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PCM

ART A - PHYSICS

3. A dielectric slab of thickness d is inserted in a


parallel plate capacitor whose negative plate is

1. Two capacitors C1 and C2 are charged to 120V

x = 0 and positive plate is at x = 3d. The slab is

and 200V respectively. It is found that by

equidistant from the plates. The capacitor is

connecting them together the potential on each

given some charges. As we go from o to 3d,

one can be made zero. Then,

potential difference variation is

a) 5C1 = 3C2

b) 3C1 = 5C2

c) 5C1 + 3C2 = 0

d) 9C1 = 4C2

2. A parallel plate capacitor is made as follows

a)

b)

c)

d)

capacitance of the arrangement is

4. In the circuit given,

a)

0 Kab
d

0 Kab
c)
b

b)

0 Kab
2d

d)

0 Kab
2b

The charge and potential difference across 8P


PF
capacitor will be respectively
a) 320.P
PC, 40V
c) 214.P
PC, 27V

b) 420.P
PC, 50V
d) 360.P
PC, 45V

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5.

Three identical capacitors are charged by


connecting them in parallel across a battery of

a) the charge q will be there at outer surface A

V volt. They are then allowed to discharge via

b) the charge

resistor R1, R2 and R3. Here, Q charge versus t

c) the charge -q will be at inner surface of B

time graphs are shown. Then,

d) the charge q (1 b/c) will be there at outer

bq
will be there at outer surface A
c

surface of C
7. The graph of current versus time in a wire is
given by

6.

a) R1 is smallest

b) R2 is smallest

c) R3 is smallest

d) R3 > R2 > R1

The given figure shows three concentric thin


spherical shells A,B and C of radii a,b and c.
The shells A and C are given charges q and -q
respectively, and shell B is earthed. Then
choose the wrong option.

If charge that flows through a wire in 7.5s is q1


and that flows through the wire in 15s is q2,
then ratio q1 : q2 is
a) 2 : 1

b) 1 : 2

c) 4 : 1

d) 1 : 4

8. Current flows through the given conductor.


Which of these quantities remains constant
throughout the complete length of a conductor?

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a) current
c) electron mobility

b) current density
d) electric field

9. V-l graph for a conductor at temperatures

a) RAB = R
c) RAB =

T1 and T2 are given by

3R
2

b) RAB =

R
2

d) RAB =

5R
2

11. Eight cells marked 1 to 8 each of emf 5V and


internal resistance 0.2:
: are connected as
shown in the figure. What is the reading of the
ideal voltmeter V?

Then (T2 T1) is proportional to


a) cos 2T
T
c) cot 2T
T

b) sinT
T
d) tanT
T

10. If twelve resistors each of 5:


: are connected
between points A and B, then

a) 40 V

b) 20 V

c) 5 V

d) zero

12. For the given circuit,

If internal resistance of cell is 1.5:


:, then

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a) VP VQ = 0
c) VP VQ = 4V

b) VP VQ = 4V
d) VP VQ = 2.5 V

15. A 100 W bulb B1, two 60 W bulbs B2 and B3 are


connected to a 250 V source as shown. If W1, W2
and W3 are powers of the bulbs, then

13. In a large building, there are 15 bulbs of 40W, 5


bulbs of 100W, 5 fans of 80W and 1 heater of
1kW. The voltage of the electric mains is 220
V. The minimum capacity of the main fuse of
the building will be
a) 8 A

b) 10 A

c) 12 A

d) 14 A

14. A meter bridge is set-up as shown in the figure,


to determine an unknown resistance X using

a) W1 > W2 = W3

b) W1 > W2 > W3

c) W1 < W2 = W3

d) W1 < W2 < W3

a standard 10:
: resistor. The galvanometer
shows null point, when tapping-key is at 52 cm

16. A particle with a charge Q moving with a

mark. The end corrections are 1cm and 2cm

normally. The magnetic field has magnitude B

respective for the ends A and B. Then determine

and is confined to a region of width d, where

the value of X is

momentum p enters a uniform magnetic field

d<

p
. The particle is deflected by an angle T
BQ

in crossing the field.

a) 10.2 :
c) 10.8 :

b) 10.6 :
d) 11.1 :

a) sin T =

BQd
p

b) sin T =

p
BQd

c) sin T =

Bp
Qd

d) sin T =

pd
BQ

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17. A current i flows around a closed path in the


horizontal plane of the circle as shown in the

18. A conducting wire bent in the form of a parabola


y2 = 2x carries a current i = 2A as shown in

figure. The path consists of eight arcs with

figure. The wire is placed in a uniform magnetic

alternating radii r and 2r. Each segment of arc

field B = 4k T

subtends equal angle at the common centre P.


