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TABLES

May 2011

103-87668

Table 2-1: Fuel Analysis, Highlands EnviroFuels


Design Values
Sugarcane Bagasse
Parameter
Specific Gravity
Heating Value (Btu/lb)
Heating Value (Btu/gal)
Heating Value (Btu/scf)
Ultimate Analysis:
Carbon
Hydrogen
Nitrogen
Oxygen
Sulfur
Ash/Inorganic
Chlorine
Moisture

Sorghum Bagasse

Wood

As Fired

3,900 (as fired)

Dry Basis

7,800, dry

As Fired

3,900 (as fired)

Dry Basis

7,800, dry

(Dry Basis)

4,250, wet

Natural Gas

1,020

24.8
3
0.2
20.4
0.06
1.52
0.02
50

49.6
6.0
0.4
40.8
0.12
3.04
0.04
NA

23
2.75
0.32
20.9
0.11
2.8
0.12
50

46
5.5
0.64
41.8
0.22
5.6
0.24
NA

49.6
5.87
0.4
40.9
0.07
9
0.21
30 - 50

Note: values represent average fuel characteristics, see Appendix A for detailed summary.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-1, A-1 Fuel Specs.xlsx

May 2011

103-87668

Table 2-2: Biomass Boiler Design Parameters, Highlands EnviroFuels


Parameter

Value

Unit

Boiler
Hours of Operation

8,040 hr/yr

Basis
Based on 335 days of operation

Maximum Steam 24-Hour


Maximum Steam 1-Hour

250,000 lb/hr
275,000 lb/hr

Highlands Ethanol
Based on 110% of 24-Hour steam rate

Net Enthalpy

1,247.1 Btu/lb

See Appendix A

Thermal Efficiency (Biomass)


Thermal Efficiency (Natural Gas)

68 %
82 %

Boiler manufacturer
Estimate

Total Heat Output Required

2,506,671 MMBtu/yr

Based on net enthalpy and 335 days/yr

Sugar Cane Bagasse


Heating Value
Heating Value
Sugarcane Harvested
Bagasse from Sugarcane
Sugarcane Bagasse

3,900
7.8
1,074,091
22
236,300

Btu/lb, wet
MMBtu/ton
Tons
%
Tons

See Appendix A
Calculated
Based on heat output requirement
Fagen Engineering
Calculated

3,900
7.8
984,584
24
236,300

Btu/lb, wet
MMBtu/ton
Tons
%
Tons

See Appendix A
Calculated
Based on heat output requirement
Fagen Engineering
Calculated

Sweet Sorghum Bagasse


Heating Value
Heating Value
Sweet Sorghum Harvested
Bagasse from Sweet Sorghum
Sweet Sorghum Bagasse
Wood
Heating Value
Heating Value

4,250 Btu/lb, wet


8.5 MMBtu/ton

See Appendix A
Calculated

Natural Gas
Heating Value

1,020 Btu/scf

See Appendix A

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-2, 2-3, 2-12, 2-13.xlsx

May 2011

103-87668

Table 2-3: Maximum Fuel Usage for the Biomass Boiler, Highlands EnviroFuels
Fuel Type

Heat Inputb

Maximum 1-hour/3-Houra
Biomass - Sugarcane Bagasse
- Sorghum Bagasse
- Wood
Natural Gas
Maximum 24-Houra
Biomass - Sugarcane Bagasse
- Sorghum Bagasse
- Wood
Natural Gas
Annual Average

Heat Output Fuel Firing Rate

(MMBtu/hr)
504.3
504.3
504.3
249.0
(MMBtu/hr)
458.5
458.5
458.5
249.0

(MMBtu/hr)
343
343
343
204
(MMBtu/hr)
312
312
312
204

64.66
64.66
59.33
244,118

58.78
58.78

TPH
TPH
TPH
scf/hr

TPH
TPH

53.94
244,118

TPH
scf/hr

(MMBtu/yr)

(MMBtu/yr)

1,843,140
1,843,140
0
0
3,686,281

1,253,336
1,253,336
0
0
2,506,671

236,300
236,300
0
0

TPY
TPY
TPY
MMscf/yr

Maximum Wood Firing (10%Wood / 90% Bagasse)


Sugarcane Bagasse
1,658,826
Sorghum Bagasse
1,658,826
Wood
368,628
Natural Gas
0
Total
3,686,281

1,128,002
1,128,002
250,667
0
2,506,671

212,670
212,670
43,368
0

TPY
TPY
TPY
MMscf/yr

Maximum Natural Gas Firing (30% Natural Gas / 70% Bagasse)


Sugarcane Bagasse
1,215,145
Sorghum Bagasse
1,215,145
Wood
0
Natural Gas
1,041,553
Total
3,471,844

826,299
826,299
0
854,074
2,506,671

155,788
155,788
0
1,021

TPY
TPY
TPY
MMscf/yr

Normal Operations (100% Bagasee Firing)


Sugarcane Bagasse
Sorghum Bagasse
Wood
Natural Gas
Total

Notes:
Maximum 3-hour heat input based on 275,000 lb/hr steam rate; maximum 24-hour based
on 250,000 lb/hr. Fuels may be burned in combination, not to exceed total heat outputs.
b
Heat input and output rates are calculated based on the design parameters shown in Table 2-2.
a

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-2, 2-3, 2-12, 2-13.xlsx

May 2011

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Table 2-4: Specifications for VOL Storage Tanks


Fuel Ethanol
Storage Tank
1

200 Proof Ethanol


Storage Tank
2

Off-Spec
Tank
3

Denaturant/Gasoline Tank
4

Corrosion
Inhibitor Tank
5

Yes

Yes

Yes

Yes

No

Ethanol

Ethanol

Off-Spec Ethanol Product

Gasoline (4.5% of ethanol for


denaturant)

Methanol, xylene and ethylbenzene

Internal Floating Roof

Internal Floating Roof

Internal Floating Roof

Internal Floating Roof

Vertical Fixed Roof

Tank Height (ft)

52.0

32.0

32.0

32.0

8.0

Tank Diameter (ft)

58.0

25.0

25.0

25.0

7.0

Tank Capacity (gallons)

1,000,000

100,000

100,000

100,000

2,300

Throughput (gal/yr)

36,000,000

36,000,000

3,600,000

1,620,000

2,700

Turnovers per Year

36

360

36

16

Tank Description
Tank ID No.
Subpart Kb Applies (Yes/No)

Tank Content
Tank Type

See MSDS in Appendix D for corrosion inhibitor speciation.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-4, D1-D3 Tanks.xlsx

May 2011

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Table 2-5: Ethanol Process: CO2 and Distillation Scrubbers


Manufacturer and Model No.

Vogelbusch (or equivalent)

CO2 Scrubber
Inlet Flue Gas Temp (F)
Inlet Design Flow Rate (acfm)
Scrubbing Liquid
Scrubbing Liquid Flow Rate (gpm)
Recirculation Liquid Flow Rate (gpm)
Ethanol Removal Efficiency (%)
Distillation Scrubber
Inlet Flue Gas Temp (F)
Inlet Design Flow Rate (acfm)
Scrubbing Liquid
Scrubbing Liquid Flow Rate (gpm)
Ethanol Removal Efficiency (%)

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-5 to 2-9 APCD.xlsx

77
4,566
Process Water
64
101
98

77
120
Soft Water
4
98

May 2011

103-87668

Table 2-6: Boiler Control Equipment Parameters: Wet Sand Separator (Cyclone)
Manufacturer and Model No.

Wet Cyclone (or equivalent)a

Inlet Flue Gas Temp (oF)


Inlet Design Flue Gas Flow Rate (acfm)
Moisture (% Volume)
Cyclone Diameter (ft)
Cyclone Height (ft)
No. of Spray Nozzles (Cyclone)
No. of Spray Nozzles (Inlet Duct)
Total Water Flow to Nozzles (gpm)
Pressure Drop (in H2O)
Overall PM Collection Efficiency (%)
a

Vendor for the Biomass Boiler Cyclone not yet selected.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-5 to 2-9 APCD.xlsx

510
256,832
18
22
35
5
9
713
9
80

May 2011

103-87668

Table 2-7: Boiler Control Equipment Parameters: Electrostatic Precipitator


Manufacturer and Model No.

Factory Sales (or equivalent)a


Model No.39R-1330-3712P

Inlet Flue Gas Temp (oF)


Inlet Design Flue Gas Flow Rate (acfm)
Moisture (% Volume)
Inlet PM Loading (lb/MMBtu)

510
256,832
18
0.41

No. of Precipitators
Precipitation Type
Total Number of Fields
Total Installed Collection Area (ft2)
Gas Velocity (ft/s)
Specific Collection Area (ft2/1,000 acfm)
Power Consumption (kw)
Pressure Drop (in H2O)

Pollutants
Particulate Matter
a

1
Rigid Electrode
4
71,656
3.66
279
121
0.5
Inlet
Loading
(lb/MMBtu)
0.41

Vendor for the Biomass Boiler ESP not yet selected.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-5 to 2-9 APCD.xlsx

Outlet
Loading
(lb/MMBtu)
0.015

Control
Efficiency
%
96.3

May 2011

103-87668

Table 2-8: Boiler Control Equipment Parameters: Selective Non-Catalytic Reduction System
Manufacturer and Model No.

DNTa (or equivalent)

Flue Gas Flow Rate (acfm)


NOx Reduction Reagent

256,832
19% Ammonia

Ammonia Injectors
Ammonia Flow Control Section
Pressure Drop (in of wc)

6
1
0.8
Inlet
Loading
(lb/MMBtu)
0.25

Pollutants
Nitrogen Oxides
Notes:
a
Vendor for the Biomass Boiler SNCR system not yet selected.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-5 to 2-9 APCD.xlsx

Outlet
Loading
(lb/MMBtu)
0.10

Control
Efficiency
%
60

May 2011

103-87668

Table 2-9: Boiler Control Equipment Parameters: Dry Sorbent Injection System
Manufacturer and Model No.

Factory Sales (or equivalent)a


Model No. T-268

Inlet Flue Gas Temp (oF)


Inlet Design Flue Gas Flow Rate (acfm)
Moisture (% Volume)

510
256,832
18

No. of Injection Fans


No. of Feed Hoppers
No. of Pulverizers
No. of Classifiers
Reagent
Dry Sorbent Injection Rate (lb/hr)
Pulverizer Motor (hp)
Classifier Motor (hp)
Blower Motor (hp)

Pollutants
HCl
SO2
a

1
1
1
1
Trona or sodium bicarbonate
219
40
8
20
Inlet
Loading
(lb/hr)
37
64

Outlet
Loading
(lb/hr)
1.8
16.0

Vendor for the Biomass Boiler Acid Gas Removal System not yet selected.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-5 to 2-9 APCD.xlsx

Control
Efficiency
%
79
75

May 2011

103-87668

Table 2-10: Physical, Performance, and Emissions Data for the Fermentation CO 2 Scrubber
Parameter
Performance Data
Ethanol Production (gal/yr)
Ethanol Production (gal/day)
Scrubbing Column Control Efficiency (%)
Hours of Operation
Emission Factorsa
Uncontrolled Ethanol (lb/hr)
Controlled Ethanol (lb/hr)
Uncontrolled Other VOCs - Total (lb/hr)
Controlled Other VOCs - Total (lb/hr)

Value a

Basis

36,000,000
120,000
98.0
7,296

Highlands Envirofuels
Estimated
Design Value
Maximum

770.4
15.41
180.0
3.60

Design Value
Calculated
Calculated
Design Value

Emission Calculation - Speciated a,b


Maximum Uncontrolled Emissions
(lb/hr)
(TPY)

Maximum Controlled Emissions


(lb/hr)
(TPY)

Pollutant

Factor (%)

Description

Ethanol
Ethyl Acetate

100.0
78.0

of ethanol
of other VOCs

770.4
140.4

2,810.4
512.2

15.41
2.81

56.21
10.24

Acetaldehydec

19.8

of other VOCs

35.6

130.0

0.71

2.60

Methanol c

2.2

of other VOCs
Total VOC
Total HAP

4.0
950.4
39.6

14.4
3,467.1
144.5

0.079
19.01
0.79

0.29
69.34
2.89

Based on data from Highlands EnviroFuels, 2011.

Example Calculation - Ethyl Acetate:


Hourly Average: 3.6 lb/hr Total Controlled Other VOCs x (78 % Maximum of VOC / 100) = 2.81 lb/hr Ethyl Acetate
Annual Average: 2.81 lb/hr Ethyl Acetate x 7,296 hr/yr / 2,000 lb/hr = 10.24 TPY Ethyl Acetate

Hazardous Air Pollutants (HAP).

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-10, 2-11 Ethanol Process.xlsx

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Table 2-11: Physical, Performance, and Emissions Data for the Distillation Vent Scrubber
Parameter
Performance Data
Ethanol Production (gal/yr)
Ethanol Production (gal/day)
Scrubbing Column Control Efficiency (%)
Hours of Operation
Emission Factorsa
Uncontrolled Ethanol (lb/hr)
Controlled Ethanol (lb/hr)
Uncontrolled Other VOCs - Total (lb/hr)
Controlled Other VOCs - Total (lb/hr)

Value a

Basis

36,000,000
120,000
98
7,296

Highlands Envirofuels
Estimated
Design Value
Maximum

79.20
1.58
1.20
1.20

Design Value
Calculated
Design Value
Design Value

Emission Calculation - Speciated a,b


Maximum Uncontrolled Emissions
(lb/hr)
(TPY)

Maximum Controlled Emissions


(lb/hr)
(TPY)

Pollutant

Factor (%)

Description

Ethanol
Ethyl Acetate

100.0
78.0

of ethanol
of other VOCs

79.20
0.94

288.92
3.41

1.58
0.94

5.78
3.41

Acetaldehydec

19.8

of other VOCs

0.24

0.87

0.24

0.87

Methanol c

2.2

of other VOCs
Total VOC
Total HAP

0.026
80.4
0.26

0.096
293.3
0.96

0.026
2.78
0.26

0.096
10.16
0.96

Based on data from Highlands EnviroFuels, 2011.

Example Calculation - Ethyl Acetate:


Hourly Average: 1.2 lb/hr Total Controlled Other VOCs x (78 % Maximum of VOC / 100) = 0.94 lb/hr Ethyl Acetate
Annual Average: 0.94 lb/hr Ethyl Acetate x 7,296 hr/yr / 2,000 lb/hr = 3.41 TPY Ethyl Acetate

Hazardous Air Pollutants (HAP).

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-10, 2-11 Ethanol Process.xlsx

May 2011

103-87668

Table 2-12: Maximum Short-Term Emissions for the Biomass Boiler, Highlands EnviroFuels

Regulated
Pollutant
1-hr Averages
Sulfur Dioxidej

Sugarcane Bagasse
Emission
Activity
Maximum
Factor a
Factorb
Emissions
(lb/MMBtu)
(MMBtu/hr)
(lb/hr)
0.078

Nitrogen Oxides (uncontrolled)

0.25

Carbon Monoxide (cold-startup)

3.0

504
e

39.1

Sweet Sorghum Bagasse


Emission
Activity
Maximum
Factor a
Factorb
Emissions
(lb/MMBtu)
(MMBtu/hr)
(lb/hr)
0.14

504

126.1

0.25

183

550.2

6.5

504
e

Emission
Factor a
(lb/MMBtu)

Wood
Activity
Factorb
(MMBtu/hr)

0.075

504

70.6

504

126.1

0.25

183

1,192.1

6.5

Maximum
Emissions
(lb/hr)
37.8

Natural Gas
Activity

Emission
Factor a
(lb/MMBtu)

Factor
(MMBtu/hr)

Maximum

Maximum
Emissions

Emissions
(lb/hr)

for all fuels


(lb/hr)

0.00059

249

0.15

70.6

249

34.18

126.1

504

126.1

0.14

183

1,192.1

0.00059

249

0.15

1,192.1

3-hr Averages
Particulate (PM)
Particulate (PM10)

0.015

504

7.6

0.015

504

7.6

0.015

504

7.6

0.0075

249

1.9

7.6

0.015

504

7.6

0.015

504

7.6

0.015

504

7.6

0.0075

249

1.9

7.6

Particulate (PM2.5)c

0.0098

504

4.9

0.0098

504

4.9

0.0098

504

4.9

0.0075

249

1.9

4.9

0.078

504

39.1

0.14

504

70.6

0.075

504

37.8

0.00059

249

0.15

70.6

504

126.1

0.25

504

126.1

0.25

504

126.1

0.14

249

34.18

126.1

183

1,192.1

0.082

249

20.5

1,192.1

Sulfur Dioxidej
Nitrogen Oxides (uncontrolled)
Carbon Monoxide (cold-startup)

0.25
3.0

183

550.2

6.5

183

1,192.1

6.5

VOC

0.017

504

8.6

0.017

504

8.6

0.017

504

8.6

0.0054

249

1.34

8.6

Lead

9.60E-05

504

0.048

9.60E-05

504

0.048

8.4E-05

504

0.042

4.9E-07

249

1.2E-04

0.048

Mercury

1.38E-05

504

0.0070

1.38E-05

504

0.0070

3.6E-06

504

0.0018

2.5E-07

249

6.3E-05

0.0070

6.0E-04

504

0.30

--

249

--

0.30

Fluorides
Sulfuric Acid Mist g

504

0.30

6.0E-04

0.0038

504

1.9

0.018

504

Particulate (PM)
Particulate (PM10)

0.015

Particulate (PM2.5)c

Ammonia h

504

0.30

6.0E-04

0.0069

504

3.5

0.0037

504

1.9

2.9E-05

249

7.2E-03

3.46

8.8

0.018

504

8.8

0.018

504

8.8

0.018

249

4.4

8.8

458

6.9

0.015

458

6.9

0.015

458

6.9

0.0075

249

1.9

6.9

0.015

458

6.9

0.015

458

6.9

0.015

458

6.9

0.0075

249

1.9

6.9

0.0098

458

4.5

0.0098

458

4.5

0.0098

458

4.5

0.0075

249

1.9

4.5

0.078

458

35.5

0.14

458

64.2

0.075

458

34.4

0.00059

249

0.15

64.2

24-hr Averages

Sulfur Dioxidej
Nitrogen Oxides
Carbon Monoxide (cold-startup)

0.10
3.0

458

45.8

0.10

183

550.2

6.5

458

45.8

0.10

183

1,192.1

6.5

458

45.8

0.10

249

24.90

45.8

183

1,192.1

0.082

249

20.5

1,192.1

VOC

0.017

458

7.8

0.017

458

7.8

0.017

458

7.8

0.0054

249

1.34

7.8

Lead

9.60E-05

458

0.044

9.60E-05

458

0.044

8.4E-05

458

0.039

4.9E-07

249

1.2E-04

0.044

Mercury

1.38E-05

458

0.0063

1.38E-05

458

0.0063

3.6E-06

458

0.0017

2.5E-07

249

6.3E-05

0.0063

6.0E-04

458

0.28

--

249

--

0.28

Fluorides
Sulfuric Acid Mist g

458

0.28

6.0E-04

458

0.28

6.0E-04

0.0038

458

1.7

0.00686

458

3.1

0.003675

458

1.7

2.9E-05

249

7.2E-03

Ammonia h

0.018

458

3.15

8.0

0.018

458

8.0

0.018

458

8.0

0.018

249

4.4

8.0

30-day Rolling Averages


Sulfur Dioxidej

0.078

458

35.5

0.14

458

64.2

0.075

458

34.4

0.00059

Nitrogen Oxides

0.10

458

45.8

0.10

458

45.8

0.10

458

45.8

0.10

Carbon Monoxide
Ammonia h

0.30

458

137.5

0.30

458

137.5

0.30

458

137.5

0.082

0.018

458

8.0

0.018

458

8.0

0.018

458

8.0

0.018

Notes:
Based on Proposed BACT limits, unless otherwise noted.

a
b

Maximum 1-hour and 3-hour heat input based on 275,000 lb/hr steam; maximum 24-hour and 30-day rolling average heat input based on 250,000 lb/hr steam.

Based on wood residue combustion, Section 1.6, AP-42, September 2003; 65 percent of PM emissions.

Based on AP-42 emission factor for Natural Gas (Section 1.4, July 1998), divided by the heating value for natural gas (1,020 Btu/scf).

e
f

Under cold startup conditions, boiler will be limited to 100,000 lb/hr of steam. Cold startup heat input rate is based on this limited steam rate.

Based on highest stack test results for New Hope Power Company Boilers A, B, and C (1999-2002) excluding 1999 wood test for Unit C.

Based on 4% of the SO2 emissions becomes SO3 from AP-42 for fuel oil burning; then convert to SAM (98/80).

Ammonia emission rate of 30 ppmvd @ 7% O2. Gas flow rate = 101,300 dscfm for 24-hour average. Other fuels based on same emissions factor (0.018 lb/MMBtu).

