216

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Section - C : Assertion - Reason Type

1.

Answer (2)
Temporary hardness of water is due to presence of soluble Ca and Mg bicarbonates this can be removed by
boiling because on heating bicarbonates of Ca and Mg converted into insoluble carbonates

CaCO3 + CO2 + H2O

Ca(HCO3)2

(Soluble)
2.

(Insoluble)

Answer (1)
AgCl is more soluble in ammonia solution than water because it forms complex with ammonia
Ag+ (aq) + Cl (aq)

AgCl(g)

Ag+ (aq) + 2NH3 [Ag(NH3)2]+ (complex)

3.

Answer (2)

N
H

H
H
Addition

N
F
F
Subtraction

Therefore dipole moment of NH3 is more than NF3

4.

Answer (2)
For Balmer series of H-atom

1
1
1
R 2 2 for the maximum wavelength n2 = 3

n 2
2

1
1 1 5R
R

4 9 36

max

36
5R

Balmer series belongs to visible region.

5.

Answer (1)
CO2 + Ca(OH)2 CaCO3 + H2O
Lime water

milky

On prolong treatment milkiness get disappeared due to formation of soluble Ca(HCO3)2

CaCO3 + CO2 + H2O Ca(HCO3)2
(excess)
6.

(soluble)

Answer (3)

2B3N3H6 + 12H2
3B2H6 + 6NH3 3[BH2(NH3)2]+ [BH4]
(borazine)

in diborane the hybridisation of boron is sp3

7.

Answer (1)
Nitrogen at azo group and nitro group does not change to ammonium sulphate under normal condition.

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8.

Miscellaneous Questions

217

Answer (2)
Presence of lone group in OH group, it acts as a source of electron therefore has strong tendency to donate
the electrons to anhydrous AlCl3 which is electron deficient forms bond with OH group of phenol.

OH

AlCl3

+ (anhy) AlCl3
(deactivates)
therefore deactivates the benzene ring
9.

Answer (2)
Borax dissolves in water to give an alkaline solution
Na2B4O7 + 7H2O 2NaOH + 4H3BO3
Na2B4O710H2O can be represented as Na2[B4O5(OH)4]8H2O, therefore it is clear that 4 hydroxyl groups are
directly attached with boron.

10. Answer (1)

Due to high bond enthalpy of (C C) bonds, among the group carbon show catenation.
11. Answer (1)

OCH3
In anisole

the lone pair of electrons are in resonance therefore phenyl oxygen bond has partial

double bond character cannot be cleaved easily.

12. Answer (3)

OH

Br

OH

Br

+ 3Br2
Br
(2, 4, 6 tribromo phenol)
PhOH + NaHCO3 PhONa + H2CO3
(weaker acid)

(stronger acid)

13. Answer (4)

Cl
CH3 CH = CH2 + H+ CH3 CH CH3
CH3 CHCl CH3 (major)

14. Answer (3)

1-butyne and 2-butyne can be distinguished by Tollens reagent because 1-butyne has acidic hydrogen and
gives white precipitate with Tollens reagent
15. Answer (1)
In neopentane all the hydrogen are 1H.
16. Answer (2)
: CCl2 (dichlorocarbene) are electron deficient species therefore acts as an electrophile.
17. Answer (3)
In Rock salt structure (NaCl) Na+ are present in octahedral void and Cl forming CCP; CN of Na+ is 6 therefore
CN of Cl is also 6.

interionic distance r r

a
2

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18. Answer (2)

Rate = K[CH3COOC2H5)] [H+]a

K H2SO 4 K H

a
H2SO 4

K HCl K H

a
HCl

H2SO4

H+ + HSO4

0.05
M
2

0.05
0.05
M
M
2
2
H+ + SO42

HSO4
0.05

0.05

H2SO 4

is always less than

where a > 1

0.05
M
2

0.05

H2SO 4

In case of HCl,
H+ +

Cl

0.05 M

0.05 M

HCl

0.05 M

[H+]HCl = 0.05 M

HCl

H2SO 4

K HCl K H2SO4

19. Answer (4)

t1
2

1
a

n = order of reaction

n 1

t1 a
2

Half life of zero order reaction is directly proportional to the initial conc.
20. Answer (1)

y
z
x

electron density in xz plane is zero therefore it is called nodal plane.

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Miscellaneous Questions

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21. Answer (4)

Oxidation No. of sulphur in H2S2O8 is + 6

+1

1 +1 +2 1
O S O
+1 +2
1

1 +1 +2 1
O S O
+2 +1
1

+1

there is one peroxy linkage is present.

22. Answer (2)
A mixture of K2Cr2O7 acidified with dilute H2SO4 and H2O2 is shaken with ether, the ether layer turns deep
blue. It is due to formation of CrO5. Which is more soluble and stable in ether.
K2Cr2O7 + H2SO4 + 4H2O2 2CrO5 + K2SO4 + 5H2O
23. Answer (2)
BeO + C + Cl2

600-800C

BeCl2 + CO

In vapour phase BeCl2 tends to form a chloro bridged dimer which dissociates into the linear monomer at high
temperature.
24. Answer (1)
Both maleic acid and fumaric acids are dicarboxylic acids and hence two ionizable H-atoms thus has two
dissociation constant K1 and K2. After removal of a proton resulting monoanion of maleic acid (cis) is stabilized
by H-bonding but not that of fumaric acid. Therefore more energy is needed to remove this chelate H-atom
thus K2 of fumaric acid is higher than that of maleic acid.
25. Answer (3)
In K2 [PtCl6] there is no Cl atom present in ionisable form.
K2[PtCl6] 2K+ + [PtCl6]2
26. Answer (3)

O
In HCHO, carbonyl group

is less hindered therefore facilitates the nucleophilic attack more than the

CH3COCH3
27. Answer (4)
Concentration of pure solid is constant. So addition of CaCO3(s) there is no change in concentration, therefore
equilibrium will not be affected.
28. Answer (2)
Rate of diffusion

1
Molecular mass

29. Answer (4)

K = AeEa/RT positive catalyst decreases activation energy therefore it is clear that value of rate constant will
be increased.
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30. Answer (3)

rn 0.529

n2

for He+ Z = 2
rn = 0.529

n=2

4
= 2 0.529
2

which is double than the radius of first Bohrs orbit of H-atom

31. Answer (3)

p p S
n

p
nN
Relative lowering of vapour pressure is colligative property

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