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CHAPTER

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SOLUTIONS MANUAL
Introduction to Chemistry
Section 1.1 A Story of Two Substances
pages 48
6. Explain why the concentration of CFCs
increased in the atmosphere.
The use of CFCs continued to increase.
Section 1.1 Assessment
page 8
7. Evaluate why it was important for Dobsons
data to be confirmed by satellite photos.
All scientific hypotheses, tests, experiments, and data must be independently co
nfirmed to make them valid.
1. Explain why the study of chemistry should be
important to everyone.
Chemistry is the study of matter and everything and everyone is made of matter.
2. Define substance and give two examples of
Section 1.2 Chemistry and Matter
pages 911
things that are substances.
A substance, which is also known as a chemical, is matter that has a definite co
mposition. Possible examples: table salt (NaCl) and table sugar (sucrose, C12H22
O11)
Section 1.2 Assessment
page 11
8. Explain why there are different branches of
chemistry.
The study of chemistry is a very broad field, so chemists specialize in small ar
eas.
3. Describe how the ozone layer forms and why
it is important.
When oxygen gas (O2) is exposed to ultraviolet radiation in the upper regions of
the stratosphere, the molecule breaks apart. The individual oxygen particles (O
) combine with other oxygen gas molecules to form ozone (O3). Ozone is important
because it forms a protective layer in the atmosphere that protects living orga
nisms from harmful radiation.
9. Explain why scientists use mass instead of
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

weight for their measurements.


Mass is constant regardless of location and is not affected by gravity. Weight v
aries with gravity.
10. Summarize why it is important for chemists to
4. Explain why chlorofluorocarbons were develstudy changes in the world at a submicroscopic level.
The changes you see with your eyes begin with changes at the submicroscopic leve
l.
oped and how they are used.
Chlorofluorocarbons were developed as a safe alternative to ammonia, a common re
frigerant. Chlorofluorocarbons are used as refrigerants, in foams, and as propel
lants in spray cans.
11. Infer why chemists use models to study submicroscopic matter.
Models enable chemists to understand difficult concepts that they cannot normall
y see.
5. Explain If cells have the ability to repair
themselves after exposure to UVB, why are the increasing levels of UVB in the at
mosphere concerning scientists?
Cells have some ability to repair themselves, but some scientists believe that c
ells have a limit in the amount of UVB exposure that can be tolerated.
12. Identify three different models that scientists
use and explain why each model is useful.
Possible answers: Aircraft models allow scientists to test their designs before
money is spent on the actual aircraft. Computer models of chemical processes all
ow chemists to test processes before actual manufacturing facilities are built.
Car models allow scientists to test certain features, such as wind resistance, b
efore a car is actually built. Chemistry: Matter and Change Chapter 1
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13. Evaluate How would your mass and weight
18. Distinguish Jacques Charles described the
differ on the moon? The gravitational force of the moon is one-sixth the gravita
tional force on Earth.
Your mass would be the same, but your weight would be 1/6 your weight on Earth.
direct relationship between temperature and volume of all gases at constant pres
sure. Should this be called Charless law or Charless theory? Explain.
It is called Charless law because it describes a phenomenon that consistently tak
es place.
14. Evaluate If you put a scale in an elevator and
weigh yourself as you ascend and then descend, does the scale have the same read
ing in both instances? Explain your answer.
As the elevator moves up and down at constant velocity, the reading on the scale
will be the same as it is when the elevator is stationary. However, during the
time the elevator accelerates upward, the scale reading will be higher, during t
he time when the elevator accelerates downward, the scale reading will be lower.
19. Explain Good scientific models can be tested
and used to make predictions. What did Molina and Rowlands model of the interacti
ons of CFCs and ozone in the atmosphere predict would happen to the amount of oz
one in the stratosphere as the level of CFCs increased?
Their models predicted that as CFC concentrations increased, ozone levels would
decrease.
Section 1.3 Scientific Methods
pages 1216
Section 1.4 Scientific Research
pages 1722
Section 1.3 Assessment
page 16
Section 1.4 Assessment
page 22
15. Explain why scientists do not use a standard
20. Name three technological products that have
The nature of investigations varies a great deal and the steps needed to perform
a wide array of investigations must also vary.
Possible answers: computer, internal combustion engine, and vaccinations.
21. Compare and contrast pure research and
16. Differentiate Give an example of quantitative

applied research.
Pure research is done for the sake of knowledge. Applied research is done to sol
ve a specific problem.
and qualitative data.
Possible answers: qualitative, silver-colored liquid; quantitative, 5 mL.
17. Evaluate You are asked to study the effect of
22. Classify Is technology a product of pure
temperature on the volume of a balloon. The balloons size increases as it is warm
ed. What is the independent variable? The dependent variable? What factor is hel
d constant? How would you construct a control?
Independent variable, the temperature; dependent variable, the size of the ballo
on; factor held constant, the amount of air in the balloon; control, an identica
l balloon kept at the original temperature
research or applied research? Explain.
Technology can be the product of either one. It can be a product of pure researc
h when scientists realize their discovery has a practical application. It can al
so be a product of applied research when scientists perform research to solve a
particular problem.
2
Chemistry: Matter and Change Chapter 1
Solutions Manual
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set of steps for every investigation they conduct.
improved our lives or the world around us.

