Beruflich Dokumente
Kultur Dokumente
JOSEPH J. SANTOLERI
Thermal Research & Engineering Corp.
Conshohocken,
(1) Acetone,
ABSTRACT
(4) Acetaldehyde,
(5)
Chloroprene, and
be removed [1-3].
FOREWORD
Pennsylvania
[4].
If an ineffective incineration system is used, exhaust
plants:
66
The
NITTETU PROCESS
to
[5].
HCl
gas at temperatures of
27 30
F to
3000 F.
These
exchanger surface
HCI
HCl
18
HCl
gas
35
most cases.
percent) or
( 100 percent).
COMBUSTION PRINCIPLES
(CHCl=CCI2)
is to be
H20 + Cl2
2
(PHCI)
Kp =
(PH20)
following reaction
CHCI=CCI2 + 202
('l
0
3::
tll
C
C/I
..,
(5
Z
:t
t'l
)-
..,
n
I'>
10,000
2 HCl + 1/2 O2
(P02)
(PCI2)
EXPERIENCED RESULTS
t:7iJ:===t==========J=======18000
-+--126UO
9000fii
7200
_.
______
--
__
__
__
-----l---
-+-,..<-
c----=i'_l
,
,..
>
r-
c:
54UO
3600
1,000 __________________________________
30
20
10
50
40
60
1800
CHLORINE CONTENT
(%wt)
67
2732F
1832F
180
...: -
VV
100
,/
./
V
./
/
If
Co
);:
II
E-<
Z
..: 1.0
E-<
II
/
III
Z
o
u
::E
;:l
@
J
5
S
o.
1,000
1,500
TEMPERATURE (Oe)
po,),
z PHCI)
PH,O) PCI,)
,
Kp
.!.
68
2,000
WASTE
INJECTOR
.PILOT BURNER
AIR INLET
ALKALI
WATER
ATOMIZING AIR
--
'-+-_
..
P-1
B-1
TO NElITRALIZING
PROCESS
P-2
Fig. 4 Flow sheet for incineration of chlorinated hydrocarbon
waste liquid (neutralization method).
69
Neutralization
WASTE LIQUID
, ATOMIZING AIR
AUXILIARY
FUEL GAS
FUEL GAS
(FOR PILOT BURNER)
AIR
AIR
BURNER
INCINERATOR
----
--------------
----;
COOLING
WATER
-
DILUTED LIQUID
WEIR
CONCENTRATED
LIQUID
OOWNCOR
COPeUSTION
PRODUCTS
70
in this top zone which has worked out very well [5].
Absorption
(SO to
IS
percent to 20 percent
tank. The piping and bottom end of the tower are lined
71
1.
SUBMERGED INCINERATOR
2.
ABSORBER
3.
TO NEtrrRALIZING TOWER
WATER
P-l
P-2
P-3
P-4
P-5
B-1
AIR BLOWER
ATOMIZING AIR
t:'\
WASTE
LIQUID
AIR
B-1
P-2
P-5
P-3
P-4
CD
Fig.6 Flow sheet for HCI recovery process (15-20% HCI re
covery process).
72
SUBMERGED INCINEHATOR
ABSORBER
NEUTRALIZING TOWER
STRIPPER FEED TANK
STRIPPER
6. CONDENSER
7. 35 % HCI SOLUTION RECEIVER
S. REBOILER
B-1 AIR BLOWER
P-l WASTE I.IQUID PUMP
P-2 DIL. HCl SOLUTION CIRCULATING PUMP
n
p_)
P-4
ATOMIZING AIR P-5 NaOH SOLUTION CIRCULATING PUMP
STRIPPER FEED PUMP
DIL. CaCI, SOLUTION RETURN PUMP
35% HCl SOLUTION PUMP
I.
2.
3.
4.
5.
TO ATMOSPHERE
WASTE
LIQUID
AIR
WATER
P-3
P-I
P_d
B-1
COOLING WATER
l'------J
P-S
P-7
Fig. 7 Flow sheet for Hel recovery process (35% Hel recovery
process).
CONCENTRATED CaCI, SOLUTION FROM SUBMERGED INCINERATOR
18-20% HCI FROM ABSORBER
BRINE
,.
CONe. CoC"
RECEIVER
so'"
P-3
P--4
STEAM
f.:\
II
P-4
73
Organics:
10 ppm (WT)
Overall Recovery Efficiency: 95 percent
CONCLUSIONS
12 ] R. W. Gerstle and
18, 1971.
1. J. Santoleri, "Perfor
Progress, July
74
1967
Chemical Engineering