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You are on page 1of 40

PHYSICS

(HELD ON SUNDAY 22nd MAY, 2016)

PART-I : PHYSICS

1.

This section contains Five questions.

Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct

For each question, darken the bubble corresponding to the correct option in the ORS

For each question, marks will be awarded in one of the following categories :

Full Marks

: +3 If only the bubble corresponding to the correct option is darkened.

Zero Marks

: 0 If none of the bubbles is darkened.

Negative Marks : 1 In all other cases

A parallel beam of light is incident from air at an angle on the side PQ of a right angled triangular prism

of refractive index n 2 . Light undergoes total internal reflection in the prism at the face PR when

has a minimum value of 45. The angle of the prism is :

n=2

(A) 15

Ans. (A)

(B) 22.5

(C) 30

(D) 45

45

r1=30

r2 = 45

Sol.

Q

1 sin 45 =

2 sin r1

r2 r1 =

= 45 30

= 15

CODE-9

1/40

PHYSICS

2.

In a historical experiment to determine Planck's constant, a metal surface was irradiated with light of

different wavelengths. The emitted photoelectron energies were measured by applying a stopping

potential. The relevant data for the wavelength () of incident light and the corresponding stopping

potential (V0) are given below:

m V0 Volt

0.3

0.4

0.5

8

2.0

1.0

0.4

19

Given that c = 3 10 ms and e = 1.6 10 C, Planck's constant (in units of J s) found from such

an experiment is :

34

34

(A) 6.0 10

(B) 6.4 10

34

(C) 6.6 10

(D) 6.8 10

34

Ans. (B)

hC

Sol. KE max

eVs

hC

1.6 10 19 2

h 3 108

3000 1010

... (i)

1.6 1019 1

h 3 108

4000 1010

... (ii)

h 3 108

1.6 10 19

From (ii)

10

4000 10

1.6 1019 2

1.6 1019

h 3 108 1 1 h 3 108 4 3

107 3 4

107 12

1.6 1019

h 3 108 1

107

12

1.6 4

1019 10 7

h

108

6.4 10

2/40

h 3 108

h 3 108

1.6 10 19

3000 1010 4000 1010

34

Js = h

JEE(Advanced) 2016 Final Exam/Paper-1/Held on Sunday 22nd May, 2016

CODE-9

3.

A uniform wooden stick of mass 1.6 kg and length rests in an inclined manner on a smooth, vertical

wall of height h (<) such that a small portion of the stick extends beyond the wall. The reaction force

of the wall on the stick is perpendicular to the stick. The stick makes an angle of 30 with the wall

and the bottom of the stick is on a rough floor. The reaction of the wall on the stick is equal in magnitude

to the reaction of the floor on the stick. The ratio h/ and the frictional force f at the bottom of the

stick are:

2

(g = 10 ms )

(A)

h

3

16 3

,f

N

16

3

(B)

h 3

16 3

,f

N

16

3

(C)

h 3 3

8 3

,f

N

16

3

(D)

h 3 3

16 3

,f

N

16

3

Ans. (D)

N1

Sol.

30

N2

mg

60

N1 cos 30 f = 0

... (i)

N1 sin 30 + N2 mg = 0

... (ii)

h

mg cos 60 N1

0

2

cos 30

... (iii)

Also, given N1 = N2

... (iv)

solving (i), (ii), (iii) & (iv) we have

h 3 3

16 3

& f

16

3

CODE-9

3/40

PHYSICS

PHYSICS

4.

A water cooler of storage capacity 120 litres can cool water at constant rate of P watts. In a closed

circulation system (as shown schematically in the figure), the water from the cooler is used to cool

an external device that generates constantly 3 kW of heat (thermal load). The temperature of water

fed into the device cannot exceed 30C and the entire stored 120 litres of water is initially cooled

to 10C. The entire system is thermally insulated. The minimum value of P (in watts) for which the

device can be operated for 3 hours is :

Cooler

Device

Hot

Cold

(Specific heat of water is 4.2 kJ kg1 K1 and the density of water is 1000 kg m3)

(A) 1600

Ans. (B)

(B) 2067

(C) 2533

(D) 3933

dT

dt

dT

20

dt 60 60 3

P = 2067 W

5.

An infinite line charge of uniform electric charge density lies along the axis of an electrically conducting

infinite cylindrical shell of radius R. At time t = 0, the space inside the cylinder is filled with a material of

permittivity and electrical conductivity . The electrical conduction in the material follows Ohm's law.

Which one of the following graphs best describes the subsequent variation of the magnitude of current density

j(t) at any point in the material?

j(t)

j(t)

(A)

j(t)

(B)

(0,0)

j(t)

(C)

(0,0)

(D)

(0,0)

(0,0)

Ans. (A)

4/40

CODE-9

So due to leakage current, charge & current density will exponentially decay & will become zero at

infinite time. So correct answer is (A)

for any small element

dr

Resistance R = 2r

Capacitance C =

2r

dr

Product R C =

= constant

q q0e

dq q 0

e

I=

dt

t

q0 e

I

Current density =

A

2r

je

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these

four option(s) is (are) correct.

For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

For each question, marks will be awarded in one of the following categories :

Full Marks

Partial Marks : +1 For darkening a bubble corresponding to each correct option, Provided NO

incorrect option is darkened.

Zero Marks

for example, if (A), (C) and (D) are all the correct options for a question, darkening all these three

will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and

(B) will result in 2 marks, as a wrong option is also darkened

CODE-9

5/40

PHYSICS

PHYSICS

6.

A transparent slab of thickness d has a refractive index n(z) that increases with z. Here z is the vertical

distance inside the slab, measured from the top. The slab is placed between two media with uniform refractive

indices n1 and n2 (> n1), as shown in the figure. A ray of light is incident with angle i from medium 1 and

emerges in medium 2 with refraction angle f with a lateral displacement .