Based on maximum sorghum fuel content, sorghum fuel analysis September 2009. Maximum values used. Assumed 90% control efficiency for Lead.
j
Uncontrolled emission rates for SO2 are 0.31 for sugarcane bagasse, 0.56 lb/MMBtu for sorghum bagasse, and 0.30 lb/MMBtu for wood.
A control efficiency of 75 percent is applied to all emisison rates, except those due to natural gas combustion.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-2, 2-3, 2-12, 2-13.xlsx

249

0.15

64.2

249

24.9

45.8

249

20.5

137.5

249

4.4

8.0

May 2011

103-87668

Table 2-13: Maximum Annual Emissions for the Biomass Boiler, Highlands EnviroFuels

Regulated
Pollutant

Sugarcane Bagasse
Emission
Activity
Annual
Factor a
Factor
Emissions
(lb/MMBtu)

(1012 Btu/yr)

(TPY)

Sweet Sorghum Bagasse


Emission
Activity
Annual
Factor a
Factor
Emissions
(lb/MMBtu)

(1012 Btu/yr)

(TPY)

Emission
Factor a
(lb/MMBtu)

Wood
Activity

Annual

Factor
Emissions
12
(10 Btu/yr)
(TPY)

Emission
Factor a

Natural Gas
Activity

Annual

Factor
Emissions
12
(lb/MMBtu) (10 Btu/yr)
(TPY)

Total Annual
Emissionsc
(TPY)

Particulate (PM)
Particulate (PM10)

0.015
0.015

1.843
1.843

13.8
13.8

0.015
0.015

1.843
1.843

13.8
13.8

0.015
0.015

0.000
0.000

0.0
0.0

0.0075
0.0075

0.000
0.000

0.0
0.0

27.6
27.6

Particulate (PM2.5)

0.010

1.843

9.0

0.010

1.843

9.0

0.010

0.000

0.0

0.0075

0.000

0.0

18.0

Sulfur dioxide
Nitrogen oxides
Carbon monoxide
VOC
Lead
Mercury
Fluorides

0.078
0.10
0.30
0.017
9.60E-05
1.38E-05
6.0E-04

1.843
1.843
1.843
1.843
1.843
1.843
1.843

71.4
92.2
276.5
15.7
0.088
0.0127
0.55

0.14
0.10
0.30
0.017
9.60E-05
1.38E-05
6.0E-04

1.843
1.843
1.843
1.843
1.843
1.843
1.843

129.0
92.2
276.5
15.7
0.088
0.0127
0.55

0.075
0.10
0.30
0.017
8.4E-05
3.6E-06
6.0E-04

0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.0
0.0
0.0
0.0
0.000
0.0000
0.00

0.00059
0.10
0.082
0.0054
4.9E-07
2.5E-07
--

0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.0
0.0
0.0
0.0
0.0
0.0
--

200.4
184.3
552.9
31.3
0.18
0.025
1.1

Sulfuric acid mistb

0.00380

1.843

3.50

0.00686

1.843

6.32

0.00368

0.000

0.00

2.9E-05

0.000

0.0

9.8

0.018

1.843

16.2

0.018

1.843

16.2

0.018

0.000

0.0

0.018

0.000

0.0

32.3

Ammonia
Notes:
a

Refer to Table 2-12 for basis of emission factors.

Based on 4% of the SO2 emissions becomes SO3 from AP-42 for fuel oil burning; then convert to SAM (98/80).

Denotes maximum for any fuel combination.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-2, 2-3, 2-12, 2-13.xlsx

May 2011

103-87668

Table 2-14: Short-Term Emissions of Hazardous Air Pollutants from the Biomass Boiler
Emission
Factor
HAP
Biomass Boiler

Sugarcane Bagasse
Activity
Control
Hourly
Ref
Factor
Efficiency Emissions

(lb/MMBtu)

(MMBtu/hr)

(lb/MMBtu)

459

UD

UD

459

ND

ND

459

UD
ND

UD
ND

459
90

9.40E-04

2.05E-05

459

2.29

5.00E-03

459

90

1.77E-03

3.85E-05

459

UD

Acetophenone

ND

Acrolein

UD
ND

2.05E-05

459

5.00E-03

459

3.85E-05

459

Antimony
Arsenic

Benzene
Beryllium

bis(2ethylhexyl)phthalate

6.71E-04

459

Cadmiuma

3.33E-05
ND

459

Carbon Disulfide
Carbon Tetrachloride
Chlorine

ND
0.00040

Chlorobenzene
Chloroform
Chromiuma
Chromium+6

ND
ND
2.05E-03
1.37E-04

459

90

6.30E-03
ND

Ethylbenzene

ND

Formaldehyde

1.50E-03
ND

Hexane
Hydrogen Chlorideb

9.90E-03

459

Hydrogen Fluoride

6.00E-04

459

Lead-Totala

9.60E-05

459

2.31E-03

459

90

Mercury

1.38E-05

Methanol

UD
ND

Methyl Isobutyl Ketone


Methylene Chloride

ND

Phosphorus
Propionaldehyde
Seleniuma
Styrene
Dioxin/Furan (2, 3, 7, 8Tetrachlorodibenzo-p-dioxin)
Toluene
1, 1, 2-Trichloroethane
Trichloroethylene
Vinyl Chloride
m- & p-Xylene
o-Xylene

459

ND

0.24

ND

7.90E-06

459

0.0036

ND

0.24

ND

3.62E-03

Antimony

90

9.40E-04

1.13E-04

459

90

0.24

90

459

0.24

4.88E-06
5.13E-04

5.18E-03
2.29

Arsenic

0.0042

2.00E-04
0.0021

2.29

0.0052
1.93

90

1.77E-03

5.09E-07

459

90

2.33E-05

0.24

90

2.93E-07
ND

1.77E-03
0.31

Beryllium

2.15E-05

1.20E-05
ND

bis(2ethylhexyl)phthalate

1.88E-04

0.0011

90

1.53E-03

Cadmiuma

ND
0.021

ND

0.24

2.69E-05
ND

ND

0.24

ND

Carbon Tetrachloride

0.31

4.70E-08

4.10E-06

459

459

1.53E-03
ND

459

ND

4.50E-05

459

459

1.47

3.10E-03

459

1.42

ND

0.24

ND

2.06E-02
1.47

459

ND
ND

3.3E-05

459

0.015

ND

0.24

ND

1.51E-02

Chlorobenzene

2.8E-05

459

0.013

ND

0.24

ND

1.28E-02

Chloroform

459

0.0014

9.40E-02

Chromiuma

8.40E-05
ND

90

90

459

ND

459

90

9.40E-02

5.22E-05

90

459

90

6.30E-03
ND

3.50E-06

459

2.39E-03
0.0016

6.50E-06

459

0.0030

0.24
0.24

90

ND

Carbon Disulfide
Chlorine

0.24
0.24

3.42E-05
ND

6.30E-03

Chromium+6

0.24

2.05E-05

2.98E-03

Cobalt

0.24

ND

ND

m&p-Cresol

0.24
0.24

ND
ND

Cumene
Dibenzofurans

0.24

ND
ND
ND

ND

Dibutylphthalate

0.24

2.93E-04

2.93E-04

1,4-Dichlorobenzene(p)

0.24

ND

Ethylbenzene

ND

459

ND
ND
ND
ND

ND

459

ND

459
459
459

ND
1.78E-09

ND
ND

ND

459
459
459

459

ND

ND

459

ND

ND

459

0.0012

459

ND

ND

459

ND

3.1E-05

459

ND
0.014

459

0.69
ND

1.50E-03
ND

459

0.69
ND

0.0044

459

2.02

0.075

0.24

1.83E-02

1.42E-02
2.02

459

ND

1.8

0.24

4.39E-01

0.44

Hexane

4.54

0.08

10

459

36.68

0.097

459

44.47

ND

95

ND

44.47

Hydrogen Chlorideb

0.275

6.00E-04

459

0.275

6.0E-04

459

0.275

ND

ND

2.75E-01

Hydrogen Fluoride

90

4.40E-03

9.60E-05

459

90

4.40E-03

8.4E-05

459

90

3.85E-03

5.00E-04

0.24

90

1.22E-05

Lead-Totala

0.11

2.31E-03

459

90

0.11

0.0016

459

90

3.80E-04

0.24

90

459

6.33E-03

1.38E-05

459

6.33E-03

3.6E-06

459

7.34E-02
0.0017

0.24

6.33E-03

Mercurya

459

UD
ND

459

459

ND

0.24

ND

ND

Methanol

459

UD
ND

ND

459

UD
ND

2.60E-04
ND

9.28E-06
6.35E-05

4.40E-03
0.11

ND

459

ND

ND

0.24

ND

ND

Methyl Isobutyl Ketone

459

ND

ND

459

ND

ND

459

ND

ND

0.24

ND

ND

Methylene Chloride

5.04E-02

1.10E-03

5.04E-02

3.30E-05

1.51E-03

0.0021

5.04E-02

Nickela

459

90

ND

459

ND

459
459

0.0142
ND

3.10E-05
ND

459

ND

ND

2.94E-04

6.41E-06

459

90

459

459

90

ND

ND

90

ND
ND
ND

0.24
0.24

Manganesea

459

5.04E-05

ND

0.24

5.13E-05
ND

5.04E-05

4-Nitrophenol

ND

0.24

ND

2.34E-05

Pentachlorophenol (PCP)

ND

0.24

ND

2.34E-02

Phenols

0.24

90

Formaldehyde

ND

459

ND

1.10E-07

459

ND

459

ND

5.10E-08

459

459

5.10E-05

459

459

0.0142
ND

2.34E-05
0.023

2.70E-05

459

0.012

ND

0.24

ND

1.24E-02

Phosphorus

459

ND

6.10E-05

459

0.028

ND

0.24

ND

2.80E-02

Propionaldehyde

2.94E-04

2.80E-06

459

2.40E-05
ND

5.86E-07
ND

2.94E-04
0.87

Seleniuma

459

1.28E-04
0.87

ND

3.94E-09

8.30E-04
ND
ND
ND
ND
ND

0.42
ND
ND
8.25E-03
ND
1.15E-02

459

90

90

ND

459

ND

ND

459

ND

0.0019

ND

459

ND

ND

459

ND

8.60E-12

459

3.94E-09

ND

459
459
459
459
459
459

0.046
ND
ND
ND
ND
ND

1.00E-04
ND
ND
ND
ND
ND

459
459
459
459
459
459

0.046
ND
ND
ND
ND
ND

9.20E-04
ND
ND
1.80E-05
ND
2.50E-05

459
459
459
459
459
459

0.42
ND
ND
0.0083
ND
0.011

0.0034
ND
ND
ND
ND
ND

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-14, 2-15 Appx B HAPs.xlsx

ND

4
4

Benzene

ND
ND
ND
ND

ND

1.00E-04
ND
ND
ND
ND
ND

459

459
8

Acrolein

ND
ND
ND
ND

ND

4.0E-03

ND

459

459

6.41E-06

UD

459

ND

459

ND

459

2.05E-03
1.37E-04

9.40E-02

Acetophenone

ND
ND

ND

3.10E-05
ND

Acetaldehyde

1.47E-06
1.83

0.0032

1,4-Dichlorobenzene(p)

Phenols

0.38

ND

ND
ND

Dibutylphthalate

Pentachlorophenol (PCP)

ND

0.24

0.18

459
459
459

4-Nitrophenol

0.24

ND

459
90

ND

1.47E-06
1.83

459

459

1.10E-03

0.38

459

ND

ND
ND
ND
ND

Nickela

459

ND

m&p-Cresol

459

459

HAP

3.2E-09

459

(lb/hr)

8.3E-04

459

459

(lb/hr)

ND

(lb/hr)

Maximum
Emissions for
All Fuels

UD

(%)

Hourly
Emissions

459

3.33E-05
ND

(MMBtu/hr)

Natural Gas
Emission
Activity
Control
Factor
Ref
Factor
Efficiency
6
(lb/10 scf)
(MMscf/hr)
(%)

459

6.71E-04

Ref

Wood
Activity
Control
Hourly
Factor
Efficiency Emissions

(lb/MMBtu)

0.31

459

Manganese

(%)

Emission
Factor

(lb/hr)

1.53E-03
ND

90

ND

(MMBtu/hr)

459

Cobalt
Cumene
Dibenzofurans

Sorghum Bagasse
Activity
Control
Hourly
Ref
Factor
Efficiency Emissions

(lb/hr)

Acetaldehyde

(%)

Emission
Factor

4
4

0.24
0.24

0.24
0.24
0.24
0.24
0.24
0.24
0.24

90

Styrene
Dioxin/Furan (2, 3, 7, 8Tetrachlorodibenzo-p-dioxin)
Toluene
1, 1, 2-Trichloroethane
Trichloroethylene
Vinyl Chloride
m- & p-Xylene
o-Xylene

May 2011

103-87668

Table 2-14: Short-Term Emissions of Hazardous Air Pollutants from the Biomass Boiler
Emission
Factor
HAP

Sugarcane Bagasse
Activity
Control
Hourly
Ref
Factor
Efficiency Emissions

(lb/MMBtu)

(MMBtu/hr)

ND

459
459

Acenaphthylene

ND
1.00E-06

459

Anthracene

4.56E-07

459

Benzo (a) anthracene


Benzo(a)pyrene

3.00E-06

1.00E-06

Benzo(b)fluoranthene
Benzo(e)pyrene
Benzo(g,h,i)perylene
Benzo(j,k)fluoranthene

1.97E-06

Chrysene

3.00E-06

(%)

(lb/hr)

Emission
Factor

Sorghum Bagasse
Activity
Control
Hourly
Ref
Factor
Efficiency Emissions

(lb/MMBtu)

(MMBtu/hr)

ND

ND

459

ND

459

4.59E-04

ND
1.00E-06

459

2.09E-04

4.56E-07

459

459

1.38E-03

3.00E-06

459

4.59E-04

1.00E-06

3.00E-06

459

1.38E-03

1.00E-06

459

4.59E-04

459

ND

ND

459

9.03E-04

1.97E-06

459

1.38E-03

3.00E-06

(%)

(lb/hr)

Emission
Factor

Ref

Wood
Activity
Control
Hourly
Factor
Efficiency Emissions
(%)

(lb/hr)

Natural Gas
Emission
Activity
Control
Factor
Ref
Factor
Efficiency
6
(lb/10 scf)
(MMscf/hr)
(%)

Hourly
Emissions

Maximum
Emissions for
All Fuels

(lb/hr)

(lb/hr)

4.39E-07

3-Methylcholanthrene

(MMBtu/hr)

ND

ND

459

ND

1.80E-06

0.24

4.39E-07

ND

4
4

459

4.39E-07

4.17E-04

1.80E-06

7
7

0.24

459

4.17E-04
0.0023

1.80E-06

4.59E-04

9.1E-07
5.0E-06

0.24

4.39E-07

2.29E-03

Acenaphthene
Acenaphthylene

2.09E-04

3.0E-06

459

0.0014

5.86E-07

1.38E-03

Anthracene

1.38E-03

6.5E-08

459

0.24

4.39E-07

1.38E-03

459

4.59E-04

2.6E-06

459

2.98E-05
0.0012

7
7

0.24

459

2.40E-06
1.80E-06

2.93E-07

1.19E-03

Benzo (a) anthracene


Benzo(a)pyrene

459

1.38E-03

1.0E-07

459

4.59E-05

7
7

0.24

3.00E-06

1.20E-06
1.80E-06

0.24

4.39E-07

1.38E-03

Benzo(b)fluoranthene

1.00E-06

459

4.59E-04

2.6E-09

459

1.19E-06

ND

0.24

ND

4.59E-04

459

ND

9.3E-08

459

4.26E-05

0.24

2.93E-07

4.26E-05

Benzo(e)pyrene
Benzo(g,h,i)perylene

459

9.03E-04

1.6E-07

459

7.34E-05

1.20E-06
1.80E-06

ND

9.03E-04

Benzo(j,k)fluoranthene

459

1.38E-03

3.8E-08

459

1.74E-05

1.80E-06

7
7

0.24

0.24

4.39E-07

1.38E-03

Chrysene

4.17E-06
ND

1.20E-06
ND

0.24

2.93E-07

4.17E-06

Dibenzo(a,h)anthracene

0.24

ND

7.34E-04
0.0016

3.00E-06

0.24

7.32E-07

ND
5.50E-03

Fluoranthene

2.80E-06

0.24

6.84E-07

1.56E-03

Fluorene

3.99E-05

indeno(1,2,3-cd)pyrene
Naphthalene

POMs
3-Methylcholanthrene
Acenaphthene

POMs

ND

Dibenzo(a,h)anthracene

ND

459

ND

ND

459

ND

9.1E-09

459

Dimethylbenz(a)anthracene

ND

459

ND

ND

459

ND

ND

459

459

0.0055

1.20E-05

459

0.0055

1.6E-06

459

ND

459

ND

ND

459

ND

3.4E-06

459

ND

459

ND

ND

459

ND

8.7E-08

459

459

0.0105

2.30E-05

459

0.0105

9.7E-05

459

Fluoranthene
Fluorene

HAP

(lb/MMBtu)

1.20E-05

1.80E-06

0.24

4.39E-07

6.10E-04
ND

0.24

1.49E-04

4.45E-02

0.24

ND

2.38E-07

1.70E-05

0.24

4.15E-06

3.21E-03

Perylene
Phenanthrene

0.0017

5.00E-06

0.24

1.22E-06

4.59E-03

Pyrene

0.057

6.58E-04

0.24

1.61E-04

0.06

Total POMs**

indeno(1,2,3-cd)pyrene
Naphthalene

2.30E-05

Perylene
Phenanthrene

459

ND

ND

459

ND

5.2E-10

459

5.00E-06

459

0.0023

5.00E-06

459

0.0023

7.0E-06

459

2.38E-07
0.0032

Pyrene

1.00E-05

459

0.0046

1.00E-05

459

0.0046

3.7E-06

459

Total POMs**

6.44E-05

459

0.030

6.44E-05

459

0.030

0.00012

459

ND

Dimethylbenz(a)anthracene

3.99E-05
0.044

MAXIMUM SINGLE HAP

4.54

36.68

44.47

0.439

44.47

MAXIMUM SINGLE HAP

TOTAL

8.65

42.07

53.92

0.460

55.27

TOTAL

UD = Undetected
ND = No Data available
a
Assumed 90% control efficiency for all metals, except mercury for which zero control was assumed.
b
For HCl a control efficiency of 95 percent was applied.
References
1. Based on highest stack test results for New Hope Power Company Boilers A, B, and C (1999-2002) excluding 1999 wood test for Unit C.
2. Based on HAP Emissions for U.S. Sugar-Clewiston Boiler 7 - Highest of three runs January 31, 2000.
3. Based on average of three stack testing runs of Boiler No. 7. (December, 2002)
4. Based on AP-42 emission factors for wood combustion (Section 1.6).
5. Based on the maximum of stack test result for boilers firing wood or a combination of wood and bagasse, 2004-2007. See Appendix B, Table B-4.
6. Based on AP-42 emission factors for natural gas combustion (Section 1.4).
7. Based on HAP testing of bagasse fired boilers. Maximum of 18 runs for HCl. Emissions for Cl 2 based on AP-42 for wood firing and Appendix B, Table B-4, which shows 4% of HCl is emitted as Cl 2.
8. Based on the maximum of fuel analysis results for SRF sweet sorghum analysis conducted Sept. 2009.
9. Based on the ratio of wood emission factor for Chromium VI to Chromium.
10. Based on maximum chlorine content of sorghum (0.24% Cl or 0.32 lb/MMBtu as HCl) and assuming 75% inherent removal in ash. Chlorine emissions are 4% of HCl, based on AP-42 for wood firing and Appendix B, Table B-4.
**Sum of all POMs, unless emission factors are only listed for Total POMs, not individuals, and will be noted.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-14, 2-15 Appx B HAPs.xlsx

May 2011

103-87668

Table 2-15: Summary of Annual Emissions of Hazardous Air Pollutants from the Biomass Boiler

Fuel Scenario

Maximum Single HAP


(TPY)

Total HAPs
(TPY)

Bagasse Only

6.91

15.84

90% Bagasse/10% Wood

6.85

18.26

70% Bagasse/30% Natural Gas

4.56

11.40

Worst-Case HAPs Total

6.91

18.26

See Appendix B, Tables B-5, B-6, and B-7.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-14, 2-15 Appx B HAPs.xlsx

May 2011

103-87668

Table 2-16. Maximum Annual Fugitive Dust Emissions for Highlands EnviroFuels, LLC

M
SOURCE

TYPE OF
OPERATION

MOISTURE
WIND
CONTENT a SPEED b
(%)

(MPH)

UNCONTROLLED

UNCONTROLLED

UNCONTROLLED

PM EMISSION

PM10 EMISSION

PM2.5 EMISSION

CONTROL

CONTROL

TYPE

EFFICIENCY

FACTOR

(%)

(LB/TON)

FACTOR

FACTOR

FACTOR

(LB/TON) c

(LB/TON) c

(LB/TON) c

CONTROLLED

CONTROLLED

CONTROLLED

PM EMISSION

PM10 EMISSION

PM2.5 EMISSION

ACTIVITY

MAXIMUM ANNUAL EMISSIONS

FACTOR

FACTOR

FACTOR

(LB/TON)

(LB/TON)

PM (TSP)

PM10

PM2.5

(TONS/YR)

(TONS/YR)

(TONS/YR)

