Beruflich Dokumente
Kultur Dokumente
EXPERIMENT 1
POROSITY MEASUREMENT
OBJECTIVE
To determine the porosity of reservoir rock samples.
APPARATUS
Helium Porosimeter
Mercury Porosimeter
Vanier Caliper
BASIC THEORY
a)
Porosity
Porosity is a measure of storage capacity of a reservoir. It is defined as the ratio of the
pore volume to bulk volume. In general, a core sample can have three types of
volumes, namely the pore volume, the grain volume, and the bulk volume. Thus,
porosity can determine from these equations:
Porosity
Vp
Vb
Vb Vgr
Vb
Vp
Vp Vgr
-1-
(1)
where,
Vp = pore volume
Vgr = grain volume
Vb = bulk volume
Porosity is may be expressed as either a percent or a fraction.
Two types of porosity may be measured: total or absolute porosity and effective
porosity. Absolute porosity is the ratio of all the pore spaces in the rock to the bulk
volume of the rock. Effective porosity is the ration of interconnected void spaces to
the bulk volume. Thus only the effective porosity contains fluids that can be produced
from the wells. For granular materials such as sandstone, the effective porosity may
approach the total porosity, however, for shales and for highly cemented or vugular
rocks such as some limestones, large variations may exist between effective and
absolute porosity.
1)
Absolute porosity =
(2)
Effective porosity =
(3)
2)
-2-
3)
b)
Grain Density
Sometime density of the grain is required in the porosity calculation, for example, in
the determination of grain volume if the weight of grain is known. Further more, grain
density may be also needed in the porosity calculation by density log. In equation
form
gr
Wgr
(4)
Vgr
where,
gr = grain density
Wgr = grain weight
Vgr = grain volume
BASIC THEORY OF THE EQUIPMENT
Helium porosimeter is an equipment to measure volume. It may be used to measure the grain
volume (Vgr)or the pore volume (Vb) of a rock sample. It is applying the Boyle Law of gas
expansion principle.
Some quantity of helium gas with known volume (reference cell volume) as measured at an
initial pressure is let to expand isothermally to fill the cell of the unknown volume. After
expansion, the resulted pressure is recorded. How big the value of this unknown cell volume
is further calcuted using Boyle Law.
-3-
Referring to above figure, some standard pressure (usually 100 psig) is applied between
source valve and core holder valve. When the core holder valve is opened, 100 psig pressure
will expand and fill the unknown volume (initial at 0 psig). When both pressures have
reached equilibrium, Boyle Law may be used to calculate the total unknown volume.
The processes are summarized as follow:
From Boyle Law,
P1VR P2 V P3 VR V
T1
T2
T3
where,
P1 = pressure of reference cell (core holder valve is closed), psia
P2 = pressure in the unknown volume, psia
P3 = pressure at equilibrium (core holder valve is opened), psia
VR = volume of reference cell, cm3
V = the unknown volume, cm3
T1, T2, T3 = absolute temperatures, oR or oK
Normally, P1 = 100 psig, and P2 = 0 psig.
Eqn. 5 becomes,
-4-
(5)
P1 B VR BV P3 B VR V
P1 VR BVR BV P3 VR BVR P3 V BV
P3 V VR P1 P3
P1
100
1 VR
1
P
P
3
3
V VR
(6)
where,
B = barometer pressure, psi
P1, P3 = pressure in psig
However, the values of VR and V are constant. Volume VR which is consist of Heise gauge
with bourdon tube will expand and shrink according to pressure changes. This is due to small
changes of volume in pipe and valve during pressure equilibrium process. It may be proofed
that:
P1
P B
1 3
G 100 P3
P
P
3
3
V VR
(7)
where,
G = system expansion factor, cm3/psi
EXPERINMENTAL PROCEDURES
1.
Weight the core sample, and measure the core length and diameter using Vanier
caliper.
2.
Connect the helium gas source at the panel with all valves are closed except the core
holder valve and exhaust valve are opened. Adjust the pointer to 0 psi.
3.
Close the core holder valve, and then open the supply valve and the source valve.
Adjust the pointer of cylinder measuring gauge to 100 psi with the regulator. Slowly
tap the porosimeter so the dial reading is at 100 psi.
4.
Repeat steps 2 and 3 above several times until the stable reading is achieved.
5.
Insert core sample into the matrix cup, followed by the disk until both are at the same
level or slightly lower than the height of the cup, and tighten the lid up to maximum.
