Beruflich Dokumente
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as con
volume
n
constan
te y
variable
INTEGRANTE:
SOLUCION
A + B k1C
0.40
0.40
0.11
Inerts 0.09
The reaction takes place in an isothermal reactor that is maintained at a constant
pressure of 1 atm. If the reaction is first- order in A and first-order in B, and if
the value of k is 2 liters/mole-min, how long will it be before the mole fraction C
reaches 0.15?
A K1 BK 2C
This network can represent a wide variety of important classes of reactions. For
example, oxidation reactions occurring in excess oxidant, where B is the desired
product. Calculate the time when production is high.
SOLUCION
4. Problem 6.9: Principles of Chemical Reactor Analysis and Design: New Tools
for Industrial Chemical Reactor Operations
Uzi Mann (Author), Ed. Wiley, 2 edition, Chap. 6, pag. 234 problem 6.9.
Elemental dimerization reaction 2A P gas phase is carried out in an isothermal,
isobaric reactor manner. A pure loaded into the reactor, which operates at 5 atm
and 300 C. Based on the data below, determine:
a. The time required for converting 80% of A.
b. The reactor volume at that time.
Datos: La constante de velocidad de reaccin a 300C,
k =1min1(
mol 1
)
L
2AP
-rA=KCA2
Fase gaseosa: sistema de volumen (o densidad) variable.
P=5 atm y T= 300C V0=500L
INCOGNITA
xA=80% t= ?
Velocidad de reaccin con respecto a un componente:
r A=
1 d n A
(1)
V dt
( )
r A=k C A (2)
Igualando (1) con (2):
1 d n A
=k C2A
V dt
( )
n
1 d n A
=k A2
V dt
V
( )
d n A
n2A
=k
(3)
dt
V 0 ( 1+ A x A )
Pero sabemos que:
n A =n A (1x A ) (4 )
0
A=
12 1
=
(5)
2
2
n2A (1x A )2
d(1x A )
n A
=k
dt
V 0 ( 11 /2 x A )
0
n A (1x A )
d (1x A )
=k
dt
V 0 ( 11/2 x A )
0
( 2x A )
d ( 1x A )
( 1x A )
=2 k
2
nA
dt
V0
0
V 0=500 L
P=5 atm
PV =nRT
T =300 C
n A =53.193 mol
0
El volumen cuando
x A=0.8
V =V 0 ( 1+ A x A )
V =V 0 ( 11 /2 x A )
V =300 L
Entonces tenemos:
x A=0.8 ,
V 0=500 L ,
mol 1
k =1min (
)
L
1
n A =53.193 mol
0
Reemplazando en (6)
t= 26.364min
5. Problem 6.6. Principles of Chemical Reactor Analysis and Design: New
Tools for Industrial Chemical Reactor Operations
Uzi Mann (Author), Ed. Wiley, 2 edition, Chap. 6, pag. 233.
The dimerization reaction 2A second order B is carried out in an aqueous
solution. When the reactor is charged with a solution of Co concentration = 1
mol / L 50% conversion is reached after one hour. What is the conversion
after one hour if the initial concentration is 10 mol / L?
DATOS
2AB
-rA=KCA2
Solucin acuosa: sistema de volumen (o densidad) constante.
CA=1 M y t= 1h xA=0.5
INCOGNITA
CA=10 M y t= 1h xA=?
Velocidad de reaccin con respecto a un componente:
r A=
1 d n A
V dt
( )
( ddtC ) (1)
A
r A=
r A=k C 2A (2)
Igualnado (1) con (2):
( ddtC )=k C
A
2
A
Despejando:
dCA
=kdt
C 2A
( )
e integrando:
CA
C Ao
d CA
C 2A
=k dt
o
Obtenemos:
( C1 C1 )=kt (3)
A
Ao
Sabemos que:
C A =C Ao ( 1x A ) ( 4)
Reemplazando (4) en (3):
xA
1
=kt (5)
C Ao 1x A
xA
1
=kt ( 5 )
C Ao 1x A
1
0.5
=k (1h)
1 mol / L 10.5
El valor de K es:
k =1
L
mol . h
CA=10 M y t= 1h xA=???
Utilizando la ecuacin 5:
xA
1
L
=1
( 1h )
10 mol / L 1x A
mol .h
Resolviendo:
x A=0.909