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Dislocationsprovidestepwisemotionscaledtothespacingofatoms
incrystals.
LineDefects:DislocationsandtheirScale
Vacancies,
impurities
dislocations
Grainandtwin
boundaries
Voids
Inclusions
precipitates
TheoreticalStrengthofCrystals
Onceitwasestablishedthatcrystalsdeformbysliponspecific
crystallographicsystems,physiciststriedtocalculatethestrengthof
crystals.However,theagreementbetweentheircalculated
strengthandtheexperimentalvalueswereverypoor(orderof
magnitudetoohigh).
Considerthefollowingarrangementshownand
assumethattheindividualplanesdonotdistort
whenashearstressisapplied.Underanapplied
stress,atomswillpasssequentiallythrough
equilibriumpositions(i.e.,A,B,C,etc).Ateach
equilibriumposition,itisassumedthat =0.
Plasticdeformationwilloccurwhentheapplied
shearstress(app)islargeenoughtoovercome
thesebarriers.Atomswillmoveuntiltheplanes
separate(i.e.,fractureoccurs).
Betweenequilibriumpositions, varies
2x
= K sin(
)
cyclically.Assumingthevariationis
b
sinusoidal,wecanexpressitas:
WhereK isaconstantthatdescribesthe
amplitudeoftheshearstress(sinewave)and
x
2x
=
K
=
G
=
G
bistheperiodofthesinewave.
a
b
ForsmalldisplacementsHookes Lawapplies
SolvingforK
b
= Max
K =G
2a
Whereb isthedistancebetweenatomsonlinesof
contactanda isthedistancebetweenplanes
Considerafacecenteredcubic(fcc)crystal.The
relationshipbetweenthelatticeparameter(ao)and
theinterplanar spacing(d)isgivenby:
a
ao
b= o
d=
2
h2 + k 2 + l 2
ForFCCcrystals,shearwilloccurinthe(111)plane
Max
ao 3
G
=G
=
2 ao 2 5.13
Formostcubic
crystalsa andb are
ofthesameorderof
magnitudeand
Max
Max
d=
ao
3
DislocationsLinearDefects
Dislocationsareabruptchangesintheregularorderingofatoms,
alongaline(dislocationline)inthesolid.Theyoccurinhigh density
andareveryimportantinmechanicalpropertiesofmaterial.
TheyarecharacterizedbytheBurgersvector,foundbydoingaloop
aroundthedislocationlineandnoticingtheextrainteratomic
spacingneededtoclosetheloop.TheBurgersvectorinmetals
pointsinaclosepackeddirection.
Edgedislocationsoccurwhenanextraplaneisinserted.The
dislocationlineisattheendoftheplane.Inanedgedislocation,the
Burgersvectorisperpendiculartothedislocationline.
Screwdislocationsresultwhendisplacingplanesrelativetoeach
otherthroughshear.Inthiscase,theBurgersvectorisparalleltothe
dislocationline.
EdgeDislocations
Itcanbevisualizedasanextrahalfplane.
b
G
b
Pointsindirection
ofextrahalfplane
MotionofanEdgeDislocation
Thecaterpillarorrugmovinganalogy
Burgers
Vector=b
Shearstress
Thearrowjoiningthestartingandendingatomsfollowing
thiscircuitistheBurgersvector,denotedby
Twootherdirectionalquantitiescharacterizeadislocation:
thedirectionofmovement..
Andthedirectionoftheline
G
M
Foredgedislocations:
G G
b
G G
M b
G
G
M
G
b
Edgedislocation
conventions
Theshearstresstomaintainmotionof
anisolateddislocationinanabsolutely
purecrystalwithnonearbydislocations
iscalledthePeierls stress.
Itsvalueisestimatedat~108G,whichisseveralordersofmagnitude
lowerthanthemeasuredstressneedtosustainslipinannealedmetals.
Thepresenceofotherdislocationsandofimpuritiesrangingfromatoms
tolargeagglomeratesisresponsiblefortheactualstressrequiredto
causeslipinrealcrystals.
ScrewDislocations
G
b
Forascrewdislocation:
G G
b //
G G
M b
G G
M //
Directionofscrewdislocation
line
b
Burgers
Vector
Ofscrew
screwmovesthisway
ThemagnitudeoftheBurgers
vector,b,forthesimplecubic
lattice,whetherscreworedge,
isequaltothelatticeparameter
ao,theslipdirectionis[100],
andtheslipplaneinwhichit
movesis(100). Thenotationfor
thisBurgersvectoris: G
bSC = ao [100](100)
wherethefirsttermontherightisthemagnitude
ofb,thesecondisthedirection ofb andthelast
termdesignatestheslipplane.
MixedDislocations
Theexactstructureofdislocations
inrealcrystalsisusuallymore
complicatedthantheonesshown.
Edgeandscrewdislocationsarejust
extremeformsofthepossible
dislocationstructures.Most
dislocationshavemixededge/screw
character.
Toaddtothecomplexityofreal
defectstructures,dislocationare
oftensplitin"partial dislocations
thathavetheircoresspreadout
overalargerarea.
TheBurgersvectorforthemixeddislocationis
neitherperpendicularnorparalleltothe
dislocationlinebutretainsafixedorientation
inspaceconsistentwiththeprevious
definitionsforthepureedgeandscrew
dislocations.Theatomicarrangementarounda
mixeddislocationisdifficulttovisualizebutthe
Burgersvectorprovidesaconvenientand
usefuldescription.