BIOMASS DELIVERIES
SUGARCANE TRUCK TRAFFIC ON PAVED ROADSi

VEHICULAR TRAFFIC

--

--

0.11 lb/VMT

0.022 lb/VMT

0.0054 lb/VMT

WATER/SWEEP

50

0.055 lb/VMT

0.011 lb/VMT

0.0027 lb/VMT

25,500 VMT

0.70

0.14

SORGHUM TRUCK TRAFFIC ON PAVED ROADSi

VEHICULAR TRAFFIC

--

--

0.11 lb/VMT

0.022 lb/VMT

0.0054 lb/VMT

WATER/SWEEP

50

0.055 lb/VMT

0.011 lb/VMT

0.0027 lb/VMT

25,500 VMT

0.70

0.14

0.035

WOOD TRUCK TRAFFIC ON PAVED ROADSi

VEHICULAR TRAFFIC

--

--

0.11 lb/VMT

0.022 lb/VMT

0.0054 lb/VMT

WATER/SWEEP

50

0.055 lb/VMT

0.011 lb/VMT

0.0027 lb/VMT

1,475 VMT

0.041

0.0081

0.0020

BAGASSE FROM DRYING SYSTEM-TO-TRANSFER CONVEYOR

CONTINUOUS DROP

50

6.9

0.000040

0.000019

0.0000028

ENCLOSURE

0.000040

0.000019

0.0000028

467,874 TPY

0.0093

0.0044

0.00067

TRANSFER CONVEYOR-TO-HOPPER

CONTINUOUS DROP

50

6.9

0.000040

0.000019

0.0000028

ENCLOSURE

0.000040

0.000019

0.0000028

467,874 TPY

0.0093

0.0044

0.00067

467,874 TPY

0.0093

0.0044

0.00067

467,874 TPY

0.0093

0.0044

0.00067

46,787 TPY

0.00093

0.00044

0.000067

0.035

BAGASSE HANDLING

HOPPER-TO-BAGASSE DISTRIBUTION CONVEYOR

CONTINUOUS DROP

BAGASSE DISTRIBUTION CONVEYOR-TO-METER BINS

CONTINUOUS DROP

BAG. DIS. CONV. OVERFLOW-TO-SURPLUS BAGASSE CONVEYOR


SURPLUS BAGASSE CONVEYOR-TO-BAGASSE STORAGE PILE
FRONT END LOADER (RECLAIM)-TO-RECLAIM CONVEYOR
RECLAIM CONVEYOR-TO-RETURN CONVEYOR

CONTINUOUS DROP

BAGASSE STORAGE PILE

FRONT END LOADER BAGASSE STORAGE PILE MAINTENANCE


BULLDOZER BAGASSE STORAGE PILE MAINTENANCE

6.9

0.000040
0.000040

0.000019
0.000019
0.000019

0.0000028
0.0000028
0.0000028

ENCLOSURE
ENCLOSURE
ENCLOSURE

0
0
0

0.000040
0.000040
0.000040

0.000019
0.000019
0.000019

0.0000028
0.0000028
0.0000028

50

6.9

0.000040

0.000019

0.0000028

ENCLOSURE

0.000040

0.000019

0.0000028

46,787 TPY

0.00093

0.00044

0.000067

BATCH DROP

50

6.9

0.000040

0.000019

0.0000028

NONE

0.000040

0.000019

0.0000028

46,787 TPY

0.00093

0.00044

0.000067

46,787 TPY

0.00093

0.00044

0.000067

46,787 TPY

0.00093

0.00044

0.000067

46,787 TPY

0.00093

0.00044

0.000067

46,787 TPY

0.00093

0.00044

0.000067

--

0.015

0.0076

0.0076

10,950 VMT

0.37

0.044

0.0044

2,190 hr/yr

0.008

0.0005

0.00018

CONTINUOUS DROP

HOPPER-TO-BAGASSE DISTRIBUTION CONVEYOR

50

6.9

0.000040

CONTINUOUS DROP

CONTINUOUS DROP

BAGASSE TRANSFER CONVEYOR-TO-HOPPER

50

6.9

CONTINUOUS DROP

RETURN CONVEYOR-TO-BAGASSE TRANSFER CONVEYOR

50

50
50
50

6.9
6.9
6.9

CONTINUOUS DROP

50

6.9

WIND EROSION

--

--

VEHICULAR TRAFFIC

--

--

VEHICULAR TRAFFIC

--

--

0.000040
0.000040
0.000040
0.000040
-0.27 lb/VMT
0.031 lb/hr

0.000019
0.000019
0.000019
0.000019

0.0000028
0.0000028
0.0000028
0.0000028

-0.032 lb/VMT
0.0018 lb/hr

-0.0032 lb/VMT
0.00067 lb/hr

ENCLOSURE
ENCLOSURE
ENCLOSURE

0
0
0

ENCLOSURE

WATERING

50

PARTIAL ENCLOSURE/WATERING

75

PARTIAL ENCLOSURE/WATERING

75

0.000040
0.000040
0.000040
0.000040
-0.07 lb/VMT
0.008 lb/hr

0.000019
0.000019
0.000019
0.000019
-0.008 lb/VMT
0.00046 lb/hr

0.0000028
0.0000028
0.0000028
0.0000028
-0.0008 lb/VMT
0.00017 lb/hr

WOOD HANDLING
TRUCK DUMP-TO-WOOD STORAGE PILE
UNLOADING CONVEYOR-TO-HOGGER
HOGGER
HOGGER-TO-STORAGE CONVEYOR

BATCH DROP

40

6.9

0.000054

0.000026

0.0000039

NONE

0.000054

0.000026

0.0000039

47,705 TPY

0.0013

0.00061

0.000093

CONTINUOUS DROP

40

6.9

0.000054

0.000026

0.0000039

ENCLOSURE

0.000054

0.000026

0.0000039

47,705 TPY

0.0013

0.00061

0.000093

CRUSHING

--

--

0.020

0.0095

0.0014

ENCLOSED

95

0.0010

0.00047

0.000072

47,705 TPY

0.024

0.011

0.0017

BATCH DROP

40

6.9

0.000054

0.000026

0.0000039

ENCLOSURE

0.000054

0.000026

0.0000039

47,705 TPY

0.0013

0.00061

0.000093

SCREEN-TO-STORAGE CONVEYOR

CONTINUOUS DROP

40

6.9

0.000054

0.000026

0.0000039

ENCLOSURE

0.000054

0.000026

0.0000039

47,705 TPY

0.0013

0.00061

0.000093

STORAGE CONVEYOR-TO-WOOD STORAGE PILE

CONTINUOUS DROP

40

6.9

0.000054

0.000026

0.0000039

ENCLOSURE

0.000054

0.000026

0.0000039

47,705 TPY

0.0013

0.00061

0.000093

BATCH DROP

40

6.9

0.000054

0.000026

0.0000039

NONE

0.000054

0.000026

0.0000039

47,705 TPY

0.0013

0.00061

0.000093

RECLAIM CONVEYOR-TO-RETURN CONVEYOR

CONTINUOUS DROP

40

6.9

0.000054

0.000026

0.0000039

ENCLOSURE

0.000054

0.000026

0.0000039

47,705 TPY

0.0013

0.00061

0.000093

RETURN CONVEYOR-TO-HOPPER

CONTINUOUS DROP

40

6.9

0.000054

0.000026

0.0000039

ENCLOSURE

0.000054

0.000026

0.0000039

47,705 TPY

0.0013

0.00061

0.000093

HOPPER-TO-HORIZONTAL DISCHARGE CONVEYOR


WOOD STORAGE PILEf

CONTINUOUS DROP

40

6.9

0.000054

0.000026

0.0000039

ENCLOSURE

0.000054

0.000026

0.0000039

47,705 TPY

0.0013

0.00061

0.000093

WIND EROSION

--

--

WATERING

50

VEHICULAR TRAFFIC

--

--

3.52 lb/VMT

0.86 lb/VMT

0.086 lb/VMT

PARTIAL ENCLOSURE/WATERING

75

0.88 lb/VMT

0.21 lb/VMT

VEHICULAR TRAFFIC

--

--

3.32 lb/hr

0.61 lb/hr

0.073 lb/hr

PARTIAL ENCLOSURE/WATERING

75

0.83 lb/hr

0.15 lb/hr

ASH DROP TO DRAG CONVEYOR 1

CONTINUOUS DROP

10

6.9

0.000378

0.000179

0.0000271

ENCLOSURE

0.000378

0.000179

0.0000271

21,634 TPY

DRAG CONVEYOR 1 TO DRAG CONVEYOR 2

CONTINUOUS DROP

10

6.9

0.000378

0.000179

0.0000271

ENCLOSURE

0.000378

0.000179

0.0000271

21,634 TPY

DRAG CONVEYOR 2 TO DRAG CONVEYOR 3

CONTINUOUS DROP

10

6.9

0.000378

0.000179

0.0000271

ENCLOSURE

0.000378

0.000179

0.0000271

DRAG CONVEYOR 3 TO ASH SILO

CONTINUOUS DROP

10

6.9

0.000378

0.000179

0.0000271

ENCLOSURE

0.000378

0.000179

0.0000271

FRONT END LOADER (RECLAIM)-TO-RECLAIM CONVEYOR

FRONTEND LOADER WOOD STORAGE PILE MAINTENANCE


BULLDOZER WOOD STORAGE PILE MAINTENANCE

--

--

--

--

--

-0.021 lb/VMT
0.018 lb/hr

--

0.20

0.10

10,950 VMT

4.81

1.18

0.10
0.12

2,190 hr/yr

0.91

0.17

0.020

0.0041

0.0019

0.00029

0.0041

0.0019

0.00029

21,634 TPY

0.0041

0.0019

0.00029

21,634 TPY

0.0041

0.0019

0.00029

21,634 TPY

0.0041

0.0019

0.00029

ASH HANDLING

ASH SILO TO TRUCK


ASH TRUCK TRAFFIC ON PAVED ROADSj

CONTINUOUS DROP

10

6.9

0.000378

0.000179

VEHICULAR TRAFFIC

--

--

0.11 lb/VMT

0.022 lb/VMT

PRODUCT LOAD OUT


ETHANOL TRUCK TRAFFIC ON PAVED ROADSi

VEHICULAR TRAFFIC

--

--

0.13 lb/VMT

DENATURANT/GASOLINE TRUCK TRAFFIC ON PAVED ROADSi

VEHICULAR TRAFFIC

--

--

LIME DELIVERIES
LIME TRUCK TRAFFIC ON PAVED ROADSi

VEHICULAR TRAFFIC

--

--

0.0000271

ENCLOSURE

0.000378

0.000179

0.0000271

0.0054 lb/VMT

WATER/SWEEP

50

0.06 lb/VMT

0.011 lb/VMT

0.0027 lb/VMT

735 VMT

0.020

0.0041

0.0010

0.027 lb/VMT

0.0065 lb/VMT

WATER/SWEEP

50

0.066 lb/VMT

0.013 lb/VMT

0.0033 lb/VMT

1,640 VMT

0.055

0.011

0.0027

0.13 lb/VMT

0.027 lb/VMT

0.0065 lb/VMT

WATER/SWEEP

50

0.066 lb/VMT

0.013 lb/VMT

0.0033 lb/VMT

74 VMT

0.0025

0.00049

0.00012

0.11 lb/VMT

0.022 lb/VMT

0.0054 lb/VMT

WATER/SWEEP

50

0.055 lb/VMT

0.011 lb/VMT

0.0027 lb/VMT

47 VMT

0.00129

0.00026

0.000064

DENATURANT/GASOLINE DELIVERIES

TOTAL
Notes:
Bagasse will be dried to 50% moisture after it is sent through the drying system. Wood moisture content based on sample testing conducted March 2008, New Hope Power Company, LLC.

a
b

Based on the average of hourly windspeed data from Fort Myers International Airport for 2001-2005.

Batch Drop and Continuous Drop Emission Factors are computed from AP-42 (USEPA, 2006) Section 13.2.4: E= k x 0.0032 x (U/5)^1.3 / (M/2)^1.4 lb/ton, where k = 0.74 for PM, 0.35 for PM10, and .053 for PM2.5.

Refer to Table 2-2 for biomass usage, worst-case fugitive is for the 10% wood scenario. Usage rates for bagasse (425,340 TPY) and wood (43,368 TPY), and an additional 10% was added to account for year-to-year variations.

Assuming 10% of biomass is overfeed.

Refer to Table C-1, Appendix C for calculation.

Refer to C-2 in Appendix C.

Refer to Table C-3 in Appendix C.

Refer Table C-4 in Appendix C.

Refer to Table C-4, Appendix C, for emissions calculation. Table 2-25 shows ash generation based on sugarcane bagasse at 1.5% ash, sorghum bagasse at 2.7% ash, wood at 9% ash.
Emission factor reference: AP-42 (USEPA, 2004) Section 11.19.2. PM 2.5 assumed to be equal to PM10.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-16 C1-C5.xlsx

7.9

1.8

0.33

May 2011

103-87668

Table 2-17: Physical, Performance, and Emissions Data for the Cooling Tower
Parameter
Physical Data
Number of Cells
Deck Dimensions (ft)
Length
Width
Height
Stack Dimensions
Height (ft)
Stack Top Effective Inner Diameter per cell (ft)
Effective Diameter, all cells (ft)
Performance Data
Circulating Water Flow Rate (CWFR) (gal/min)
Design Wet Bulb Temperature (F)
Design Cold Water Temperature (F)
Heat Rejected (MMBtu/hr)
Design Air Flow Rate per cell (acfm)
Hours of Operation

Typical Valuesa

Basis

CAD Drawing

80
40
30

CAD Drawing
CAD Drawing
Estimated

35
33
33.0

Estimated
Estimated
Estimated

34,000
77

Fagen

272.22
211,860
8,760

Fagen

Emission Data
Drift Rateb (DR) (percent)

0.0010

Fagen

Total Dissolved Solids (TDS) Concentration, maximum (ppm)c

500

Estimated

Solution Driftd (SD) (lb/hr)

170

Calculated

PM Drifte (lb/hr)
(TPY)

0.0851
0.373

PM10 Drift
PM10 Portion (percent) of PM Drift
PM10 Emissions (lb/hr)
(TPY)

50

Estimated

0.0425
0.186

PM2.5 Drift
PM2.5 Portion (percent) of PM Drift
PM2.5 Emissions (lb/hr)
(TPY)

50

Estimated

0.0425
0.186

Footnotes:
a

Typical cooling tower design for indicated conditions.

Drift rate is the percent of circulating water.

TDS estimated based on typical TDS value for freshwater in the vicinity of the proposed project.

Includes water and based on circulating water flow rate and drift rate (CWFR x DR x 8.34 lb/gal x 60 min/hr).

PM calculated based on total dissolved solids and solution drift (TDS x SD).

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-17 Cooling Tower.xlsx

May 2011

103-87668

Table 2-18: Physical, Performance, and Emissions Data for the Truck/Rail Loading Rack Flare
Parameter

Values

Basis

30
1

Estimated
Estimated

Physical Data
Dimensions (ft)
Stack Height
Stack Diameter
Performance Data
3

Hourly Ethanol/Blends Throughput (10 gallons/hr)


3

Annual Ethanol/Blends Throughput (10 gallons/yr)


Flare Pilot Heat Rate (MMBtu/hr)
Flare Control Efficiency (%)
Flare Pilot Hours of Operation (hr/yr)
Flare Hours of Operation (hr/yr)
VOC Loading Emission Factor Calculation
Saturation Factor (unitless)
Molecular Weight of Vapors (lb/lb-mol)
Product Temperature (R)
True Vapor Pressure (psia)
3

VOC Loading Loss - Total (lb/10 gal)

36

600 gpm, truck or railcar filling

37,620,000
0.184
98.0
8,760
3,120

Highlands Envirofuels, LLC


based on 3 scfm natural gas
Estimated
Maximum
Maximum

1
64
534.3

AP-42 Table 5.2-1


TANKS 4.0.9d
TANKS 4.0.9d

8.63

TANKS 4.0.9d (Based on


gasoline RVP of 12)

12.9

Flare Heat Input Calculation


Gasoline Heat Content (Btu/gal)
Gasoline Density (lb/gal)
Gasoline Heat Content (Btu/lb)

130,000
6.17
21,070

AP-42 Appendix A
AP-42 Appendix A
displaced truck gasoline vapors

9.8

Calculated

Flare Heat Input Rate (MMBtu/hr)b


VOC Loading Emission Calculation
Uncontrolled VOCs
Controlled VOCs

lb/hr
463.66
9.27

TPY
242.3
4.85

Flare Combustion Emission Factors


SO2 (lb/MMBtu)c

0.00059

AP-42 Table 1.4-2

NOx (lb/MMBtu)d

0.068

AP-42 Table 13.5-1

CO (lb/MMBtu)d

0.37
0.0034

AP-42 Table 13.5-1


AP-42 Table 13.5-1

0.14

AP-42 Table 13.5-1

PM/PM10/PM2.5 (lb/MMBtu)d
VOCs - Total Hydrocarbons (lb/MMBtu)e
Emissions Calculations
SO2 (lb/MMBtu)
NOx (lb/MMBtu)
CO (lb/MMBtu)
PM/PM10/PM2.5 (lb/MMBtu)
VOCs - Total Hydrocarbons (lb/MMBtu)
Loading and Combustion Total VOCs
a

Activity Factor
(MMBtu/hr)
9.8
9.8
9.8

(lb/hr)
0.0057
0.66
3.61

Emissions

9.8
9.8

0.034
1.37

0.052
2.13

--

10.64

6.98

(TPY)
0.0090
1.04
5.64

The emission factor for VOCs is based on the following equation for loading loss:
VOC Loading Loss (lb/10 3 gal) = 12.46 x Saturation Factor x Vapor Pressure (psia) x Molecular Weight (lb/lb-mol)
/ Temperature (R)

The flare heat input rate is calculated based on the following equation:
Flare Heat Rate (MMBtu/hr) = Hourly Ethanol Throughput (10 3 gallons/hr) x VOC Loading Loss (lb/10 3 gal)
x Gasoline Heat Content (Btu/lb)/10 6

Based on AP-42 Table 1.4-2, 0.6 lb/106 scf for Natural Gas, and 1,020 Btu/scf for natural gas.

AP-42 Table 13.5-1 (Industrial Flares), soot for lightly smoking flares (40 g/L).
Assuming all PM is converted to PM10 and PM2.5.

Assumed all hydrocarbons are VOCs for conservative estimate.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-18, 2-19 Truck Loading Rack Flare.xlsx

May 2011

103-87668

Table 2-19: Truck/Rail Loading Rack Flare HAP Emission Estimates


Total VOC Emissions
Maximum Hourly (lb/hr)
Total Losses (TPY)
Speciated Constituents of
Gasoline VOCsa

10.64
6.98
VOC Emissions
(lb/hr)
(TPY)

CAS Number

% of Total Vapor
Released

71-43-2
106-97-8
590-18-1
624-64-6
627-20-3
110-82-7
287-92-3
75-83-2
108-08-7
74-84-0

1.41
28.53
0.83
1.02
0.67
0.43
0.61
1.04
0.43
0.07

0.150
3.04
0.0883
0.109
0.0713
0.0458
0.0649
0.111
0.0458
0.00745

0.098
1.99
0.058
0.071
0.047
0.030
0.043
0.073
0.030
0.0049

Ethylbenzeneb
Heptane, n-

100-41-4
142-82-5

0.06
0.40

0.00638
0.0426

0.0042
0.028

Hexane, n-b
Isobutane
Isopropyl Benzene
Methylcyclohexane
Methylcyclopentane
Methylheptane, 3Methylhexane, 3Methylpentane, 3Octane, nPentane, nPentene, 1Propane

110-54-3
75-28-5
98-82-8
108-87-2
96-37-7
589-81-1
589-34-4
96-14-0
111-65-9
109-66-0
109-67-1
74-98-6

3.75
8.34
0.01
0.12
1.41
0.06
0.42
1.99
0.03
7.25
0.86
1.06

0.399
0.887
0.00106
0.0128
0.150
0.00638
0.0447
0.212
0.00319
0.771
0.0915
0.113

0.26
0.58
0.00070
0.0084
0.098
0.0042
0.029
0.139
0.0021
0.51
0.060
0.074

Tolueneb
Trans-2-Pentene
Trimethylbenzene, 1,2,4Trimethylbenzene, 1,3,5-

108-88-3
646-04-8
95-63-6
108-67-8

1.25
1.37
0.05
0.02

0.133
0.146
0.00532
0.00213

0.087
0.096
0.0035
0.00140

Trimethylpentane, 2,2,4-b
Trimethylpentane, 2,3,4-

540-84-1
565-75-3

0.42
0.07

0.0447
0.00745

0.029
0.0049

Xylene, o-b
Unidentified VOC

95-47-6
NA

0.04
35.98

0.00426
3.83
10.64
0.34

0.0028
2.51
6.98
0.22

Benzeneb
Butane, nButene, cis-2Butene, trans-2Pentene, cis-2Cyclohexane
Cyclopentane
Dimethylbutane, 2,2Dimethylpentane, 2,4Ethane

Total VOC
Total HAPs

Speciation is based on EPAs SPECIATE 3.2 program for profile No. 2490.

Hazardous Air Pollutant (HAP).

