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CHEMI
ISTRY OLYM
MPIAD PRAC
CTICE T
TEST-1
TIME : 2 HR.
D
DATE
: 16-11-2012
MARK
KS : 160
1. A C6H12 compou
und reacts with
w ozone to
t yield a siingle C3H6O product. G
Gas phase free
f
radical bromination
n of the hyd
drocarbon gives a single C6H11Br product.
p
A likely identiffication
of this compound
c
is.
(A) cycllohexane
(C) 3-he
exene
(B) cyclohexene
(D) 2,3--dimethyl-2-butene
2. The terpene
t
ocimene has the
t IUPAC name
n
(3E)-3,7-dimethyyl-1,3,6-octa
atriene, wha
at is the
structurral formula of
o this comp
pound?
ethylcyclobu
utanes is ch
hiral ?
3. Whicch of the folllowing dime
(A) tran
ns-1,2-dimetthylcyclobutane
(C) tran
ns-1,3-dimethylcyclobutane
(B) cis-1,2-dimethyylcyclobutan
ne
(D) cis--1,3-dimethyylcyclobutane
(B) metthylcyclopen
ntane
(D) propylcyclopro
opane
5. The radical
r
halo
ogenation off 2-methylpropane give
es two products: (CH3)2CHCH2X (minor)
and (CH
H3)3CX (majjor) Chlorin
nation givess a larger am
mount of the
e minor pro
oduct than does
d
bromina
ation, Why?
?
(A) Bromine is morre reactive than
t
chlorin
ne and able to attack th
he less reacctive 3C-H.
(B) Bromine atomss are less re
eactive (more selective
e) than chlorine, and prreferentially
y attack
the wea
aker 3 C-H bond.
(C) The
e methyl gro
oups are mo
ore hindered
d to attack by the large
er bromine a
atom.
(D) Bromination is reversible and
a the more stable 3-alkyl brom
mide is forme
ed exclusively.
6. Whicch of the folllowing is no
ot an electro
ophile?
(A) C2H5OC2H5
(C) [CH
H3]3C(+)
(B) BF3
(D) HOCl
11. Cycclooctatetrae
ene, C8H8, appears to be a conjug
gated annulene. In ad
ddition to the
planar configuratio
c
on, three non-planar strructures ma
ay be consid
dered, all off which are shown
below. Which of th
hese is mosst likely to be
b the favore
ed conformation? notte that D is planar.
(A) (2E,4E)
(B) (2Z,4Z)
(C) (2Z,4E)
(D) (2E
E,4Z)
14. Wh
hich isomer of hexane has only tw
wo different sets
s
of struccturally equ
uivalent hydrogen
atoms.?
?
(A) 2,2--dimethylbutane
(C) 3-m
methylpentan
ne
(B) 2-m
methylpentan
ne
(D) 2,3--dimethylbu
utane
15. The
e monochlo
oroisomer th
hat predomiinates in the
e mixture re
esulting from
m the free ra
adical
chlorina
ation of CH3CH2CH2CH
H=CH2 is
(B).CH3CHClCH2CH=CH
C
2
(D)..CH
H3CH2CH2CCl=CH2
(A).ClC
CH2CH2CH2CH=CH
C
2
(C).CH3CH2CHClC
CH=CH2
16. Wh
hich is NOT
T characterisstic of a free
e radical chain reaction
n?
(A).It prroduces a mole
m
of prod
duct for a mole
m
of free radical
r
initia
ated.
(B) It gives
g
the pro
oduct derive
ed from the most stable free radiccal.
(C) It may
m be initia
ated by pero
oxides.
(D) It may
m be initia
ated by high
h heat.
17. Wh
hich anion iss the weake
est base?
(A). C2H5O1(C) CN1-
(B).NO31(D).CH3COO1-
18. Wh
hich of the amines
a
liste
ed below wo
ould have th
he lowest bo
oiling point?
?
(A). CH
H3CH2CH2NH2
(C). (CH
H3)3N
(B).CH3CH2NHCH3
(D).(CH
H3)3CNH2
19. Exa
amine the reaction
r
sho
own below and
a then predict what product
p
wou
uld be formed.
H3C CH2 CH2 Mg
M Br
(A)
(B)
(C)
(D)
20.Which one of the following does not correctly describe one or all of the hydrogen halides,
HX?
(A) Their aqueous solutions are acidic.
(B) HF has the lowest of the H-X bond energies.
(C) HI is the largest.
(D) HCl has the lowest boiling point.
21.Of the oxyacids listed below, which one possesses the greatest acid strength in water?
(A) HClO4
(C) H3BO3
(B) H2CO3
(D) HClO
(B) 123 kg
(D) 144 kg
24.In which one of the following is the oxidation state of nitrogen given incorrectly?
