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This safety data sheet is prepared in accordance with EU directive 91/155/EC ammended by
directive 2001/98/EC.
Recommended use
Registration number
(Denmark) , PR-983028,
Company
Sigma Coatings BV
Amsterdamseweg 14
1422 AD Uithoorn
Telephone
+31297541234
Telefax
+31297541806
+31204075210
2. COMPOSITION/INFORMATION ON INGREDIENTS
Components
CAS-No.
Symbol(s)
R-phrase(s)
Concentration
EINECS
No
203-550-1
108-10-1
F, Xn
2.50 - 10.00%
xylene
215-535-7
1330-20-7
Xn
265-199-0
64742-95-6 Xn, N
colophony
copper (I) oxide
Zinc oxide
diuron
232-475-7
215-270-7
215-222-5
206-354-4
8050-09-7
1317-39-1
1314-13-2
330-54-1
R11, R20,
R36/37, R66
R10, R20/21,
R38
R10, R51/53,
R65, R37,
R66, R67
R42/43
R22, R50/53
R50/53
R22, R40,
R48/22,
R50/53
Xn
Xn, N
N
Xn, N
0.00 - 2.50%
10.00 - 25.00%
10.00 - 25.00%
25.00 - 50.00%
10.00 - 25.00%
2.50 - 10.00%
3. HAZARDS IDENTIFICATION
Hazardous components :
copper (I) oxide
colophony
diuron
R-phrase(s) :
FLAMMABLE.
HARMFUL IF SWALLOWED.
IRRITATING TO RESPIRATORY SYSTEM.
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P-phrase(s) :
Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use.
Eye contact
Skin contact
Inhalation
Ingestion
Burns
When symptoms persist or in all cases of doubt seek medical advice. Never
give anything by mouth to an unconscious person.
Irrigate copiously with clean, fresh water for at least 10 minutes, holding the
eyelids apart. Remove contact lenses. Seek medical advice.
Take off all contaminated clothing immediately. Wash skin thoroughly with
soap and water or use recognized skin cleanser. Do NOT use solvents or
thinners.
Remove to fresh air. Keep patient warm and at rest. If breathing is irregular
or stopped, administer artificial respiration. If unconscious place in recovery
position and seek medical advice.
If accidently swallowed obtain immediate medical attention. Keep at rest. Do
not induce vomiting.
If spills on clothing catch fire, wash with plenty of water. Remove loose
clothing. Do not remove clothing that has melted to the skin.Obtain medical
attention.
5. FIRE-FIGHTING MEASURES
Specific hazards during fire
fighting
Environmental precautions
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Avoid exceeding of the given occupational exposure limits (see section 8).
Use only in area provided with appropriate exhaust ventilation. Avoid contact
with skin, eyes and clothing. Smoking, eating and drinking should be
prohibited in the application area. Avoid inhalation of vapour or mist. For
personal protection see section 8.
Prevent the creation of flammable or explosive concentrations of vapour in
air and avoid vapour concentration higher than the occupational exposure
limits. When transferring from one container to another apply earthing
measures and use conductive hose material. No sparking tools should be
used. The product should only be used in areas from which all naked lights
and other sources of ignition have been excluded. No smoking. The
accumulation of contaminated rags and dry overspray, particularly in spray
booth filters, may result in spontaneous combustion. Good housekeeping
standards, regular safe removal of waste materials and regular maintenance of
spray booth filters will minimise the risks of spontaneous combustion and
other fire hazards.
Additional advice
Storage
Requirements for storage areas
and containers
3,170 m3/l
TO REACH 10 % LEL
89 m3/l
119 mg/m3
Components on the national MAC list and/or the European TLV list (98/24/EC):
Components
CAS-No.