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-18, 2-19 Truck Loading Rack Flare.xlsx

May 2011

103-87668

Table 2-20: Physical, Performance, and Emissions Data for the Emergency Generator
Parameter

Values

Basis

Performance Data
Capacity (hp)
(ekW)

2,682
2,000

Caterpillar
Caterpillar

Fuel: No. 2 Fuel Oil or Natural Gas


Maximum Sulfur Content (%)
Average Heat Input Rate (MMBtu/hr)
(gal/hr)
Hours of Operation (hr/yr)

0.0015
19.45
138.9
500

On-road diesel fuel


Estimated
Calculated
Maximum

Emission Factors
SO2 (lb/MMBtu)

0.00059

for Natural Gas firing

NOx (g/hp-hr)

5.39

CAT

CO (g/hp-hr)a

0.29
0.026

CAT

0.11

CAT

PM/PM10/PM2.5 (g/hp-hr)a
a

VOC (g/hp-hr)

CAT

Emissions Calculations

SO2
NOx
CO
PM/PM10/PM2.5
VOC
a

Activity Factor
19.45 MMBtu/hr
2,682 hp
2,682 hp
2,682 hp
2,682 hp

(lb/hr)
0.011
31.80
1.71
0.15
0.65

Emissionsb

(TPY)
0.0029
7.95
0.43
0.038
0.16

Subpart IIII emission factors are based on a weighted cycle. Manufacturer data, based on 100% load, for
Caterpillar diesel engine (CAT 3516C TA) is considered more representative. Therefore, the manufacturer
emission factors were used.
Example Calculation:
0.29 g/hp-hr CO x 2,682 hp/generator x lb/454.6 g = 1.71 lb/hr CO
1.71 lb/hr CO x 500 hr/yr x 1 ton/2,000 lb = 0.43 TPY CO

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-20 to 2-23 Emergency Equip.xlsx

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Table 2-21: HAPs Emission Estimates for the Emergency Generator

Pollutant

Activity Factor

Emission Factor
(lb/MMBtu) a

(MMBtu/hr)

2.52E-05
7.88E-06
7.76E-04
7.89E-05
2.79E-03
1.30E-04
2.81E-04
1.93E-04

19.45
19.45
19.45
19.45
19.45
19.45
19.45
19.45

Acetaldehyde
Acrolein
Benzene
Formaldehyde
Propylene
Naphthalene
Toluene
Xylene

(MMBtu/yr)

9,725
9,725
9,725
9,725
9,725
9,725
9,725
9,725
TOTAL HAP

Based on information provided in EPA's AP-42, Tables 3.4-3 and 3.4-4.

Based on 500 hr/yr.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-20 to 2-23 Emergency Equip.xlsx

Total Emissions
(lb/hr)

(TPY)

4.90E-04
1.53E-04
1.51E-02
1.53E-03
5.43E-02
2.53E-03
5.47E-03
3.75E-03
0.083

1.23E-04
3.83E-05
3.77E-03
3.84E-04
1.36E-02
6.32E-04
1.37E-03
9.38E-04
0.021

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Table 2-22: Physical, Performance, and Emissions Data for the Emergency Fire Pump Engine
Parameter
Performance Data
Capacity (hp)
(eKw)
Fuel: No. 2 Fuel Oil or Natural Gas
Maximum Sulfur Content (%)
Average Heat Input Rate (MMBtu/hr)
Hours of Operation (hr/yr)
Emission Factors
SO2 (lb/MMBtu)

Values

Basis

600
448

Caterpillar
Caterpillar

0.0015

On-road diesel fuel

4.3
500

Calculated
Maximum

0.00059

for Natural Gas firing

NOx (g/Kw-hr)
CO (g/Kw-hr)
PM/PM10/PM2.5 (g/Kw-hr)

3.60
3.50
0.20

Subpart IIII, Table 4


Subpart IIII, Table 4

VOC (g/Kw-hr)b

0.40

Subpart IIII, Table 4

Subpart IIII, Table 4

Emissions Calculations

SO2
NOx
CO
PM/PM10/PM2.5
VOC

Activity Factor
4.3 MMBtu/hr
448 kW
448 kW
448 kW
448 kW

(lb/hr)
0.0025
3.55
3.45
0.20
0.39

Emissionsc

(TPY)
0.0006
0.89
0.86
0.049
0.10

Based on 31.4 gal/hr diesel and 136,000 Btu/gal.

Based on Subpart IIII emission limit for NOx + NMHC of 4.0 g/Kw-hr. Assuming 90% is NOx, and 10% is VOCs.

Example Calculation:
3.5 g/Kw-hr CO x 448 Kw x lb/454.6 g = 3.45 lb/hr CO
3.45 lb/hr CO x 500 hr/yr x 1 ton/2,000 lb = 0.86 TPY CO

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-20 to 2-23 Emergency Equip.xlsx

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Table 2-23: Fire Pump HAPs Emission Estimates

Pollutant
Acetaldehyde
Acenaphthylene
Acrolein
Anthracene
Benzene
Benzo(a)anthracene
Benzo(a)pyrene
1,3-Butadiene
Chrysene
Fluoranthene
Formaldehyde
Indeno(1,2,3-cd)pyrene
Phenanthrene
Propylene
Naphthalene
Toluene
Xylene

Emission
Factor
(lb/MMBtu) a

(MMBtu/hr)

7.67E-04
1.42E-06
9.25E-05
1.87E-06
9.33E-04
1.68E-06
1.88E-07
3.91E-05
3.53E-07
7.61E-06
1.18E-03
3.75E-07
2.94E-05
2.58E-03
8.48E-05
4.09E-04
2.85E-04

4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3

Activity Factor

Based on information provided in EPA's AP-42, Table 3.3-2.

Based on 500 hr/yr.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-20 to 2-23 Emergency Equip.xlsx

(MMBtu/yr)b
2,135
2,135
2,135
2,135
2,135
2,135
2,135
2,135
2,135
2,135
2,135
2,135
2,135
2,135
2,135
2,135
2,135
TOTAL HAP

Emissions
(lb/hr)

(TPY)

3.28E-03
6.06E-06
3.95E-04
7.99E-06
3.98E-03
7.17E-06
8.03E-07
1.67E-04
1.51E-06
3.25E-05
5.04E-03
1.60E-06
1.26E-04
1.10E-02
3.62E-04
1.75E-03
1.22E-03
0.027

8.19E-04
1.52E-06
9.88E-05
2.00E-06
9.96E-04
1.79E-06
2.01E-07
4.17E-05
3.77E-07
8.12E-06
1.26E-03
4.00E-07
3.14E-05
2.75E-03
9.05E-05
4.37E-04
3.04E-04
0.0068

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Table 2-24. Summary of Particulate Emissions from Silo Bagfilters

Emission Source

Loading Rate
(TPH)
(TPY)

Ash Silo

--

--

Lime Silo (Wastewater Treatment)

25

500

Lime Silo (Dry Sorbent Injection)

219

880

Bin Vent Filter


Gas Flow
Rate

Emission Rate

8,040

2,458 scfm

0.01 gr/dscf

0.21

0.847

20

2,458 scfm

0.01 gr/dscf

0.21

0.002

4.0

2,458 scfm

0.01 gr/dscf

0.21

0.00042

0.63

0.849

Loading Time
(hr/yr)
a

Total Particulate Emissions =


a

Based on 52 lb/hr of lime to the boiler and 8,040 hr/yr for boiler operation.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-24 Material Silos.xlsx

PM/PM10/PM2.5
Hourly
Annual
Emissions
Emissions
(lb/hr)
(TPY)

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Table 2-25. Estimation of Truck Traffic


Maximum Heat Input
from Biomass a
(MMBtu/yr)

Fuel
Sugarcane Bagasse
Sorghum Bagasse
Wood
TRUCK TRAFFIC

1,843,140
1,843,140
368,628
Activity Factor

Trucks/yearb

Sugarcane

Annual Sugarcane Harvested

750,000 TPY

30,000

750,000 TPY

30,000

Wood
Annual Wood Deliveries

43,368 TPY

1,735

Ashc
Annual Ash Generation

13,828 TPY

553

36,000,000 Gallons/yr

4,000

1,620,000 Gallons/yr

180

1,380 TPY

55

Sorghuma
Annual Sorghum Harvested
a

Ethanol
Annual Final Product
Denaturant/Gasoline Deliveries
Annual Denaturant/Gasoline
Limed
Annual Lime Deliveries
a

Refer to Table 2-2.

Based on 25 tons per truck load capacity or 9,000 gallons per truck.

Total future ash is based on 9% ash in wood, 1.5% ash in sugarcane bagasse, and 2.7% ash
in sorghum bagasse. Worst case is therefore burning 30% wood with remainder bagasse.
d
Total includes dry sorbent injection reagent and wastewater treatment lime (see Table 2-24).

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-25 Truck traffic.xlsx

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Table 2-26: VOC Emission Estimates for Fugitive Equipment Leaks, HEF Ethanol Process

Uncontrolled Emissionsd

Control
Efficiency

Controlled Emissionsd

Emission Factors

Weighted Average

(kg/hr/source)a

VOC Content (%)b

(lb/hr)

(TPY)

(%)c

(lb/hr)

(TPY)

Component Type

Service

Component
Count

Valves

Gas/Vapor

25

0.00597

100

0.33

1.44

87

0.043

0.187

Valves

Light Liquid

200

0.00403

96

1.70

7.46

84

0.272

1.193

Valves

Heavy Liquid

100

0.00023

0.0025

0.0111

0.0025

0.0111

Sealless Valves

Light Liquid

200

4.90E-07

96

0.00021

0.00091

84

0.00003

0.00015

Sealless Valves

Heavy Liquid

100

Pump Seals

Light Liquid

0.0199

96

69

Pump Seals

Heavy Liquid

0.00862

Pump Seals, Dual Mech.

Light Liquid

50

0.0199

96

2.101

9.204

69

0.651

2.853

Pump Seals, Dual Mech.

Heavy Liquid

10

0.00862

Agitator Seals

Light Liquid

10

0.0199

96

0.42

1.84

69

0.13

0.57

Agitator Seals

Heavy Liquid

10

0.00862

0.0095

0.0415

0.009

0.042

Compressor Seals

Gas/Vapor

0.228

100

Pressure Relief Valves

Gas/Vapor

0.104

100

Connectors

All

1250

0.00183

30

1.51

6.61

93

0.11

0.46

Open-Ended Lines

All

60

0.0017

30

0.067

0.295

0.067

0.295

Sampling Connections

All

20

0.015

30

0.20

0.87

0.198

0.867

6.35

27.81

Total VOCs

1.49

6.52

Total HAPse

0.074

0.33

Emission factors are based on Protocol for Equipment Leak Emission Estimates , EPA-453/R-95-017, November 1995. Table 2-1 for SOCMI Average Emission
Factors, or Table 2-11 for Default-Zero Values.

For components in heavy liquid service, weighted average VOC content estimated at 5 perecent.
For components in light liquid service, weighted average VOC content estimated at 96 percent.
For components in liquid service, weighted average VOC content estimated at 30 perecent.

Control Efficiency for LDAR program for each component is based on Table 5-2 of Protocol for Equipment Leak Emission Estimates , EPA-453/R-95-017, November 1995.

Emissions were calculated assuming 8,760 hours of operation. Example Calculations are shown below:
Uncontrolled for Gas/Vapor Valve:
Short term emissions - 25 sources x 0.00597 kg/hr/source x 2.2 lb/kg x (% VOC content / 100)= 0.33 lb/hr
Annual - 0.33 lb/hr x 8,760 hr/yr / 2,000 lb/ton = 1.44 TPY
Controlled for Gas/Vapor Valve:
Short term emissions - 0.33 lb/hr x (1-(87/100)) = 0.043 lb/hr
Annual - 0.043 lb/hr x 8,760 hr/yr / 2,000 lb/ton = 0.19 TPY

HAP emissions are conservatively estimated to be 5% of VOC emissions.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-26 Fug VOC Equip Leaks.xlsx

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Table 2-27: Emission Summary, Highlands EnviroFuels


Source
Description

Pollutant Emission Rate (TPY)


SO2

NOx

CO

PM

PM10

PM2.5

VOC

TRS

SAM

Mercury

Lead

Fluoride

Non-Biogenic CO2eb

200.4
---0.0090
--0.0057
0.00063
--

184.3
---1.04
--7.95
0.89
--

552.9
---5.64
--0.43
0.86
--

27.6
14.2
-0.37
0.052
--0.038
0.049
0.85

27.6
3.4
-0.19
0.052
--0.038
0.049
0.85

18.0
0.7
-0.19
0.052
--0.038
0.049
0.85

31.3
-79.5
-2.13
3.9
6.5
0.16
0.10
--

-----------

9.8
----------

0.025
----------

0.18
----------

1.1
----------

8,023.0
---2,429.0
------

200.4

194.2

559.8

43.2

32.2

19.8

123.6

--

9.8

0.0

0.2

1.1

10,452.0

Future Potential Emissions From Affected Sources a


Biomass Boiler
Boiler Materials Handling, Storage, and Truck Traffic
Ethanol Process
Cooling Tower
Truck Load Out Flare
Facility Tanks
Facility Fugitive Equipment Leaks
Emergency Generator
Emergency Fire Pump Engine
Ash and Lime/Limestone Silos
TOTAL PROPOSED PROJECT EMISSIONS
a
b

Refer to Tables 2-4 through 2-29, Appendix C and Appendix D for emission calculations.
Greenhouse gases expressed as non-biogenic CO2 equivalents, see Table 2-28.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-27, 2-28 Emissions sum.xlsx

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Table 2-28: Total Facility Potential HAPs Emissions


HAP Emission Ratea
(lb/hr)
(TPY)

Source
Description
Biomass Boiler
Ethanol Process
Truck Load Out Flare
Facility Tanks
Facility Fugitive Equipment Leaks
Emergency Generator
Emergency Fire Pump Engine

TOTAL

55.3
1.05
0.34
0.024
0.074
0.083
0.027
56.9

18.3
3.85
0.22
0.094
0.33
0.021
0.0068
22.8

Refer to Tables 2-4 through 2-29, Appendix C, and Appendix D for emission calculations.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-27, 2-28 Emissions sum.xlsx

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Table 2-29. Potential Direct GHG Emissions, Highlands EnviroFuels


Potential Annual GHG Emissions
CO2
Allowable
E.U.

Fuel Heating value

Fuels

Operation

Fuel Use

Factor

Emissions
a

(kg/MMBtu)

(hrs)

N2O
Emissions

Factor
a

(kg/MMBtu)

(tons)

CH4

(tons)

Emissions

Factor

CO2e tons

(kg/MMBtu)

(tons)

CO2e tons

Total CO2
Equivalent

Non-Biogenic
h
CO2 Equivalent

(tons)

(tons)

Biomass Boiler
Bagasse Only Scenario

Sugarcane Bagasse
Sorghum Bagasse

3,900 Btu/lb, wet


3,900 Btu/lb, wet

4,020
4,020

236,300 TPY, wet


236,300 TPY, wet

NA
NA
Subtotal

10% Wood Scenario

Sugarcane Bagasse

3,900 Btu/lb, wet

2,814

212,670 TPY, wet

NA

199,280

203,291

4,011

17.1

5,291

130.1

2,731

406,582

8,023

7.68

2,381

3.20E-02

58.5

1,229

182,962

3,610

3.20E-02

58.5

1,229

182,962

3,610

3.20E-02

13.0

273

37,376

802

130.1

2,731

403,300

8,023

5,291

5.63

1,744

3.20E-02

42.9

900

134,026

2,645

3.20E-02

42.9

900

134,026

2,645

1.00E-03

1.15

24

76,617

60

36,574

1,021 MMscf/yr

1,366

17.1

93.80

2,412

65.0

43,368 TPY, wet

0.00102 MMBtu/scf

3.20E-02

529

2,412

Natural Gas

4,011

2,646

1.71

4,250 Btu/lb, wet

155,788 TPY, wet

203,291

8.53

4.20E-03

Wood

2,814

2,381

179,352

3,900 Btu/lb, wet

1,366

7.68

NA

Sorghum Bagasse

65.0

4.20E-03

212,670 TPY, wet

155,788 TPY, wet

3.20E-02

2,814

2,814

3,900 Btu/lb, wet

3,900 Btu/lb, wet

4.20E-03

2,646

8.53

179,352

Sorghum Bagasse

Sugarcane Bagasse

4.20E-03

398,559

Subtotal
30% Natural Gas Scenario

199,280

4.20E-03

395,277
131,381

NA

131,381

4.20E-03

5.63

1,744

66.83

76,558

1.00E-04

0.11

36

NA

4.20E-03

Subtotal

339,320

11.4

3,524

86.9

1,825

344,669

5,349

Worst-Case Subtotal Boiler =

398,559

17.1

5,291

130.1

2,731

406,582

8,023

0.020

6.3

3.00E-03

0.10

2.1

2,310

2,310

0.00018
0.020

0.1
6.3

1.00E-03

0.0018
0.10

0.04
2.2

119
2,429

119
2,429

NA
NA

NA
NA

NA
NA

NA
NA

122,096
2,880
124,976

0
0
0

17

5,298

130

2,733

533,987

10,451

Flares
Truck Loadout - flaring
Truck Loadout - pilot

Ethanol/Gasoline
Natural Gas

0.130 MMBtu/gal
0.00102 MMBtu/scf

3,120
8,760

9.8 MMBtu/hr
0.184 MMBtu/hr

68.44
66.83
Subtotal Flares =

2,302

118
2,420

6.00E-04
1.00E-04

CO2 g
Ethanol Process CO2 Scrubbing Columns
Fermentation
Distillation

Vapors
Vapors

---

7,296
7,296

lb/hr
33,469
790
Subtotal Ethanol Process =
Totals

tons
122,096
2,880
124,976

NA
NA

525,956

Note: tonnes = metric tons.


a
b

Emission factors based on default values found in tables C-1 and C-2 of 40 CFR 98 Subpart C.
N2O is multiplied by a factor of 310 to determine CO 2 equivalence.

CH4 is multiplied by a factor of 21 to determine CO 2 equivalence.

CO2 emissions from biomass based on fuel carbon content and annual fuel usage to estimate CO 2 emissions (Equation C-3 of 40 CFR 98 Subpart C).
Biomass: CO2 (tons) = (44/12) x Fuel Use (short tons) x Carbon Content (percent by weight, expressed as a decimal fraction) x 0.91.
Carbon content of 23.0 % (at 50% moisture) for bagasse.

Emissions based on fuel use, site specific fuel heat content, and default emission factor. Example calculation:
Emissions (tons) = Fuel Use (short tons) x HHV (average of fuel high heat value) x EF (Default emission factor for CH 4 or N2O from 40 CFR 98, Table C-2) x 0.001 (tonnes/kg)

Emissions based on: fuel use x emission factor x hours of operation.

CO2 emissions based on design data.

CO2 emissions are excluded from biomass combustion.

x (2205 lb/tonne / 2000 lb/ton).

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-29 GHG Emissions.xlsx

NA
NA

May 2011

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Table 2-30: Stack Parameters for Project Sources


Physical Data
Height

Diameter
(ft)
(m)

Temperature
(F)
(K)

Operating Data
Flow Rate
(acfm)

Velocity
(ft/s)
(m/s)

Project Source

(ft)

(m)

Biomass Boiler

150

45.72

14

4.3

340

444

204,080

22.1

6.7

Cooling Tower 1 - Machine

35

10.7

33

10.1

77

298

211,860

4.1

1.3

--

5.2

1.6

Truck Load Out Flare

30

9.1

1.0

0.3

1,832

1,273

Ash Silo

35

10.7

1.5

0.5

77

298

--

23.6

7.2

Lime Silo 1

35

10.7

1.5

0.5

77

298

--

23.6

7.2

Lime Silo 2
CO2 Scrubber

35

10.7

1.5

0.5

77

298

--

23.6

7.2

--

--

--

--

--

--

4,566

--

--

Distillation Vent Scrubber

--

--

--

--

--

--

120

--

--

Default temperature used in AERMOD for flare modeling.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\2\Table 2-30 Stack parameters.xlsx

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TABLE 3-1
3
NATIONAL AND STATE AAQS, ALLOWABLE PSD INCREMENTS, AND SIGNIFICANT IMPACT LEVELS (g/m )

Pollutant
c
Particulate Matter
PM10

National AAQS
Primary
Secondary
Standard
Standard

Averaging Time

Florida
a
AAQS

PSD Increments

Significant
b
Impact Levels

Class I

Class II

Class I

Class II

Annual Arithmetic Mean


24-Hour Maximum

50
150

50
150

50
150

4
8

17
30

0.2
0.3

1
5

Annual Arithmetic Mean


24-Hour Maximum

15
35

15
35

NA
NA

NA
NA

4
9

0.06
0.07

0.3
1.2

Annual Arithmetic Mean


24-Hour Maximum
3-Hour Maximum

NA
NA
NA

1-Hour Maximumd

196

NA
NA
1,300
NA

60
260
1,300
NA

2
5
25
NA

20
91
512
NA

0.1
0.2
1.0
NA

1
5
25
h
7.9

Carbon Monoxide

8-Hour Maximum
1-Hour Maximum

10,000
40,000

10,000
40,000

10,000
40,000

NA
NA

NA
NA

NA
NA

500
2,000

Nitrogen Dioxide

Annual Arithmetic Mean


e
1-Hour Maximum

100
188

100
NA

100
NA

2.5
NA

25
NA

0.1
NA

1
h
7.6

Ozone

1-Hour Maximum
g
8-Hour Maximum

235
147

235
147

235
NA

NA
NA

NA
NA

NA
NA

NA
NA

Lead

Calendar Quarter
Arithmetic Mean
3-Month Average

1.5

1.5

1.5

NA

NA

NA

NA

0.15

0.15

NA

NA

NA

NA

NA

PM2.5

Sulfur Dioxide

Note:

NA = Not applicable, i.e., no standard exists.


