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1. (a) What is meant by thermodynamic equilibrium? How does it differ from ther-
mal equilibrium?
(b) A mass of gas is compressed in a quasi static process from 80 KPa 0.1 m3 To
0.4 MPa, 0.03 m3 . Assuming that the pressure and volume are related by PVn
= Constant, find the work done by the gas system. [8+8]
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of gases is 100 Kg/min, estimate the net change of entropy. Take Cp (water)
= 4.186 KJ/Kg-K and Cp (gas) = 1.0 KJ/Kg-K. [8+8]
4. In a closed vessel the 100 kg of steam at 100 KPa, 0.5 dry is to be brought to a
pressure of 1000KPa inside the vessel. Determine the mass of dry saturated steam
admitted at 2000 KPa for raising pressure. Also determine the final quality. [16]
5. (a) Define
i. Compressibility factor Z
ii. Isothermal compressibility.
(b) 1- kg of mole of O2 undergoes a reversible non-flow isothermal compression
and volume decreases from 0.2m3 /kgto0.08m3 /kg and the initial temperature
is 600 C. The gas obeys Vander waal’s equation during the compression. Find
i. The work done during the process
ii. The final pressure.
T akea = 139250N m4 /(kg−mole)2 ; b = 0.0314m3 /kg−mole; R = 8314n−
m/kgmoleK [7+9]
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(d) Partial pressure and partial volumes
(e) volume and density of the mixture
(f) Cp &Cv of the mixture. [16]
7. (a) Discuss the use of air standard cycle analysis for the study of internal com-
bustion engines.
(b) An engine of 250 mm bore and 375 mm stroke works on Otto cycle. The
clearance volume is 0.00263m3 . The initial pressure is limited to 25 bar, find
the following: (i) The air standard efficiency of the cycle. (ii) The mean
effective pressure for the cycle. [6+10]
?????
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1. (a) Define the term property. State the differences between extensive, intensive
and specific properties of a thermodynamic system. Give few example for
each.
(b) A mass of 2.5 kg of air is compressed in a quasi static process from 0.1 MPa to
0.7 MPa for which PV = constant. The initial specific volume is 0.80 m3 /kg.
Find the work done by the piston to compress the air. [8+8]
2. (a) What are the practical difficulties associated with the use of ideal gas ther-
mometer?
(b) A new temperature scale in Degree N is desired with freezing point at 1000
N and the boiling point at 4000 N. Establish a correlation between degrees
Centigrade and degrees N. What will be the absolute temperature at 00 N?
[6+10]
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(c) An engine operating on a Carnot cycle works with in temperature limits of
600 K and 300 K. If the engine receives 2000 KJ of heat, evaluate the work
done and thermal efficiency of the engine. [6+2+8]
5. (a) What is compressibility factor. Sketch and discuss the salient features of the
generalized compressibility chart.
(b) 1 kg of air is initially at temperature of 100 C. If goes through the following
processes to complete a cycle.
i. Reversible adiabatic compression until the pressure is increased to 2.5
times.
ii. Reversible heat addition at constant pressure. The addition of heat is to
controlled that initial volume is reached.
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6. Dry bulb and wet bulb temperature of moist air are found as 290 C and 200 C
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respectively. From the psychometric chart obtain:
7. (a) With the help of P-V diagram and T-s diagram explain Otto cycle clearly
showing the pressure during which the heat is supplied and rejected.
(b) The minimum pressure and temperature in a Otto cycle are 100 kPa and
27o C. The amount of heat added to the air per cycle is 1500 kJ/kg. (i).
Determine the pressure and temperatures at all points of air standard Otto
cycle. (ii). Calculate the specific work and thermal efficiency of the cycle for
a compression ratio of 8:1. [6+10]
8. The pressure limits of an air refrigeration system working on bell coleman cycle
is 4.3 bar aznd 1 bar. The temperature of air entering in to the compressor and
expander are −10 C. and 270 C. respectively. find
(a) COP of the cycle if the compression and expansion are isentropic.