(A) N2O3, +3
(C) HNO3, +5
(B) N2H4, +2
(D) NaNO2, +3
(B) HNO2
(D) N2O4
(B) Na2HPO4
(D) NaH2PO4
(B) Ca(NO3)2
(D) Zn(CH3COO)2
29.Which of the following statements is FALSE given the following net ionic equation?
H3PO4(aq) + 3OH-(aq)
PO43-(aq) + 3H2O(l)
(A) If all the water evaporated away, the salt remaining could possibly be Na3PO4.
(B) The acid, H3PO4, is a weak electrolyte.
(C) The base involved must be a strong soluble base.
(D)This could be the net ionic equation for H3PO4 reacting with Al(OH)3.
30.Given that the Activity Series is: Na>Mg>Cu>Ag>Au, which one of the following answers
represents the ions that would not be displaced from aqueous solution (reduced) by metallic
magnesium?
(A) Na+
(C) Cu2+ and Au+
(B) Cu2+
(D) Cu2+, Ag+ and Au+
32.In the gold plating process, sodium cyanide solution is used as an electrolyte instead of
nitric acid because
(A).cyanide forms a complex with gold and thus helps uniform deposition of gold
(B).sodium cyanide is a better solvent for gold ions
(C).cyanide binds with impurity ions and keeps the impurities in solution
(D).deposition of gold from nitric acid bath is slow
33.Sodium hydroxide cannot be used as a primary standard for acid base titration because
(A).it is corrosive and reacts with glass
(B)the dissolution of sodium hydroxide in water is highly exothermic, hence its
concentration changes on dissolution
(C)it is hygroscopic and also reacts with atmospheric carbon dioxide
(D)hydroxides cannot be used as primary standards
34.The diagonal relationship of elements in the periodic table arises because of similarity in
(A).ionic radius
(C)crystal structure
(B)electronic configuration
(D)charge/radius ratio of the corresponding ions
35.The metal that can be extracted from its oxide by reduction with carbon is
(A)sodium
(B)calcium
(C)iron
(D)aluminium
(B)chromium trioxide
(D)potassium dichromate
(B)nitrous oxide
(D)dinitrogen pentoxide
38.The molar conductivities of H+, Li+ and Na+ ions in aqueous solutions at infinite dilution
45.The reaction 3O2(g) 2O3 (g) is endothermic. What can be concluded about the average
energy per bond in O2 and O3?
(A).the average energy per bond in O2 is greater than that in O3
(B)Al(OH)3
(C)B(OH)3
(D)TlOH
(B)K2[Fe(CN)4(NH3)2]
(D)Na2[Fe(CN)5NO]
49.A coordination complex of type MX2Y2 [M = metal ion; X,Y = monodentate ligands], can
have either a tetrahedral or a square planar geometry. The maximum number of possible
isomers in these two cases are respectively
(A)1 and 2
(B)2 and 1
(C)1 and 3
(D)3 and 2
50.Platinum metal (Pt) dissolves in aqua-regia but not in concentrated HCl or HNO3 because
(A).HCl oxidizes Pt in the presence of HNO3
(B)HNO3 reacts with HCl to form chlorine which attacks Pt
(C)HNO3 oxidizes Pt which is followed by formation of a chloro complex
(D)HCl and HNO3 together give O2 that oxidizes Pt
51.The least stable metal carbonyl as per the bonding considerations should be
(A)Cr(CO)6
(B)Mn(CO)6
(C)Fe(CO)5
(D)Ni(CO)4
52.Dimethyl glyoxime forms a square planar complex with Ni2+. This complex should be
(A)diamagnetic
(B)paramagnetic having 1 unpaired electron
(C)paramagnetic having 2 unpaired electrons
(D)ferromagnetic
53.The compound that cannot be formed by xenon is
(A).XeO3
(C)XeCl4
(B)XeF4
(D) XeOF4
56. What compound will be formed from the peroxide-catalyzed addition of HBr to 1hexyne?
(A)CH3CH2CH2CH2CBr=CH2
(C)CH2BrCH2CH2CH2CH=CH2
(B)CH3CH2CH2CH2CH=CHBr
(D)CH3CH2CH2CBr=CHCH
(B) CH3CH2-C(OH)=CH2
(D)CH3CH2CH2CH=O
58.Calculate U for a system that loses 325 kJ of heat while doing 200 kJ of work on the
surroundings.
(A)+125 kJ
(B)
-525 kJ
(C)
0 kJ
(D)
-125 kJ
59.When 1 mole of white tin changes to gray tin at 13.0oC, the change in entropy is -7.5 J
K-1. This means that
(A)the change from white to gray tin is predicted to be spontaneous on the basis of the
entropy change.