Which of the following statement(s) is(are) true ?

n1= constant

z

n(z)

d

n2= constant

(D) n1sini = n2sinf

(A) is independent of n2

(C) n1sini = (n2 n1)sinf

Ans. (A,B,D)

n1 sini = n2sinf

7.

A conducting loop in the shape of right angled isosceles triangle of height 10 cm is kept such that

the 90 vertex is very close to an infinitely long conducting wire (see the figure). The wire is electrically

insulated from the loop. The hypotenuse of the triangle is parallel to the wire. The current in the triangular

1

loop is in counterclockwise direction and increased at constant rate of 10 A s . Which of the following

statement(s) is(are) true?

10cm

90

(A) The induced current in the wire is in opposite direction to the current along the hypotenuse.

(B) There is a repulsive force between the wire and the loop

0

volt

(C) If the loop is rotated at a constant angular speed about the wire, an additional emf of

is induced in the wire

Ans. (B,D)

6/40

CODE-9

Sol.

PHYSICS

E

dx

by direction of induced electric field, current in wire is in same direction of current along the hypotenuse.

0.1

0i

0i

2x 2xdx 10

0

Mutual inductance =

Induced emf in wire =

0 di 0

10 0

10 dt 10

A plano-convex lens is made of a material of refractive index n. When a small object is placed 30

cm away in front of the curved surface of the lens, an image of double the size of the object is produced.

Due to reflection from the convex surface of the lens, another faint image is observed at a distance of 10

cm away from the lens. Which of the following statement(s) is(are) true?

8.

0

10

(C) The faint image is erect and real

Ans. (A,D)

60cm

h

O

30cm

2h

1 1 1

v u f

1

1

1

f 20cm

60 30 f

Also

1

1 1 n 1

n 1

f

R

R

... (i)

... (ii)

CODE-9

7/40

////

/

///

////

////////////////////

PHYSICS

////

/

30cm

10cm

1 1 1 2

v u f R

1

1

1 2

10 30 f R

... (iii)

R= 30 cm

from (i), (ii) & (iii)

n = 2.5,

9.

An incandescent bulb has a thin filament of tungsten that is heated to high temperature by passing an electric

current. The hot filament emits black-body radiation. The filament is observed to break up at random locations

after a sufficiently long time of operation due to non-uniform evaporation of tungsten from the filament.

If the bulb is powered at constant voltage, which of the following statement(s) is(are) true?

(A) The temperature distribution over the filament is uniform

(B) The resistance over small sections of the filament decreases with time

(C) The filament emits more light at higher band of frequencies before it breaks up

(D) The filament consumes less electrical power towards the end of the life of the bulb

Ans. (C,D)

Sol. Because of non-uniform evaporation at different section, area of cross-section would be different at

different sections.

Region of highest evaporation rate would have rapidly reduced area and would become break up crosssection.

Resistance of the wire as whole increases with time.

Overall resistance increases hence power decreases. At break up junction temperature would be highest,

thus light of highest band frequency would be emitted at those cross-section.

10.

A length-scale () depends on the permittivity () of a dielectric material, Boltzmann constant kB, the absolute

temperature T, the number per unit volume (n) of certain charged particles, and the charge (q) carried by

each of the particles, Which of the following expressions(s) for is(are) dimensionally correct?

nq 2

(A)

k T

B

k B T

(B) nq 2

q2

(C)

n 2 / 3 k T

B

q2

(D)

n1/3 k T

B

Ans. (B,D)

8/40

CODE-9

1 q2

F

4 0 r 2

PHYSICS

Sol. We know,

q2

(Fr 2 )4

0

So, dimension

q2

dim (Fr 2 ) = MLT2 L2 = ML3T2

0

3

2

(B)

(C)

(D)

L3 ML3 T 2 1

ML2 T 2

L

(A)

nq 2

k B T

(E) vol

ML2 T 2 L3

L

Fr 2

MLT 2 L2

Fr 2 (vol)2 / 3

MLT 2 L2 L2

L3 L3 / 2

(K)

ML2 T 2

Fr 2 (vol)1/ 3

MLT 2 L2 L

L

Energy

ML2 T 2

1

3

L ]

vol

[ dimension n = dim

11.

Highly excited states for hydrogen like atoms (also called Rydberg states) with nuclear charge Ze are

defined by their principal quantum number n, where n >> 1. Which of the following statement(s) is

(are) true?

(A) Relative change in the radii of two consecutive orbitals does not depend on Z

(B) Relative change in the radii of two consecutive oribitals varies as 1/n

(C) Relative change in the energy of two consecutive orbitals varies as 1/n3

(D) Relative change in the angular momenta of two consecutive orbitals varies as 1/n

Ans. (A, B, D)

CODE-9

9/40

PHYSICS

n2

Sol. As radius r

z

2

n 1 n

2 1

r z z

2n 1

2

2

n n

r

n

n

z

2

as energy E z 2

n

z2

z2

2

2

2

n 1 n 2

E n n 1

2

. n 1

2

2

z

E

n . n 1

2

n 1

E 2n 1 2n 1

2

E

n2

n

n

as angular momentum L =

12.

nh

2

n 1 h nh

2

nh

2

2 1 1

n n

The position vector r of a particle of mass m is given by the following equation r(t) t 3 i t 2 j ,

where

10 3

ms , = 5 ms2 and m = 0.1 kg. At t = 1 s, which of the following statement(s) is(are)

3

(A) The velocity v is given by v (10i 10 j)ms 1

(B) The angular momentum L with respect to the origin is given by L k Nms

3

20

(D) The torque with respect to the origin is given by k Nm

3

Ans. (A, B, D)

10/40

CODE-9

r t i t 2 j

PHYSICS

Sol.

dr

v

3t 2 i 2 tj

dt

d2 r

a 2 6ti 2j

dt

At t = 1

10

(A) v 3 1i 2 J 1j

3

= 10i 10j

(B) L r p

10

3

5

= k

3

10

F

(C) m 6 1i 2 5 j = 2i j

3

(D) r F

10

= i 5j 2i j

3

10

k 10 k

3

20

k

3

CODE-9

11/40

PHYSICS

13.

