KIMIA LANJUT UNTUK

TEKNIK SIPIL
Cindy Rianti Priadi
Week I Semester 4 2014/2015

Introduction

Background
Positioning on chemistry

What do you remember about

chemistry?

Why Chemistry?

Was ist das?

Quest-ce que cest?

zh.wikipedia.org

blogs.nvcc.edu

Why?

How would you handle these

situations?

Your GPA is below target

en.wikipedia.org

Study case example

Diagnose
Why is this happening to the concrete?

How can we avoid this degradation?

Material Properties

Raw
Material
Pre-requisite
Advanced
chemistry

Built
Material

Material Protection

Introduced in
Advanced Chemistry

Deterioration
Material

Material Innovation

Get to know its chemical composition

Know how it interacts with the

environment

Additive for concrete admixture

www.smooth-on.com

Questions to be answered

Chemical properties vs material properties:

The impact of composition to materials
durability
Durability: Impact from environmental
deterioration (errosion, acidity, alkalinity) to
material
Environmental effect: Toxicity during
production, usage and disposal stage

Course Structure

Advanced chemistry
Total credits

: 2 (two)

Kompetensi akhir:
mahasiswa diharapkan mampu
mengaplikasikan dan melaporkan
pengetahuan tentang kimia dasar dan
lingkungan untuk menyelidiki interaksi antara
material dengan lingkungannya
Untuk lengkapnya lihat BPKM

What it is not
Building physics
Advanced solid chemistry
- Mineralogy, cristallography
- Density, solidity, and porosity
- Thermal properties
- Mechanical properties (tensile, tension, etc)

Basic Chemistry Revision

Basic concepts: Revision

Oxidation Reduction
Thermodynamics

Define
1. Oxidation and Reduction
2. Acid Base Reaction
3. What does it mean for a reaction to be
exotherm?
4. What do you know about entropy?

Galvanic Cell
8. Write the balanced net ionic equation, and
calculate Eo for the following galvanic cell: Al
(s) and Cu (s)
The half-reactions and their standard reduction
potentials are:
- Al3+ (aq) + 3 e- Al (s)
Eo = - 1,66V
- Cu2+ (aq) + 2 e- Cu (s) Eo = +0,34 V

Nernst?
9. Calculate the equilibrium constants for the
reaction involving copper and tin (solid and
ionic) using the standard reduction potential
table
EoCu2+/Cu = 0,34 V
EoSn2+/Sn=-0,14 V
Note:
-RT ln K = -nFEo
F = 96500 Coulomb/mol
R = 8.314 J/mol

Introduction to spontaneity

What physical things happen around

you spontaneously?

Discuss
What are their characteristics?

Messy is spontaneous

Disorder is fate

What about chemical disorder?

Why is the concept of spontaneity

important?

Iron Corrosion

Redox spontaneous
in room temperature

Spontaneity
A spontaneous change is any change that
happens freely in time without intervention.
It is important to know how a reaction can
occur spontaneously to avoid /make the
reaction occur?
What are the conditions for a reaction to take
place spontaneously?

Review

Applied Chemistry for Civil Engineering

Basic Chemistry is a pre-requisite
Active Learning
Question = How do you define disorder and
spontaneity thermodynamically?
SCELE: Enrollment code: 7457
Ganti kuliah minggu depan?

http://sd.keepcalm-o-matic.co.uk/i/keepcalm-and-study-chemistry-17.png

QUESTIONS?

Using Standard Reduction Potentials

The half-reactions and their cell potentials are:
Al3+ (aq) + 3 e- Al (s)
Eo = - 1,66V
Cu2+ (aq) + 2 e- Cu (s) Eo = +0,34 V
Eo Al < Cu, therefore:
Al (s) undergoes oxidation
Cu (s) undergoes reduction
2Al (s) + 3Cu2+ (aq) 2Al3+ (aq) + 3Cu (s)
E total = (0,34) - (- 1,66) = 2 V

Sn(s) + Cu2+ (aq) Cu (s)+ Sn2+

Eo = 0,34-(-0,14) = 0,48 V

-RT ln K = -nFEo
Ln K = nFEo/RT
= 2 *96500 Coulomb/mol*0,48 V/8,314 J/mol
K*298 K = 37
K= 1,7 * 1016