Answers & Solutions Chemistry Part - A: T A A T

Answers & Solutions
Chemistry
Part A
1.
1.
The electron configuration of Cu is :
1s 2s 2p 3s 3p 3d
10
Number of electrons with l = 0 is 6

Number of electrons with l = 2 is 10
Total number of electrons = 16
2.
2.
Phosphorus undergoes sp d hybridization instead of dsp .
3.
3.
t
t
1
2 2
1
2 1
1n
a
2
a1
1n
1 1
8 2

1n
1 1
or,
2 2
or, 1 n = 3 or n = 2
4.
4.
At equilibrium, pX + pY + pZ = 6
Since the concentration of the reacting species are same, p x = py = pz = 2atm
Kp
5.
5.
22
2 atm
2
n n 1
2
6n 4
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Six-different transitions takes place.

n = 4 n = 3, n = 4 n = 2, n = 4 n = 1
n = 3 n = 2, n = 3 n = 1
n=2n=1
The visible region (Balmer series) involves the transitions n = 3 n = 2 and n = 4 n = 2.
6.
6.
Since carbon is more electronegative than hydrogen, the bp - bp repulsion is highest for the two CH
bonds.
7.
7.
It is a zero order reaction for which the half-life is given as :
t1
2
a
t1/2 a (initial concentration of reactant)
2k
8.
8.
SO3 (g) CO(g)

SO2 (g) CO2 (g)
Initial
At Equilibrium
1 0.5
1 0.5
1 + 0.5
1 + 0.5
Kc
1.5 1.5
9
0.5 0.5
34
6 Q KC,
1 2
The reaction will proceed towards forward direction
9.
9.
10.
nRT 4 0.0821 400
13.136 atm
V
10
2
10.
Rate = k[X] [Y]

4 108 = k [0.1] [0.1]
2
4 108
4 105 mol2L2 sec 1
102 101
11.
11.
The reaction is second order with respect to X.
t1/2
1
1
t1/2
Ka
a
12.
AB
12.
Spin-multiplicity = 2S + 1
= 2n
1
1
1 2 3 1 4
2
2
It contains 8 electrons with l = 0 ( 1s2 2s2 3s2 4s2 )

It contains 3 unpaired electrons.
Its magnetic moment =
n(n 2) 3(3 2) B.M.
Its tripositive ion contains 30 electrons which is not the atomic number of any inert gas.
13.
ABC
13.
The corrects structure is:

F
Cl
P
Cl
Cl
F
14.
AB
Sol.
The reaction moves towards forward direction by increasing temperature as it is an endothermic reaction.
Decreasing pressure favours the reaction towards more number of moles.
15.
ABD
Sol.
The concentration of a reactant can be increased to such a label where the change in concentration is
minimum ~ negligible. The order due to this reactant will be zero. Catalyst can change the mechanism
as well as order. Due to similarity in concentration and gas pressure, pressure change can also affect the
order.
Part C
1.
Cl 1s22s22p63s23p5
Sol.
=1
2.
Sol.
N 1s 2s 2p (3 unpaired electron)
2
N2 No unpaired e
O 2 unpaired electrons
O2 2 unpaired electrons
3.
Sol.
3X Y
a
a 3x
At t *X+ = *Y+
a 3x = x a = 4x x = a/4
a t1/ 2 a
t1/ 2
a

2
4
t = 2 t1/2 = 2 4 = 8 sec
4.
8
Sol.
KP pNH3 pHCl 16
pNH3 pHCl ,pNH3 pHCl pequm = 4 + 4 = 8 atm
5.
Sol.
The orbitals that hold electrons are 4s, 4px, 4pz, 4dz2 and 4dxz
Since s = - , the five orbitals will contain one electron each.
Mathematics
Single Correct Choice (01 07)
1.
M120322
1.
4x 3
4x 3
f x 2 sin2
2cos
2
2
6
3
4x 3
4x 3
1 cos
2cos
2
2
3
3
4x 3
1 cos2
2
3
1
8x 6
2 1 cos
2
2
3
3 1
8x 6
cos
2
2 2
3
Period of f x
2.
2 63 33
8
8
4
3 2
M120317
2
2.
1
3 3
9x 3x 1 3 x
2
4 4
For x ,1 ,
3
28
9x 3x 1
.
4
4
3.
M120315
3.
2 x2 3
x x
2
x2 x2 2
2x 3
Also,
or
1
1
x
2
1 1