The magnetic field produced by current path at
point P is

The magnetic force on the wire is

a)

b)

3 P 0i
.
; perpendicular to the plane of the
8 r
paper and directed inwards
3 P 0i
.
; perpendicular to the plane of the
8 r

a) 16 i

b)

32 i

c) 32 i

d) 16 i

19. A loop carrying current i lies in the XY-plane as


shown in the figure. The unit vector k is coming
out of the plane of the paper. The magnetic
moment of the current loop is

paper and outwards


c)

1 P 0i
.
; perpendicular to the plane of the
8 r
paper and inwards

d)

1 P 0i
.
; perpendicular to the plane of the
8 r
paper and outwards
2
a) a I k

b)

S 2
+1 a I k
2

S 2
c) +1 a I k
2

d)

2S +1 a 2 I k

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20. A moving coil galvanometer has 150 equal


division. Its current sensitivity is 10 div/mA

the region, the emf induced across the ends of


the rod is

and voltage sensitivity is 2 div/mV. In order that


each division read 1V, the resistance (in ohm)
needed to be connected is series with the coil
is
a) 99995
3

c) 10

b) 9995
d) 105

21. For the figure, B is flux density inside a sample


of unmagnetised ferromagnetic material varies
with B0, the magnetic flux density in which the

a)

2BZl 3
2

b)

3BZl 3
2

c)

4BZl 2
2

d)

5BZl 2
2

sample is kept. For the sample to be suitable


for making a permanent magnet

23. A conducting square loop of side L and


resistance R moves in its plane with a uniform
velocity v perpendicular to one of its sides. A
magnetic induction B, constant in time and
space pointing perpendicular and into the plane
of the loop exists everywhere.

a) OQ should be large, OR should be small


b) OQ and OR should both be large
c) OQ should be small and OR should be large
d) OQ and OR should both be small
22. A metallic rod of length l is tied to a string of
length 2l and made to rotate with angular speed
Z on a horizontal table with one end of the string
fixed. If there is a vertical magnetic field B in

The current induced in the loop is


a) BvL/R, clockwise
b)

BvL
, anti-clockwise
R

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c)

a) after a long time internal potential


difference across capacitor and inductor will

2BvL
, anti-clockwise
R

be zero

d) zero

b) after a long time internal charge on


24. A rod of length 10cm made up of conducting and

capacitor will be EC

non-conducting material (shaded part is

c) after a long time internal current in the

non-conducting). The rod is rotated with

E
R
d) after a long time internal current through

constant angular velocity Z rad/s about point


O, in a constant magnetic field 2T as shown in

inductor will be

the figure. The induced emf between the point

battery will be same as the current through

A and B of rod will be

it initially
26. A triangular wire frame (each side = 2m) is
placed in a region of time variant magnetic field
having

dB
= 3 T / s . The magnetic field is
dt

perpendicular to the plane of the triangle. The

base of the triangle AB has a resistance 1 :


while the other two sides have resistance 2:
:
each. The magnitude of potential difference
between the points A and B will be
a) 0.029 V

b) 0.1 V

c) 0.051 V

d) 0.064 V

25. In the circuit shown in figure, switch S is closed


at t = 0. Then,

a) 0.4 V

b) 0.6 V

c) 1.2 V

d) None of these

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27. What is the mutual inductance of a two loop


system as shown with centre separation l ?

a)

P 0 Sa
8l 3

b)

P 0 Sa
4l 3

d)