Two loudspeakers M and N are located 20m apart and emit sound at frequencies 118 Hz and 121

Hz, respectively. A car is initially at a point P, 1800 m away from the midpoint Q of the line MN

and moves towards Q constantly at 60 km/hr along the perpendicular bisector of MN. It crosses Q

and eventually reaches a point R, 1800 m away from Q. Let (t) represent the beat frequency measured

by a person sitting in the car at time t. Let P, Q and R be the beat frequencies measured at locations

P, Q and R, respectively. The speed of sound in air is 330 ms1. Which of the following statement(s)

is(are) true regarding the sound heard by the person ?

(A) The plot below represents schematically the variation of beat frequency with time

(t)

P

Q

(B) The plot below represents schematically the variations of beat frequency with time

(t)

P

(C) The rate of change in beat frequency is maximum when the car passes through Q

(D) P + R = 2 Q

Ans. (A, C, D)

Sol. fM =

C V cos

f1

C

fN =

C V cos

f2

C

(f1)M

(f2)N

f = fN fM

=

C V cos

f 2 f1

C

d f

V

d

f 2 f1 sin

dt

C

dt

&

12/40

d f

is maximum when = 90

dt

JEE(Advanced) 2016 Final Exam/Paper-1/Held on Sunday 22nd May, 2016

CODE-9

PHYSICS

[ C is correct]

V

P = 1 cos f

C

Q = f

V

R = 1 cos f

C

P + r = 2 Q

This section contains FIVE questions.

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

For each question, darken the bubble corresponding to the correct integer in the ORS.

For each question, marks will be awarded in one of the following categories :

Full Marks

: +3 If only the bubble corresponding to the correct answer is darkened.

Zero Marks

: 0 In all other cases.

Consider two solid spheres P and Q each of density 8 gm cm3 and diameters 1 cm and 0.5 cm, respectively.

Sphere P is dropped into a liquid of density 0.8 gm cm3 and viscosity = 3 poiseulles. Sphere Q is dropped

into a liquid of density 1.6 gm cm3 and viscosity = 2 poiseulles. The ratio of the terminal velocities of

P and Q is.

Ans. 3

14.

Sol. VT

r 2 d m d L

n

2

VTP rP n L2 d m d L1

VTQ rQ n L1 d m d L2

2

VTP 2 2 8 0.8

VTQ 1 3 8 1.6

VTP

3

VTQ

15.

Two inductors L1 (inductance 1 mH, internal resistance 3 ) and L2 (inductance 2mH, internal resistance

4), and a resistor R (resistance 12 ) are all connected in parallel across a 5V battery. The circuit is

switched on at time t = 0. The ratio of the maximum to the minimum current (Imax/Imin) drawn from the

battery is.

Ans. 8

CODE-9

13/40

PHYSICS

L1=1mH

r1=3

L2=2mH

r2=4

R=12

Sol.

= 5V

I max

5

A (Initially at t = 0)

R 12

I min

1 1 1

(finally in steady state)

R eq

r1 r2 R

= 5

3 4 12

10

A

3

I max

8

I min

16.

12

12

12

The isotope 5 B having a mass 12.014 u undergoes -decay to 6 C. 6 C has an excited state of the

nucleus (126 C*) at 4.041 MeV above its ground state. If 125 B decays to 12

C*, the maximum kinetic energy

6

of the -particle in units of MeV is (1u = 931.5 MeV/c2, where c is the speed of light in vacuum).

Ans. 9

Sol.

12

5

0

B 12

6 C 1e v

Energy used for excitation of

12

6

C = 4.041 MeV

= 13.041 4.041 = 9 MeV

17.

A hydrogen atom in its ground state is irradiated by light of wavelength 970 . Taking

hc/e = 1.237 106 eV m and the ground state energy of hydrogen atom as 13.6 eV, the number

of lines present in the emission spectrum is

Ans. 6

14/40

CODE-9

Sol.

PHYSICS

hc 12370

970

13.6 + 12.7 =

13.6

n2

n = 16

n=4

Number of lines = nC2 = 6

18. A metal is heated in a furnace where a sensor is kept above the metal surface to read the power radiated

(P) by the metal. The sensor has a scale that displays log2(P/P0), where P0 is a constant. When the metal

surface is at a temperature of 487 C, the sensor shows a value 1. Assume that the emissivity of the metallic

surface remains constant. What is the value displayed by the sensor when the temperature of the metal

surface is raised to 2767 C ?

Ans. 9

Sol. P = eAT4 where T is in kelvin

log 2

log 2

eA 487 273

P0

eA 2767 273

P0

...(i)

...(ii)

(ii) (i)

3040

log 2

x 1

760

x=9

CODE-9

15/40

CHEMISTRY

19.

PART-II : CHEMISTRY

SECTION1 : (Maximum Marks : 15)

This section contains Five questions.

Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct

For each question, darken the bubble corresponding to the correct option in the ORS

For each question, marks will be awarded in one of the following categories :

Full Marks

: +3 If only the bubble corresponding to the correct option is darkened.

Zero Marks

: 0 If none of the bubbles is darkened.