x x
1
x
Hence,
x2 2
or
x3 2x 1 0
or
x 1 x2 x 1 0
4.
4.
1 e
x 0
M120316
1/ x 1
1 5
2
0 e
1/ x 1
1
x 1
1 0
0
x
x
+
O
x ,0 1,
5.
5.
For x 0 , sin x x
M110603
sin x
1
x
For x 0 , sin x x
sin x
1
x
100x
99 sin x
100 98 198
x
Hence, lim
x 0
sin x
6.
6.
Clearly, R is reflexive and symmetric.
M120306
Let z1Rz2 and z2Rz3
z1 z2
is real, say k
z1 z2
and
z 2 z3
is real, say l
z 2 z3
Now,
z1 z2
z
1 k
k 1
z1 z2
z2 1 k
and
z 2 z3
z
1 l
l 2
z 2 z3
z3 1 l
Thus,
z1 1 k 1 l
z3 1 k 1 l
z1 z3 1 k 1 l 1 k 1 l
z1 z3 1 k 1 l 1 k 1 l
which is real.
7.
M120412
7.
f x x2 3x 2 cos x x 1 x 2 cosx
x 2 3x 2 cos x, x 0
2
x 3x 2 cos x,0 x 1
2
x 3x 2 cos x,1 x 2
x 2 3x 2 cos x, x 2
2x 3 sin x, x 0
2x 3 sin x,0 x 1
f ' x
2x 3 sin x,1 x 2
2x 3 sin x, x 2
It is clear that f(x) is not differentiable at x = 1, since
f ' 1 1 sin1
and
f ' 1 1 sin1
Comprehension Type (08 11)

8.
M120324
8.
Only one positive root

2
y= g(x)
1
y= h(x)
2
1
9.
M120325
9.
a 0, 1/ 2
1/2
10.
10.
In triangle OPR, PR tan
x
1
M110606
T x
x
QR
2
1
1
x
.PR.QR.sin PRQ tan2 sin x
2
2
2
1
x
x 1
sec 2 1 sin x tan sin x
2
2
2 2
S x
1 2
1 2
x sin x
1 x 1 sin x
2
2
2
x
sin x
2
Now, lim
lim
x 0 S x
x 0
x sin x
T x
tan2
2
tan 2 sin x
x
x
1
lim 2
.
x 0
x sin x
4
x3
x sin x 1

lim
3
x 0
6
x
by
L
'Hospital'
srule
.1 3
1
2
4.
6
11.
M120504
11.
S x
x sin x
2
S' x
1 cos x
2
Multi Correct Type (12 15)
12.
ABCD
M120308, M120309, M120317
12.
gof x 2x sin x
1/3
Range of (gof) (x) is R.
13.
ABCD
M120322
13.
Option (a) : Periods of sin x and sin x are 2 and respectively.
Period of f(x) = LCM of 2, 2

Option (b) : Period of g x
Option (c) : Period of h x LCM of 2,2 2
Option (d) : p x x x
1
2
x
3
3
1
2
x x x 11
3
3
10
1
2
11 x x x
3
3
Period of p(x) is 1.
14.
14.
BC
M110609, M110603,M110605,M110607
lim x
lim
x 1 x
x
x 1 x
lim
1
1
x
1
2
x2 x3
... x
x
ln 1 x x
2
3
1
Option (a) : lim

lim
2
2
x 0
x
0
2
x
x
1 cos x
lim
Option (b) : lim
x 0
x 0
x2
x
2 1
2
2
x
4
2
2 sin2
1 x 1
1 x 1
lim
x 0
x
1 x 1
1/2
Option (c) : lim

x 0
Option (d) : lim

x 0
lim
x x 2 2x
15.
AD
15.
f x 1 1 t dt, x 2
1/2
x 0
1 1
1
2
2
x
1
2
M120410
x
2 t dt t dt
1
1 2
x 1
2
1 2
x 1, x 2
We have, f x 2
5x 1, x 2
lim f x 3 and lim f x 11
x 2
x 2
Hence, f(x) is not continuous at x = 2.

