PROF.

ANAND YADAVS CHEMISTRY PRIVATE TUITIONS

PRELIM -5 ( SOLID STATE , SOLN COLL , THERMO , ELECTRO )

1) A single substance that exists in two or

more forms is called.
a) Polymorphous
b) Amorphous
c) Isomorphous
d) Mono-morphous
2) Diamond is a
a) Metallic crystal
b) Covalent crystal
c) Ionic crystal
d) Molecular crystal
3) The ratio of close packed atoms to
tetrahedral holes in cubic packing is
a) 1:1
b) 1:2
c) 2:1
d) 1:3
4)
a)
b)
c)
d)

The major binding force in silicon is

Ionic bond
Covalent bond
Dipole-dipole attraction
Induced dipole-dipole attraction

5)
a)
b)
c)
d)
6)

The major binding force of graphite is

Ionic bond
Covalent bond
Hydrogen bond
London force
The number of tetrahedral sites per
sphere in ccp structure is,
1
2
3
4

a)
b)
c)
d)

7) The packing efficiency for a body

centred cubic structure is
12) When NaCl is added to water.
a) Freezing point is raised
b) Freezing point does not change

a)
b)
c)
d)

50 MIN

0.42
0.53
0.68
0.82

8) Due to Frenkel defect the density of

ionic solid
a) Increases
b) Decreases
c) Remains same
d) Fluctuates
9) An ionic crystal lattice has +/ radius
ratio of 0.524. Its coordination number
is
a) 2
b) 4
c) 6
d) 8
10) An ionic compound occurs in fcc
type crystal structure with B ion at the
centre of each face and A ion occupying
corners of the cube. Give the formula
.
a) 3
b) 4
c) 3
d) 4

11) In crystalline solid few of the cations

moved from their positions into the
interstitial position. The defect is called
as,
a) Interstitial defect
b) Frenkel defect
c) Schottky defect
d) Line defect

c) Boiling point is depressed

d) Boiling point is raised

13) Which of the following 0.1 M aqueous solutions will exert highest osmotic pressure?
a) NaCl
c) MgSO4
b) BaCl2
d) Al2(SO4)3
14) According to the Raoults law, the relative lowering of vapour pressure is equal to the
a) mole fraction of solvent
c) mole fraction of solute

PROF. ANAND YADAVS CHEMISTRY PRIVATE TUITIONS

PRELIM -5 ( SOLID STATE , SOLN COLL , THERMO , ELECTRO )

b) independent of mole fraction of solute

50 MIN

d) molality of solution

15) Partial pressure of solvent in solution of non-volatile solute is given by equation,

a) = 2
c) = 1
b) =
d) = 1

16) When partial pressure of solvent in solution of non-volatile solute is plotted against its mole
fraction, nature of graph is
a) a straight line passing through origin
b) a straight line parallel to mole fraction of solvent
c) a straight line parallel to vapour pressure of solvent
d) a straight line intersecting vapour pressure axis.
17) Lowering of vapour pressure of solution
a) is a property of solute
c) is a property of solute as well as solvent
b) is a property of solvent
d) is a colligative property
18) The determination of molar mass from elevation in boiling point is called as
a) cryoscopy
c) ebullioscopy
b) osmometry
d) spectroscopy
19) Vapour pressure of solution of non volatile solute is always
a) equal to the vapour pressure of pure solvent
b) higher than vapour pressure of pure solvent
c) lower than vapour pressure of pure solvent
d) constant
20) In osmosis
a) Solvent molecules pass from high concentration of solute to low concentration.
b) Solvent molecules pass from a solution of low concentration of solute to a solution of high
concentration of solute.
c) Solute molecules pass from low concentration to high concentration
d) Solute molecules pass from high concentration to low concentration
21) Abnormal molar mass is produced by
a) association of solute
b) dissociation of solute
c) both association and dissociation of solute
d) separation by semipermeable membrane
22) Which of the following aqueous solutions will have minimum elevation in boiling point?
a) 0.1M KCl
c) 1M AlPO4
b) 0.05M NaCl
d) 0.1M MgSO4
23) Which of the following will have maximum depression in freezing point?
a) 0.5M Li2SO4
c) 1M KCl
b) 0.5M Al2(SO4)3
d) 0.5M BaCl

PROF. ANAND YADAVS CHEMISTRY PRIVATE TUITIONS

PRELIM -5 ( SOLID STATE , SOLN COLL , THERMO , ELECTRO )

25) The heat evolved in the following reaction

() + () (), =
to produce 9g of water is
a) 484 kJ
b) 121 103 J
c) 242 kJ
d) 968 kJ
26) When a sample of an ideal gas is allowed to
expand at constant temperature against an
stmospheric pressure,
a) Surroundings does work on the system
b) U = 0
c) No heat exchange takes place between the
system and surroundings
d) Internal energy of the system increases.
27) In what reaction of the following, work is
done by the system on the surroundings?
a) () ()
b) 32 () 23 ()
c) 2 () + 2 () 2 ()
d) 2 () + 32 () 23 ()