Negative Marks : 1 In all other cases

P is the probability of finding the 1s electron of hydrogen atom in a spherical shell of infinitesimal

2

thickness, dr, at a distance r from the nucleus. The volume of this shell is 4r dr. The qualitative sketch

of the dependence of P on r is -

(B)

(A)

(C)

(D)

Ans. (B)

3

(r)

1 2

2 e a0

a0

probability of finding an e in a spherical shell of thickness, 'dr' at distance 'r' from nucleus,

P = 2(r) . 4r2dr

3

2r

1 a0

= 16r e dr

a0

2

So P is zero at r = 0 and r =

16/40

CODE-9

20.

One mole of an ideal gas at 300 K in thermal contact with surroundings expands isothermally from

1.0 L to 2.0 L against a constant pressure of 3.0 atm. In this process, the change in entropy of surroundings

1

(Ssurr) in J K is (1 L atm = 101.3 J)

(A) 5.763

(B) 1.013

(C) 1.013

(D) 5.763

Ans. (C)

Sol. From 1st law of thermodynamics

qsys = U w = 0 [Pext.V]

= 3.0 atm (2.0 L 1.0 L) = 3.0 L-atm

Ssurr =

q

(q rev )surr

sys

T

T

3.0 101.3J

300K

= 1.013 J/K

21.

(A) Al < Ga < In < Tl

Ans. (B)

th

Sol. The order of radius of 13 group elements is Ga < Al < In < Tl.

Reason Due to poor shielding effect of d-orbital, radius of Ga is smallar than Al.

22.

(A) ethylene-propylene copolymer

(C) polypropylene

(D) polybutylene

Ans. (A)

CH3

CH3

CH2 = C CH = CH2

Sol.

Polymerisation

Isoprene

Natural rubber

H2(excess)

catalyst

CH3

CH3

CH2 = CH2 + CH2 = CH

Ethylene

CODE-9

( CH2C=CHCH2 )n

Propylene

Copolymerisation

Completely hydrogenated

Natural rubber

17/40

CHEMISTRY

CHEMISTRY

23.

Among [Ni(CO)4], [NiCl4] , [Co(NH3)4Cl2]Cl, Na3[CoF6], Na2O2 and CsO2, the total number of

paramagnetic compounds is (A) 2

(B) 3

(C) 4

(D) 5

Ans. (B)

Sol. Compound/Ion

1.

[Ni(CO)4]

Diamagnetic

2.

[NiCl4]2

Paramagnetic

3.

[Co(NH3)4Cl2]Cl

Diamagnetic

4.

Na3[CoF6]

Paramagnetic

5.

Na2O 2

Diamagnetic

6.

CsO2

Paramagnetic

So total number of paramagnetic compounds is 3.

24.

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these

four option(s) is (are) correct.

For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

For each question, marks will be awarded in one of the following categories :

Full Marks

: +4 If only the bubble(s) corresponding to the correct option(s) is (are) darkened.

Partial Marks : +1 For darkening a bubble corresponding to each correct option, Provided NO

incorrect option is darkened.

Zero Marks

: 0 If none of the bubbles is darkened.

Negative Marks : 2 In all other cases.

for example, if (A), (C) and (D) are all the correct options for a question, darkening all these three

will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and

(B) will result in 2 marks, as a wrong option is also darkened

A plot of the number of neutrons (N) against the number of protons (P) of stable nuclei exhibits upwards

deviation from linearity for atomic number, Z > 20. For an unstable nucleus having N/P ratio less

than 1, the possible mode(s) of decay is(are) (A) decay ( emission)

Ans. (B, D)

Sol. As

N

N

ratio is less than 1, for possible decay mode ,

ratio should increase. The possible modes

P

P

are -decay, K-capture and + -decay. Hence, correct option are (B), (D).

(In -decay or neutron decay ,

18/40

N

ratio will decrease further)

P

CODE-9

25.

CHEMISTRY

The correct statements(s) about of the following reaction sequence is(are)

(i) O2

Cumene(C9H12)

(ii) H3O

CHCl3/NaOH

Q (major) + R (minor)

NaOH

S

PhCH2Br

Q

(A) R is steam volatile

(C) S gives yellow precipitate with 2, 4,-dinitrophenylhydrazine

(D) S gives dark violet coloration with 1% aqueous FeCl3 solution

Ans. (B, C)

CH3

CH3

O2

CH

Sol.

CH3

CH3

H /

OH

+ H3CCCH3

(Acetone)

(phenol)

P

OH

OH

CH=O

CHCl3

+NaOH

(P)

OH

Q

(major)

Steam volatile

(forms intramolecular

hydrogen bonding)

OH

CH=O

NaOH

PhCH2Br

CH=O

R

(minor)

inter molecular H-bonding

So R is not steam volatile

OCH2Ph

CH=O

S

(does not give dark violet

coloration with 1% FeCl3 solution)

Q gives dark violet coloration with 1% aqueous FeCl3 solution because it has phenolic (OH) group.|

CODE-9

19/40

CHEMISTRY

26.

H

OH

CHO

(A)

(B)

Ph

(C) Ph

(D)

Ph

Ph

Ans. (A,B,C)

Sol. Tollens's test is given by compounds having aldehyde group. Also -hydroxy carbonyl gives positive

tollen's test.

H

(A)

C =O

Tollen's

reagent

CO2

+ Ag mirror

(+ve test)

Acraldehyde

CH=O

(B)

CO2

Tollen's

reagent

+ Ag mirror

(+ve test)

Benzaldehyde

(C) PhCHCPh

Tollen's

reagent

PhCCPh

OH O

Benzoin

+ Ag mirror

(+ve test)

O O

(D) PhCH=CHCPh

Tollen's

reagent

No reaction

(ve test)

27.