11
f 2 h f 2
Rf ' 2 lim
h0
1
2
2 h 1 11
lim 2
h 0
h
2 h
lim
h 0
20
2h

Part C
Integer Type (01 05)
1.
M120411
1.
LHL = VF = RHL
lim f x f lim f x
x
2 x 2
2
lim f h a lim f h
h0
h0
2
lim
1 cosh 1 cosh cos2 h

lim
h 0
3 1 cosh 1 cosh
b 1 cosh
1 cos3 h
a lim
2
h0 3 sin h
h0
4h2
3 2
b
8
2.
2.
Given, f x f y f
or
a lim
b 1 cosh
h0
4h2
b
8
a
M120414
xy
1 xy
Putting x = 0, y = 0, we get f (0) = 0
..(i)
and putting y = x, we get
f x f x f 0 0
f x f x
Now, f ' x lim

h0
.(ii)
f x h f x
h
12
lim
f x h f x
h0
[from Eq. (ii)]
xhx
f
1 x h x
lim
h 0
h
h
2
1 x xh
lim
h 0
h
2
1 x 2 xh . 1 x xh
f ' x
f ' 2
and
f x
2
lim
x 0
x
2
1 x2
2
2
1 4 5
f x 2 tan1 x c
f 0 0 c 0
3.
c=0
f x 2 tan1 x
M110601
3 2 tan
2
3
lim f x lim f 0 h
3.
x 0
lim
h0
sin1 1 0 h .cos1 1 0 h
2 0 h. 1 0 h
h0
lim
sin1 1 1 h .cos1 1 1 h
2 1 h . 1 1 h
h0
lim
sin1 h.cos1 h
h 0
4.
2 1 h .h
2 2
M120322
13
4.
x
is 24
12
The period of sin
x 24
x 24
x
x
sin
sin 2
sin
12
12
12
12
as sin
x
x 2
is 3 and the period of cos
is 8 .
3
4
Similarly, the period of tan
Hence, the period of the given function LCM of (24, 8, 3) = 24.
5.
5.
M120324
x
sin 1 x 2 2x 2
2
2
x
sin 1 x
2
LHS 0 and RHS 0 .

Then solution is obtained if LHS = RHS = 0 and x satisfies both.
Physics
HINTS AND SOLUTIONS
Part-A
1.
C (Concept code: P110216)
Sol.
cos =
Q
R
2.
A (Concept code: P110321)
14
Sol.
v r should be same in both the situations.
vr
vm
Thus, v r 3 2 km/hr.
vm
vr
45
vm
6km/hr = v m
= 3km/hr.
3
3.
Sol.
Let u be the initial speed of the particle

2
v = u 2gh
or
u = v + 2gh
or
u2x u2y = v 2x v 2y 2gh
or
u2y = v 2y 2gh
or
u2y = (2)2 + (2) (10) (0.4) = 12
uy =
and
ux = vy = 6 m/s
or
4.
Then
tan =
(vx = ux)
12 or 2 3 m / s
uy
ux
2 3
1
6
3
= 30
B (Concept code: P110420)
Sol.
n1 = k(l1 l)
where l is its natural length
n2 = k(l2 l)
n1
(l l)
= 1
n2
(l2 l)
On solving,
Now,
l=
n1l2 n2l1
(n1 n2 )
n1 = k[(l1 l)]
= k l1
(n1l2 n2l1 )
(n1 n2 )
15
(n1 n2 )
(l1 l2 )
k=
5.
Sol.
Since, mg cos > mg sin

Force of friction is
f = mg sin
= 2 9.8 sin 30
= 2 9.8
6.
Sol.
Power P = F .v =
1
= 9.8 N
2
K
.v K cons tan t
v
W = P. t = Kt
7.
Sol.
W = Kf Ki =
1
m v 2f vi2
2
2
2
1 1
1

m a2 t 2 a1t1
2 2
2

ma12 4 4
t
1 t 24 2
m 2 a1 a12 t12 Since, a2 2 a1 =
(t 2 t1 )
8 t1
t1
8t12

8.
D (Concept code: P110314)
9.
Sol.
Question number 8, 9: Take components of V and a along X and Y axis. If at time t, velocity is V t .
Then, if V t is to V i . We have V t Vi = 0.
10.

