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Revision Number 1
1. Identification
Product Name
Valeraldehyde
Cat No. :
Synonyms
Recommended Use
Laboratory chemicals.
No Information available
Uses advised against
Details of the supplier of the safety data sheet
Company
Fisher Scientific
One Reagent Lane
Fair Lawn, NJ 07410
Tel: (201) 796-7100
2. Hazard(s) identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Flammable liquids
Acute Inhalation Toxicity - Vapors
Skin Corrosion/irritation
Serious Eye Damage/Eye Irritation
Skin Sensitization
Specific target organ toxicity (single exposure)
Target Organs - Respiratory system.
Category 2
Category 4
Category 2
Category 1
Category 1
Category 3
Label Elements
Signal Word
Danger
Hazard Statements
Highly flammable liquid and vapor
Harmful if inhaled
Causes skin irritation
Causes serious eye damage
May cause respiratory irritation
May cause an allergic skin reaction
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Precautionary Statements
Prevention
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Wash face, hands and any exposed skin thoroughly after handling
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Take precautionary measures against static discharge
Contaminated work clothing should not be allowed out of the workplace
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
If skin irritation or rash occurs: Get medical advice/attention
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor/physician
Fire
Explosion risk in case of fire
Fight fire with normal precautions from a reasonable distance
Evacuate area
Storage
Store locked up
Store in a closed container
Store in a well-ventilated place. Keep cool
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified
CAS-No
110-62-3
Weight %
>95
4. First-aid measures
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Obtain medical attention.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.
Inhalation
Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth
resuscitation if victim ingested or inhaled the substance; induce artificial respiration with a
respiratory medical device. Obtain medical attention.
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Breathing difficulties. . Inhalation of high vapor concentrations may cause symptoms like
headache, dizziness, tiredness, nausea and vomiting
Treat symptomatically
Notes to Physician
5. Fire-fighting measures
Suitable Extinguishing Media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Cool closed
containers exposed to fire with water spray.
No information available
Flash Point
Method -
12 C / 53.6 F
No information available
220 C / 428 F
Autoignition Temperature
Explosion Limits
No data available
Upper
No data available
Lower
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of
ignition and flash back.
Hazardous Combustion Products
Carbon monoxide (CO) Carbon dioxide (CO2)
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Thermal decomposition can lead to release of irritating gases and vapors.
NFPA
Health
3
Flammability
3
Instability
0
Physical hazards
N/A
Environmental Precautions
Ensure adequate ventilation. Use personal protective equipment. Remove all sources of
ignition. Take precautionary measures against static discharges. Avoid contact with skin,
eyes and clothing.
Should not be released into the environment. See Section 12 for additional ecological
information. Do not flush into surface water or sanitary sewer system.
Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.
Up
Ensure adequate ventilation. Wear personal protective equipment. Do not get in eyes, on
skin, or on clothing. Avoid ingestion and inhalation. Keep away from open flames, hot
surfaces and sources of ignition. Use only non-sparking tools. Use explosion-proof
equipment. Take precautionary measures against static discharges. To avoid ignition of
vapors by static electricity discharge, all metal parts of the equipment must be grounded.
Storage
Flammables area. Keep away from heat and sources of ignition. Keep container tightly
closed in a dry and well-ventilated place. Keep refrigerated.
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Component
Valeraldehyde
Component
Valeraldehyde
ACGIH TLV
TWA: 50 ppm
OSHA PEL
(Vacated) TWA: 50 ppm
(Vacated) TWA: 175 mg/m3
NIOSH IDLH
TWA: 50 ppm
TWA: 175 mg/m3
Quebec
Ontario TWAEV
TWA: 50 ppm
TWA: 50 ppm
TWA: 176 mg/m3
Legend
ACGIH - American Conference of Governmental Industrial Hygienists
OSHA - Occupational Safety and Health Administration
NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health
Ensure that eyewash stations and safety showers are close to the workstation location.
Ensure adequate ventilation, especially in confined areas. Use explosion-proof
electrical/ventilating/lighting/equipment.
Engineering Measures
Respiratory Protection
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Liquid
Light yellow
Odorless
No information available
No information available
-92 - 0.00 C / -133.6 - 32 F
103 C / 217.4 F @ 760 mmHg
12 C / 53.6 F
No information available
Not applicable
No data available
No data available
35 hPa @ 20 C
2.97
0.807
No information available
No data available
220 C / 428 F
No information available
0.6 mPa s at 20 C
C5 H10 O
86.13
Stability
Conditions to Avoid
Incompatible products. Excess heat. Keep away from open flames, hot surfaces and
sources of ignition.
Incompatible Materials
Hazardous Reactions
Product Information
Component Information
Component
Valeraldehyde
LD50 Oral
3200 mg/kg ( Rat ) 5660 L/kg (
Rat )
LD50 Dermal
5 mL/kg ( Rabbit ) 4860 mg/kg (
Rabbit )
LC50 Inhalation
14000 mg/m3 ( Rat ) 4 h
No information available
Toxicologically Synergistic
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation
Sensitization
No information available
Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component
Valeraldehyde
CAS-No
110-62-3
IARC
Not listed
NTP
Not listed
Mutagenic Effects
No information available
Reproductive Effects
No information available.
Developmental Effects
No information available.
Teratogenicity
No information available.
Respiratory system
None known
Aspiration hazard
No information available
ACGIH
Not listed
OSHA
Not listed
Mexico
Not listed
Symptoms / effects,both acute and Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,
tiredness, nausea and vomiting
delayed
No information available
Endocrine Disruptor Information
Other Adverse Effects
The toxicological properties have not been fully investigated. See actual entry in RTECS for
complete information.
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Freshwater Algae
Not listed
Freshwater Fish
11.3 - 13.6 mg/L LC50 96 h
Microtox
Not listed
Water Flea
Not listed
Mobility
log Pow
1.4
UN2058
VALERALDEHYDE
3
II
UN2058
VALERALDEHYDE
3
II
2058
VALERALDEHYDE
3
II
2058
VALERALDEHYDE
3
II
TSCA
X
DSL
X
NLP
PICCS
X
ENCS
X
AICS
X
IECSC
X
KECL
X
Legend:
X - Listed
E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.
F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.
N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated
polymer made with any free-radical initiator regardless of the amount used.
P - Indicates a commenced PMN substance
R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
S - Indicates a substance that is identified in a proposed or final Significant New Use Rule
T - Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base
Production and Site Reports (40 CFR 710(B).
Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants
that comprises one of the eligibility criteria for the exemption rule.
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Not applicable
SARA 313
Not applicable
Yes
No
Yes
No
No
Not applicable
Not applicable
California Proposition 65
State Right-to-Know
Component
Valeraldehyde
Massachusetts
X
New Jersey
X
Pennsylvania
X
Illinois
-
Rhode Island
X
N
N
N
No information available
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR
WHMIS Hazard Class
B2 Flammable liquid
D1B Toxic materials
D2B Toxic materials
E Corrosive material
Prepared By
Regulatory Affairs
Thermo Fisher Scientific
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22-Sep-2009
10-Feb-2015
10-Feb-2015
This document has been updated to comply with the US OSHA HazCom 2012 Standard
replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
Harmonized System of Classification and Labeling of Chemicals (GHS)
Disclaimer
The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
material or in any process, unless specified in the text.
End of SDS
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