P 0a 4
2l 3

P 0 Sa 4
c)
6l 3

c) 500 PF

d) 200 PF

c) zero

d) 4.8 V

of 120:
: has angular resonance frequency
3
4 u 10 rad/s. At resonance, the voltage across

capacitance of the circuit is equal to

b) 300 PF

b) 10 V

30. A series L-C-R circuit containing a resistance

28. The power factor of the circuit is 1/ 2 . The

a) 400 PF

a) 2 V

resistance and inductance are 60V and 40V,


respectively. The values of L and Care
respectively.
a) 20mH,

25
PF
8

b)

2 mH,

1
PF
35

c) 20 mH,

1
PF
40

d)

2 mH,

25
PF
8

29. An AC circuit having supply voltage E consists


of a resistor of resistance 3:
: and an inductor
of reactance 4:
: as shown in the figure. The
voltage across the inductor at t = T/2 is

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PART B - CHEMISTRY

a) I
b) II

31. Sodium chloride dissolves in dimethy

c) II

sulphoxide (DMSO) a polar aprotic solvent

d) all are equally stable

because of
a) hydrogen bond

b) cation-dipole force

c) anion-dipole force

d) all the three

36. Which of the following is most basic compound.


a) Dimethylamine

b) Diethylamine

c) Propylamine

d) Diphenylamine

32. Which of the following is aprotic nonpolar


37. Which of the following undergoes nitration fast?

solvent?
a) liquified NH3

b) (CH3)2 S = O

c) CCl4

d) HCON (CH3)2
a)

b)

c)

d)

33. The central atom of which of the following does


not use HO? (Hybrid orbital)
a) H2S

b) PH3

c) Both (a) and (b)

d) None of (a) and (b)

34. 2, 4, 6-Trinitroiodobenzene has C-N bonds

38. The kind of delocalization involving W bond


orbital is called
labelled as a, b and c. The

a) Inductive effect
b) Mesomeric effect
c) Hyperconjugation effect

correct bond length of the three bonds is


a) a = b = c

b) a > b > c

c) a = b > c

d) a = b < c

d) Electromeric effect
39. Which one of the following compounds would
have the highest heat of hydrogenation ?

35. Which of the following is more stable?

a) (CH3) CH = C(CH3)2
b) CH3 CH2 CH = CH2
c) H3C CH = CH CH3
d) (CH3)2 C = C(CH3)2

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40. In the following compounds, the least basic is

a)

b)

42. The most acidic among the following is

a)

b) H2O

c) H3+ O

d) CH3 OH

43. Anti-aromatic species posses which of the

c)

d)

following S electrons
a) 4n

b) 4n 1

c) 4n + 1

d) 4n + 2

44. The reaction > C = O + H2NOH o > C = NOH +


H2O is an example of
a) Radical Substitution reaction
b) Addition reaction
c) Elimination reaction
41. Of the following compounds the least basic is

d) Addition followed by elimination reaction


45. Which of the following will undergo hydrolylsis
fastest?

a)

b)

a) (CH3)3 CBr

b) CH3Br

c) CH3CH2Br

d) (CH3)2 CHBr

46. In the reaction

c)

d)
the product is

a)

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b)

PCM

11

c)

increasing order of the reactivity of three


compounds towards dehydration is

d)

a) iii, i, ii

b) ii, i, iii

c) i, iii, ii

d) i, ii, iii

47. The most stable carbonium ion is


52. W hich of the following will not show

a) Tertiary carbonium ion


b) Methyl carbonium ion
c) Secondary carbonium ion

hyperconjugation?

d) Primary carbonium ion

b) (CH3)2 CH CH = CH2

a) CH3 CH = CH2
c) (CH3)3 C CH = CH2

48. Which of the following is the least stable

d) CH3 CH2 CH = CH2

carbonium ion?

a) C6 H5 C H2
c)

CH3

CH

53. Which of the following group will be meta

b)

CH2 = C H

d)

CH3 C H2

49. Which of the following is the most stable


carbanion?
b)

CH3

d)