(B)gray tin has an entropy of -7.5 J K-1.
(C)gray tin is more ordered than white tin.
(D)gray tin has a higher molar entropy than white tin.
60.Which one of the following statements is true?
(A)Spontaneous reactions always have Hro < 0.
(B)Reactions with positive values of Sro always become spontaneous at high
temperatures.
(C)All of these statements are false.
(D)Spontaneous reactions always have Hro > 0.
61.Which of the following statements about colligative properties is TRUE?
(A)Both vapor pressure and freezing point INCREASE when a non- volatile solute is added
to a solvent.
(B)Both freezing point and boiling point INCREASE when a non- volatile solute is added to a
solvent.
(C)Both vapor pressure and boiling point DECREASE when a non- volatile solute is added to
a solvent.
(D)Colligative properties depend only upon the NUMBER of solute particles in a solution and
not upon their identity.
62. Calculate the PERCENT BY MASS of hydrogen peroxide (H2O2, MW = 34.0 g/mole) in a
5.88 M solution of H2O2 in water. The density of the solution is 1.00 g/mL.
(A) 1.00%
(B) 3.00%
(C) 5.00%
(D)20%
Ssoln
(B)
Hsoln
(C)
Wsoln
(D)
Esoln
65.Which of the following contains TWO anions that form soluble salts with most metal ions
and TWO anions that form insoluble salts with most metal ions?
(A)Sulfate, hydroxide, chromate, sulfide
66.Consider an aqueous solution that contains 0.10 M each of Pb2+, Hg2+ and Ni2+. If a
solution containing 2.0 x 10-20 M S2- is added to the solution containing the metal ions, which
sulfides will precipitate from the solution?
PbS: Ksp = 8.0 x 10-28; HgS: Ksp = 4 x 10-53; NiS: Ksp = 3.2 x 10-19
(A)PbS, HgS and NiS
(C)HgS
S and NiS
(D)NiS only
67.Fluo
orine-18 is one
o of the ra
adioactive nuclides
n
utilized in Positron Emisssion Tomogrraphy
(PET) scans.
s
Fluorrine-18 can be synthessized by bom
mbarding oxygen-18 n
nuclei with
hydroge
en-1 nuclei,,
oxygen-18 + hydro
ogen-1 --> fluorine-18 + X
What iss the identityy of the othe
er product, X, in this re
eaction?
(A)alpha particle
(B)beta
a particle
(C)positron
(D)neuttron
69.
Following represents
r
e
equation
of state for n moles of real gas
n 2a
P
+
[ V nb ] = nRT
V2
Se
elect correcct statementts :
n 2a
2
(A)
Constant a is a measu
ure of force of attraction
n between gas
g molecu
ules and V is
also called internal pressure
(B)
ed in L mol1
a is expressed in atm L2 mol2, b is expresse
(C)
(D)
All of the ab
bove are co
orrect statem
ments
Pb
1 +
RT
on involving a single re
eactant in each case, a plot of ratte of the
70.The three differrent reactio
reaction on
n the y-axis,, versus con
ncentration of the reactant on the x-axis, yield
ds three
different cu
urves shown
n below :
10
(i) dc
(iii) dc
(ii) dc
dt
dt
dt
what are the possible orders of the reactions (i), (ii), (iii).
(A) 1, 2, 3
(B) 2, 1,
1
2
(C) 0, 1, 2
(D) 0, 1,
1
2
71
A mixture of N2O4(g) and NO2(g) under equilibrium has an average molar mass of 76.
The mol-fraction of N2O4 at equilibrium and the percent N2O4 dissociated are
(A)
0.6 and 25
(B)0.8 and 40
72. Which of the following amines could be made successfully in a Gabriel synthesis?
(A) aniline
73. Which compound would NOT be readily made from benzenediazonium chloride?
(A) chlorobenzene
(B) iodobenzene
(C) benzonitrile
(B) N-methyl-1-phenylethylamine
(C) N,N-dimethylaniline
(D) N-methylbenzylamine
75. The compound below that will be most reactive in a nucleophilic substitution reaction is
(A) p-chlorotoluene
(B) p-fluorotoluene
(C) p-chloronitrobenzene
(D) p-fluoronitrobenzene
76. The cyclic transition state in the Claisen rearrangement involves reorganization of how
many electron pairs?
(A) 1
(B) 2
(C) 3
(D) 4
(B) erythrose
(D) glucose
11
(A) C-1
(B) C-2
(C) C-3
(D) C-4
(B) C-2
(C) C-3
(D) C-5
(B) D-ribose
(C) D-mannose
(D) D-galactose
12