-5-
Note:
For 1.5 inch diameter core the height of the disk must be slightly lower than the height of the
cup to avoid it from touching the internal O ring (actually the O ring is for 1 inch core).
Otherwise, remove the internal O ring.
6.
Close the Cell 1 Valve, the Cell 2 Valve and the Core Holder Valve.
Open the Supply Valve and the Source Valve.
Adjust regulator until the dial reading shows exactly at 100 psi.
Close the Source Valve, followed by the Supply Valve and the Exhaust Valve.
Open the Core Holder Valve, and observe the movement of the dial in opposite
direction from the clockwise.
When the dial stops, tap the porosimeter and record the reading of the outside
scale. This is a volume with sample (i.e. sample volume + disk volume).
Record the gauge reading.
Close the Core Holder Valve so gas is released out.
Open Exhaust Valve so the pressure in the matrix cup becomes 0 psi.
7.
Loosen up the lid and removed matrix cup from its holder. Remove the core sample
but left the disk inside and retighten the lid.
8.
Repeat steps 6(a-h). Record the reading of volume without sample (disk volume
only).
9.
For bigger unknown volume such as between 50 cc to 450 cc, open cell 1 and
repeat steps 6 to 8.
10.
For much bigger unknown volume such as between 150 cc to 880 cc, open cell 1
and cell 2, and repeat steps 6 to 8.
11.
12.
13.
-6-
Data
Room Temperature
____________________
Barometric Pressure =
____________________
1.
Basic Data
Name of
Sample
2.
Name of
Sample
Weight
(gm)
Length
(cm)
Diameter
(cm)
Volume
with
Sample
(cc)
Volume
without
Sample
(cc)
Grain Volume
(Vgr)
(cc)
-7-
Porosity ()
(%)
Determine the values of porosity and density for the all rock samples. What type of
porosity that you are measured?
2.
Make comparison of the bulk volume of the rocks measured from mercury
displacement method and ordinary measurement method.
3.
Give three reasons why helium gas is used not other gases for this experiment.
4.
Is it possible for the helium porosimeter to be used for other than cylindrical core
samples, such as square or irregular shape core samples?
a)
b)
5.
A core sample was taken from a well and porosity measurement was conducted. Is
true that the porosity measured in the laboratory is the same with the porosity of the
sample at the reservoir conditions?
6.
What are the advantages of the porosity measurement in the laboratory as compared
to from the logging tools?
7. The porosity of the rock sample can also be determined by measurement of grain
volume method. This method requires the weight and the density of the grain. Explain
the calculation procedures, and give advantages and disadvantages of this method.
EXPERIMENT 2
-8-
Objective
Measuring absolute permeability of a rock sample using liquid as a fluid
Apparatus
1.
Liquid Permeameter
2.
Vernier Caliper
Basic Theory:
-9-
1.
Rock Permeability
Permeability is a measure of the ability of a porous media to permit fluid to pass
through it. For rocks, it describes the relative ease of the fluid to move through the
network of pores inside the rock.
If only one fluid is present inside the rock, the measured permeability is referred to as
Absolute Permeability. If more than one fluid is present, the measured permeability
will be lower and the value is now referred to as Effective Permeability.
2.
Darcy Equation
The equation used to measure rock permeability is called Darcy Equation. For a linear
system with liquid as the fluid, Darcy equation can be written as:
Q
kA P1 P2
uL
Where,
k = permeability (darcies)
A = cross sectional area of the sample (cm2)
P1 P2 = pressure difference (atmosphere)
u = viscosity (cp)
L = length of the core (cm)
Q = flow rate (cc per sec)
3.
Measurement of Permeability
- 10 -
Method
1.
2.
Make sure the system is connected to the gas source through a closed _valve
3.
Insert the sample which had been saturated with the liquid into the rubber stopper
4.
Insert the rubber stopper containing the sample into the core holder
5.
Tighten the core holder underneath the apparatus and connect to the top part. Tighten
using the handle, nether too tight, nor too loose.
7.
Open by turning the discharge fill valve to fill the burette and the core holder
8.
When the liquid level inside the burette has reached the uppermost mark (with a slight
extra of 1 cm), close the core holder valve
10.
Slowly open the gas regulator valve and increase the pressure to 1.5 atm
11.
Turn the discharge fill valve to drain the liquid from the burette into the sample
12.
Use the stop watch to measure time needed for the liquid to flow from the top level to
the bottom level. Note the flow rate.
13.
15.
