Beruflich Dokumente
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Organic Chemistry
151
1 . 4 Na ( V v )
, where V and v are volumes of acid and base respectively.
W
Answer (4)
%N
(AIEEE 2010)
1.4 NV
W
700
23.7
29.5
3. Answer (1)
Nitro group, azo group cannot give Kjeldahls test.
C3. 1. Answer (1)
In Ist, inductive, electromeric, resonance and hyperconjugation may present
2. Answer (4)
Due to R and I effect
3. Answer (1)
Due to +I effect
C4. 1. Answer (1)
Less is the pKa, more is the acidic.
2. Answer (2)
Chlorine atom decreases negative charge of molecule
3. Answer (3)
The order of acidity of alcohol is 1 > 2 > 3.
C5. 1. Answer (2)
2. Answer (1)
Percentage of (+) form
=
6.76
100 50
13.52
3. Answer (3)
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152
Organic Chemistry
Peroxide
Free radical
mechanism
+ HBr
2. Answer (4)
OH
OH
dil KMnO4
Cold
CH2OH
Conc.
H2SO4
3. Answer (3)
+ CHBr3
NaOH
50%
Br
Br
A1, A2, A3
CH 3
CH
CH2
CH3
CH3
CH3
CH3
or (CH2 C ) group
|
A1 is CH3
CH
CH3
CH3
2. Answer (2)
A2 & A3 both gives 1 alcohol it indicates both have (CH2 =)
grouping at the terminal position. Therefore A2 is CH3
CH2 C
CH2
CH3
CH3
CH2
CH2
CH3
Hydroboration
Oxidation
CH3
CH2
CH
CH2
OH
CH3
(X)
(A2)
3. Answer (3)
A3 is the isomer of A1 and A2.
A3 is CH3
CH
CH
CH2
CH3
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Organic Chemistry
153
HN
44
= 32 + 1
= 33 22 = 11
2
2
A = (C + 1)
Because, it absorbs one mole of H2 under the presence of P-2 catalyst, therefore, it has one triple bond.
C9. 1. Answer (2)
Due to presence of some acidic gas in atmosphere.
2. Answer (1)
N2O is neutral.
3. Answer (4)
Fact
C10. 1. Answer (1)
I
s
FeX 3
+ I Cl
+ HCl
2. Answer (4)
We cannot prepare iodobenzene and Flourobenzene by this method.
3. Answer (2)
Halogen act as deactivating group because of I effect.
C11. 1. Answer (3)
As the order of leaving group is I > Br > Cl
2. Answer (2)
CH3CH2CH2Br + CN
SN2 DMF
CH3CH2CH2CN + Br
3. Answer (1)
The dielectric constant of H2O = 80, HCOOH = 59, CH3OH = 33 and CH3COOH = 6
C12. 1. Answer (4)
With 3 alkyl halide elimination is favoured by CN.
2. Answer (1)
RX + AgNO2 RNO2 + AgX
3. Answer (1)
In polar protic solvent, SN1 mechanism is favoured and in this mechanism, more electronegative atom
attack.
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154
Organic Chemistry
CH3
CH3
|
Answer (2)
2.
Answer (3)
SN
CH3
|
CH3COC2H5
|
CH3
RO act as nucliophile.
3.
Answer (4)
CH2OH
C14.
CHO
CHO
CH2Cl
CH2
1. Answer (3)
2. Answer (3)
3. Answer (2)
R OH + PCl5 R Cl + HCl + POCl3
O H
|| |
C15. RCCH + OH
I
H
H2O
O
||
RCCH2 + I I
O
||
RCCH2I + I
I2/NaOH
O
||
RCCI3
1.
Answer (1)
2.
Answer (3)
3.
Answer (1)
CH3
C16.
CH3
OH
CH2
CH3
CH2
CH2
CHO
CH2
OH
CH3 CH
1. Answer (2)
(CH2)4
CHO
Aldehyde is protected
2. Answer (4)
It has no OH group
3. Answer (3)
Five membered ring is more stable in condensation.
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C17. RCH
Organic Chemistry
H
|
+
RCHCH2BH
|
H
CH2 + BH3
+
RCHCH2BH2
RCH2CH2BH2
+
1.
Answer (1)
2.
Answer (4)
3.
Answer (2)
C18. C 2H 5NO 2
H2/Ni
(A)
155
C2H5NH2
CHCl3/KOH
(B)
(Na)
C2H5NC
(C)
1. Answer (4)
Both form C2H5NH2 and B form C3H7NH2
2. Answer (1)
C2H5CN is functional isomer of (C)
3. Answer (4)
AgNO2
C2H5Cl
C2H5NO2
NH2
NO2
NH4SH
C19.
N2Cl
NaNO 2/HCl
Boiling
cold
NO2
NO2
CH3
(A)
CH3
OH
NO2
CH3
(B)
NH2
NH2
CH3
(D)
NO2
CH3
(C)
N2Cl
C2H5OH
NaNO2/HCl
Sn/HCl
H2O
Cold
N2Cl
CH3
(E)
CH3
(F)
1. Answer (3)
CH3
NO2
OH
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156
Organic Chemistry
2. Answer (1)
CH3
COOH
KMnO
3. Answer (4)
A and D are aniline derivates therefore no Friedel Craft alkylation is possible.
CH3
CH3
C20.
CH3
(1) Sn/HCl
(2) NaNO2/HCl
(1) Zn dust
(3) H2O/boiling
(2) Na/NH3(lq)
NO2
(A)
OH
(B)
(3-methylcyclohexene)
(C)
CH3
CH3
PCl5
KNH2
Cl
NH2
(due to benzyne
mechanism)
1. Answer (3)
CH3
NO2
2. Answer (4)
All are correct statement.
3. Answer (2)
See above solution.
C21. 1. Answer (4)
CH2OH
HO
HO
OH *
OH
M.P. = 146C
-D-glucose
[]D25 112
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Organic Chemistry
157
2. Answer (4)
3. Answer (1)
CH2OH
HO
HO
O
OH
HO
-D-glucose
M.P. = 150C
[]D25 18.7
C22. 1. Answer (2)
Polystyrene is an addition polymer of styrene.
2. Answer (1)
Vinyl chloride polymerises by anionic mechanism.
3. Answer (1)
Glyptal is a condensation polymer.
C23. 1. Answer (2)
Since DNA is double stranded and complementary bases resist changes, so more suitable.
2. Answer (2)
There are ten base pairs in one helix separated by 0.34 nm apart.
3. Answer (2)
tRNA (Transfer RNA) has recognition site for picking up appropriate amino acid at the time of protein
synthesis.
C24. 1. Answer (1)
ABS Alkyl benzene sulphonates
+
Ex. Na O3 S
(CH2)11 CH3
Sod-p-dodecyl benzenesulphonate
Anionic Larger part should be anion.
2. Answer (2)
158
Organic Chemistry
PbCl2 + H2S
PbS
3. Answer (1)
PbS +
3
O PbO + SO2
2 2
75%
2. Answer (2)
CH3
n CH2 = C CH = CH2
1, 4 addition
3. Answer (4)
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