Particulate matter (PM10) = particulate matter with aerodynamic diameter less than or equal to 10 micrometers.
Particulate matter (PM2.5) = particulate matter with aerodynamic diameter less than or equal to 2.5 micrometers.
a
Short-term maximum concentrations are not to be exceeded more than once per year, except for PM10 and O3 AAQS, which are based on expected exceedances.
b
Maximum concentrations are not to be exceeded.
c
On October 17, 2006, EPA promulgated revised PM10 and PM2.5 AAQS. The PM2.5 AAQS had been promulgated on July 18, 1997. For PM10, the annual standard was revoked and the 24hour standard was retained. The 24-hour PM2.5 standard was revised to 35 g/m3 based on the 3-year averages of the 98th percentile values. The annual PM2.5 standard of 15 g/m3, based
on 3-year averages at community monitors, was retained. FDEP has not yet adopted the revised standards, which must be implemented in the 2009-2010 timeframe.
d
The 1-hour SO2 standard is met when the 3-year average of the 99th percentile of the daily 1-hour maximum values is less than 196 g/m3.
e
The 1-hour NO2 standard is met when the 3-year average of the 98th percentile of the daily 1-hour maximum values is less than 188 g/m3.
f
On March 27, 2008, EPA promulgated revised AAQS for ozone. The O3 standard was modified to be 0.075 ppm (147 g/m3) for the 8-hour average; achieved when the 3-year average of 99th
percentile values is 0.075 ppm or less. FDEP has not yet adopted the revised standards.
g
0.12 ppm; achieved when the expected number of days per year with concentrations above the standard is fewer than 1.
h
For NO2 and SO2 1-hour averaging periods, an interim Class II significant impact level is shown.
Sources: 40 CFR 50; 40 CFR 52.21, Florida Chapter 62.204, F.A.C.
C:\Users\nvaseen\AppData\Local\Microsoft\Windows\Temporary Internet Files\Content.Outlook\9V2HNS7H\Table 3-1.docx

May 2011

103-87668
TABLE 3-2
PSD SIGNIFICANT EMISSION RATES AND DE MINIMIS MONITORING
CONCENTRATIONS

Pollutant
Sulfur Dioxide
Particulate Matter [PM(TSP)]
Particulate Matter (PM10)
Particulate Matter (PM2.5)

Nitrogen Dioxide
Carbon Monoxide
Volatile Organic
Compounds (Ozone)
Lead
Sulfuric Acid Mist
Total Fluorides
Total Reduced Sulfur
Reduced Sulfur Compounds
Hydrogen Sulfide
Mercury
MWC Organics (dioxin/furan)
MWC Metals (as PM)
MWC Acid Gases (SO2+HCl)
MSW Landfill Gases (as NMOC)
Greenhouse Gases (as CO2e)

Significant
Emission
Rate
(TPY)

De Minimis
Monitoring
Concentrationa
(g/m3)

40
25
15
10, or
40 of SO2,
or
40 of NOx

13, 24-hour
NA
10, 24-hour
NA

14, annual

40
100

575, 8-hour

40
0.6
7
3
10
10
10
0.1
3.5x10-6
15
40
50
75,000

100 TPYb
0.1, 3-month
NM
0.25, 24-hour
10, 1-hour
10, 1-hour
0.2, 1-hour
0.25, 24-hour
NM
NM
NM
NM
NA

Note: Ambient monitoring requirements for any pollutant may be exempted if the impact of the
increase in emissions is less than de minimis monitoring concentrations.
Note:

NA =
NM =
3

g/m =
MWC =
MSW =
NMOC =
CO2e =
a
b

Not applicable.
No ambient measurement method established; therefore, no de minimis
concentration has been established.
micrograms per cubic meter.
Municipal waste combustor.
Municipal solid waste.
Non-methane organic compounds
Carbon dioxide equivalents

Short-term concentrations are not to be exceeded.


No de minimis concentration; an increase in VOC emissions of 100 TPY or more will require a
monitoring analysis for ozone.

Sources:

40 CFR 52.21.
Rule 62-212.400, F.A.C.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\3\Table

3-2.docx

May 2011

103-87668

Table 3-3: PSD Applicability Analysis


Source

Pollutant Emission Rate (TPY)


SO2

NOx

CO

PM

PM10

PM2.5

VOC

TRS

SAM

Mercury

Lead

Fluoride

Non-Biogenic CO2eb

Biomass Boiler
Boiler Materials Handling, Storage, and Truck Traffic
Ethanol Process
Cooling Tower
Truck Load Out Flare
Facility Tanks
Facility Fugitive Equipment Leaks
Emergency Generator
Emergency Fire Pump Engine
Ash and Lime/Limestone Silos

200.4
---0.0090
--0.0057
0.00063
--

184.3
---1.04
--7.95
0.89
--

552.9
---5.64
--0.43
0.86
--

27.6
7.9
-0.37
0.052
--0.038
0.049
0.85

27.6
1.8
-0.19
0.052
--0.038
0.049
0.85

18.0
0.3
-0.19
0.052
--0.038
0.049
0.85

31.3
-79.5
-2.13
3.9
6.5
0.16
0.10
--

-----------

9.8
----------

0.025
----------

0.18
----------

1.1
----------

8,023.0
---2,429.0
------

Total Potential Emission Rates


TOTAL CHANGE DUE TO PROPOSED PROJECT

200.4

194.2

559.8

36.9

30.6

19.5

123.6

0.0

9.8

0.025

0.2

1.1

10,452.0

40

40

100

25

15

10

40

10

0.10

0.6

100,000

Yes

Yes

Yes

Yes

Yes

Yes

Yes

No

Yes

No

No

No

No

Description
Future Potential Emissions From Affected Sources a

PSD SIGNIFICANT EMISSION RATE

PSD REVIEW TRIGGERED?

a
b

Refer to Table 2-27.


Greenhouse gases expressed as non-biogenic CO2 equivalents, see Table 2-29.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\3\Table 3-3.xlsx

May 2011

103-87668
Table 4-1
Maximum Predicted Impacts for HEF Project Only
Compared to EPA De Minimis Concentration Levels
De Minimis

Pollutant

Averaging
Time

Maximum Concentration
(g/m3)

Concentration
(g/m3)

SO2

24-Hour

8.1

13

NO2

Annual

0.6

14

CO

8-Hour

297.0

575

PM2.5

24-Hour

23.4

PM10

24-Hour

33.7

10

O3

NA

123.6a

100a

Values shown are for VOCs, in TPY. No de minimis concentration for ozone. An increase
in emissions of 100 TPY or more requires a monitoring analysis for ozone.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\4\Table 4-1.xlsx

May 2011

103-87668
Table 4-2: Summary of Measured PM10/PM2.5 Concentrations for Monitors near HEF, 2008 to 2010

Distance
to HEF
(km)

Measurement Period
Year
Months

Highest
NA

150 g/m

NA

NA

50 g/m

Jan-Dec
Jan-Dec
Jan-Dec

74
40
64

60
39
59

NA
NA
NA

NA
NA
NA

20.0
18.4
18.8

Jan-Dec
Jan-Dec
Jan-Dec

65
44
62

52
41
47

NA
NA
NA

NA
NA
NA

19.0
17.8
16.0

NA

NA

NA

35 g/m

15 g/m

Jan-Dec
Jan-Dec
Jan-Dec

29.1
19.9
15.0

19.0
18.6
13.9

17.1
13.8
12.0

18.0
16.4
14.7

6.53
6.05
6.35

2008
2009
2010

Jan-Dec
Jan-Dec
Jan-Dec

20.2
20.4
18.3

19.0
19.6
15.8

16.1
17.2
14.6

20.9
20.2
16.2

8.58
7.62
8.14

111

2008
2009
2010

Jan-Dec
Jan-Dec
Jan-Dec

19.4
20.2
15.7

17.2
13.4
15.5

17.6
13.4
15.3

18.1
16.5
15.3

8.66
7.24
7.71

85

2008
2009
2010

Jan-Dec
Jan-Dec
Jan-Dec

20.2
17.2
21.5

16.2
15.7
14.0

16.2
13.0
12.8

17.4
14.6
12.9

7.44
6.52
6.97

Location

PM10 a

Florida AAQS:

12-115-1006

Sarasota

114

2008
2009
2010

12-115-2006

Mulberry

97

2008
2009
2010

PM2.5 a

Florida AAQS:

12-099-0008

Belle Glade

86

2008
2009
2010

12-057-3002

Plant City

121

12-105-6006

Lakeland

12-071-0005

Fort Myers Beach

NA = not applicable.
AAQS = ambient air quality standard.

On October 17, 2006, EPA promulgated revised PM 10 and PM2.5 AAQS. The PM2.5 AAQS had been promulgated on July 18, 1997. For PM 10,

the annual standard was revoked and the 24-hour standard was retained. The 24-hour PM 2.5 standard was revised to 35 g/m 3 based on the
3-year averages of the 98th percentile values. The annual PM 2.5 standard of 15 g/m 3, based on 3-year averages at community monitors,
was retained. FDEP has not yet adopted the revised standards.
Source: State of Florida Air Quality Quicklook Reports 2008-2010.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\4\Table 4-2 - 4-5.xlsx

Annual

2nd
Highest

Site No.

Note:

Concentration (g/m3)
24-Hour
98th
3 Year Avg. 98th
Percentile
Percentile

Average

May 2011

103-87668

Table 4-3: Summary of Maximum Measured SO2 Concentrations near HEF, 2008 to 2010
3

Site No.

Location

Distance
to HEF
(km)

Measurement Period
Year
Months

Concentration (g/m )
3-Hour
3 Year Avg. 99th
2nd
Percentile
Highest Highest

Highest

2nd
Highest

1-Hour
99th
Percentile

24-Hour
2nd
Highest Highest

Annual

NA

NA

NA

196.5

NA

1,300

NA

365

60

Average

Sulfur Dioxide

Florida AAQS:

12-095-2002

Winter Park

154

2008
2009
2010

Jan-Dec
Jan-Dec
Jan-Dec

31.4
28.8
26.2

26.2
26.2
23.5

--18.3

--18.3

23.5
23.5
--

18.3
15.7
--

5.2
7.8
8.4

5.2
5.2
5.8

2.6
2.6
0.4

12-057-3002

Plant City

121

2008
2009
2010

Jan-Dec
Jan-Dec
Jan-Dec

143.8
47.1
70.6

73.2
44.5
44.5

--39.2

--39.2

52.3
26.2
--

39.2
26.2
--

13.1
10.5
9.4

10.5
7.8
8.6

2.6
1.6
1.8

Note:

NA = not applicable.
AAQS = ambient air quality standard.

Source: State of Florida Air Quality Quicklook Reports 2008-2010.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\4\Table 4-2 - 4-5.xlsx

May 2011

103-87668

Table 4-4: Summary of Maximum Measured O3 Concentrations in Vicinity of HEF, 2008 to 2010

Site No.

Location

Ozone a

Florida AAQS:

12-055-0003

Sebring

Note:

Distance
to HEF
(km)

Measurement Period
Year
Months

2008
2009
2010

Jan-Dec
Jan-Dec
Jan-Dec

Concentration (g/m3)
1-Hour
8-Hour
2nd
2nd
3-year Average
Highest
Highest
Highest Highest
4th Highest
NA

235

NA

NA

147

153.0
156.9
125.5

151.0
153.0
121.6

135.4
135.4
107.9

135.4
127.5
105.9

127.5
125.5
113.8

NA = not applicable.
AAQS = ambient air quality standard.

On March 27, 2008, EPA promulgated revised AAQS for ozone. The O3 standard was modified to be 0.075 ppm (147 g/m 3)
for the 8-hour average; achieved when the 3-year average of 99th percentile values is 0.075 ppm or less. FDEP has not yet
adopted the revised standards.
Source: State of Florida Air Quality Quicklook Reports 2008-2010.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\4\Table 4-2 - 4-5.xlsx

May 2011

103-87668

Table 4-5: Summary of Maximum Measured NO2 Concentrations near HEF, 2008 to 2010

Site No.

Location

Nitrogen Dioxide

Florida AAQS:

121-151-1006

Sarasota

Note:

Distance
to HEF
(km)

114

Measurement Period
Year
Months

2008
2009
2010

NA = not applicable.
AAQS = ambient air quality standard.

Source: State of Florida Air Quality Quicklook Reports 2008-2010.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\4\Table 4-2 - 4-5.xlsx

Jan-Dec
Jan-Dec
Jan-Dec

Concentration (g/m3)
1-Hour
98th
3 Year Avg. 98th
Percentile
Percentile

Annual

Highest

2nd
Highest

NA

NA

NA

189a

100

58.3
52.6
56.4

56.4
50.8
48.9

--45.1

--45.1

5.6
6.6
7.5

Average

May 2011

103-87668

Table 5-1: BACT Determinations for PM/PM 10/PM2.5 Emissions from Biomass-Fired Electric Utility and Industrial Boilers

Company

State

RBLC ID /

Permit

Permit Number

Date

BAGASSE
Southeast Renewable Fuels

FL

PSD-FL-412

U.S. Sugar Corp. - Clewiston - Boiler No. 8


New Hope Power Partnership - Boilers A, B, C

FL
FL

PSD-FL-333Bb
PSD-FL-196(P)b

U.S. Sugar Corp. - Clewiston - Boiler No. 8


Atlantic Sugar Association - Boiler No. 5

FL
FL

ALL OTHER BIOMASS


Georgia Power Co.
NRG Energy
Sappi Fine Paper PLC

Emission Limits
As Provided in
Throughput

Pollutant

RACT/BACT/LAER Clearinghouse

Removal
Efficiency

Converted to
lb/MMBtua

Control Equipment Description

12/22/2010

488 MMBtu/hr

PM/PM10

0.015 lb/MMBtu

0.015

Wet Cyclone & ESP

4/7/2006

936 MMBtu/hr

PM

0.025 lb/MMBtu

0.025

Wet Cyclone & ESP

99

FL-0257
PSD-FL-078Bb

6/6/2005
11/21/2003
7/1/2002

760 MMBtu/hr
936 MMBtu/hr
255.3 MMBtu/hr

PM
PM
PM

0.026 lb/MMBtu
0.026 lb/MMBtu
0.15 lb/MMBtu

0.026
0.026
0.150

Cyclones & ESPs


Wet Cyclone & ESP

-99

Wet Scrubber

--

GA

GA-0140

12/3/2010

328 MMBtu/hr

PM10

CT
MN

CT-0156
MN-0078

4/6/2010
10/28/2009

600 MMBtu/hr
430 MMBtu/hr

PM
PM2.5

Aspen Power LLC


Loblolly Green Power

TX
SC

TX-0555
1780-0051CA

10/26/2009
9/3/2009

693 MMBtu/hr
675 MMBtu/hr

PM
PM/PM10

Koda Energy Boilers Nos. 1 and 3


Simpson Paper Company
Sierra Pacific Industries - Skagit Co. Lumber Mill

MN
WA
WA

MN-0074
WA-0335
WA-0327c

8/23/2007
5/22/2007
1/25/2006

308 MMBtu/hr
595 MMBtu/hr
430 MMBtu/hr

PM
PM10
PM10

Darrington Energy LLC


Temple Inland Inc. - Rome

WA
GA

WA-0329
GA-0114

2/11/2005
10/13/2004

403 MMBtu/hr
856 MMBtu/hr

PM10
PM10

792 MMBtu/hr

PM10

0.02 lb/MMBtu (30-day avg)

0.020

PM
PM
PM
PM10

0.02
171
0.03
8

0.020
0.030
0.030
0.026

ESP

0.01

ESP

Powerminn 9090 LLC

MN

MN-0057

10/23/2002

Sierra Pacific Industries - Aberdeen Div.


S.D. Warren Co. - Boiler No. 2
District Energy St. Paul Inc.
Trigen Biopower

WA
ME
MN
GA

WA-0298
ME-0021
MN-0046
GA-0117

10/17/2002
11/27/2001
11/15/2001
5/24/2001

NON-BACT LIMITS
FBEnergy

FL

0810226-001-AC

6/8/2010

833 MMBtu/hr

PM/PM10

Burlington Electric Department

VT

AOP-07-020

4/21/2008

750 MMBtu/hr

PM

Burlington Electric Department


Biomass Energy

VT
OH

AOP-07-020
OH-0307

4/21/2008
4/4/2006

750 MMBtu/hr
318 MMBtu/hr

PM
PM10

FLUIDIZED BED BOILERS


We Energies

WI

10-SDD-058

3/28/2011

800 MMBtu/hr

Greenhunter Energy
Gainesville Renewable Energy Center
Laidlaw Berlin Biopower, LLC
Highlands Ethanol

CA
FL
NH
FL

1732D-1
PSD-FL-411
NH-0018
PSD-FL-406

7/20/2010
12/28/2010
7/26/2010
3/22/2010

PM10/PM2.5
PM10/PM2.5
PM/PM10
PM/PM10/PM2.5
PM/PM10

Lindale Renewable Energy LLC


ADAGE Hamilton LLC

TX
FL

TX-0553
0470016-001-AC

1/8/2010
1/15/2010

657 MMBtu/hr
800 MMBtu/hr

PM
PM/PM10

Public Service of New Hampshire - Schiller Station

NH

NH-0013

10/25/2004

720 MMBtu/hr

PM10

310
1,300
550
302.2

180
1,358
1,013
218

MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr

MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr

0.040

ESP & Multiclone

--

0.026 lb/MMBtu
13.5 lb/hr

0.04 lb/MMBtu (3-hour avg)

0.026
0.031

Dry ESP
ESP & Multiclone

95
99

0.012 lb/MMBtu (30-day rolling avg)


0.029 lb/MMBtu

0.012
0.029

ESP
ESP

--

0.03 lb/MMBtu
0.02 lb/MMBtu
0.02 lb/MMBtu (24-hr avg)

0.030
0.020
0.020

Cyclone and ESP


ESP
ESP

-99
99

0.02 lb/MMBtu (24-hr avg)


0.025 lb/MMBtu

0.020
0.025

Dry ESP
ESP
Fabric Filter

---

lb/MMBtu (24-hr avg)


TPY
lb/MMBtu
lb/hr

0.01 lb/MMBtu
9.7 lb/hr

b
c

This information obtained from actual PSD permit, not Clearinghouse.


From the draft BACT determination.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-1,3,7,9,10,12 BACT.xlsx

-99
99
--

0.013

Mechanical Dust Collectors & ESP

--

0.020
0.012

Mechanical Dust Collectors & ESP


Pulse Jet Baghouse

---

0.024
0.010
0.015
0.010
0.01

Fabric Filter
Fabric Filter
Fabric Filter
Baghouse
Fabric Filter Baghouse

------

0.02 lb/MMBtu (30-day rolling avg)


22.0 lb/hr

0.020
0.028

ESP
Fabric Filter Baghouse

-99.9

0.029 lb/MMBtu
0.025 lb/MMBtu
0.03 lb/MMBtu (30-day rolling avg)

0.029
0.025
0.030

Fabric Filter Baghouse


Fabric Filter
NSPS Limit; Fabric Filter

99.9
99
99

0.02 lb/MMBtu
3.97 lb/hr

0.024
0.01
0.015
0.01
0.01

lb/MMBtu
lb/MMBtu
lb/MMBtu
lb/MMBtu
lb/MMBtu

Reference: RACT/BACT/LAER Clearinghouse on EPA's Webpage, May 2011. Based on utility and large industrial-size boilers/furnaces greater than 250 MMBtu/hr firing biomass.
Notes:
a
To convert from lb/hr, the emission limit was divided by the throughput rate. To convert from TPY, 8,760 hr/yr operation is assumed.