NH2

(i) Acetic anhydride/pyridine

(ii) KBrO3 / HBr

+

(iv) NaNO2 / HCl, 273-278 K

(v) Cu/HBr

Br

Br

Br

Br

(A)

(B)

Br

Br

Br

(C)

Br

(D)

Br

Br

Ans. (B)

20/40

Br

CODE-9

O

NH2

Sol.

NH

O

Py.

NH

NH2

+

KBrO3 + HBr

Bromination

Acylation

or

acetylation

CHEMISTRY

H3O

Hydrolysis /

Br

Br

NaNO2 + HCl

273-278 K

N2+ Cl

Br

Cu

HBr

Br

28.

Br

The compound(s) with TWO lone pairs of electrons on the central atom is(are)

(B) ClF3

(C) XeF4

(A) BrF5

(D) SF4

Ans. (B,C)

Br

Sol. (A)

3 2

sp d hybridisation

Number of lone pair on centre atom = 1

square pyramidal

F (distorted octadehdral)

(B)

Cl

sp d hybridisation

T-shape

F

Xe

(C)

3 2

sp d hybridisation

square planar

F

F

(D)

sp d hybridisation

see-saw

F

F

Hence Ans. (B,C)

CODE-9

21/40

CHEMISTRY

29.

(A) Tetranuclear [B4O5(OH)4]2 unit

(B) All boron atoms in the same plane

2

(D) One terminal hydroxide per boron atom

Ans. (A,C,D)

OH

B

Sol. HO

OH

OH

(B) All boron atoms not in same plane

2

(C) Two boron are sp hybridised and two boron are sp hybridised

(D) One terminal hydroxide per boron atom is present.

30.

The reagent(s) that can selectively precipiate S2 from a mixture of S2 and SO42 in aqueous soltuion

is(are) :

(A) CuCl2

(B) BaCl2

(C) Pb(OOCCH3)2

(D) Na2[Fe(CN)5NO]

Ans. (A OR A, C)

S2

(A) CuCl2

(Soln)

CuS

(Soln)

(Soln)

(Black ppt.)

+ SO42 No ppt.

CuCl2

(Soln)

(Soln)

(B) BaCl2

BaS

(Sol )

(Sol )

2Cl

(No ppt.)

(Sol )

BaCl2

n

(Sol )

(Sol )

(Sol )

PbSO4

(Soln)

(D) Na2[Fe(CN)5NO]

n

(Sol )

Na2[Fe(CN)5NO]

n

(Sol )

+ 2CH3COO

n

(Black ppt.)

Pb(OOCCH3)2 + SO42

(Soln)

(Sol )

PbS

(Sol )

(White ppt.)

(C) Pb(OOCCH3)2 + S

22/40

2Cl

(Sol )

+ 2CH3COO

(White ppt.)

+ S2

(Sol )

2

+ SO4

(Soln)

Na4[Fe(CN)5NOS]

(Purple colour solution)

No ppt.

(Sol )

JEE(Advanced) 2016 Final Exam/Paper-1/Held on Sunday 22nd May, 2016

CODE-9

As in question selective precipitation is asked PbS will be precipitate much easier than PbSO4 though

both are insoluble. Hence answer should be (C) also alongwith (A)

31.

(A) A high activation energy usually implies a fast reaction

(B) Rate constant increase with increase in temperature. This is due to a greater number of collisions

whose energy exceeds the activation energy

(C) Higher the magnitude of activation energy, stronger is the temperature dependence of the

rate constant

(D) The pre-exponential factor is a measure of the rate at which collisions occur, irrespective of

their energy.

Ans. (B,C,D)

Sol. (A) k Ae E

/ RT

(B) eEa/RT = fraction of molecules having kinetic energy greater than activation energy which increase

as temperature increases.

k

E 1

2

2

a

(C) ln k R T T i.e., ln k E a

1

1

2

1

(D) Rate of reaction Total number of collisions Fraction of collisions which can form product

Rate of reaction

Ea/RT

ZAB (P e

Ea/RT

A e

32.

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

For each question, darken the bubble corresponding to the correct integer in the ORS.

For each question, marks will be awarded in one of the following categories :

Full Marks

: +3 If only the bubble corresponding to the correct answer is darkened.

Zero Marks

: 0 In all other cases.

The mole fraction of a solute in a solution is 0.1. At 298 K, molarity of this solution is the same as

3

its molality. Density of this solution at 298 K is 2.0 g cm . The ratio of the molecular weights of

MWsolute

, is

the solute and solvent, MW

solvent

Ans. (9)

CODE-9

23/40

CHEMISTRY

Let

M2 = Molar mass solvent

Molality,

0.1

m = 0.9 M 1000

2

....(1)

Molarity,

0.1

M = 0.1M + 0.9 M 2 1000

1

2

.....(2)

m=M

0.11000

200

0.9 M 2

0.1M1 0.9 M 2

M1

9

M2

CHEMISTRY

Sol. 1 mole solution has 0.1 mole solute and 0.9 mole solvent

Alternate solution :

M=m

Wsolute Wsolvent

Wsolvent

2

Wsolute = Wsolvent

33.

M solute

9

M solvent

In the following monobromination reaction, the number of possible chiral products is

CH2CH2CH3

Br2(1.0 mole)

Br

H

300C

CH3

(1.0 mole)

(enantiomerically pure)

Ans. (5)

Sol.

CH2CH2CH3

Br

H

CH3

(1.0 mole)

(enantiomerically pure)

24/40

CH2CH2CH3

Br2(1.0 mole)

300C

Br

CH2CH2CH3

+

CH2 Br

(Chiral)

Br

Br

CH3

(Achiral)

CODE-9

CH3

H

H

CH2CH3

Br

Br

Br

H

CH3

(Chiral)

34.

