Beruflich Dokumente
Kultur Dokumente
Departamento de Ingeniera Metalrgica, Facultad de Ingeniera, Universidad de Santiago de Chile, Avenida Libertador
Bernardo OHiggins 3363, Casilla 10233, Fono: 56-2-7183224, Santiago, Chile
2
Departamento de Ingeniera Qumica, Facultad de Ingeniera, Universidad de Santiago de Chile, Santiago, Chile
3
Departamento de Ingeniera Mecnica, Facultad de Ingeniera, Universidad de Santiago de Chile, Santiago, Chile
4
Departamento de Ingeniera Metalrgica, Universidad Catlica del Norte, Avenida Angamos 0610, Antofagasta, Chile
*
gerardo.cifuentes@usach.cl
I. INTRODUCTION
In the processes for obtaining de copper by
pyrometallurgy, a fundamental stage is the electrorefining of
impure copper anodes (98-99.8% de Cu). In this stage by
applying a potential difference, the copper present in the
anode is dissolved electrochemically in the electrolytic
solution, and is deposited on a stainless steel or pure copper
cathode. At the same time, some of the impurities contained
in the anode (As, Sb, Bi, S, Fe, Zn, Ni, Co) are dissolved in
the electrolytic solution and the rest of those impurities (Ag,
Se, Te, Pb) do not go into the solution and precipitate as
anode slime. In turn, as a result of matter transfer
mechanisms, physical contamination of the pure copper
cathodes occurs (occlusion of solids), affecting the electric
properties of the copper and the quality of the pure copper
cathodes [1].
1.
2.
3.
4.
B. Breakthrough Curve
The continuous path of a concentrated solution with an
element of interest (Sb) through a fixed bed (porous) of
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where:
N Li k Li AL C Li C Li
(2.1)
C Li* :
N Si k Si AS CSi CSi
(2.2)
where:
volume of resin.
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(2.3)
we have
A
As L
1
(2.4)
1
(2.5)
N Si
N Li
1
Substituting Equations (2.1) and (2.2) in (2.5) we get
k A C Li C Li*
N Si k Si AS C Si* C Si Li L
1
(2.6)
Input U f S C Li | z
Output U f S C Li | z dz
Accumulation
Generation 0
C Li S dz
t
U f
(3.1)
where:
C Li 1
C Li
N si
t
z
(3.4)
Input 1 N Si Sdz
Output 0
Generation 0
Accumulation
N Si 1 Sdz
U f
C Li k Li AL
C Li
C Li C Li*
t
z
(3.5)
1 CSi Sdz
t
C Si k Li AL
C C*
1 Li Li
t
C Li
C Li k Li AL
C Li C Li*
U f
t
z
(3.3)
(3.5)
N Si
C Si
t
(3.2)
C Si k Li AL
C Li C Li*
1
t
(3.3)
e S CL0
t* t z
U
f
(3.6)
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k
CSi
la Li C Li C L*
*
t Z 1
C Li
D. Experimental Validation
la Li C Li C Li*
Uf
t*
(3.7)
(3.8)
for
t* 0
CSi 0
for all
z0
CL 2 :
for
z0
C Li C L 0
for all
t* 0
(3.9)
C Li
C L0
m C Si
C L0
(3.11)
(3.12)
m t * k la Li
1
where
CL0 = initial solute concentration in the fluid;
m = equilibrium isotherm constant;
z = height of the resin bed;
kla = volumetric matter transfer coefficient.
(3.13)
X
X Y
CL2 :
for
0
0
X 1
H+
[g/L]
0.2167
39.4
0.174
9.76
220
Resin
MX-2
UR-3300S
Duolite C-467
t [h]
Sb [kg/m3]
Sb [kg/m3]
Sb [kg/m3]
0.0296
0.0366
0.0398
0.1025
0.0544
0.1085
0.1071
0.0615
0.1170
0.1095
0.0616
0.1139
0.1195
0.0605
0.1175
0.1198
0.0611
0.1186
0.1201
0.0617
0.1191
0.1201
0.0619
0.1189
(3.15)
Y 0
As
[kg/m3]
(3.14)
Y
X Y
for
Fe
[kg/m3]
C L1 :
Cu
[kg/m3]
(3.10)
z S k la Li
Uf
Sb
[kg/m3]
(3.16)
J0 2i d
CLi t CL0 1 e
0
(3.17)
J 0 2 i
e
0
1 e
C Li ( t ) f correction C L 0
(3.18)
This equation was programmed in MATLAB in order
to generate the modeled and simulated breakthrough curve.
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f correction
% Error
MX-2
0.5531
3.72
UR-3300S
0.2839
2.94
Duolite C-467
0.5455
2.38
k La
MX-2
UR-3300S
Duolite C-467
[kg/m3 h]
0.0238
0.0431
0.0257
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ACKNOWLEDGEMENTS
The authors acknowledge the support of DICYT of the
Universidad de Santiago de Chile, Usach
REFERENCES
[1] K. Biswas, W.G. Davenport, Extractive Metallurgy of Copper;
[3]
UR-3300S
k la
[kg/m3h]
Vr
[m3]
[4]
CSb
[kg/m3]
0.0431
0.0001078
0.2167
0.0517
0.0002
0.3
0.0560
0.0003
0.5
[5]
[6]
III. CONCLUSIONS
[7]
[8]
[9]
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