Mechanical Dust Collector & ESP


Cyclone & ESP
ESP & Wet Scrubber

99

May 2011

103-87668

Table 5-2: PM/PM10 Control Technology Feasibility Analysis for HEF Cogeneration Boiler

Estimated
Efficiency

Feasible and
Demonstrated?
(Y/N)

Rank Based on
Control
Efficiency

Employed by
HEF Boiler?
(Y/N)

NA

< 10%
< 10%
10 - 20%
20 - 30%
60 - 90%

Y
Y
Y
Y
Y

6
6
5
4
3

N
N
N
N
Y

PM Abatement Method

Technique Now Available

Fuel Techniques

Fuel Substitution

Pretreatment

Settling Chambers
Elutriators
Momentum Separators
Mechanically-Aided Separators
Cyclones

Electrostatic Precipitators (ESP)

Dry ESP
Wet ESP
Wire-Plate ESP
Wire-Pipe ESP

>97%
>97%
>97%
>97%

Y
Y
Y
Y

1
1
1
1

Y
N
N
N

Fabric Filters

Shaker-Cleaned

>97%

Reverse-Air

>97%

Pulse-Jet

>97%

50 - 95 %
50 - 95 %
50 - 95 %
50 - 95 %
50 - 95 %
50 - 95 %

Y
Y
Y
Y
Y
Y

2
2
2
2
2
2

N
N
N
N
N
N

Wet Scrubbers

Spray Chambers
Packed-Bed
Impingement Plate
Venturi
Orifice
Condensation

Note: NTF = Not Technically Feasible.


a
Technically feasible for fluidized bed boiler only.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-2,4,8,11,13 BACT Feas.xlsx

a
a

May 2011

103-87668

Table 5-3: BACT Determinations for NOx Emissions from Biomass-Fired Electric Utility and Industrial Boilers
Emission Limits
As Provided in

Permit
Company

State

RBLC ID

BAGASSE
Southeast Renewable Fuels
U.S. Sugar Corp. - Clewiston - Boiler No. 7

FL
FL

New Hope Power Partnership - Boilers A, B, C


U.S. Sugar Corp. - Clewiston - Boiler No. 8

FL
FL

Atlantic Sugar Association - Boiler No. 5

FL

PSD-FL-412
PSD-FL-389
PSD-FL-196(P)c
FL-0257
PSD-FL-078Bc

NRG Energy

CT

Boise White Paper, LLC

AL

Lindale Renewable Energy LLC


Aspen Power LLC
Loblolly Green Power
Koda Energy Boiler No. 3
Simpson Paper Company
Archer Daniels Midland Company

TX
TX
SC
MN
WA
ND

Sierra Pacific Industries - Skagit Co Lumber Mill

WA

Fort James Operating Company, Inc.--Old Town

Date

Throughput

12/22/2010
12/6/2007

488 MMBtu/hr
738 MMBtu/hr

6/6/2005
11/21/2003

760 MMBtu/hr
936 MMBtu/hr

7/1/2002

CT-0156
AL-0250

1/8/2010
10/26/2009
9/3/2009
8/23/2007
5/22/2007
5/1/2006

ME

TX-0553
TX-0555
1780-0051CA
MN-0074
WA-0335
ND-0022
WA-0327b
A-180-71-AI-Ac

Del-Tin Fiber LLC

AR

Palm Beach Power Corporation


Powerminn 9090 LLC

RACT/BACT/LAER Clearinghouse
0.10
0.31
0.15
0.14

Converted to
lb/MMBtua

Removal
Efficiency
Control Equipment Description

lb/MMBtu
lb/MMBtu
lb/MMBtu
lb/MMBtu

0.10
0.310

SNCR or SCR
Boiler Design and Operation

70
--

0.150
0.140

SNCR, Good Combustion Practices


SNCR, Good Combustion & Operating Practices

-50

255.3 MMBtu/hr

0.16 lb/MMBtu

0.160

Good Combustion Practices

--

4/6/2010

600 MMBtu/hr

0.06 lb/MMBtu

0.060

Regenerative SCR

70

3/23/2010

435 MMBtu/hr

Low NOx burners

60

0.15 lb/MMBtu (30-day rolling avg)


0.075 lb/MMBtu (30-day rolling avg)

0.300
0.150
0.075

SNCR
SCR

---

0.25 lb/MMBtu
0.2 lb/MMBtu (30-day rolling avg)
0.2 lb/MMBtu (30-day rolling avg)

0.250
0.200
0.200

SNCR
Proper combustion control with Overfire Air
Combustion Control

--30

0.13 lb/MMBtu (Calendar Day)

0.130
0.250

SNCR
Low NOX burners, overfire air, FGR

48

0.25 lb/MMBtu

ALL OTHER BIOMASS

657
693
675
308
595
280

MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr

0.3 lb/MMBtu (3-hr avg)

1/25/2006

430 MMBtu/hr

7/28/2004

265.2 MMBtu/hr

AR-0072

2/28/2003

291 MMBtu/hr

87.2 lb/hr

0.300

Low NOX burners & SNCR

--

FL
MN

PSD-FL-329b
MN-0057

1/16/2003
10/23/2002

760 MMBtu/hr
792 MMBtu/hr

0.15 lb/MMBtu
0.16 lb/MMBtu (30-day avg)

0.150
0.160

SNCR
SNCR

-50

NON-BACT LIMITS
We Energies
Greenhunter Energy
FBEnergy
Clean Power Berlin, LLC
Concord Steam Corporation
Burlington Electric Department

WI
CA
FL
NH
NH
VT

10-SDD-058
1732D-1
0810226-001-AC
NH-0016
NH-0015
AOP-07-020

3/28/2011
7/20/2010
6/8/2010
9/25/2009
2/27/2009
4/21/2008

0.010
0.014
0.018
0.065
0.065
0.230
0.193

SNCR
SCR
SCR
SCR w/ Staged Combustion
SCR
---

-95
-70
70
---

0.075 lb/MMBtu (CEMS Quarterly Avg)

0.075

Regenerative SCR

--

Biomass Energy

OH

OH-0307

4/4/2006

318 MMBtu/hr

27.98 lb/hr

0.088

SCR

80

FLUIDIZED BED BOILERS


Gainesville Renewable Energy Center

FL

PSD-FL-411

12/28/2010

1,358 MMBtu/hr

0.070 lb/MMBtu (30-day rolling)

0.070

Laidlaw Berlin Biopower, LLC

NH

NH-0018

7/26/2010

1013 MMBtu/hr

0.06 lb/MMBtu

0.06

SCR
SCR with Ammonia Injection

---

Highlands Ethanol

FL

PSD-FL-406

3/22/2010

218 MMBtu/hr

0.075 lb/MMBtu

0.075

SNCR

--

ADAGE Hamilton LLC

FL

0470016-001-AC

1/15/2010

800 MMBtu/hr

0.066
0.30

SCR
SCR

---

800
180
833
40.75
305
750

MMBtu/hr
MMBtu/hr
MMBtu/hr
TPH Wood
MMBtu/hr
MMBtu/hr

0.10
0.014
0.018
0.065
0.065
0.23
145

lb/MMBtu (30-day rolling avg)


lb/MMBtu (30-day rolling avg)
lb/MMBtu (12-month rolling)
lb/MMBtu
lb/MMBtu (30-day rolling avg)
lb/MMBtu
lb/hr

53.1 lb/hr (12-month rolling average)


0.30 lb/MMBtu (30-day rolling avg)

Reference: RACT/BACT/LAER Clearinghouse on EPA's Webpage, May 2011. Based on utility and large industrial-size boilers/furnaces greater than 250 MMBtu/hr firing biomass.
Notes:
a
To convert from lb/hr, the emission limit was divided by the throughput rate. To convert from TPY, 8,760 hr/yr operation is assumed.
b
c

From the draft BACT determination.


This information obtained from actual PSD permit, not Clearinghouse.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-1,3,7,9,10,12 BACT.xlsx

--

May 2011

103-87668

Table 5-4: NOx Control Technology Feasibility Analysis for HEF Cogeneration Boiler

Estimated
Efficiency

Feasible and
Demonstrated?
(Y/N)

Rank Based
on Control
Efficiency

Employed by
HEF Boiler?
(Y/N)

NOx Abatement Method

Technique Now Available

1. Removal of nitrogen

Ultra-Low Nitrogen Fuel

No Data

2. Oxidation of NOx with subsequent


absorption

Inject Oxidant

60 - 80%

NTF

NTF

Non-Thermal Plasma Reactor (NTPR)

60 - 80%

NTF

NTF

3. Chemical reduction of NOx

Selective Catalytic Reduction (SCR)

75%

Regenerative Selective Catalytic Reduction (RSCR)

75%

50 - 60%

EMx (SCONOX)

35 - 80%

NTF

NTF

Air Staging of Combustion

50 - 65%

Fuel Staging of Combustion

50 - 65%

Inject Steam

50 - 65%

Flue Gas Recirculation (FGR)

15 - 25%

Natural Gas Reburning (NGR)

15 - 25%

Over Fire Air (OFA)

15 - 25%

Less Excess Air (LEA)

15 - 25%

Combustion Optimization

15 - 25%

Low NOx Burners (LNB) (natural gas/fuel oil only)

15 - 25%

Selective Non-Catalytic Reduction (SNCR)


TM

4. Reducing residence time at peak


temperature

5. Reducing peak temperature

Note: NTF = Not Technically Feasible.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-2,4,8,11,13 BACT Feas.xlsx

May 2011

113-87668

Table 5-5: Summary of Air Emission Control Capital and Operating Costs for HEF Bagasse Boiler

Control Option

Capital

Annual

Cost

Cost

Wet Cyclone/DSI/ESPa

6,800,000

1,180,000

Wet Cyclone/DSI/ESP/SNCRa

8,800,000

1,830,000

Wet Cyclone/DSI/ESP/SCRa,b

10,500,000

1,960,000

Wet Cyclone/DSI/ESP/SCR/Ox-Cata,b

11,900,000

2,320,000

Includes wet cyclone capital cost of $500,000 and annual cost of $80,000 per year.

Includes $600,000 capital cost and $80,000 per year annual cost for relocatoing boiler air heater.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-5_HEF Cost Summary_Capital & Operating.xlsx

May 2011

103-87668

Table 5-6: Summary of Top-down BACT Analysis Impact Results for HEF Biomass Boiler
Economic Impacts

Control Alternative

Control
Efficiency
(%)

Controlled
Emissions
(lb/MMBtu)

70
60
0

0.075
0.10
0.25

138.2
184.3
460.8

322.5
276.5
--

3,700,000
2,000,000
--

780,000
650,000
--

2,418
2,351
--

2,821
2,351
--

84
75
0

0.070
0.109
0.435

128.3
200.4
802.0

673.7
601.6
--

8,000,000
6,800,000
--

1,700,000
1,180,000
--

2,523
1,961
--

7,214

60/40
25
0

0.12+0.01
0.225+0.013
0.30+0.017

239.6
438.2
584.3

344.7
146.1
--

1,400,000
3,100,000
--

360,000
500,000
--

1,044
3,423
--

(705)
3,423
--

377.8
622.5
768.6
1,045.1

667.2
422.5
276.5
--

5,100,000
5,100,000
2,000,000
--

1,140,000
1,150,000
650,000
--

1,709
2,722
2,351
--

(41)
3,423
2,351
--

Maximum
Emissions
(TPY)

Emissions
Reduction
(TPY)

Installed
Total
Capital Cost Annualized
($)
Cost ($/yr)

Average Cost
Effectiveness
($/ton)

Incremental Cost
Effectiveness
($/ton)

NOx
SCR
SNCR
Uncontrolled
SO2
Lime Spray Dryer/FF
DSI/ESP
No Add-On Control
CO + VOC
Oxidation Catalyst
Advanced Over-Fire Air
Modern Over-Fire Air
NOx + CO + VOC
SCR+ Oxidation Catalyst
SNCR + Advanced Over-Fire Air
SNCR + Modern Over-Fire Air
Uncontrolled

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-6 BACT Cost Analysis Summary.xlsx

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May 2011

103-87668

Table 5-7: BACT Determinations for SO2 Emissions from Biomass-Fired Industrial and Electric Utility Boilers
Emission Limits
As Provided in

Permit
Company

State

RBLC ID

Date

Throughput

BAGASSE
Southeast Renewable Fuels

FL

488 MMBtu/hr

FL

PSD-FL-412
PSD-FL-196(P)b

12/22/2010

New Hope Power Partnership - Boilers A, B, C

6/6/2005

760 MMBtu/hr

U.S. Sugar Corp. - Clewiston - Boiler No. 8

FL

FL-0257

11/21/2003

936 MMBtu/hr

RACT/BACT/LAER Clearinghouse
0.06
0.20
0.10
0.06
0.06

lb/MMBtu (30-day rolling avg.)


lb/MMBtu (24-hr rolling avg.)
lb/MMBtu (30-day rolling avg.)
lb/MMBtu (12-month rolling avg.)
lb/MMBtu

Converted to
lb/MMBtua
0.06
0.20
0.10
0.060
0.060

%
Control Equipment Description

Efficiency

Low S fuels, Dry Sorbent Injection


Low S supplemental fuel; ESP; SNCR; carbon injection
Low S supplemental fuel; ESP; SNCR; carbon injection
Low S supplemental fuel; ESP; SNCR; carbon injection
Fuel specifications: bagasse and distillate oil (<0.05 % S by wt.)

----

ALL OTHER BIOMASS


NRG Energy

CT

CT-0156

4/6/2010

600 MMBtu/hr

0.025 lb/MMBtu (3-hr avg.)

--

TX

TX-0553

1/8/2010

657 MMBtu/hr

0.025 lb/MMBtu (30-day rolling avg)

0.025
0.025

Low sulfur fuels

Lindale Renewable Energy LLC

--

--

Aspen Power LLC

TX

TX-0555

10/26/2009

693 MMBtu/hr

0.025 lb/MMBtu (30-day rolling avg)

0.025

--

--

Loblolly Green Power


Smurfit Stone Container Corp.
Archer Daniels Midland Company
Inland Paperboard and Packaging (Gaylord)
Smurfit-Stone - Stevenson
Meadwestvaco Kentucky Inc.
S.D. Warren Co. - Boiler No. 2

SC
AL
ND
LA
AL
KC
ME

9/3/2009
7/14/2006
5/1/2006
11/23/2004
9/30/2002
2/27/2002
11/27/2001

Sierra Pacific Industries


Grayling Generating Station L.P.

WA
MI

1780-0051CA
AL-0223
ND-0022
LA-0188
AL-0198
KY-0085
ME-0021
WA-0327 c
MI-0285

lb/hr (3-hr avg.)


lb/MMBtu
lb/hr
lb/MMBtu
lb/MMBtu
lb/MMBtu
lb/MMBtu (3-hr avg.)
lb/hr (24-hr avg.)

0.150
0.470
1.536
0.100
0.800
0.270
0.025

No controls feasible
No controls feasible
Limit annual fuel oil capacity factor to <= 10%
No controls feasible
No controls feasible
Sodium-based wet scrubber
No controls feasible

--------

0.021

Multicyclones, ESP, SNCR

--

NON-BACT LIMITS
Greenhunter Energy
FBEnergy
Burlington Electric Department
Biomass Energy

CA
FL
VT
OH

1732D-1
0810226-001-AC
AOP-07-020
OH-0307

lb/MMBtu (12-month rolling)


lb/MMBtu (12-month rolling)
lb/MMBtu
lb/hr

0.015
0.015
0.133
0.070

Woody Biomass, dry sorbent injection


Woody Biomass, dry sorbent injection
No controls
Spray Dryer Absorber or Dry Sodium Bicarbonate Injection System

-20

Gainesville Renewable Energy Center


Laidlaw Berlin Biopower, LLC

FL
NH

PSD-FL-411
NH-0018

12/28/2010
7/26/2010

1,358 MMBtu/hr
1013 MMBtu/hr

0.029
0.012

Clean Fuels (biomass) and Dry Sorbent Injection


Wood Fuel Sorbent Injection

--

Highlands Ethanol
ADAGE Hamilton LLC
Public Service of New Hampshire

FL
FL
NH

PSD-FL-406
0470016-001-AC
NH-0013

3/22/2010
1/15/2010
10/25/2004

218 MMBtu/hr
800 MMBtu/hr
720 MMBtu/hr

0.06
0.043
0.020

Bubbling fluidized bed, limestone injection


CEMS & IDSIS (lime, limestone, trona or sodium bicarbonate)
Lime injection

--70

675
620
280
787.5
620
631
1,300

1/25/2006
9/18/2001

MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr
430 MMBtu/hr
523 MMBtu/hr

7/20/2010
6/8/2010
4/21/2008
4/4/2006

180
833
750
318

MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr

93
0.47
1209.8
0.1
0.8
0.27
0.025
11.2

0.015
0.015
100
22.13

FLUIDIZED BED BOILERS


0.029 lb/MMBtu
0.012 lb/MMBtu
0.06 lb/MMBtu (30-day rolling)
34.1 lb/hr (12-month avg, rolled monthly)
0.02 lb/MMBtu (24-hr avg.)

Reference: RACT/BACT/LAER Clearinghouse on EPA's Webpage, May 2011. Based on utility and large industrial-size boilers/furnaces greater than 250 MMBtu/hr firing biomass.
Notes:
a
To convert from lb/hr, the emission limit was divided by the throughput rate. To convert from lb/day, assumed 24 hr/day operation.
b
c

This information obtained from actual PSD permit, not Clearinghouse.


From the draft BACT determination.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-1,3,7,9,10,12 BACT.xlsx

May 2011

103-87668

Table 5-8: SO2 Control Technology Feasibility Analysis for HEF Cogeneration Boiler

Estimated
Efficiency

Feasible and
Demonstrated?
(Y/N)

Rank Based
on Control
Efficiency

Employed by
HEF Boiler?
(Y/N)

50%
50%
75%

Y
Y
Y

6
6
5

N
N
Y

SO2 Abatement Method

Technique Now Available

Sorbent Injection

Sorbent Furnace Injection


Sorbent Economiser Injection
Sorbent Duct Injection

Wet Flue Gas Desulfurization

Various

50 - 98%

Spray Dryer Scrubbers

Lime or Calcium Oxide

70 - 96%

Regenerative Process

Elemental Sulphur Recovery

>95%

Note: NTF = Not Technically Feasible.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-2,4,8,11,13 BACT Feas.xlsx

May 2011

103-87668

Table 5-9: BACT Determinations for SAM Emissions from Biomass-Fired Electric Utility and Industrial Boilers
Emission Limits
Converted to
As Provided in
lb/MMBtub
RACT/BACT/LAER Clear.

Removal
%
Efficiency

State

RBLC ID

Permit
Date

BAGASSE
Southeast Renewable Fuels
U.S. Sugar Corp. - Clewiston - Boiler No. 8

FL
FL

PSD-FL-412
FL-0257

12/22/2010
11/21/2003

488 MMBtu/hr
936 MMBtu/hr

0.003 lb/MMBtu
0.004 a lb/MMBtu

0.003
0.004

Fuel Specifications: Bagasse and Distillate Oil (<0.05% S)


Fuel Specifications: Bagasse and Distillate Oil (<0.05% S)

--

ALL OTHER BIOMASS


Smurfit Stone Container Corp. - Stevenson Mill
Grayling Generating Station L.P.

AL
MI

AL-0223
MI-0285

7/14/2006
9/18/2001

620 MMBtu/hr
523 MMBtu/hr

13.6
0.003

lb/hr (3-hr avg.)


lb/MMBtu

0.022
0.003

No Controls Feasible
No Controls Feasible

---

FLUIDIZED BED BOILERS


Gainesville Renewable Energy Center
Laidlaw Berlin Biopower, LLC

FL
NH

PSD-FL-411
NH-0018

1,358 MMBtu/hr
1013 MMBtu/hr

1.4
0.002

lb/hr
lb/MMBtu

Clean Fuels (biomass) and Dry Sorbent Injection


Wood Fuel Sorbent Injection

--

Company

12/28/2010
7/26/2010

Throughput

0.0010
0.002

Control Equipment Description

Reference: RACT/BACT/LAER Clearinghouse on EPA's Webpage, May 2011. Based on utility and large industrial-size boilers/furnaces greater than 250 MMBtu/hr firing biomass.
Notes:
a
SO2 is a surrogate for SAM. These are expected emissions limits.
b

To convert from lb/hr, the emission limit was divided by the throughput rate.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-1,3,7,9,10,12 BACT.xlsx

May 2011

103-87668

Table 5-10: BACT Determinations for CO Emissions from Biomass-Fired Electric Utility and Industrial Boilers
Emission Limits
RBLC

Permit

State

ID

Date

Southeast Renewable Fuels

FL

U.S. Sugar Corp. - Clewiston - Boiler No. 8

FL

PSD-FL-412
PSD-FL-333Bb

New Hope Power Partnership - Boilers A, B, C

FL

PSD-FL-196(P)

New Hope Power Partnership - Boilers A, B, C

FL

PSD-FL-196(P)

U.S. Sugar Corp. - Clewiston - Boiler No. 8

FL

Atlantic Sugar Association - Boiler No. 5

FL

FL-0257
PSD-FL-078Bb

7/1/2002

255.3 MMBtu/hr

Georgia Power Co.

GA

GA-0140

12/3/2010

328 MMBtu/hr

NRG Energy

CT

CT-0156

4/6/2010

600 MMBtu/hr

Company

As Provided in
Throughput

RACT/BACT/LAER Clearinghouse

Removal
Converted to
lb/MMBtua

Efficiency
Control Equipment Description

BAGASSE
12/22/2010

488 MMBtu/hr

0.10 lb/MMBtu, 30-day rolling avg.

0.10

4/7/2006

936 MMBtu/hr

400 ppmvd @ 7% O2

0.38

Good combustion practices; Oxidation catalyst as needed


Good Combustion & Operating Practices

--

6/6/2005

760 MMBtu/hr

0.35 lb/MMBtu (12-month rolling avg.)

0.35

Good Combustion & Operating Practices

--

6/6/2005

760 MMBtu/hr

0.50 lb/MMBtu (30-day rolling avg.)

0.50

Good Combustion & Operating Practices

--

11/21/2003

936 MMBtu/hr

0.38 lb/MMBtu (12-month rolling avg.)

0.38

Good Combustion & Operating Practices

--

6.50

Good Combustion & Operating Practices

--

0.45

Good combustion practices

--

6.5 lb/MMBtu

ALL OTHER BIOMASS


0.45 lb/MMBtu (3-hour avg)
0.026 lb/MMBtu
0.31 lb/MMBtu (30-day rolling avg)

0.026
0.31

Oxidation Catalyst

70

Good Combustion Practices

--

0.075

Oxidation Catalyst

Lindale Renewable Energy LLC

TX

TX-0553

1/8/2010

657 MMBtu/hr

Loblolly Green Power

SC

1780-0051CA

9/3/2009

675 MMBtu/hr

Koda Energy Boiler No. 3

MN

MN-0074

8/23/2007

308 MMBtu/hr

0.43 lb/MMBtu (30-day rolling avg.)