CH2CH3

H

H

H

Br + H

CH3

(Chiral)

CH3

Br

H

Br

CH3

(Achiral)

Br

H

+

H

H

H

H

+ H

Br

H

CH3

(Chiral)

CHEMISTRY

CH2Br

H

H

Br

CH3

(Chiral)

The diffusion coefficient of an ideal gas is proportional to its mean free path and mean speed. The

absolute temperature of an ideal gas is increased 4 times and its pressure is increased 2 times. As a

result, the diffusion coefficient of this gas increases x times. The value of x is

Ans. (4)

U Avg

Rate of diffusion

Sol.

2 2 N*

UAvg

UAvg

2 2 N*

UAvg (kT)

Rate of diffusion

2 2 P

3

T2

rfinal

(4) 2

=

rinitial

2

rfinal

4

rinital

35.

The number of geometric isomers possible for the complex [CoL2Cl2] (L = H2NCH2CH2O ) is

Ans. (5)

Sol. [CoL2Cl2]

(L = H2NCH2CH2O)

[Co(H2NCH2CH2O)2 Cl2]

It is

CODE-9

[M(AB)2C2]

type of complex

25/40

CHEMISTRY

M

C

M

C

M

C

and

A

B

In neutral or faintly alkaline solution, 8 moles permanganate anion quantitatively oxidize thiosulphate

anions to produce X moles of a sulphur containing product. the magnitude of X is

Ans. (6)

36.

MnO2 SO2

4

X

83=X4

X=6

26/40

CODE-9

MATHEMATICS

(HELD ON SUNDAY 22nd MAY, 2016)

This section contains Five questions.

Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct

For each question, darken the bubble corresponding to the correct option in the ORS

For each question, marks will be awarded in one of the following categories :

Full Marks

: +3 If only the bubble corresponding to the correct option is darkened.

Zero Marks

: 0 If none of the bubbles is darkened.

Negative Marks : 1 In all other cases

A debate club consists of 6 girls and 4 body. A team of 4 members is to be selected from this club

including the selection of a captain (from among these 4 member) for the team. If the team has to

include at most one boy, then the number of ways of selecting the team is

(A) 380

(B) 320

(C) 260

(D) 95

Ans. (A)

Sol. (6C4 + 6C3.4C1). 4C1 = 380

38.

37.

(A)

Ans. (C)

1

64

1

32

(B)

1

1 , for all x > 0, is x

(C)

1

27

(D)

1

25

1

2

Sol. x 4x ; x 0

x

' x 8 x

1

x2

8x 3 1

x2

1/ 3

1

(x) attains its minimum at x

8

1 1/ 3

1

8

1

4

8

2/3

31 / 3 1

CODE-9

1/ 3

1

27

JEE(Advanced) 2016 Final Exam/Paper-1/Held on Sunday 22nd May, 2016

27/40

MATHEMATICS

39.

Let

. Suppose 1 and 1 are the roots of the equation x2 2xsec + 1 = 0 and 2 and

6

12

2

2 are the roots of the equation x + 2xtan 1 = 0. If 1 > 1 and 2 > 2, then 1 + 2 equals

(A) 2(sec tan)

(B) 2sec

(C) 2tan

(D) 0

Ans. (C)

2 sec 4sec 2 4

2

1 sec | tan | { 1}

Sol. 1

2 tan 4 tan 2 4

2

2 tan sec

{ }

1 = sec tan ,

6 12

1 + 2 = 2tan

2

40.

(A)

Ans. (C)

Sol.

7

9

(B)

2

9

(C) 0

(D)

5

9

cos 2x cos x

3

2x 2n x

3

x 6n 1

or 6n 1

3

9

7

5

x , ,

and

in ()

3 9 9

9

sum = 0

41. A computer producing factory has only two plants T1 and T2. Plant T1 produces 20% and plant T2

produces 80% of the total computers produced. 7% of computers produced in the factory turn out

to be defective. It is known that

P(computer turns out to be defective given that is produced in plant T1)

= 10P(computer turns out to be defective given that it is produced in plant T2)

where P(E) denotes the probability of an event E. A computer produces in the factory is randomly

selected and it does not turn out to be defective. Then the probabality that it is produced in plant T2

is

36

47

78

75

(A)

(B)

(C)

(D)

73

79

93

83

Ans. (C)

28/40

CODE-9

JEE(Advanced) 2016 Final Exam/Paper-1/Held on Sunday 22nd May, 2016

Sol. P T1

20

100

P(T2) =

MATHEMATICS

80

100

D

Let P x

T2

D

P 10x

T1

P D

7

(given)

100

7

D

D

P T1 P P T2 P

T1

T2 100

20

80

7

10x

x

100

100

100

1

40

D

P

T2

D

1

40 P T

39

40

D 30

D 10

P

P

T1 40

T1 40

80 39

78

T2

100

40

P

D 20 30 80 39 93

100 40 100 40

This section contains EIGHT questions.

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these

four option(s) is (are) correct.

For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

For each question, marks will be awarded in one of the following categories :

Full Marks

: +4 If only the bubble(s) corresponding to the correct option(s) is (are) darkened.

Partial Marks : +1 For darkening a bubble corresponding to each correct option, Provided NO

incorrect option is darkened.

Zero Marks

: 0 If none of the bubbles is darkened.