TEMimageofthedislocationstructureinatitaniumalloymagnified
50,000times.FromW.D.Callister,Jr.,MaterialsScienceandEngineering,
Wiley&Sons(1985)
DislocationLoops
Loopsareclosedcurveswhoseperipheryconsistsofadislocation.
Theloopmayormaynotbeplanar.Therearetwovarieties.Inone
type,theinterioroftheloopconsistsofatomsthathavebeenshifted
byoneBurgersvector.Thecrystalstructureattheinteriorplaneof
theloopisperfect.
Thedistortioncaused
bytheshiftofatomsis
accommodatedbythe
peripheraldislocation.
Thistypeofloopis
calledashearloop
becauseitisproduced
bytheactionofashear
stressontheslipplane.
Thedislocationthatforms
theperipheryoftheshear
loopismosteasily
understoodbyconsidering
thelooptobeasquare
ratherthanacircleonthe
slipplane.Themagnitude
oftheshiftisoneatomic
spacinginasimplecubic
structureorthemagnitude
oftheBurgersvectorfor
othercrystaltypes.
Aremarkablefeatureoftheloop,whetheritbesquareorcircular,planarornon
planar,isthatitischaracterizedbyasingleBurgersvector.TheBurgersvectoris
perpendiculartothepureedgeportionsoftheloopandparallel tothepurescrew
components.Onlythedirectionsofb arereversedbetweenthenegativeand
positiveedgeportionsandtherighthandandlefthandparts.Whenashearstress
isappliedtotheslipplane,theloopexpandsoutwardonallsides.
Theothertype,theloopisformedbytheremoval/additionofadiskof
atomsfrom/betweenclosepackedatomicplanes.Theperipheryof
theseloopsarealsodislocations.Thistypeofloopiscalleda prismatic
loop.Thistypeisfundamentallydifferentfromtheshearloop;theonly
featuresthetwotypeshaveincommonistheircircularshapeandtheir
abilitytoexpandorcontractradially.
Theinterstitialloopconsistsofadiskshapedlayer(seenendoninthe
figure)ofatomsformedbyassemblingfreeinterstitialatomsfromthe
bulksolid.Theatomlayeragglomerationisthermodynamicallymore
stablethanthesamenumberofatomsdispersedinthelatticeas self
interstitials.
Vacancyloopsareformedbythe
collapseofadiskofvacanciesona
closepackedplane.Incommonwith
theinterstitialloop,theperipheryof
thevacancyloopisacircularedge
dislocationwithaBurgersvector
perpendiculartotheplaneoftheloop.
However,theBurgersvectorsofthe
twotypesareofoppositesign.
Prismaticloop(Interstitial)
Prismaticloop(Vacancy)
Dislocationscanannihilateoneanother!
Nonoverlappingedgescreatevacancies.
Overlappingedgescreateinterstitials.
Almostcomplete
planeofatoms
Slipplane
vacancies
Slipplane
Nonoverlapping
Overlapping
Slipplane
Slipplane
Extraatoms
gointointerstitial
ClimbandCrossSlipsofdislocations
Dislocationsarecapableofleaveitsslipplaneviatwomechanisms:a
dislocationclimb(foredgedislocations)andcrossslip(forscrew
dislocations.
Thepresenceofobstaclesinthesolidsuchasprecipitates,voids,grain
boundariesandothers,caneffectivelyhaltdislocationglide(orslip).Ifa
mobiledislocationispushedbyashearstressintooneofthese
obstructions,oneofthreeeventsoccur:
1.Themobiledislocationisstopped
2.Themobiledislocationliterallycutsthrough theobstacle
3.Themobiledislocationmovestoanotherslipplanethatisparallelto
theoriginalslipplane,onwhichitcancontinuetoglide.
Theabilityofadislocationtoevadetheobstaclesinitspathis
crucialtoplasticdeformation;ifdislocationsdidnotpossessthis
flexibility,theywouldquicklybecomeimmobile.
Prismaticloops
FromHallandBacon4thEd
Foranedgedislocation,movementfromoneslipplanetoaparallel
onerequiresmovementcallclimb.Inthismechanism,theextrahalf
planeofatomsthatconstitutesthedislocationliterallygrowsor
shrinks.Itdoessobyabsorbingvacanciesorinterstitialsfrom the
bulksolid.
Becauseclimbrequiresmobilityofvacanciesinthelattice,itisactive
onlyathightemperatures(say1/3ofthemeltingpointandhigher)
whilesliphasnotemperaturedependenceandisthesolemechanism
ofedgedislocationmovementatroomtemperature.
DislocationDensity
Todefinethequantityofdislocationswithinamaterial,thedislocation
densityisgivenas:
=
ConsidertheTEMshowing20
dislocationstakenfromafoil200nm
thick.Thetotalareaofthemicrograph
is1.5mand1.25mandthetotal
lengthofthedislocationsisabout
15m
L
15 106
13 2
=
m
=
=
4
10
6
6
9
V 1.5 10 1.25 10 200 10
N
20
13 2
= =
=
1
.
1
10
m
6
6
A 1.5 10 1.25 10