Date 28/05/2011

XII

SEEDS INSTITUITE

Class

Solution
DPP
1. On dissolving 10.8 g glucose (m.w. = 180) in 240 g of water its boiling point increase by
0.130C. Calculate the molecular elevation constant of water.
2. A solution of 2.5 g of a non volatile sold in 100 g benzene boiled at 0.42 0C higher than the
boiling point of pure benzene. Calculate the molecular mass of the substance. Molal elevation
constant of benzene is 2.67 K kg mol-1 .
3. The molal elevation constant for water is 0.56 K kg mol -1. calculate the boiling point of a
solution made by dissolving 6.0 g of urea (NH 2CONH2) in 200 g of water.
4. By dissolving 13.6 g of a substance in 20 g of water the freezing point decreased by3.7 0C.
Calculate the molecular mass of the substance. [ Molal depression constant for water = 1.863 K
kg mol-1.]
5. On dissolving 0.25 g of a non volatile substance in 30 mL benzene (density 0.8 g/mL), its
freezing point decrease by 0.400C. Calculate the molecular mass of non volatile substance
( Kf = 5.12 K kg mol-1)
6. A solution of 1.25 certain non volatile substance in 20 of water freezes at 271.94 K.
Calculate the molecular mass of the solute. [( Kf = 1.86 K kg mol-1]
7. Two element A and B from compounds having molecular formula AB 2 and AB4. When
dissolving in 20.0 g of benzene 1.0 g of AB 2 lowers the freezing point by 2.30C, whereas 1.0 g of
AB4 lowers the freezing point by2.3 0C. the molal depression constant for benzene in 1000 g is
5.1. Calculate the atomic masses of A and B.
8. 1.355 g of a substance dissolved in 55 g of CH3COOH produced a depression in the freezing
point of 0.6180C. Calculate the molecular weight of the substance (K f = 3.85 ).
9. An aqueous solution of a non volatile solute boils at 100.17 0C. At what temperature will the
solution freeze?
[Given: kb = 0.512 K kg mol-1 and Kf = 1.86 K kg mol-1]
10. 18 g of glucose, C6H12O6 is dissolved in 1 kg of water in a saucepan. At what temperature
will the water boil (1.013 bar pressure)? Kb for water is 0.52 K kg mol-1 .
11. A solution of urea in water gas boiling point of 100.15 0C. Calculate the freezing point of the
same solution if Kf and Kb for water are 1.87 K kg mol-1 and 0.52 K kg mol-1 respectively.
12. In a cold climate water gets frozen causing damage to radiator of a car. Ethylene glycol to
antifreezing agent. Calculate the amount of ethylene glycol to be added to 4 kg of water to
prevent it from freezing at 60C. [Kf for water = 1.85 k mold-1 ]
13. A solution containing 0.2563 g of naphthalene (molecular mass = 128) in 50 g of carbon
tetrachloride yields a boiling point elevation of 0.201 0C while a solution of 0.6216 g of an
unknown solute in the same mass of the solvent gives a boiling point elevation of 0.647 0C. Find
the molecular mass of the unknown solute.
14. Calculate the molal depression constant of a solvent which has freezing point 16.6 0C abd
latent of fusion 180.75 J g-1 .

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