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Value
[mg/m3]
Value
[ppm]
Basis
108-10-1
104.00
208.00
83.00
208.00
25.00
50.00
20.00
50.00
xylene
can be absorbed through skincan be absorbed
through skin
1330-20-7
210.00
221.00
442.00
50.00
50.00
100.00
64742-95-6
125.00
ESIG TWA
diuron
330-54-1
10.00
Hand protection
Eye protection
Skin and body protection
:
:
Additional advice
Environmental protection
Personal protection
SigmaKalon Internal Safety
Code (INSACO)
Please contact your personal protection equipment supplier for further advice
:
:
:
:
Autoignition temperature
Upper explosion limit
Lower explosion limit
Density
Water solubility
:
:
:
:
:
pH
viscous
various
mild acetone-like
29.0 C
Note: see user defined free text
7.45 %(V)
0.95 %(V)
1.7 g/cm3
not applicable
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Viscosity, dynamic
1,300 mPa.s at 23 C
Flow time
>= 60 s
Transversal section: 6 mm
Method: ISO 2431 (EN 535) 6 mm CUP
Conditions to avoid
Hazardous reactions
Hazardous decomposition
products
Avoid temperatures above 60C (140 F), direct sunlight and contact with
sources of heat.
Keep away from oxidising agents, strongly alkaline and strongly acid
materials in order to avoid exothermic reactions.
In case of fire hazardous decomposition products may be produced such as:
Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx),
dense black smoke.
Skin irritation
Eye contact
Further information
:
:
DIURON (330-54-1)
Acute oral toxicity
Acute inhalation toxicity
The preparation has been assessed following the conventional method of the
Dangerous Preparations Directive 1999/45/EC and is classified for
ecotoxicological properties accordingly. See sections 2 and 15 for details.
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The product should not be allowed to enter drains, water courses or the soil.
Disposal together with normal waste is not allowed. Special disposal required
according to local regulations.
:
:
:
P
solvent naphtha (petroleum), light aromatic
F-E, S-E
Note
If pack sizes less than 450L, under the terms of 2.2.3.1.5, this product is not subject to the provisions of ADR.
Harmful
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R-phrase(s)
R10
R22
R37
R40
R50/53
Flammable.
Harmful if swallowed.
Irritating to respiratory system.
Limited evidence of a carcinogenic effect.
Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Repeated exposure may cause skin dryness or
cracking.
May cause sensitization by inhalation and skin
contact.
R66
R42/43
S-phrase(s)
S61
S21
S36/37/39
S60
S42c
P-phrase(s)
P95
Further information
This product does not contain organotin compounds acting as biocides and
complies with the International Convention on the Control of Harmful AntiFouling Systems on Ships as adopted by IMO in October 2001 (IMO
document AFS/CONF/26).
Active ingredients :
Components
copper (I) oxide
diuron
CAS-No.
1317-39-1
330-54-1
Weight %
36.90
4.10
National legislation
Registration number
Vlarem
:
:
(Denmark) , PR-983028,
P2, N
CPR Classification
K3 N
NER Classification
R11
R20
R36/37
R66
Highly flammable.
Harmful by inhalation.
Irritating to eyes and respiratory system.
Repeated exposure may cause skin dryness or cracking.
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xylene
R10
R20/21
R38
Flammable.
Harmful by inhalation and in contact with skin.
Irritating to skin.
R10
R51/53
R65
R37
R66
R67
Flammable.
Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Harmful: may cause lung damage if swallowed.
Irritating to respiratory system.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
colophony
R42/43
R22
R50/53
Harmful if swallowed.
Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Zinc oxide
R50/53
diuron
R22
R40
R48/22
Harmful if swallowed.
Limited evidence of a carcinogenic effect.
Harmful: danger of serious damage to health by prolonged
exposure if swallowed.
Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R50/53
Version: 4.10
The information contained in this safety data sheet is based on the present state of knowledge and current European and
National legislation at the date of issue. The supplier reserves the right to modify data on the safety data sheet without
further notice. Any change in data will normally be followed by the issue of a new safety data sheet. The user should
check the date of issue and if more than 12 months have elapsed, then the data should only be used after checking with
the nearest sales office of the supplier to establish that the data is still valid. As the specific conditions of use of the
product are outside the suppliers control, the supplier is not reponsible for the (negative) consequences of these specific
conditions of use, which are outside of the suppliers. control and which are not compliant with the handling, storage
and other instructions in this safety data sheet.
After all component(s) stated on the relevant Technical Data Sheet have been mixed the safety precautions mentioned
on each of the component(s) safety data sheets and labels should be used in assessing the safety precautions of the
mixed product.
For further information see technical data sheet number: 7297
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