CH

a) Cl

b) NH2

c) CH3

d) CHO

54. Among the three possible isomers of dibromo


benzenes, the highest melting point is

a) C6 H5 C H2
c)

directing and deactivationg

CH3

possessed by

a) Odiromobenzene

CH3 CH2

b) p-dibromobenzene
c) m-dibromobenzene

50. In the acid-catalyzed dehydration of alcohol to

d) bromobenzene

alkene, the reactive intermediate is


a) Free radical

b) Carbanion

c) Carbocation

d) Hydronium ion

55. When N+(CH3)3 group is attached to the benzene


ring, it orients the incoming electrophile into
a) metaposition

51. Consider the following compounds

b) orthoposition

i) CH3CH2CH2CH2OH

c) paraposition

ii) CH3CH2CH(OH)CH3

d) equally directs group to ortho-para position

iii) (CH3)3COH
These compounds are dehydrated by treatment
with sulphuric acid. The correct sequence of

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56. Which of the following represents correct order

60. Nonaromatic species among the following is as

of stability of free radicals?


a) 30 > 10 > 20 > vinyl
0

a)

b)

c)

d)

b) 1 > 2 > 3 > vinyl


c) 30 > 20 > 10 > vinyl
d) vinyl > 30 > 20 > 10
57. Which of the following behaves as an ambiphilic
reagent ?
a) H2O

b) CH3CHO

c) CH3CN

d) All of these

58. Best leaving group among the following :


NH2

a) F

b)

c) OH

d) F3CSO2O

59. Least acidic among the following compounds is

a)

b)

c)

d)

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13

PART C - MATHS
t
66. xlof
61. If l t

x o0

ln 1 + x ax
= l, then a + l is
x2

1
a)
2

b)

c) 1

d) 2

2x

x+

8x 7

x + 5 + 5 3x + 4

a) e

1x

dy
+ ecot1x, then dx

x/2

b)

c) 1 ex/2

1
2

c)

is equal to
x =0

1 ex
2

is equal P

b) an irrational no

1
2

d) 1

1+sin x
dy
S
; x , S , then
is
1 sin x
dx
2

a) 1
c)

d) 1 e

x 5
=
f
x
63. Let

3x 2

a) 1

1
67. If y = tan

62. If y = esin

b) 1

1
2

d)

1
2

68. Let f : R oR


o be defined by

1
sin
; x ! 5
x 5
x =5

x x
f x
x 2
If xlota f x

;
;

x Q
x Q

exist, then the range of a is

If f (x) is continuous at x = 5, then, complete

(where [.] denotes greatest integer function)

range of k is

a) (2, 3)

b) [2, 3)

c) (2, 1)

d) (1, 2)

a) (0, 1)

b) [0, 1)

c) (0, f)

d) (1, f]

x + 3x + O x + 5 ;
64. If f x =
3x P
;

x2
1
69. If y = sin ln
, then
2

x 1
x t1

is differentiable for all x


R, then |1 P| is
a) 4
b) 6
c) 2

d) 0

xy1

x 2 2
ln
1

a) 2

b) 2

c) 4

d) 4

is

65. If f (x) = (x2013 + 1)|x2 2x 3|


+ sin|x + 1|+ cos|x 1|
a) 2 points

b) 3 points

c) 9 points

d) 1 point

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1
1
t n 1 +
+ 31
2 is equal to
70. nlof
2n
3n

a)

1
4

b)

5
4

c)

5
36

d)

13
36

d 2 x dy d 2y dy
2
2
d y dt dt dt dt
=
d)
3
dx 2
dy

dt
2

73. A twice differentiable function f (x) is such that


f(xy), f(x) f(0) & f(x+y) are in A.P for x,y R and

2 x
71. The point(s) of discontinuity of f x =

1 + x

f(0) z 0 then
i) f(x) is an even function

tion)

ii) f cc(2)
f cc(1)
= 0
cc
cc
iii) f c (2) + f c(2) z 0
iv) f(0) = 2

a) at x = 1

a) TFTF

b) TTFT

b) at x = 0

c) FFTF

d) TTFF

is (where [.] denotes greatest of integer func-

c) at x = 0, 1
d) continuous for all x
72. The second order derivative of a single valued