16
- 11 -
L = -------------------------- cm
u = ------------------------- cp
D = ------------------------ cm
Test 1
Test 2
Test 3 ( Opposing
direction)
P1 = -------------- atm
V = -------------- cc
T1
T2
T3
Tavg
sec
sec
sec
sec
P1 = -------------- atm
V = -------------- cc
T1
T2
T3
Tavg
sec
sec
sec
sec
P1 = -------------- atm
V = -------------- cc
T1 T2 T3 Tavg
sec sec sec sec
Q = -------------- (cc/sec)
Q = -------------- (cc/sec)
Q = -------------- (cc/sec)
K = -------------- mD
K = -------------- mD
K = -------------- mD
Questions:
1.
Based on the experiment, is there any difference in the value of permeability among
the tests. Explain
2.
Explain the sources of error that might be committed during the measurements of
permeability using liquid
4.
What is the dimension for permeability, k? Show explicitly how you can obtain it.
What other units can be used for permeability?
5.
If the permeability of a sandstone core is measured using salt water, and the
permeability is measured 300 md, what will be the permeability of the same core if
fresh water is used instead? Why is that so?
6.
EXPERIMENT 3
- 12 -
ii.
iii.
iv.
THEORY :
DYNAMIC VISCOSITY
As a fluid moves, a shear stress is developed in it, the magnitude of which depends on the
viscosity of the fluid. Sheer stress () can be defined as the force required to slide one unit
area of a substance over another. Thus, is a force divided by an area and can be measured in
the unit of N/m2 ( or Pa). In a fluid such as water, oil, alcohol or other common liquids the
magnitude of the shearing stress is directly proportional to the change of velocity between
different positions in the fluid.
= ( / y)
where :
(Equation 1)
= sheer stress
= change in velocity of fluid particle
y = distance traveled by the fluid particle
= constant of proportionality, called dynamic viscosity.
- 13 -
For the purpose of clarity, let gives the symbol d for dynamic viscosity.
Dynamic viscosity ( d ) Units
N.s/m2, Pa.s or kg/m.s
lb.s/ft2 or slug (ft.s)
Poise = dyne.s/cm2=g/(cm.s)=0.1 Pa.s
Centipoises = poise/100 = 0.001 Pa.s = 1.0 mPa.s
Unit System
SI System
US System
cgs system
KINEMATIC VISCOSITY
Many calculations in fluid mechanics involve the ratio of the dynamic viscosity to the density
of fluid.
k = d /
where :
(Equation 2)
k = kinematic viscosity
d = dynamic viscosity
= density of fluid
Unit System
SI system
US system
cgs system
MEASUREMENT OF VISCOSITIES
The direct measurement of viscosity is based on the correlation,
= R4tP/8VL
(Equation 3)
where:
V = volume of liquid, cc
t = flowing time, second
r = radius of capillary tube, cm
L = length of pipe, cm
P = Pressure N/cm2
= absolute viscosity, poise
- 14 -
The direct measurement of absolute viscosity is difficult. For simplicity, the measurement of
viscosity normally used the same equipment and two types of liquid. Using the following
relationship:
1/ 2 = (1 t1) / (2 t2)
where;
. (Equation 4)
Basically the method used to measure the viscosity is by measuring the time taken for the
liquid to flow in the capillary at a given temperature.
k = c t
(Equation 5)
Where;
c = viscometer constant, cts/s
t = time of flow, s
k = kinematic viscosity
APPARATUS :
a.
b.
c.
d.
e.
f.
g.
- 15 -
PROCEDURES:
a. Use water as the standard liquid.
b. Use pipette to pour 10 ml of water into the capillary glass viscometer. Put the
capillary glass viscometer into the bath. Wait until the temperature of water and
instrument is equal.
c. Using a vacuum pump, suck water in the capillary glass viscometer until the water
level is about 5 mm above the level in the viscometer.
d. Measure the time taken for the water to flow from the high level to the low level
of the viscometer. If the flowing time is less than 200 seconds , repeat the test by
using a smaller capillary.
e. Repeat the above experiment at different temperatures.
f. When the kinematic viscosity, k of water is known, the viscometer constant can
then be calculated.
Determination of Liquid Density:
a. Weigh the empty pycnometer.
b. Fill in the pycnometer with the liquid and weigh it.
c. The difference in weight is the weight of the liquid in the pycnometer.
d. By knowing the volume and density, the viscometer constant at each test
temperature can be determined.
