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Abstract
Malaysia is the largest producer and exporter of palm oil. Palm oil processing is carried out in palm oil mills where
oil is extracted from a palm oil fruit bunch. Large quantities of water are used during the extraction of crude palm oil
from the fresh fruit bunch, and about 50% of the water results in palm oil mill effluent (POME). POME is a thick
brownish liquid that contains high amounts of total solids (40,500 mg/L), oil and grease (4000 rag/L), COD
(50,000 mg/L) and BOD (25,000 mg/L). The disposal of this highly polluting effluent is becoming a major problem if
it is not being treated properly besides a stringent standard limit imposed by The Malaysian Department of Environment
for effluent discharged. A POME treatment system based on membrane technology shows high potential for eliminating
the environmental problem, and in addition, this alternative treatment system offers water recycling. The treated effluent
has a high quality and crystal clear water that can be used as the boiler feed water or as the source of drinking water
production. In our current research, a pilot plant was designed and constructed for POME treatment; two stages of
treatment have been conducted whereby coagulation, sedimentation and adsorption play their roles at the first stage as
a membrane pretreatment process, and ultrafiltration and reverse osmosis membranes are combined for the membrane
separation treatment. Results from the total treatment system show a reduction in turbidity, COD and BOD up to 100%,
98.8% and 99.4%, respectively, with a fmal pH of 7. Thus, the results show that this treatment system has a high
potential for producing boiler feed water that can be recycled back to the plant.
Keywords: Palm oil mill effluent; Pretreatment; Membrane technology; Water recycling
*Corresponding author.
Presented at the European Conference on Desalination and the Environment: Fresh Walerfor All, Malta, 4-8 May 2003.
European Desalination Society, International Water Association.
0011-9164/03/$- See front matter 2003 Elsevier Science B.V. All rights reserved
PII: SOOl 1-9164(o3)00387-4
88
1. Introduction
Table 1
Characteristics of POME and its respective standard discharge limit by the MalaysianDepartmentof the Environment [4]
Parameter
pH
Oil and grease
BOD
COD
Total solids
Suspended solids
Total nitrogen
Concentration,Standard
mg/L
limit, mg/L
4.7
5-9
4,000
50
25,000
100
50,00O
-40,500
-18,000
400
750
150
89
90
treatment technique because of its multifunctional nature and the fact that it adds nothing
detrimental to the treated water [15].
In the current research a new approach in
treating POME is being studied. A pilot plant
was designed and constructed which integrates
pretreatment methods and membrane technology
(UF and RO) to treat POME. Another purpose of
this research is to recover the treated water to be
recycled for internal plant usage such as boiler
feed water for the sterilization processes of fresh
fruit bunches, water for clarification of the extracted crude palm oil or water for hydrocyclone
separation of the cracked mixture of kernels and
shells. The pre-treatment process is necessary to
remove the high content of suspended solids and
oil in POME that would otherwise severely foul
the membrane and lead to a shorter membrane
life.
The pretreatment processes consist of two
stages of chemical treatment and activated carbon
treatment; for membrane separation treatment,
UF and RO membranes are used to refine the
treated water further. A simplified flow diagram
of the process is shown in Fig. 1.
After this membrane separation treatment
system, the product is suitable for recycling
purposes, especially for boiler feed water. Fig. 2
shows the possibility of water recycling in an
average palm oil mill of 30 tonnes of fresh fruit
bunches (FFB)/h.
l
Tvdnsf~r
tank
.3
-3
Raw POME
| st
2 nd
Chemical
treatment
tank
Chemical
treatment
tank
UF
Feed
Tank
POME
o
P2
....
Treated
V3
P1
I't
P3
P4
-C>
for pilot plant use where pH was 4.5-9; coagulant dosage, 0.01-0.075 v/v; and flocculant
dosage, 0-0.025 v/v.
2.2. Pilot plant experimental set-up
"1
14 - 29
Tonnes
Water/hr
-1
91
30 Tonnes FFB/hr
85 % water
recovery
16 Tonnes of Water/hr
92
RAW
POME
Chemical
treatment
Chemical
treatment
Carbon
treatment
I I
4] uF
treatment
Treated
treatment-'"~POME
6
93
Table 2
Tabulated results for preliminary test (no flocculation
dosage)
80
800
6O
500
50
pH
Coagul~ion
dosage(v/v)
Supern~ant
recovery(%)
Turbidity
(NTU)
4.5
0.01
0.02
0.03
0.04
0.05
0.075
0.01
0.02
0.03
0.04
0.05
0.075
0.01
0.02
0.03
0.04
0.05
0.075
0.01
0.02
0.03
0.04
0.05
0.075
65.2
64.8
58.0
57.0
56.4
52.8
57.4
46.5
44.4
44.0
45.9
43.9
53.0
44.5
45
42.4
44.6
43.1
36
16.5
16.5
16.5
18
24
1444
1169
1062
1122
1171
1287
2239
1057
1053
1023
846
741
2926
1172
1091
1022
831
704
2926
972
709
690
635
604
,~ 4o
,e_.,.3o
400
1-
5.5
6.5
20
L?'
I0
I Supernatant (%L
200
. . . . .
0.005
~iil]~i/T
0.01
0.015
1 ~
0.02
o
0,025
1
2
3
4
5
6
Parameter
Turbidity
(NTU)
COD
(mg/L)
BOD
(mg/L)
10,563
3,012
318
190
1.17
0.81
26,107
16,967
13,883
11,460
7,835
314
15,800
6,320
4,920
4,570
1,752
91
94
100
'~\
80 \,~, \
&
oo
#
Turbidity
- - I , - - - COD
',"
-..--Boo
40
20
Sampling point
Acknowledgement
The authors would like to gratefully
acknowledge Yayasan Felda for their financial
support for this research. The authors would also
like to thank United Oil Palm Industry, Nibong
Tebal, Pulau Pinang, for providing the sample o f
POME to conduct this research.
References
[1] Malaysia Palm Oil Promotion Council Home Page :
http://www.mpopc.org.my (accessed January 2003).
[2] A.N. Ma, Palm Oil Developments, 30 (2000) 1-10.
95