5tan x sin x
74. xlot0
is equal to (where [.] denotes
x2

function parametrically represented by x = f(t)

of greatest integer function)

and y = g(t), where f(t) and g(t) are differentiable

a) 4

b) 5

function and f c(t) z 0 is given by

c) 2

d) 1

dx d 2y d 2 x dy

d y dt dt 2 dt 2 dt
=
a)
3
dx 2
dx

dt

75. Let f (x) = x [sinx] [x] then f (x) (where [ . ]

d 2y
=
dx 2

a) discontinuous at x = 0
b) continuous at x = 0 but not differentiable

dx d y d x dy

2 2

dt dt dt dt
2

b)

denotes greatest integer function) is

dx

dt

there
c) differentiable at x = 0
d) twice differentiable at x = 0

d 2 x dy dx d 2y

d 2y dt dt dt dt
=
c)
3
dx 2
dx

dt

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76. Let f (x) and g(x) are two polynomials such that
f x
xof g x

= 5 then xlotf

lt

g x

of

1
a)
3
c)

is equal to

f x

b) 5

1
5

80. If tangent to the curve f (x) = x3 Dx2 x + E at


point (1, 3) on the curve, cut equal non zero intercepts on co-ordinate axes, then
a) D + E=
E 6

b) D E=
E 3

c) D E=
E 27

d)

E
=6
D

d) does not exist


81. Let f(1) = a, f(3) = a2 and f c (x) d 6  x [1, 3],
then greatest possible value of a is

77. f x =

e4 x + e3 x +1
, then f c(S
S) is equal to
e2x ex +1

a) eS(1 + 2eS)

b) e4SS + 2e2SS

c) eS (1 2eS)

d) e S

a) 2

b) 4

c) 5

d) 6

82. Set of values of x in which f (x) = |x2 5x 6|is


monotonic is

78. If f 2(n + 1) =

1
2

x +

64
f x

, n
N and

f(n) > 0  then l t f n


n of

is equal to

a) 4

b) 8

c) 2

d) 64

79. Let f x = ln e tan

ex

a)

e tan

ex

b)

c)

e
1  e2x

d)

c) (3, 6)

d) (5, 7)
x t0
x  0 is increasing 

x R then number of integral values of a is


a) infinite
b) 1

1
2 e tan

c) 2

d) 0

84. If f (x) is continuous and strictly decreasing


1

ex

function such the f (2) = 3, then solution set of


f (x2 x) > 3 is

ex

b) (2, 3)

ax sin x  1 ;
83. f x a x
;

, then f c(x) is equal to

ex

a) (2, 2)

2 1  e2 x

a) (1, 2)
c) (2, f)

b) (1, f)
d) (f
f, 1)

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85. In a trapezium ABCD, if rate of change in area


of trapezium is eighteen times the rate of

88. Value of

d 2y
at (1, 1) for the curve given by
dx 2

change in CD, then at the same instant rate of

2x3 4y3 + 5x2y 3xy2 = 0 will be

change of T is

a) 1

b) 0

c) 1

d)

a) 5 times to the rate of the change in CD


b) equal to the rate of change in CD

1
5

times to the rate of change in CD

2 4
86. The normal at , to the curve g = f(x) which
3 5
is defined parametrically as x =

2t 2
2t
,y =
1 + t2
1 + t2

intersect the curve again at

2 4
a) ,
5 5

b)

8 4
,
5 5

2 4
c) ,

5 3

d)

9 8
,
5 5

89. Let f be a twice differentiable function such that


f (1) = 3, f (2) = 2, f (3) = 1, then identify the
correct statement.

1
c)
times to the rate of change in CD
5
d)

a) f cc(x)
cc = 1 for atleast two x (1, 2)
b) f cc
cc(x) = 0 for atleast one x (1, 3)
c) f cc(x)
= 0 for atleast one x (1, 2)
cc
d) f cc
cc(x) = 0 for atleast one x (2, 3)
90. If for f (x) = x3 + ax2 + bx, Rolles theorem holds
in the interval [1, 2] at x =

4
, then the value of
3

a + b is
a) 3

b) 0

c) 3

d) 5

87. If f (x) = 3 sin x 4 cos x 5ax + 2 is an increasing function  x R then


a) a > 1
b) a d1
d
c) a d1
d
d) a = 5

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