0.43

Good Combustion Practices

--

Simpson Paper Company

WA

WA-0335

5/22/2007

595 MMBtu/hr

0.35 lb/MMBtu

0.35

Overfire Air System

--

Archer Daniels Midland Company

ND

5/1/2006

280 MMBtu/hr

0.63 lb/MMBtu

0.63

Good Combustion Practices

--

Sierra Pacific Industries - Skagit Co Lumber Mill

WA

ND-0022
WA-0327c

1/25/2006

430 MMBtu/hr

659 TPY

0.35

--

--

Darrington Energy LLC

WA

WA-0329

2/11/2005

403 MMBtu/hr

0.35

Good Combustion Practices

--

Inland Paperboard and Packaging (Gaylord)


Temple Inland Inc - Rome

LA
GA

LA-0188
GA-0114

11/23/2004
10/13/2004

787.5 MMBtu/hr
856 MMBtu/hr

Overfire Air & Good Combustion Practices


Staged Combustion & Good Combustion Practices

---

Good Equipment Design & Proper Combustion Techniques


Good Combustion Practices

--

0.075 lb/MMBtu

0.35 lb/MMBtu (24-hr avg)


491.5 lb/hr
368 ppm @ 3% O2

0.624
--

Boise Cascade Corp - Deridder Paper Mill

LA

LA-0178

11/14/2003

454.29 MMBtu/hr

149.9 lb/hr

0.33

Del-Tin Fiber LLC

AR

AR-0072

2/28/2003

291 MMBtu/hr

228.3 lb/hr

0.785

--

Powerminn 9090 LLC

MN

MN-0057

10/23/2002

792 MMBtu/hr

0.24 lb/MMBtu (24-hr avg)

0.24

Good Combustion Practices

--

Sierra Pacific Industries - Aberdeen Div.

WA

WA-0298

10/17/2002

310 MMBtu/hr

0.35 lb/MMBtu

0.35

Good Combustion Practices

--

S.D. Warren Co. - Boiler No. 2

ME

ME-0021

11/27/2001

1300 MMBtu/hr

520 lb/hr

0.40

Good Boiler Design & Combustion Practices

--

District Energy St. Paul Inc.

MN

MN-0046

11/15/2001

550 MMBtu/hr

0.3 lb/MMBtu

0.30

Trigen Biopower

GA

GA-0117

5/24/2001

302.2 MMBtu/hr

0.30

--

International Paper Company - Riegelwood Mill

NC

NC-0092

5/10/2001

600 MMBtu/hr

90.7 lb/hr
0.5 lb/MMBtu

Good Combustion Practices


Good Design & Combustion Practices

0.50

Good Combustion Practices

--

SCR

--

NON-BACT LIMITS
Greenhunter Energy

CA

1732D-1

7/20/2010

180 MMBtu/hr

0.10 lb/MMBtu (30-day rolling avg)

0.10

FBEnergy

FL

0810226-001-AC

6/8/2010

833 MMBtu/hr

0.028 lb/MMBtu (30-day rolling avg)

Aspen Power LLC

TX

TX-0555

10/26/2009

693 MMBtu/hr

Burlington Electric Department

VT

AOP-07-020

4/21/2008

750 MMBtu/hr

0.075 lb/MMBtu (12 month rolling avg)


1500 ppm

0.028
0.075

Biomass Energy

OH

OH-0307

4/4/2006

318 MMBtu/hr

31.8 lb/hr

We Energies

WI

10-SDD-058

3/28/2011

800 MMBtu/hr

0.12 lb/MMBtu

0.120

Good Combustion Practices

--

Gainesville Renewable Energy Center

FL

PSD-FL-411

12/28/2010

1,358 MMBtu/hr

0.08 lb/MMBtu

0.080

Good Combustion Practices

--

Highlands Ethanol
ADAGE Hamilton LLC

FL
FL

PSD-FL-406
0470016-001-AC

3/22/2010
1/15/2010

218 MMBtu/hr
800 MMBtu/hr

0.10 lb/MMBtu (30-day rolling)


56.0 lb/hr (12-month avg, rolled monthly)

0.10
0.070

Good Combustion Practices


CEMS

---

Public Service of New Hampshire - Schiller Station

NH

NH-0013

10/25/2004

720 MMBtu/hr

0.10

Good Combustion Practices

--

-0.10

Oxidation Catalyst
Good Combustion Practices
--

--

Oxidation Catalyst

50

--

FLUIDIZED BED BOILERS

0.1 lb/MMBtu (24-hr avg)

Reference: RACT/BACT/LAER Clearinghouse on EPA's Webpage, May 2011. Based on utility and large industrial-size boilers/furnaces greater than 250 MMBtu/hr firing biomass.
Notes:
a
To convert from lb/hr, the emission limit was divided by the throughput rate. To convert from TPY, 8,760 hr/yr operation is assumed.
b
c

This information obtained from actual PSD permit, not Clearinghouse.


From the draft BACT determination.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-1,3,7,9,10,12 BACT.xlsx

May 2011

103-87668

Table 5-11: CO Control Technology Feasibility Analysis for HEF Cogeneration Boiler

CO Abatement Method

Technique Now Available

Catalytic Oxidation

Tail-End Oxidation Catalyst


Regenerative Oxidation Catalyst

Enhanced Over-Fire Air Systems

Nalco Mobotec OFA


Synterprise Ecojet

Good Combustion Practices

Air Staging of Combustion


Increased Gas Residence Time
Combustion Optimization

Incinerators

Thermal
Catalytic

Note: NTF = Not Technically Feasible.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-2,4,8,11,13 BACT Feas.xlsx

Estimated
Efficiency

Feasible and
Demonstrated?
(Y/N)

Rank Based
on Control
Efficiency

Employed by HEF
Boiler? (Y/N)

60-80%
60-80%

Y
Y

1
1

N
N

70%
70%

Y
Y

2
2

N
N

50 - 75%
50 - 75%
50 - 75%

Y
Y
Y

3
3
3

Y
Y
Y

>80%
>80%

NTF
NTF

NTF
NTF

N
N

May 2011

103-87668

Table 5-12: BACT Determinations for VOC Emissions from Biomass-Fired Electric Utility and Industrial Boilers
Emission Limits
As Provided in

Permit
Company

Throughput

RACT/BACT/LAER Clearinghouse

12/22/2010

488 MMBtu/hr

0.010 lb/MMBtu

FL-0257
PSD-FL-078Bb

6/6/2005
11/21/2003
7/1/2002

760 MMBtu/hr
936 MMBtu/hr
255 MMBtu/hr

0.05 lb/MMBtu
0.05 lb/MMBtu
0.25 lb/MMBtu

GA-0140
CT-0156
AL-0250
TX-0555
AR-0083
LA-0178
AR-0072
ME-0021

12/3/2010
4/6/2010
3/23/2010
10/26/2009
7/26/2005
11/14/2003
2/28/2003
11/27/2001

State

RBLC ID

BAGASSE
Southeast Renewable Fuels
New Hope Power Partnership - Boilers A, B, C

FL
FL

PSD-FL-412
PSD-FL-196(P)b

U.S. Sugar Corp. - Clewiston - Boiler No. 8


Atlantic Sugar Association - Boiler No. 5

FL
FL

GA
CT
AL
TX
AR
LA
AR
ME

Date

Converted to
lb/MMBtua

Removal
Efficiency
Control Equipment Description

0.010

Good combustion practices; Oxidation catalyst as needed

--

0.050
0.050
0.250

Clean fuels
Good combustion & Operating practices
Good combustion practices

----

0.050
0.010
0.030
0.010
0.034
0.037
0.073
0.007

Good combustion practices


Oxidation Catalyst
--

-70
60

-Good combustion practices


Good Equipment Design & Proper Combustion Techniques
Closed loop system
Good combustion practices

---95
--

ALL OTHER BIOMASS


Georgia Power Co.
NRG Energy
Boise White Paper, LLC
Aspen Power LLC
Potlatch Corporation - Ozan Unit
Boise Cascade Corp - Deridder Paper Mill
Del-Tin Fiber LLC
S.D. Warren Co. - Boiler No. 2

328
600
435
693
110,000
454.29
291
1,300

MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr
Steam
MMBtu/hr
MMBtu/hr
MMBtu/hr

NON-BACT LIMITS
Greenhunter Energy

CA

1732D-1

7/20/2010

180 MMBtu/hr

Biomass Energy

OH

OH-0307

4/4/2006

318 MMBtu/hr

Loblolly Green Power

SC

1780-0051CA

9/3/2009

675 MMBtu/hr

FLUIDIZED BED BOILERS


We Energies
Gainesville Renewable Energy Center
Highlands Ethanol
Public Service of New Hampshire - Schiller Station

WI
FL
FL
NH

10-SDD-058
PSD-FL-411
PSD-FL-406
NH-0013

3/28/2011
12/28/2010
3/22/2010
10/25/2004

800
1,358
218
720

MMBtu/hr
MMBtu/hr
MMBtu/hr
MMBtu/hr

0.05
0.01
0.03
0.01
0.034
73.77
21.2
0.007

lb/MMBtu (3-hour avg)


lb/MMBtu
lb/MMBtu (3-hr avg)
lb/MMBtu (30-day rolling avg)
lb/MMBtu
TPY
lb/hr
lb/MMBtu

0.0085 lb/MMBtu
4.06 lb/hr

0.0085

Good combustion practices and use of oxidation catalyst

0.004 lb/MMBtu

0.004

Oxidation catalyst

-0.009 lb/MMBtu
0.005 lb/MMBtu
0.005 lb/MMBtu (24-hr avg)

-0.009
0.005
0.005

Comply with CO limit.


Good Combustion Practices
Good Combustion Practices
Good combustion practices

Reference: RACT/BACT/LAER Clearinghouse on EPA's Webpage, May 2011. Based on utility and large industrial-size boilers/furnaces greater than 250 MMBtu/hr firing biomass.
Notes:
a

To convert from lb/hr, the emission limit was divided by the throughput rate. To convert from TPY, 8,760 hr/yr operation is assumed.

This information obtained from actual PSD permit, not Clearinghouse.

From the draft BACT determination.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-1,3,7,9,10,12 BACT.xlsx

SCR, good combustion practices

0.013

--

-----

May 2011

103-87668

Table 5-13: Add-on VOC Control Technology Feasibility Analysis for HEF Cogeneration Boiler

Estimated
Efficiency

Feasible and
Demonstrated?
(Y/N)

Rank Based
on Control
Efficiency

Employed by
HEF Boiler?
(Y/N)

VOC Abatement Method

Technique Now Available

Refrigerated Condensors

Surface
Contact

Variable
Variable

NTF
NTF

NTF
NTF

N
N

Carbon Adsorbers

Fixed Regenerative Bed


Disposable/Rechargeable Cannisters
Traveling Bed Adsorbers
Fluid Bed Adsorbers
Chromatographic Baghouse

Variable
Variable
Variable
Variable
Variable

NTF
NTF
NTF
NTF
NTF

NTF
NTF
NTF
NTF
NTF

N
N
N
N
N

Catalytic Oxidation

Tail-End SCR/RSCR
Conventional SCR

40-80%
Variable

Y
NTF

1
NTF

N
N

Over-Fire Air Systems

Nalco Mobotec OFA


Synterprise Ecojet

70%
70%

Y
Y

2
2

N
N

Good Combustion Practices

Air Staging of Combustion


Increased Gas Residence Time
Combustion Optimization

50 - 75%
50 - 75%
50 - 75%

Y
Y
Y

3
3
3

Y
Y
Y

Destruction Controls

Flares

Variable

NTF

NTF

Incinerators

Thermal
Catalytic

>80%
>80%

NTF
NTF

NTF
NTF

N
N

Note: NTF = Not Technically Feasible.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\5\Table 5-2,4,8,11,13 BACT Feas.xlsx

May 2011

103-87668

Table 6-1: Major Features of the AERMOD Model, Version 11103


AERMOD Model Features

Plume dispersion/growth rates are determined by the profile of vertical and horizontal turbulence,
vary with height, and use a continuous growth function.

In a convective atmosphere, uses three separate algorithms to describe plume behavior as it


comes in contact with the mixed layer lid; in a stable atmosphere, uses a mechanically mixed
layer near the surface.

Polar or Cartesian coordinate systems for receptor locations can be included directly or by an
external file reference.

Urban model dispersion is input as a function of city size and population density; sources can
also be modeled individually as urban sources.

Stable plume rise: uses Briggs equations with winds and temperature gradients at stack top up to
half-way up to plume rise. Convective plume rise: plume superimposed on random convective
velocities.

Procedures suggested by Briggs (1974) for evaluating stack-tip downwash.

Has capability of simulating point, volume, area, and multi-sized area sources.

Accounts for the effects of vertical variations in wind and turbulence (Brower et al., 1998).

Uses measured and computed boundary layer parameters and similarity relationships to develop
vertical profiles of wind, temperature, and turbulence (Brower et al., 1998).

Concentration estimates for 1-hour to annual average times.

Creates vertical profiles of wind, temperature, and turbulence using all available measurement
levels.

Terrain features are depicted by use of a controlling hill elevation and a receptor point elevation.

Modeling domain surface characteristics are determined by selected direction and month/season
values of surface roughness length, albedo, and Bowen ratio.

Contains both a mechanical and convective mixed layer height, the latter based on the hourly
accumulation of sensible heat flux.

The method of Pasquill (1976) to account for buoyancy-induced dispersion.

A default regulatory option to set various model options and parameters to EPA-recommended
values.

Contains procedures for calm-wind and missing data for the processing of short term averages.

Note: AERMOD = The American Meteorological Society and EPA Regulatory Model.
Source: Paine et al., 2007.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-1.docx

May 2011

103-87668

Table 6-2: Modeled Emission Rates Used for the Significant Impact Analysis
Source ID
Point Sources
Bagasse Boiler
Cooling Tower
Flare
Ash Silo
Lime Silo 1
Lime Silo 2

Model ID

BOILER
COOLTWR
FLARE
ASHSILO
LIMEWWT
LIMEDSI

Description
Annuala
(TPY)
(g/s)
Bagasse Boiler
200.4
6.28
Cooling Tower
--Truck Loading Rack Flare
0.0090 0.00026
Bagfilter for Boiler Ash Silo
--Bagfilter for Lime Silo for Wastewater Treatment
--Bagfilter for Lime Silo for DSI
---

SO2

Modeled Emission Ratea


PM2.5

PM10

24-hour
(lb/hr)
(g/s)
64.2
8.09
--0.0057 0.00072
-------

1- and 3-hour
(lb/hr)
(g/s)
70.6
8.90
--0.0057 0.00072
-------

Annuala
(TPY)
(g/s)
27.6
0.87
0.19
0.0054
0.052
0.0015
0.847
0.024
0.002
0.000058
0.00042 0.000012

Area and Volume Sources


Source Type

Annual
(TPY)
(g/s)

PM10

24-hour
(lb/hr)
(g/s)
6.9
0.87
0.043
0.0054
0.034
0.0043
0.21
0.026
0.21
0.026
0.21
0.026

Annuala
(TPY)
(g/s)
18.0
0.56
0.19
0.0054
0.052
0.0015
0.847
0.024
0.002 0.000058
0.00042 0.000012

24-hour
(lb/hr)
(g/s)

Annual
(TPY)
(g/s)

24-hour
(lb/hr)
(g/s)

Area Source Size


(ft2)
(m2)

(TPY)
184.3
-1.04
----

Annuala

SAMb

NOx
(g/s)
5.78
-0.030
----

PM10 Modeled Emissions


Annual
24-hour
(g/m2-s)
(g/m2-s)

(lb/hr)
126.1
-0.66
----

1-hour

(g/s)
15.89
-0.083
----

PM2.5 Modeled Emissions


Annual
24-hour
(g/m2-s)
(g/m2-s)

Area

0.047

0.0014

0.051

0.006

0.0071

0.0002

0.0077

0.001

32,500

3,019

4.49E-07

2.13E-06

6.80E-08

3.23E-07

BIOFUGWE

Biomass storage pile wind erosion

Area

0.11

0.0031

0.29

0.037

0.11

0.0031

0.29

0.037

100,000

9,290

3.33E-07

3.95E-06

3.33E-07

3.95E-06

BIOFUGVM

Biomass storage vehicular maintenance

Area

1.39

0.040

0.45

0.057

0.14

0.0040

0.046

0.0058

100,000

9,290

4.30E-06

6.10E-06

4.34E-07

6.24E-07

0.0021

0.017

0.0021

--

--

--

--

--

--

--

--

--

--

--

--

BIOFUG

Biomass Pile Wind Erosion


Biomass Pile Vehicular Maint.
Biomass Truck Trafficb

BIOTRK

Sorghum and wood deliveries, ash, and lime


hauling

Line

0.29

0.0085

0.067

0.0084

0.072

Other Truck Traffic

ETHTRK

Ethanol and denaturant/gasoline deliveries

Line

0.011

0.00033

0.0027

0.00034

0.0028 8.05E-05

8-hour/1-hour
(lb/hr)
(g/s)
1,192.1
150.20
--3.61
0.45
-------

Conveyors, belts, and screens

Biomass Materials Handling

PM2.5

CO

24-hour
(lb/hr)
(g/s)
4.9
0.62
0.043
0.0054
0.034
0.0043
0.21
0.026
0.21
0.026
0.21
0.026

Annual averages are based on the annual emission rate in TPY over 8,040 hours for the boiler, or 8,760 for all other sources.
SAM emissions are included only for the visibility analysis. SAM is not a PSD pollutant.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-2, 6-3, 6-8 - Source Data.xlsx

6.67E-04 8.40E-05

24-hour
(lb/hr)
(g/s)
3.15
0.40
-----------

May 2011

103-87668
Table 6-3: Model Parameters Used for the Significant Impact Analysis
Source ID

Point Sources
Bagasse Boiler
Cooling Tower
Flare
Ash Silo
Lime Silo 1
Lime Silo 2

Model ID

BOILER
COOLTWR
FLARE
ASHSILO
LIMEWWT
LIMEDSI

Description

Bagasse Boiler
Cooling Tower
Truck Loading Rack Flare
Bagfilter for Boiler Ash Silo
Bagfilter for Lime Silo for Wastewater Treatment
Bagfilter for Lime Silo for DSI

Area and Volume Sources

UTM NAD83
East
North
(m)
(m)
466,365
466,512
466,387
466,257
466,461
466,346

Physical

3,008,958
3,008,828
3,009,253
3,008,965
3,008,832
3,008,942

UTM NAD83
East
North
(m)
(m)

Stack Parameters

Height
(ft)
(m)

Diameter
(ft)
(m)

Operating
Temperature
Velocity
o
( F)
(K)
(fps)
(m/s)

150
35
30
35
35
35

14
33
1.0
1.5
1.5
1.5

340
77
1,832
77
77
77

45.7
10.7
9.1
10.7
10.7
10.7

Source Type

4.3
10.1
0.30
0.46
0.46
0.46

Release Height
(ft)
(m)

444
298
1,273
298
298
298

x-dimensionc
(ft)
(m)

Length

22.1
4.1
5.2
23.6
23.6
23.6

6.74
1.26
1.60
7.19
7.19
7.19

y-dimensiond
(ft)
(m)

Conveyors, belts, and screens

466,331

3,008,877

Area

15

4.6

325.0

99.1

100.0

30.5

BIOFUGWE

Biomass storage pile wind erosion

466,289

3,008,809

Area

35

10.7

400.0

121.9

250.0

76.2

BIOFUGVM

Biomass storage vehicular maintenance

466,289

3,008,809

Area

35

10.7

400.0

121.9

250.0

76.2

Biomass Materials Handling

BIOFUG

Biomass Pile Wind Erosion


Biomass Pile Vehicular Maint.
Biomass Truck Trafficb

BIOTRK

Sorghum and wood deliveries, ash, and lime


hauling

466,506

3,009,135

Line

11.25

3.4

27.6

8.4

22.5

6.9

Other Truck Traffic

ETHTRK

Ethanol and denaturant/gasoline deliveries

466,434

3,009,136

Line

11.25

3.4

28.0

8.5

22.5

6.9

a
b

Default temperature used in AERMOD for flare modeling.

Truck traffic locations shown for one volume source only.


The x-dimension for each volume source is equivalent to the side length for each volume source (Sigma y).
d
The y-dimension for each volume source is equivalent to the vertical dimension (sigma Z).
c

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-2, 6-3, 6-8 - Source Data.xlsx

May 2011

103-87668
Table 6-4: Summary of the SO2 Facilities Considered for Inclusion in the 24-Hour AAQS and PSD Class II Air Modeling Analyses

UTM Coordinates
AIRS
Number

Facility

Modeling Area - Included all facilities within Modeling Area


0550014
Lake Placid Asphalt Plant

Threshold
Dist x 20

b,c

Include in
Modeling
Analysis ?