Negative Marks : 2 In all other cases.

for example, if (A), (C) and (D) are all the correct options for a question, darkening all these three

will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and

(B) will result in 2 marks, as a wrong option is also darkened

CODE-9

29/40

MATHEMATICS

42.

dy

y 2 0, x 0 , passes through

dx

the point (1,3). The the solution curve(A) intersects y = x + 2 exactly at one point

(B) intersects y = x + 2 exactly at two points

(C) intersects y = (x + 2)

Ans. (A,D)

2

Sol. (x xy 4x 2y 4)

dy

y2 0

dx

dy

y2

dx

Let x + 2 = X, y = Y

(X)(X Y)

dY

Y2

dX

2

X dY = Y(XdY YdX)

dY XdY YdX

Y

X2

Y

n | Y | C

X

n | y |

y

C

x2

n3 =1 + C

C = 1 n3

curve

y

n | y | 1 n3 0, x 0

x2

......(i)

then

x2

n | x 2 | 1 n3 0

x2

x = 1, 5(reject)

x + 2 + 2n(x + 2) = 1 + n3

30/40

CODE-9

MATHEMATICS

Clearly left hand side is an increasing function

Hence, it is always greater than 2 + 2n2

therefore no solution

2

for option (C) put y = (x + 3) in equation (i)

(x 3)2

n(x 3)2 1 n3 0

x2

(x 3)2

(x 3)2

n

1 0

x2

3

x>0

x+3>x+2

and x + 3 > 3

(x 3)2

(x 3)2

n

1

So

x2

3

(x 3)2

(x 3)2

n

1 0 has no solution

x2

3

43.

Consider a pyramid OPQRS located in the first octant (x > 0,y > 0, z > 0) with O as origin, and

OP and OR along the x-axis and the y-axis, respectively. The base OPQR of the pyramid is a square

with OP= 3. The point S is directly above the mid-point T of diagonal OQ such that TS = 3. Then(A) the acute angle between OQ and OS is

(C) the length of the perpendicular from P to the plane containing the triangle OQS is

3

2

15

2

Ans. (B,C,D)

3 3

S 2 , 2 ,3

R(0,3,0)

Sol.

P(3,0,0)

Q(3,3,0)

CODE-9

31/40

MATHEMATICS

Given OP = OR = 3 and OPQR is a square

OQ = 3 2

OT

and ST = 3

ST

2

OT

tan 1 2

Also, length of perpendicular from P to the plane containing the triangle OQS is PT =

3

2

3

3

Also equation of RS is r 3j t i j 3k

2

2

O(0,0,0)

3t

3t

, 3 ,3t

2

2

3t

3t

Let co-ordinates of M , 3 ,3t

2

2

44.

OM.RS 0

R(0,3,0)

9

3

3t

t 3 9t 0

4 2

2

1 5

M , ,1

2 2

OM

9t

9

9t

2

2

3 3

S 2 , 2 ,3

1

3

1 25

30

15

1

4 4

4

2

In a triangle XYZ, let x,y,z be the lengths of sides opposite to the angles X,Y,Z, respectively and

2s = x + y + z. If

sx sy sz

4

3

2

8

, then3

(B) the radius of circumcircle of the triangle XYZ is

(C) sin

35

6

6

X

Y

Z 4

sin sin

2

2

2 35

3

2XY

(D) sin

2 5

Ans. (A,C,D)

32/40

CODE-9

Sol.

sx sy sz

k

Let

4

3

2

s x = 4k y + z x = 8k

s y = 3k

x + z y = 6k

s z = 2k

x + y z = 4k

MATHEMATICS

z

Y

x = 5k, y = 6k, z = 7k

3s (x + y + z) = 9k

s = 9k

Let r be inradius

r 2

8

3

3

s

8

.s

3

9k.4k.3k.2k

24.9k 2

8

.s

3

8

9k

3

8

.9k

3

k=1

x = 5, y = 6, z = 7

8

8

.9k

.9 6 6

3

3

R = circumradius =

xyz 5.6.7

35

4 4.6 6 4 6

X

Y

Z

r

2

36.6

4

sin sin sin

s

2

2

2 4R xyz s.xyz 9.5.6.7 35

cos Z

x 2 y 2 z 2 25 36 49 1

2xy

2.5.6

5

1

Z 1 cos Z

XY

5 3

sin 2

cos2

2

2

2

5

2

1

CODE-9

33/40

MATHEMATICS

45.

Let RS be the diameter of the circle x2 + y2 = 1, where S is the point (1,0). Let P be a variable point

(other than R and S) on the circle and tangents to the circle at S and P meet at the point Q. The normal

to the circle at P intersects a line drawn through Q parallel to RS at point E. then the locus of E passes

through the point(s)-

1 1

(A) ,

3 3

1

1

(C) ,

3

3

1 1

(B) ,

4 2

1 1

(D) ,

4 2

Ans. (A,C)

(cos, sin)

y=1

Q

E(h,k)

(1,0)R

Sol.

S(1,0)

...(i)

Tangent at S : x = 1

...(ii)

1 cos

By (i) & (ii) : Q 1,

sin

y

1 cos

y tan

sin

2

Normal at P : y

......(iii)

sin

x y tan .x

cos

......(iv)

1 tan 2

Point of intersection of equation (iii) and (iv), E : h

eliminating : h

2 ; k tan

2

1 k2

y 2 1 2x

2

34/40

CODE-9

46.

The circle C1: x + y = 3, with centre at O, intersects the parabola x = 2y at the point P in the first

quadrant. Let the tangent to the circle C1 at P touches other two circles C2 and C3 at R2 and R3, respectively.

