-31 should be corrected.

g into the condensor,,

wing equation

m diameter(REFERENCE NEEDED)

inches=

1000 mm

CHECK
Overhead Properties
Overhead is @

Surface Tension of Liquid, , regression coefficients

Given that Surface Tension of Liquid, (dynes/cm)=A*(1-(T/Tc))^n
Acetone
A=
62.2
Tc=
508.2
n=
1.124
Isopropanol
A=
Tc=

65.93
508.31

n=

1.2222

ume of feed for 5minutes

m3

erhead vapor

56.09603 C

Volumetric flow rate of overhead vapor

11.39773711

329.246

HDB floors

M o le F r a c t io n o f A c e t o n e in V a p o u r , Y a c e t o n e

Equilibrium Diagram for the Acetone and I

f(x) = 0.5787049595x^3 - 1.7814359975x^2 + 2.202

M ol

f(x) = 0.5787049595x^3 - 1.7814359975x^2 + 2.202

0.00

0.10

0.20

0.30

0.40

0.50

0.60

Mole Fraction of Acetone in Liquid,

Isopropanol System at 101.3kPa

Isopropanol System at 101.3kPa

030314695

0.90

1.00

tone and Isopropanol System at 101.3kPa

5x^2 + 2.2026508424x + 0.0030314695

5x^2 + 2.2026508424x + 0.0030314695

50

0.60

0.70

0.80

ne in Liquid, Xacetone

0.90

1.00

Flow rate of feed

I. Column Diameter I. Column Radiu

0.05
0.025
0.1
0.05
0.15
0.075
0.2
0.1
0.25
0.125
0.3
0.15
0.35
0.175
0.4
0.2
0.45
0.225
0.5
0.25
0.55
0.275
0.6
0.3
0.65
0.325
0.7
0.35
0.75
0.375
0.8
0.4
0.85
0.425
0.9
0.45
0.95
0.475
1
0.5
1.05
0.525
1.1
0.55
1.15
0.575
1.2
0.6
1.25
0.625
1.3
0.65
1.35
0.675
1.4
0.7
1.45
0.725
1.5
0.75
1.55
0.775
1.6
0.8
1.65
0.825
1.7
0.85
1.75
0.875
1.8
0.9
1.85
0.925
1.9
0.95
1.95
0.975
2
1
2.05
1.025
2.1
1.05
2.15
1.075
2.2
1.1
2.25
1.125

18.94200606 L/s
0.018942006 m3/s
X-area
Height of column for 15minutes feed flow
0.001963495
8682.3760210755
0.007853982
2170.5940052689
0.017671459
964.7084467862
0.031415927
542.6485013172
0.049087385
347.295040843
0.070685835
241.1771116965
0.096211275
177.1913473689
0.125663706
135.6621253293
0.159043128
107.1898274207
0.196349541
86.8237602108
0.237582944
71.7551737279
0.282743339
60.2942779241
0.331830724
51.3750060419
0.3848451
44.2978368422
0.441786467
38.5883378714
0.502654825
33.9155313323
0.567450173
30.0428236023
0.636172512
26.7974568552
0.708821842
24.0509031055
0.785398163
21.7059400527
0.865901475
19.6879274854
0.950331778
17.938793432
1.038689071
16.4128091136
1.130973355
15.073569481
1.22718463
13.8918016337
1.327322896
12.8437515105
1.431388153
11.9099808245
1.5393804
11.0744592106
1.651299639
10.3238716065
1.767145868
9.6470844679
1.886919088
9.034730511
2.010619298
8.4788828331
2.1382465
7.9727970809
2.269800692
7.5107059006
2.405281875
7.0876538948
2.544690049
6.6993642138
2.688025214
6.3421300373
2.83528737
6.0127257764
2.986476516
5.7083340047
3.141592654
5.4264850132
3.300635782
5.1650065563
3.463605901
4.9219818714
3.63050301
4.6957144516
3.801327111
4.484698358
3.976078202
4.2875930968

2.3
2.35
2.4
2.45
2.5
2.55
2.6
2.65
2.7
2.75
2.8
2.85
2.9
2.95
3
3.05
3.1
3.15
3.2
3.25
3.3
3.35
3.4
3.45
3.5
3.55
3.6
3.65
3.7
3.75
3.8
3.85
3.9
3.95
4
4.05
4.1
4.15
4.2
4.25
4.3
4.35
4.4
4.45
4.5
4.55
4.6
4.65
4.7
4.75