- 16 -
Weight of
empty
Pycnometer,
(gm)
Weight of
pycnometer fill
with the liquid,
(gm)
Volume of the
Liquid ( cc)
Density of the
liquid (gm/cc)
Constant No. of
glass capillary
Kinematic
viscosity, k in cts/s
QUESTIONS:
1. Write down the Poiseuille Equation.
2. Does the above equation applies to turbulent flow? Explain.
3. From Equation 3 , determine the dimension of unit poise in cgs system.
4. Why does in these experiments , the velocity of liquid must not be too
high?
5. What is the effect of temperature on kinematic viscosity. Plot kinematic
viscosities against temperatures. Explain your results.
- 17 -
EXPERIMENT 4
PERMEABILITY MEASUREMENY BY GAS PERMEAMETER
Objective:
Measuring the absolute permeability of a rock sample using gas and
understanding the Klinkenberg Effect.
Apparatus:
Gas Permeameter
Vernier Caliper
Basic Theory:
1. Rock Permeability
Permeability is a measure of the ability of a porous media to permit fluid to pass
through it. For rocks, it describes the relative ease of the fluid to move through the network of
pores inside the rock.
If only one fluid is present inside the rock, the measured permeability is referred to as
Absolute Permeability. If more than one fluid is present, the measured permeability will be
lower and the value is now referred to as Effective Permeability.
- 18 -
2. Darcy Equation
The equation used to measure rock permeability is called Darcy Equation. For a linear
system with liquid as the fluid, Darcy equation can be written as:
Q
kA P1 P2
uL
Where,
k = permeability (darcies)
A = cross sectional area of the sample (cm2)
P1 P2 = pressure difference (atmosphere)
u = viscosity (cp)
L = length of the core (cm)
Q = flow rate (cc per sec)
If gas was used as the fluid, the equation used to calculate flow in porous media is as
follows:
Q
kA P1 P2
uL
or
where
Qm
Qa
L
A
P
=
=
=
=
=
- 19 -
Where
=
=
=
average permeability
Fig 2 shows example of various relationship different gases and average pressures for a rock
sample. A lighter gas will have bigger slope, which mean greater slippage effect. All the lines
extrapolated to 1/Pm equal to zero will meet at one point. The value of permeability at this
point is the real absolute permeability, , ie the permeability value measured using liquid.
- 20 -
Fig 2. Variation in gas permeability with mean pressure and type of gas
Procedure
1. Measure the length and the diameter of the core and calculate the cross-sectional
area. Use cgs unit.
2. Put the core into the rubber stopper and then into the core holder and tighten it.
3. Adjust the variable valve to large position. Turn on pressure regulator slowly until
0.1 atm.
4. Record the gas flow rate using Wet Test Flow meter by recording the volumes at
various times
5. Repeat the procedure for pressure different of 0.2, 0.4, 0.6 and 0.8 atm, and record the
volumes and times.
Note:
a. Outlet pressure P2 is 1 atmosphere (1 atm).
b. Pressure gauge reading is the pressure different (P)
c. Inlet pressure P1 = Gauge reading + 1 atm
d. Average pressure Pm = (Pinlet + Poutlet)/2 =
- 21 -
Question
1.
2.
3.
4.
5.
6.
7.
What is the dimension for permeability (k)? Show clearly the derivation of the
dimension.
Measurement of permeability by using gas will usually gives permeability value that
is different compared to the one by using liquid. Describe the reason for this
phenomena.
Permeability of a rock sample measured using gas is given by the following equation;
where
Qm
Qa
L
A
P
=
=
=
=
=
- 22 -
P1 (atm)
P inlet
P2(atm)
P outlet
Pm (atm)
P average
P (atm)
P = P12-P22
Paverage
- 23 -
Q
(cc/sec)
K
(Darcy)
K x 103
(mdarcy)
EXPERIMENT 5
API GRAVITY MEASUREMENT
Objective:
To determine the API gravity of oil by using hydrometer and picknometer.
Apparatus:
Hydrometer
Bigham Pycnometer
Basic Theory:
Determination of density or specific gravity of petroleum liquid is important for the
calculation of volume and weight of the petroleum. For crude oil, gravity also shows the
quality of the crude oil. Further more, it is also a sign of the composition and the heat of
combustion of a particular petroleum material.
- 24 -
With
This unit is always used to state the specific gravity of stock tank oil.
Example
The density of crude oil in a stock tank at 60 oF is 50.0 lb/cu.ft. Calculate the SG and the API
gravity of the oil.
