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ATP
Metal-ATP
Complex
Ag+ + Y4 -
Mn+ + Y4-
AgY3-
[MY(n-4)]
4 = [Y4-]/ cT
Where:
Where:
K1K2K3K4
[H+]4+K1[H+]3+K1K2[H+]2+K1K2K3[H+]+K1K2K3K4
Effect of reaction
completeness on
titration curve: As Kf
increases, the reaction
becomes more
complete pM/V
increases (steeper
slope) at the
equivalence point
region.
4 = 0.30 at pH 10
Effect of pH on
titration curve: as
pH increases, the
slope at the
equivalence point
region becomes
steeper (more
distinct break at the
equivalence point).
An auxiliary
complexing agent
like NH3, tartrate,
citrate or
triethanolamine,
prevents precipitation
of metal hydroxide.
Metal ion indicators change color when they bind to a metal ion.
Hardness of water
A 100-mL sample of water containing Ca2+ and
Mg2+ ions is titrated with 15.28 mL of 0.01016
M EDTA in an ammonia buffer at pH 10.00.
Another sample of 100 mL is treated with
NaOH to precipitate Mg(OH)2, and then titrated
at pH 13.00 with 10.43 mL of the same EDTA
solution. Calculate the ppm of CaCO3 (100.09)
and of MgCO3 (84.314) in the sample.
K ~ 1021