28) In the reaction, () + ()

, = , if 2 mol of reacts
with , then U is equal to
a) -184 kJ
b) -368 kJ
c) Zero
d) +368 kJ
29) For which of the following substances
is not zero
a) Ca(s)
b) He(g)
c) P(red)
d) CH3OH(l)

30) If for a reaction H is negative and S is

positive then the reaction is
a) Spontaneous at all temperatures
b) Non-spontaneous at all temperatures
c) Spontaneous only at high temperatures
d) Spontaneous only at low temperatures
31) The relationship between of a reaction
and its equilibrium constant is

a) = 1

b) = 1

50 MIN
1

c) = 1
d) = 1

32) For the conversion of liquid to solid below

the melting point of solid
(a) is negative and the process is
spontaneous
(b) is positive and the process is
spontaneous
(c) is positive and the process is nonspontaneous (d) is zero and the process is at
equilibrium.
33) Which of the following conditions
guarantee that a reaction is spontaneous at
constant T and P?
a) Entropy of system increases
b) Enthalpy of system decreases
c) Entropy of system decreases and that of
surroundings increases
d) Gibbs energy of the system decreases.
34) Which of the following processes nonspontaneous?
a) Dissolving KCl in water
b) Mixing of iodine vapour and nitrogen gas
c) Decomposition of NaCl to Na(s) and
Cl2(g)
d) Freezing of water at 270K.
35)For which of the following reactions S in
negative?
a) () + 2 () 2 ()
b) 2 () 2 ()
c) 3 () () + 2 ()
d) 2 () 2()
36) A gas expands in volume from 2L to 5L
against a pressure of 1 atm at constant
temperature. The work done by the gas will be
a) 3J
b) -303.9 J
c) -303.9 L atm
d) 303.9 L.atm
37) Given the reaction,
() + () (),
= .
The enthalpy of formation of NH3 is
a) -92.6 kJ
b) 92.6 kJ mol-1
c) -46.3 kJ mol-1
d) -185.2 kJ mol-1
38. The number of electrons that have a total
charge of 965 coulombs is

PROF. ANAND YADAVS CHEMISTRY PRIVATE TUITIONS

PRELIM -5 ( SOLID STATE , SOLN COLL , THERMO , ELECTRO )

a) 6.022 1023
b) 6.022 1022
c)
6.022 1021
d) 3.011 1023
39. The time required to produce 2F of
electricity with a current of 2.5 amperes is
a) 1.34h
b) 1200min
c)
50000s
d) 1.5h
40. The strongest oxidizing agent among the
species In3+ (E0=1.34V), Au3+ (E0=1.4V,
Hg2+ (E0=0.86V), Cr3+ (E0=0.74V) is
a) 3+
b) 3+
c)
2+
d) 3+
41. The value of constant in Nernst equation

=
at 25 is

a) 0.0592
b) 0.0592
c)
25.7
d) 0.0296
42. The reaction, () + +()
() + ()
with
the
standard

potentials,
= . , =
+. , is
a) Spontaneous in reverse direction
b) Spontaneous in forward direction
c)
At equilibrium
d) Non-spontaneous in reverse direction.
43. Daniel cell operates under nonstandard
state conditions. If the equation of the cell
reaction is multiplied by 2 then
a) E and E0 remain unchanged
b) E is doubled
c)
n remains unchanged in Nernst
equation.
d) Q is halved in Nernst equation.
44. Consider the cell,
| () | +() || ()| (). if the
standard cell potential is 0.54V then the
standard potential for cathode half reaction
will be
a) 0
b) 0.54
c)
+0.54V
d) 1.08

50 MIN

45. Consider the cell

| () | () () | () | .
if the concentration of HCl is increased, the
cell potential will
a) Increase
c) Decrease
b) remain the same d) become maximum
46. The standard potential for the cell reaction
() + +() +() + ()
where = . , = . is
a) 0.52
b) 0.52
c)
1.2V
d) +1.2
47. G0 for the reaction
+() + () +() +
(), where standard potential for silver
half cell reaction is 0.8V, will be
a) 77.2
b) +77.2
c)
154.4
d) 38.6
48. The following reaction occurs in a galvanic
cell + + + . If +,+ =

+. and
, the
+ = .
standard cell potential will be
a) 0.68
b) 0.36
c)
0.36
d) 0.68
49. The SI unit of molar conductivity is
a) 2 1
b) 2 1
c)
2
d) 2 1
50. Consider the following half reactions and
choose the correct alternative
i. () + () =
.
ii. () + () =
.
iii. () + ()
=
.
a) Br2 cannot oxidize Ib) Cl2 can oxidize Br- but not Ic)
I2 con oxidize Cld) Br2 can oxidize I- but not Cl-