1.
Calculate SG
SG = 50.00/62.37 = 0.8017
2.
Note:
API = American Petroleum Institute, is a national commercial institution that leads the
petroleum industry in standardizing equipments for drilling and production. It was
established in 1920.
- 25 -
- 26 -
Result
1. Make correction on hydrometer readings by converting the API to standard .gravity
(60 oF) using Table 5 ASTM D1250
2. Report the corrected hydrometer reading as oAPI.
Sample
Temperature
of Sample oF
API Gravity
from(Hydrometer)
- 27 -
SG Gravity
( 60/60 oF )
Refer ASTM
( table 3)
API Gravity
refer ASTM
( table 5)
Determination of Density
Procedure :
1. Thoroughly clean the pycnometer and stopper with a cleaning fluid, rinse well
with distilled water. Finally rinse with acetone and dry.
2. Weight the dry pycnometer with stopper at room temperature
3. Fill the pycnometer with liquid at the same room temperature.
4. Put on the stopper and be sure there is no gas bubble inside, and then dry the exterior
surface of the pycnometer by wiping with a lint-free cloth or paper.
5. Weight the filled pycnometer.
Weight of empty
Pycnometer (gm)
Weight of
Pycnometer fill
with the liquid
(gm)
Volume of the
Liquid
( cc)
Density of the
liquid
(gm/cc )
Question
1. Other than bubble problem, state other problems encountered during the measurement
which may lead to error in the measurement.
- 28 -
EXPERIMENT 6
Equipment
Schilling Effusiometer
Theory
Determining the density of gas relative to air at the same ambient temperature and pressure.
gas
gas
air
Method of Measurement
This method based on the Graham Law of diffusion. This method based on the fact that the
times taken by equal volumes of gases to flow under the same conditions through a small
orifice are proportional to the square roots of the densities of gases.
Relative Density
gases
air
2
t gases
2
tair
- 29 -
Open the 3-way stopcock and let high ten the water level through the calibrated orifice
from the lower to the upper mark. Take the elapsed time.
6. Repeat the test several times at the same temperature. Should the time values differ
from more than 2/5 seconds? Check the calibrated orifice eventually clean it with the
help of compressed air.
7. Calculate the average obtained value, according to the number of tests carried out.
8. Clean the measuring tube with the gas to be tested. Run several tests on the same
temperature as this one of the used air and calculate the average flow time. Repeat
several determinations with air at the same temperature after having completely blowed
out the gas. This operation serves to check the eventual presence for impurities.
- 30 -
Question
1. Determine the relative density of gases. Make conclusion based on differentiation of
molecular weight of gases was used.
2. If experiment conducted at high temperature, what happen for gas flowing time and value
of gas density?
Gas
Time
1
Gas Gravity
3
- 31 -
Average
Valve 1
Valve 2
Gasket
Upper mark
Outer
cylinder
Measuring
tube
Inner
cylinder
Lower mark
- 32 -
EXPERIMENT 7
SMOKE POINT
2.0
OBJECTIVE
To determine the smoke point of oil samples such as jet A-1 and kerosene by burning
the oil samples in an enclosed smoke point lamp so that the height of the fire tongue
can be estimated.
3.0
APPARATUS
Smoke point lamp, wick, beaker, oven and graduated cylinder. Refer Fig. 1.
THEORY/INTRODUCTION
Please refer ASTM D1322 for this information and other publish materials.
- 33 -
METHODOLOGY
1.
2.
3.
4.
Fill the lamp with 20 ml oil sample. The lamp should have already cleaned
and dried.
5.
Screw the lamp cover to the socket. Cut wick to level with the wick guide.
Pull the wick to 6 mm above the end of the wick guide.
6.
7.
Adjust wick (extent the wick) until the flame produces smoke.
8.
9.
Measure the maximum height of the flame tongue in mm (this is the smoke
point). The measurement should be done at point B as shown by Fig 2.
10.
Repeat the experiment 3 times for each sample to get the accurate average
value.
Use new clean and dry wick for new oil sample.
11.
RESULT
a)
b)
DISCUSSION
a)
Write an explanation on the result of the measured smoke point for the 2
different samples.
b)
What are the characteristics the can be inferred from the different values of
smoke points for different samples.
- 34 -
CONCLUSION
State the conclusion of this experiment.
Sample 1
No.
Sample 2
Height of flame tongue
( mm)
No.
Average
Average
- 35 -
- 36 -