East
(km)

North
(km)

X
(km)

Y
(km)

Distance
(km)

Direction
(deg)

Emissions
(TPY)

Highlands

465.6

3,008.7

-0.8

-0.3

0.87

249

170.07

SIA

YES

464.3
493.2
494.3
469.3
451.4
419.8
489.2
516.1

3,035.4
3,013.2
3,012.4
3,042.9
3,050.5
3,011.8
2,966.6
3,014.2

-2.1
26.8
27.9
2.9
-15.0
-46.6
22.8
49.7

26.4
4.2
3.4
33.8
41.5
2.8
-42.4
5.2

26.47
27.12
28.10
33.96
44.12
46.65
48.15
49.95

355
81
83
5
340
273
152
84

1,955.70
104.24
18.86
11.80
5,054.52
951.05
93.71
115.15

529.4
542.4
562.0
679.2
882.3
933.1
963.0
999.1

YES
NO
NO
NO
YES
YES
NO
NO

NA = Not applicable, ND = No data, SID = Significant impact distance for the project

Highlands Ethanol East and North Coordinates (km) are:

466.4

3,009.0

km

The significant impact distance for the project is estimated to be:

Based on the North Carolina Screening Threshold method, a background facility is included in the modeling analysis if the facility is beyond the modeling area and its emission rate is greater
than the product of Distance x 20.

"Modeling Area" is the area in which the project is predicted to have a significant impact (0.9 km). EPA recommends that all sources within this area be modeled.
"Screening Area" is the significant impact distance for the HEF Facility of 0.9 km, plus 50 km beyond the modeling area. EPA recommends that sources be modeled that are expected to
have a significant impact in the modeling area. Screening criteria within these areas are specified in the headers.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-4, 6-5, L-1 - BG SO2 Sources.xlsx

Q, (TPY)
Emission

County

Screening Area - Exclude all facilities with emissions <10 TPY d


0550018
Tampa Electric Co. - Philips Station
Highlands
0550061
Highlands Ethanol
Highlands
0550060
Compression Station No. 29
Highlands
0550046
Highlands County Dept. of Solid Waste
Highlands
0550003
Progress Energy - Avon Park
Highlands
0270016
Desoto County Energy Park
Desoto
0430008
South Florida Thermal Services, Inc.
Glades
0930001
Okeechobee Asphalt Plant
Okeechobee
Note:

Maximum
24-Hr/Annual SO2

Relative to Highlands Ethanol

0.9 km

May 2011

103-87668
Table 6-5: Summary of the SO2 Facilities Considered for Inclusion in the 1-Hour AAQS Air Modeling Analysis

AIRS
Number

Facility

UTM Coordinates
East
North

Relative to Highlands Ethanol


Y
Distance
Direction

Maximum
1-Hour SO2
Emissions

Include in
Modeling

County

(km)

(km)

(km)

(km)

(km)

(deg)

(lb/hr)

Analysis ?

Modeling Area - Included all facilities out to 10 km


0550014 Lake Placid Asphalt Plant

Highlands

465.6

3,008.7

-0.8

-0.3

0.87

249

35.32

YES

Facilities out to 50 km beyond SIA - Include if > 250 lb/hr


0550018 Tampa Electric Co. - Philips Station
0550061 Highlands Ethanol
0550060 Compression Station No. 29
0550046 Highlands County Dept. of Solid Waste
0550003 Progress Energy - Avon Park
0270016 Desoto County Energy Park
0430008 South Florida Thermal Services, Inc.
0930001 Okeechobee Asphalt Plant
0430018 Oldcaste Lawn and Garden Moore Haven

Highlands
Highlands
Highlands
Highlands
Highlands
Desoto
Glades
Okeechobee
Glades

464.3
493.2
494.3
469.3
451.4
419.8
489.2
516.1
492.0

3,035.4
3,013.2
3,012.4
3,042.9
3,050.5
3,011.8
2,966.6
3,014.2
2,961.3

-2.1
26.8
27.9
2.9
-15.0
-46.6
22.8
49.7
25.6

26.4
4.2
3.4
33.8
41.5
2.8
-42.4
5.2
-47.7

26.47
27.12
28.10
33.96
44.12
46.65
48.15
49.95
54.13

355
81
83
5
340
273
152
84
152

923.82
23.80
2.07
2.32
1,154.00
197.38
19.45
23.90
4.10

YES
NO
NO
NO
YES
NO
NO
NO
NO

Note:

NA = Not applicable, ND = No data, SID = Significant impact distance for the project

Highlands Ethanol East and North Coordinates (km) are:

The significant impact distance for the project is estimated to be:

Facilities with less than 1 lb/hr past 10 km are excluded from the screening table.

"Modeling Area" is the area in which the project is predicted to have a significant impact (4.75 km). EPA recommends that all sources within this area be modeled.
"Screening Area" is the significant impact distance for the HEF Facility of 4.75 km, plus 50 km beyond the modeling area. EPA recommends that sources be modeled that are expected to
have a significant impact in the modeling area. Screening criteria within these areas are specified in the headers.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-4, 6-5, L-1 - BG SO2 Sources.xlsx

466.4

3,009.0

km

4.75 km

May 2011

103-87668

Table 6-6: Summary of the PM 10 and PM2.5 Facilities Considered for Inclusion in the AAQS and PSD Class II Air Modeling Analyses

UTM Coordinates

Maximum
PM10

Relative to Highlands Ethanol

Q, (TPY)
Emission
b,c

Include in

County

East
(km)

North
(km)

X
(km)

Y
(km)

Distance
(km)

Direction
(deg)

Emissions
(TPY)

Threshold
(Dist - SID) x 20

Modeling
Analysis ?

Highlands

465.6

3,008.7

-0.8

-0.3

0.87

249

0.18

SIA

YES

Screening Area - Exclude all facilities with emissions <10 TPY d


0550018
Tampa Electric Company - Philips Station
Highlands
0550061
Highlands Ethanol
Highlands
0270016
Desoto County Energy Park
Desoto
0430008
South Florida Thermal Servides, Inc.
Glades

464.3
493.2
419.8
489.2

3,035.4
3,013.2
3,011.8
2,966.6

-2.1
26.8
-46.6
22.8

26.4
4.2
2.8
-42.4

26.47
27.12
46.65
48.15

355
81
273
152

72.10
36.96
327.62
20.96

471.4
484.4
875.1
905.0

NO
NO
NO
NO

AIRS
Number

Facility

Modeling Area - Included all facilities within Modeling Area


0550014
Lake Placid Asphalt Plant

Note:

NA = Not applicable, ND = No data, SID = Significant impact distance for the project

Highlands Ethanol East and North Coordinates (km) are:

The significant impact distance for the project is estimated to be:

Based on the North Carolina Screening Threshold method, a background facility is included in the modeling analysis if the facility is beyond the modeling area and its emission rate is greater
than the product of (Distance-SID) x 20.

"Modeling Area" is the area in which the project is predicted to have a significant impact (2.9 km). EPA recommends that all sources within this area be modeled.
"Screening Area" is the significant impact distance for the HEF Facility of 2.9 km, plus 50 km beyond the modeling area. EPA recommends that sources be modeled that are expected to
have a significant impact in the modeling area. Screening criteria within these areas are specified in the headers.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-6, L-2 - BG PM2.5-10 Sources.xlsx

466.4

3,009.0

km
2.9 km

May 2011

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Table 6-7: Summary of the 1-Hour NOx Facilities Considered for Inclusion in the AAQS Air Modeling Analysis
Maximum

County

UTM Coordinates
East
North
(km)
(km)

X
(km)

Modeling Area - Included all facilities out to 10 km


0550014
Lake Placid Asphalt Plant

Highlands

465.6

3,008.7

-0.8

-0.3

0.87

Facilities out to 50 km beyond SIA - Include if > 250 lb/hr


0550018
Tampa Electric Company - Philips Station
0550061
Highlands Ethanol
0550060
Compression Station No. 29
0550032
TCSC Sebring Plant
0550058
Compressor Station No. 430C
0550046
Highlands County Dept. of Solid Waste
0550003
Progress Energy - Avon Park
0270016
Desoto County Energy Park
0430008
South Florida Thermal Services, Inc.
0430018
Oldcastle Lawn and Garden Moore Haven
0510015
Southern Gardens Citrus Processing Corp.
0270003
Peace River Citrus Products
0490344
McBars, LLC - Limestone
0930109
Biomass Processing Facility - Okeechobee
0510004
Citrus Belle
7770048
Better Roads, Inc.
7775172
Plant No. 7 - Punta Gorda

Highlands
Highlands
Highlands
Highlands
Highlands
Highlands
Highlands
Desoto
Glades
Glades
Hendry
Desoto
Hardee
Okeechobee
Hendry
Hillsborough
Charlotte

464.3
493.2
494.3
469.5
472.5
469.3
451.4
419.8
489.2
492.0
487.5
409.8
411.0
525.2
456.4
425.0
423.6

3,035.4
3,013.2
3,012.4
3,038.4
3,041.7
3,042.9
3,050.5
3,011.8
2,966.6
2,961.3
2,957.6
3,010.3
3,027.3
3,017.4
2,950.3
2,963.0
2,964.0

-2.1
26.8
27.9
3.1
6.1
2.9
-15.0
-46.6
22.8
25.6
21.1
-56.6
-55.4
58.8
-10.0
-41.4
-42.9

26.4
4.2
3.4
29.4
32.7
33.8
41.5
2.8
-42.4
-47.7
-51.4
1.3
18.3
8.4
-58.7
-46.0
-45.1

26.47
27.12
28.10
29.55
33.26
33.96
44.12
46.65
48.15
54.13
55.57
56.64
58.31
59.37
59.56
61.88
62.19

AIRS
Number

Note:

Facility

Relative to Highlands Ethanol


Y
Distance
Direction
(km)
(km)
(deg)

Annual NOx
Emissions
(lb/hr)

Include in
Modeling
Analysis ?

249

15.00

YES

355
81
83
6
11
5
340
273
152
152
158
271
288
82
190
222
224

1,145.52
14.90
1.01
1.30
6.67
1.84
990.18
128.20
14.37
30.00
45.48
21.59
4.68
10.95
26.51
4.33
16.51

YES
NO
NO
NO
NO
NO
YES
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO

NA = Not applicable, ND = No data, SID = Significant impact distance for the project

Highlands Ethanol East and North Coordinates (km) are:

The significant impact distance for the project is estimated to be:

Facilities with less than 1 lb/hr past 10 km are excluded from the screening table.

"Modeling Area" is the area in which the project is predicted to have a significant impact (12 km). EPA recommends that all sources within this area be modeled.
"Screening Area" is the significant impact distance for the HEF Facility of 12 km, plus 50 km beyond the modeling area. EPA recommends that sources be modeled that are expected to
have a significant impact in the modeling area. Screening criteria within these areas are specified in the headers.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-7, L-3 - BG NOx Sources.xlsx

466.4

3,009.0

km
12 km

May 2011

103-87668
Table 6-8: Summary of Building Dimensions Used in the Modeling Analysis
Building Description
Store Room
Maintenance
Garage
Office/Lab
Distillation
Fermentation
Evaporation
Boiler Building
Air Pollution Control Housing
Turbine Building
Cooling Tower

Model ID
STORERM
MAINT
GARAGE
OFFICE
DIST
FERM
EVAP
BLRBLD
APCDBLD
TURBINE
COOLTWR

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-2, 6-3, 6-8 - Source Data.xlsx

Height
(ft)
(m)
35.0
35.0
30.0
30.0
35.0
35.0
35.0
120.0
78.0
60.0
35.0

10.7
10.7
9.1
9.1
10.7
10.7
10.7
36.6
23.8
18.3
10.7

Length
(ft)
(m)
160.0
60.0
80.0
80.0
160.0
50.0
200.0
60.0
25.0
40.0
40.0

48.8
18.3
24.4
24.4
48.8
15.2
61.0
18.3
7.6
12.2
12.2

(ft)

Width
(m)

60.0
120.0
50.0
50.0
50.0
160.0
60.0
80.0
65.0
50.0
80.0

18.3
36.6
15.2
15.2
15.2
48.8
18.3
24.4
19.8
15.2
24.4

May 2011

103-87668

Table 6-9: Maximum Predicted Impacts for HEF Project Only Compared to EPA Class II Significant Impact Levels
EPA Class II
Maximum

Predicted Concentration a
(g/m3)

UTM- East
(m)

UTM- North
(m)

Time Period
(YYMMDDHH)

Impact Levels
(g/m3)

SO2

Annual
24-Hour
3-Hour
1-Hour

0.58
8.1
23.7
29.7

465,800
466,600
466,146
466,000

3,008,900
3,009,400
3,009,372
3,009,200

NA
04090624
02123115
5 Year Avg.

1
5
25
7.9c

PM2.5

Annual
24-Hour

0.43
5.2

466,245
466,524

3,008,772
3,008,768

5 Year Avg.
5 Year Avg.

0.3
1.2

PM10

Annual
24-Hour

1.5
11.2

466,245
466,338

3,008,772
3,008,771

NA
04020324

1
5

NO2 (Tier 1)

Annual

0.63

465,800

3,008,900

NA

1-Hour

53.1

466,000

3,009,200

5 Year Avg.

7.6d

Annual

0.47

465,800

3,008,900

NA

1-Hour

42.5

466,000

3,009,200

5 Year Avg.

7.6d

8-Hour
1-Hour

296.8
562.1

465,900
466,045

3,009,200
3,009,287

04051216
03080116

500
2,000

NO2b (Tier 2)

CO

b
c
d

Significant

Averaging
Time

Pollutant

Receptor Location

Note: YYMMDDHH = Year, Month, Day, Hour Ending


Concentrations are based on concentrations predicted using 5 years of meteorological data from 2001 to 2005 of surface and upper air data
from the National Weather Service stations at Fort Myers Southwest Florida Regional (RSW) Airport and Tampa International Airport, respectively.
A NOx to NO2 converstion factor of 75% applies for the annual averaging time, and 80% for the 1-hour averaging time, based on EPA's Guidline on Air Quality Models.
EPA has not yet defined a significant impact level for SO2 1-hour impacts. However, interim guidance documents suggest a level of 3 ppb (7.9 g/m3).

EPA has not yet defined a significant impact level for NO2 1-hour impacts. However, interim guidance documents suggest a level of 4 ppb (7.6 g/m3).

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-9 - 6-12.xlsm

May 2011

103-87668

Table 6-10: Maximum Predicted Impacts for HEF Project Only Compared to EPA Class I Significant Impact Levels at ENP
EPA Class I
Maximum
Pollutant

Averaging
Time

Predicted Concentration
(g/m3)

For receptors out to 50 km in the direction of ENP


SO2
Annual
0.0091
24-Hour
0.25
3-Hour
0.92

Significant

UTM- East
(m)

UTM- North
(m)

Time Period
(YYMMDDHH)

Impact Levels
(g/m3)

461,174
467,273
466,400

2,959,274
2,959,008
2,959,000

NA
02101724
05011803

0.1
0.2
1.0

PM2.5

Annual
24-Hour

0.0010
0.061

467,273
475,940

2,959,008
2,959,919

5 Year Avg.
5 Year Avg.

0.06
0.07

PM10

Annual
24-Hour

0.0019
0.10

467,273
475,940

2,959,008
2,959,919

NA
05122324

0.2
0.3

NO2 (Tier 1)

Annual

0.0086

461,174

2,959,274

NA

0.1

NO2b (Tier 2)

Annual

0.0064

461,174

2,959,274

NA

0.1

468,145

2,909,015

02101724

0.2

For receptors out to 100 km in the direction of ENP


SO2
24-Hour
0.13

Receptor Location

Note: YYMMDDHH = Year, Month, Day, Hour Ending


Concentrations are based on concentrations predicted using 5 years of meteorological data from 2001 to 2005 of surface and upper air data
from the National Weather Service stations at Fort Myers Southwest Florida Regional (RSW) Airport and Tampa International Airport, respectively.
A NOX to NO2 converstion factor of 75% applies for the annualaveraging time, based on EPA's Guidline on Air Quality Models.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-9 - 6-12.xlsm

May 2011

103-87668

Table 6-11: Maximum Predicted SO2, PM2.5, PM10, and NO2 Impacts for All Sources, Compared to the AAQS

Averaging Time
and Rank

Maximum Concentration (g/m3) a


Modeled
Total
Sources
Background

SO2
24-Hour, HSH
1-Hour, 99th Perc.

54.1
94.7

27.9
76.4

26.2
18.3

465,400
465,400

PM2.5
Annual, Highest 5yr Avg.
24-Hour, 98th Perc. 5yr Avg.

7.5
19.2

1.0
4.5

6.5
14.7

PM10
Annual, Highest
24-Hour, H6H

22.4
72.9

2.4
12.9

NO2 (Tier 1)
1-Hour, 98th Perc. 5yr Avg.

85.7

NO2b (Tier 2)
1-Hour, 98th Perc. 5yr Avg.

77.5

Receptor Location
UTM- East
UTM- North
(m)
(m)

Time Period
(YYMMDDHH)

AAQS
(g/m3)

3,008,600
3,008,600

04092724
NA

260
196.5

465,400
465,400

3,008,600
3,008,600

NA
NA

15
35

20.0
60.0

466,245
466,300

3,008,772
3,008,700

NA
04092024

50
150

40.6

45.1

465,400

3,008,600

NA

189

32.4

45.1

465,400

3,008,600

NA

189

Note: YYMMDDHH = Year, Month, Day, Hour Ending


HSH = Highest, second-highest
H6H = Highest, sixth-highest
a

Concentrations are based on concentrations predicted using 5 years of meteorological data from 2001 to 2005 of surface and upper air data
from the National Weather Service stations at Fort Myers Southwest Florida Regional (RSW) Airport and Tampa International Airport, respectively.
A NOX to NO2 converstion factor of 80% applies for the 1-hour averaging time, based on EPA's Guidline on Air Quality Models.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-9 - 6-12.xlsm

May 2011

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Table 6-12: Maximum Predicted SO2 and PM10 Impacts for All Sources, Compared to the PSD Class II Increments

Averaging Time
and Rank

Maximum
Concentration a
(g/m3)

Receptor Location
UTM- East
UTM- North
(m)
(m)

Time Period
(YYMMDDHH)

PSD Class II
Increment
(g/m3)

SO2
24-Hour, HSH

27.9

465,400

3,008,600

04092724

91

PM2.5
Annual, Highest
24-Hour, HSH

1.1
7.6

465,400
465,700

3,008,600
3,008,900

NA
04092724

4
9

PM10
Annual, Highest
24-Hour, HSH

2.4
9.6

466,245
466,338

3,008,772
3,008,771

NA
02021624

17
30

Note: YYMMDDHH = Year, Month, Day, Hour Ending


HSH = Highest, second-highest
NA = Not Applicable
a

Concentrations are based on concentrations predicted using 5 years of meteorological data from 2001 to 2005 of surface
and upper air data from the National Weather Service stations at Fort Myers Southwest Florida Regional (RSW) Airport
and Tampa International Airport, respectively.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\6\Table 6-9 - 6-12.xlsm

May 2011

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Table 7-1: SO2 Effects Levels for Various Plant Species


Observed Effect
Level
(g/m3)

Exposure
(Time)

Reference

920 (20 percent


displayed visible
injury)

3 hours

McLaughlin and Lee, 1974

200 to 400

6 hr/wk for
10 weeks

Hart, et al., 1988

Cypress, slash pine,


live oak, mangrove

1,300

8 hours

Woltz and Howe, 1981

Jack pine seedlings

470-520

24 hours

Malhotra and Kahn, 1978

1,310

Continuously
for 1 week

Carlson, 1979

Plant Species
Sensitive to tolerant

Lichens

Black oak

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\7\Tables 7-1 - 7-3.docx

May 2011

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Table 7-2 Sensitivity Groupings of Vegetation Based on Visible Injury at Different SO2
Exposuresa
Sensitivity
Grouping

790 - 1,570 g/m


(0.3 - 0.6 ppm)

Plants
3

Sensitive

1,310 - 2,620 g/m


(0.5 - 1.0 ppm)

Intermediate

2,620 - 5,240 g/m3


(1.0 - 2.0 ppm)

1,570 - 2,100 g/m3


(0.6 - 0.8 ppm)

>5,240 g/m3
(>2.0 ppm)

>2,100 g/m3
(>0.8 ppm)

Resistant

SO2 Concentration
1-Hour
3-Hour

Ragweeds
Legumes
Blackberry
Southern pines
Red and black
oaks
White ash
Sumacs
Maples
Locust
Sweetgum
Cherry
Elms
Tuliptree
Many crop and
garden species
White oaks
Potato
Upland cotton
Corn
Dogwood
Peach

Based on observations over a 20-year period of visible injury occurring on over 120
species growing in the vicinities of coal-fired power plants in the southeastern United
States.

Source: EPA, 1982a.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\7\Tables 7-1 - 7-3.docx

May 2011

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Table 7-3:

Examples of Reported Effects of Air Pollutants at Concentrations Below


National Secondary AAQS

Pollutant
Sulfur Dioxidea

Concentration
(g/m3)

Exposure

Respiratory stress in guinea


pigs
Respiratory stress in rats

427 to 854

1 hour

267

Decreased abundance in deer


mice

13 to 157

7 hours/day; 5 day/week
for 10 weeks
continually for 5 months

1,917

3 hours

Reported Effect

Nitrogen
Dioxideb,c

Respiratory stress in mice


Respiratory stress in guinea
pigs

96 to 958

8 hours/day for
122 days

Particulatesa

Respiratory stress, reduced


respiratory disease defenses
Decreased respiratory disease
defenses in rats, same with
hamsters

120 PbO3

continually for 2 months

100 NiCl2

2 hours

Sources: a
b
c

Newman and Schreiber, 1988.


Gardner and Graham, 1976.
Trzeciak et al., 1977.

Y:\Projects\2010\103-87668 Highlands\PSD\Final\Tables\7\Tables 7-1 - 7-3.docx

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