Suppose C2 and C3 have equal radii 2 3 and centres Q2 and Q3, respectively. If Q2 and Q3 lie on

the y-axis, then(A) Q2Q3 = 12

(B) R2R3 = 4 6

Ans. (A,B,C)

Sol. On solving x2 + y2 = 3 and x2 = 2y we get point P( 2,1)

Equation of tangent at P

2.x y 3

Q2(0,9) C 2

R2

2y = x2

2 0 k 3

2 3

2 1

P(2,1)

x +y =3

R3

Q3(0,3)

k = 9, 3

C3

hence Q2Q3 = 12

R2R3

Q2Q3

2 3 2 3

122 48 96 4 6

1

1

Hence area of OR2R3 R2 R3 3 .4 6. 3 6 2

2

2

Area of PQ2Q3 =

CODE-9

1

12 2 6 2

2

35/40

MATHEMATICS

MATHEMATICS

47.

g((x)) = x and h(g(g(x))) = x for all x R. Then(A) g ' 2

1

15

(C) h(0) = 16

(D) h(g(3)) = 36

Ans. (B,C)

Sol. (A) ' x 3x 2 3

1

'0

so, g'(2) =

g '(2)

1

3

(B) h(g(g(x)) = x

h '(g(g(x))

1

g'(g(x)).g'(x)

Now, g(g(x)) = 1

g(x) = (1) = 6

x = (6) = 236

so h '(1)

1

1

h'(1) = 666

g '(6).g'(236) 1 . 1

6 111

(C) g(g(x)) = 0

so h(0) = 16

1

(D) g(x) = 3 x = g (3) x = (3) x = 38

so h(g(3)) = 38

48.

x

for all x (0,) and

x

(1) 1. Then

1

(A) lim ' 1

x

x 0

1

(B) lim x 2

x

x 0

2

(C) lim x ' x 0 (D) |(x)| < 2 for all x (0,2)

x 0

Ans. (A)

36/40

CODE-9

MATHEMATICS

Sol. Let y = (x)

dy y

2 (linear differential equation)

dx x

y.e

dx

x

2 e

dx

x

2 e

dx

x dx c

yx = 2 xdx c

yx = x2 + c

c

; As (1) 1 c 0

x

' x 1

c

,c 0

x2

(x) = x +

1

2

lim ' lim 1 cx 1

x x 0

x 0

1

1

2

(B) lim x lim x cx lim 1 cx 1

x

x

x 0

x 0

x 0

c

2

2

2

(C) lim x ' x lim x 1 2 lim x c c

x x 0

x 0

x 0

c

(D) x x , c 0

x

for c > 0

lim x function is not bounded in (0,2).

x 0

49.

3 1 2

Let P 2 0 , where R, Suppose Q = [qij] is a matrix such that PQ = kI, where k R,

3 5 0

k

k2

k 0 and I is the identity matrix of order 3. If q23 = and det(Q) = , then8

2

(A) = 0, k = 8

(B) 4 k + 8 = 0

9

13

(D) det(Qadj(P)) = 2

Ans. (B,C)

CODE-9

37/40

MATHEMATICS

Sol. PQ = kI

3

|P|.|Q| = k

|P| =2k 0 P is an invertible matrix

PQ = kI

1

Q = kP I

Q

adj.P

2

q23 =

k

8

k

3 4

k4

2

8

|P| = 2k k = 10 + 6 ...(i)

Put value of k in (i).. we get =1

4 k + 8 = 0

50.

k2

k5

29

& det (P(adj.Q)) = |P| |adj.Q| = 2k.

2

2

SECTION3 : (Maximum Marks : 15)

This section contains FIVE questions.

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

For each question, darken the bubble corresponding to the correct integer in the ORS.

For each question, marks will be awarded in one of the following categories :

Full Marks

: +3 If only the bubble corresponding to the correct answer is darkened.

Zero Marks

: 0 In all other cases.

2

Let m be the smallest positive integer such that the coefficient of x in the expansion of

2

3

49

50

51

(1 + x) + (1 + x) + ....... + (1 + x) + (1 + mx) is (3n + 1) C3 for some positive integer n.

Then the value of n is

Ans. 5

(1 + x)2 + (1 + x)3 + ....... (1 + x)49 + (1 + mx)50 is

2

50

50

49

50

C3 + 50C2m2 = (3n + 1)

51

51

C3

50.49.48 50.49 2

51.50.49

m = (3n + 1)

6

2

6

m2 = 51n + 1

must be a perfect quuared

n = 5 and

m = 16

Ans. 5

38/40

CODE-9

51.

x

x2

1 x3

2x 4x 2 1 8x 3

3x 9x 2 1 27x 3

MATHEMATICS

= 10 is

Ans. 2

1 1 1 x3

3

3

Sol. x 2 4 1 8x 10

3 9 1 27x 3

1 1 1

1 1 1

3 3

x 1 2 4 x .x 2 4 8 0

1 3 9

3 9 27

3

6x6 + x3 5 = 0

5

x3 , 1

6

52.

1 3i

Let z =

, where i =

2

(z)r

1 , and r, s {1, 2, 3}. Let P = z 2s

z 2s

and I be the identity

zr

matrix of order 2. Then the total number of ordered pairs (r, s) for which P2 = I is

Ans. 1

Sol. z =

()r

P 2s

2s 2

, P = I

r

2r 4s

r 2s (( 1) r 1)

P 2 r 2s

I

r

4s 2r

((1) 1)

r

2r

4s

also + = 1 r 3

2

4s

by r = 1 + = 1

s=1

(r, s) = (1, 1)

only 1 pair

CODE-9

39/40

MATHEMATICS

53.

t2

The total number of distinct x [0, 1] for which 1 t 4 dt = 2x 1 is

0

Ans. 1

x

t2

dt 2x 1

Sol. Let (x)

4

0 1 t

x2

2

'(x) =

1 x4

1 x4

2

as

x2

3

2

'(x)

x2

1

4

2

1 x

t2

3

dt 2

4

2

0 1 t

54.

x 0

Ans. 7

x 0

x 2 sin(x)

= 1. Then 6( + ) equals

x sin x

x sin x

0

x sin x

x

sin x

x

lim

x 0 3 x sin x

1/ 6

x

3

x

x3

6 = 1

1

6

6( ) = 7

40/40

CODE-9

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