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(b) the ice making capacity in tones of ice for the air circulation through the
system is 13 kg/min and water is supplied at 0C and ice formed at 00 and,
(c) piston displacement per minute for the compression and expansion [16]
?????
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3. (a) What is the difference between the Gibbs function and the availability func-
tion? When these two functions are numerically equal?
(b) A mass of 0.25 Kg of air in a closed system expands from 2 bar and 600 C to 1
bar and 400 C, while receiving 1.05 KJ of heat from a reservoir at 1000 C. The
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surrounding atmosphere is at 0.95 bar and 270 C. Determine the maximum
useful work. [8+8]
4. (a) Describe the process of formation of steam and give its graphical representation
(b) Steam enters an engine at a pressure 10 bar absolute and 2500 C. It is exhausted
at 0.2 bar. The steam at exhaust is 0.9 dry. Find
i. Drop in enthalpy
ii. Change in enthalpy. [7+9]
5. (a) Derive an expression for heat transfer in a non-flow constant volume process.
[7M]
(b) A spherical shaped of 14 M diameter contain ’H2 ’ at 330 C and 1.3 bar. Find
the mass of ’H2 ’ in the balloon using real gas equation. [9]
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7. (a) What is the simplest way by which an IC engine cycle can be analyzed? Do IC
engines operate on a thermodynamic cycle? What is the use of air standard
cycle analysis?
(b) In an working on the Diesel cycle the ratio of the weights of air and fuel sup-
plied is 50:1. The temperature of the air at the beginning of the compression
is 600 Cand the Compression ratio used is 15:1. What is the ideal efficiency of
the engine? Calorific value of fuel used is 42000kJ/kg. Assume Cp = 1.004
kJ/kg K and Cv = 0.717 kJ/kg K for air. [6+10]
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Liquid Vapour
9.0 36 70.55 201.88 0.6836
2.5 -7 29.62 184.5 0.7001
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1. (a) What are different forms of work energy? Explain each briefly.
(b) Why does free expansion have zero work transfer? [10+6]
2. (a) Make an energy analysis of the steam nozzle and heat exchanger.
(b) Refrigerant vapour enters the condenser of a refrigeration plant with enthalpy
223.75 KJ/kg and leaves with enthalpy 64.6 KJ/kg. Cooling water enters at
150 C and leaves at 200 C. Calculate the mass flow rate of water per unit flow
rate of refrigerant. Take for water Cp = 4.186 KJ/Kg-K. [8+8]
4. (a) Feed water pump is used for pumping water from 300 C to a pressure of 200
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Kpa determine the change in enthalpy assuming water to be incompressible
and pumping to be isentropic process? [8M]
(b) A rigid vessel contains liquid vapour mixture in the ratio of 3:2 by volume
determine quality of water vapour mixture and total mass of fluid in the vessel
if the volume of vessel is 2m3 and initial temperature is1500 C. [8M]
6. (a) The gravimetric analysis of a gaseous mixture follows C02 is15%, O2 is8%andN2 is77%.
Determine
i. The volumetric analysis
ii. Molecular weight.
iii. The gas constant for the mixture.
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iii. Dew point temperature
iv. The enthalpy of the mixture per kg of dry air. [8+8]
7. (a) Discuss the use of air standard cycle analysis for the study of internal com-
bustion engines.
(b) An engine of 250 mm bore and 375 mm stroke works on Otto cycle. The
clearance volume is 0.00263m3 . The initial pressure is limited to 25 bar, find
the following: (i) The air standard efficiency of the cycle. (ii) The mean
effective pressure for the cycle. [6+10]
8. (a) Write the differences between refrigerator and heat pump? Deribe the COP
for both of them?
(b) The capacity of refrigerator is 280 tons. Determine the quantity of icec pro-
duced at 00 C with in 24 hours when water is supplied at a temperature of
200 C. [8+8]
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