16
Sol.
For just slipping f = 3N
F cos = smg F sin )
s =
Fcos
1
mg Fsin 3
11.
Sol.
Just after t = 4 sec.
Fcos k (mg Fsin )

m
2
1
k
3
4
After t = 4 sec.
Fcos k (mg Fsin )

m
F(cos k sin )
k g
m
19 2
5
(t 16) (t 4)
48
2
At t = 20 sec, v = 112 m/s
12.
BCD (Concept code: P110503)
Sol.
Apply conservation of mechanical energy to obtain x.
13.
Sol.
BC (Concept code: P110413)

PQ = 2R
a = g cos
u = 2(g cos ) (2R)
2
u = 2 gRcos
t=
u 2 gR cos
R
2
a
gcos
gcos
In reaching upto centre.

17
2gRcos .
u = 2 (g cos ). R =
2
14.
Sol.
AC (Concept code: P110512)

Umin = 20 5 = 15 J
Kmax = E Umin = 20 15 = 5J
Umin is at sin (4x) = 1
4 =
x=
15.
Sol.
3 7
,
2 2
3 7
, ,.....
8 8
CD (Concept code: P110303)

As going up, speed of the particle is decreasing and hence time taken
in crossing the windows
(if S1 = S2 = S3) will be t1 < t2 < t3.

u = ua t
Since,
u t (as acceleration is same)

u1 < u2 < u3
So,
(as for equal windows t1 < t2 < t3)

For unequal windows,
t1 = t2 = t3 if S3 < S2 < S1.
Part-C
1.
6 (Concept code: P110412)
Sol.
For equilibrium of block
rod
m
Mg sin = (N)
= 0.5
= (Mg cos + mg cos )

37
18
2.
Sol.
a=
3.
Sol.
As stable equilibrium, U is minimum. Thus
21
6 21
, TB = 6a =
= 9 N.
14
14
And
d2U
> 0.
dx 2
dv
= 0.
dx
1 x3 ax 2
20x = 0.

dx 3
2
x 9x + 20 = 0. (x 5) (x 4) = 0.
2
x = 5 and x = 4 are points of equilibrium.

And U minimum when
d2U
> 0. i.e. at x = 5.
dx 2
4.
Sol.
Draw FBD of rod and apply condition of equilibrium.
5.
Sol.
P = F V = mv
dv 3t
dt 2
3t 2
dt
2
0
m v dv
0
V = 2 ms

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Answers & Solutions

The electron configuration of Cu is :

Number of electrons with l = 0 is 6

Phosphorus undergoes sp d hybridization instead of dsp .

Six-different transitions takes place.

It is a zero order reaction for which the half-life is given as :

SO3 (g) CO(g)

The reaction will proceed towards forward direction

nRT 4 0.0821 400

Rate = k[X] [Y]

The reaction is second order with respect to X.

It contains 8 electrons with l = 0 ( 1s2 2s2 3s2 4s2 )

n(n 2) 3(3 2) B.M.

The corrects structure is:

Clearly, R is reflexive and symmetric.

Let z1Rz2 and z2Rz3

Comprehension Type (08 11)

Only one positive root

In triangle OPR, PR tan

sec 2 1 sin x tan sin x

Multi Correct Type (12 15)

M120308, M120309, M120317

Range of (gof) (x) is R.

Option (a) : Periods of sin x and sin x are 2 and respectively.

Period of f(x) = LCM of 2, 2

Option (a) : lim

Option (c) : lim

Option (d) : lim

Hence, f(x) is not continuous at x = 2.

1 cosh 1 cosh cos2 h

Putting x = 0, y = 0, we get f (0) = 0

and putting y = x, we get

Now, f ' x lim

[from Eq. (ii)]

The period of sin

Similarly, the period of tan

Hence, the period of the given function LCM of (24, 8, 3) = 24.

LHS 0 and RHS 0 .

C (Concept code: P110216)

A (Concept code: P110321)

v r should be same in both the situations.

C (Concept code: P110313)

Let u be the initial speed of the particle

u2x u2y = v 2x v 2y 2gh

u2y = (2)2 + (2) (10) (0.4) = 12

B (Concept code: P110420)

A (Concept code: P110410)

Since, mg cos > mg sin

C (Concept code: P110504)

B (Concept code: P110502)

D (Concept code: P110314)

A (Concept code: P110314)

B (Concept code: P110411)

For just slipping f = 3N

F cos = smg F sin )

C (Concept code: P110412)

Just after t = 4 sec.

Fcos k (mg Fsin )

Fcos k (mg Fsin )

At t = 20 sec, v = 112 m/s

BCD (Concept code: P110503)

Apply conservation of mechanical energy to obtain x.