1.15
1.175
1.2
1.225
1.25
1.275
1.3
1.325
1.35
1.375
1.4
1.425
1.45
1.475
1.5
1.525
1.55
1.575
1.6
1.625
1.65
1.675
1.7
1.725
1.75
1.775
1.8
1.825
1.85
1.875
1.9
1.925
1.95
1.975
2
2.025
2.05
2.075
2.1
2.125
2.15
2.175
2.2
2.225
2.25
2.275
2.3
2.325
2.35
2.375

4.154756284
4.337361357
4.523893421
4.714352476
4.908738521
5.107051557
5.309291585
5.515458602
5.725552611
5.939573611
6.157521601
6.379396582
6.605198554
6.834927517
7.068583471
7.306166415
7.54767635
7.793113276
8.042477193
8.295768101
8.552985999
8.814130889
9.079202769
9.34820164
9.621127502
9.897980354
10.1787602
10.46346703
10.75210086
11.04466167
11.34114948
11.64156428
11.94590607
12.25417484
12.56637061
12.88249338
13.20254313
13.52651987
13.8544236
14.18625433
14.52201204
14.86169675
15.20530844
15.55284713
15.90431281
16.25970548
16.61902514
16.98227179
17.34944543
17.72054606

4.1032022784
3.9304554192
3.7683923703
3.6161499463
3.4729504084
3.3380915114
3.2109378776
3.0909134998
2.9774952061
2.8702069491
2.7686148026
2.6723225673
2.5809679016
2.4942189087
2.411771117
2.3333448054
2.2586826278
2.1875474984
2.1197207083
2.0550002417
1.9931992702
1.9341448031
1.8776764751
1.8236454571
1.7719134737
1.7223519185
1.6748410534
1.6292692852
1.5855325093
1.5435335149
1.5031814441
1.4643913006
1.4270835012
1.3911834676
1.3566212533
1.3233312027
1.2912516391
1.2603245785
1.2304954678
1.2017129441
1.1739286129
1.1470968452
1.1211745895
1.0961211995
1.0718982742
1.0484695111
1.0258005696
1.0038589457
0.9826138548
0.9620361242

4.8
4.85
4.9
4.95
5

2.4 18.09557368
2.425 18.4745283
2.45 18.8574099
2.475 19.2442185
2.5 19.63495408

0.9420980926
0.922773517
0.9040374866
0.8858663423
0.8682376021

Volume of feed for 5minutes

17.04781 m3
Velocity for overhead vapor
5804.8198432579
1451.2049608145
644.9799825842
362.8012402036
232.1927937303
161.2449956461
118.4657110869
90.7003100509
71.6644425094
58.0481984326
47.9737177129
40.3112489115
34.3480464098
29.6164277717
25.7991993034
22.6750775127
20.0858818106
17.9161106273
16.0798333608
14.5120496081
13.1628567874
11.9934294282
10.9731944107
10.0778122279
9.2877117492
8.5870116025
7.9627158344
7.4041069429
6.9022828101
6.4497998258
6.0403952583
5.6687693782
5.3304130792
5.0214704526
4.7386284435
4.4790276568
4.2401898052
4.0199583402
3.8164496011
3.628012402
3.4531944338
3.2907141969
3.139437449
2.9983573571
2.8665777004

Volumetric flow rate of overhead vapor

11.39774 m3/s

2.7432986027
2.6278043654
2.519453057
2.4176675732
2.3219279373
2.2317646456
2.1467529006
2.0665075982
1.9906789586
1.9189487085
1.8510267357
1.7866481512
1.7255707025
1.6675724916
1.6124499565
1.5600160826
1.5100988146
1.462539643
1.4171923445
1.3739218564
1.3326032698
1.2931209274
1.2553676132
1.2192438234
1.1846571109
1.1515214924
1.1197569142
1.0892887677
1.0600474513
1.0319679721
1.0049895851
0.9790554635
0.9541124003
0.9301105341
0.9070031005
0.8847462038
0.8632986085
0.8426215479
0.8226785492
0.8034352724
0.7848593623
0.7669203122
0.7495893393
0.7328392682
0.7166444251
0.700980539
0.6858246507
0.6711550287
0.6569510914
0.6431933344

0.6298632642
0.6169433355
0.6044168933
0.5922681199
0.5804819843