CHAPTER
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SOLUTIONS MANUAL
23. Summarize the reason behind each of the
26. Ozone Where is ozone located in Earths
following. a. Wear goggles and an apron in the lab even if you are only an obser
ver.
Harmful substances can get in your eyes and on your clothing if you are performi
ng an experiment or just watching it being performed.
atmosphere?
90% in the stratosphere
27. What three elements are found in
chlorofluorocarbons?
carbon, fluorine, and chlorine
b. Do not return unused chemicals to the stock
28. CFCs What were common uses of CFCs?
refrigerants, foams, propellants for spray products
bottle.
The chemicals might be contaminated and you do not want to contaminate the stock
bottle.
29. Scientists noticed that the ozone layer was thinning. What was occurring at the same time?
c. Do not wear contact lenses in the laboratory.
Contact lenses can absorb gases that can damage your eyes and they are difficult
to remove during an emergency situation. increased usage of CFCs
30. Why do chemists study regions of the universe,
such as the one shown in Figure 1.20?
d. Avoid wearing loose, draping clothing and
dangling jewelry.
It is easy to drag these items through chemicals and across flames, which might
create a hazardous situation.
24. Interpret Scientific Diagrams What safety
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
precautions should you take when the following safety symbols are listed?
Because chemists study matter and matter is found throughout the universe. Prote
ct your hands from hot or cold objects; protect yourself from possible hazardous
fumes; protect yourself from substances that can irritate your skin, mucous mem
branes, or respiratory tract; Substances are flammable, do not have an open flam
e in the lab.
Mastering Problems 31. If three oxygen particles are needed to form ozone, how m

any units of ozone could be formed from 6 oxygen particles? From 9? From 27?
2 units; 3 units; 9 units
Chapter 1 Assessment
pages 2627
32. Measuring Concentration Figure 1.6 shows
Section 1.1
Mastering Concepts 25. Define substance and chemistry.
substanceany sample with a definite composition; chemistrythe study of matter and
the changes it undergoes
that the CFC level was measured at about 272 ppt (parts per thousand) in 1995. S
ince percent means parts per hundred, what percent is represented by 272 ppt?
27.2% 272 ppt 1 part per hundred __ 10 ppt 27.2%
Solutions Manual
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Section 1.2
Mastering Concepts 33. Why is chemistry called the central science?
An understanding of chemistry is central to all sciences and to our everyday liv
es.
Section 1.3
Mastering Concepts 39. How does qualitative data differ from quantitative data?
Give an example of each.
Qualitative data, such as color or shape, are made with the five senses. Quantit
ative data, such as mass or length, are measurements.
34. Which measurement depends on gravitational
forcemass or weight? Explain.
Weight; weight is calculated using the acceleration due to gravity; mass is inde
pendent of gravity
40. What is the function of a control in an
experiment?
A control is a standard used for comparison.
35. Which branch of chemistry studies the composition of substances? The environmental impact of chemicals?
Analytical chemistry studies the composition of substances; environmental chemis
try studies the environmental impact of chemicals.
41. What is the difference between a hypothesis, a
theory, and a law?
A hypothesis is a tentative explanation about what has been observed. A theory i
s an explanation that has been supported by many experiments. A scientific law d
escribes a relationship in nature.
Mastering Problems 36. Predict whether your weight in the city of Denver, which
has an altitude of 1.7 km above sea level, will be the same as, more than, or le
ss than your weight in New Orleans, a city located at sea level.
Your weight would be less in Denver because the acceleration due to gravity is l
ess in Denver than in New Orleans.
42. Laboratory Experiments You are asked to
37. The text tells you that 1 trillion atoms could
Temperature; amount of sugar dissolved; amount of water
fit onto a period at the end of this sentence. Write out the number 1 trillion us
ing the correct number of zeroes.
1,000,000,000,000
43. Label each of the following pieces of data as
qualitative or quantitative. a. a beaker weighs 6.6 g

quantitative
38. How much mass will the cube in Figure 1.21
have if a 2-cm3 cube of matter has a mass of 4.0 g?
4 cm
b. sugar crystals are white and shiny
qualitative
c. fireworks are colorful
qualitative 4
44. If evidence you collect during an experiment
does not support your hypothesis, what should happen to that hypothesis?
4 cm 4.0 g x _ _; x 2 cm3 (4 cm)3 128 g The hypothesis should be rewritten based
on the new information and the new hypothesis should be tested.
4
Chemistry: Matter and Change Chapter 1
Solutions Manual
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
study how much table sugar can be mixed or dissolved in water at different tempe
ratures. The amount of sugar that can dissolve in water goes up as the waters tem
perature goes up. What is the independent variable? Dependent variable? What fac
tor is held constant?

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SOLUTIONS MANUAL
Mastering Problems 45. One carbon (C) and one ozone (O3) react to form one carbo
n monoxide (CO) and one oxygen gas (O2) particle. How many ozone particles are n
eeded to form 24 particles of oxygen gas (O2)?
1 particle O3 __ 1 particle O2
49. Interpret Scientific Diagrams Decide
whether each of the diagrams shown below is displaying qualitative or quantitati
ve data.
a. Types of Apples Grown in Bioscience Greenhouse Granny Smith 10% Other 5% Fuji
12% Macintosh 26%
x particles O3 __ 24 particles O2
Section 1.4
Mastering Concepts
46. Laboratory Safety Finish each statement
Delicious 47%
about laboratory safety so that it correctly states a safety rule. a. Study your
lab assignment.
before you come to the lab
quantitative data b.
Data: Characteristics of Product Formed
Color Crystal Form Odor white needles none
b. Keep food, beverages, and
chewing gum out of the lab
qualitative
c. Know where to find and how to use the
fire extinguisher, safety shower, fire blanket, and first-aid kit
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
50. Classify CFCs break down to form chemicals
that react with ozone. Is this a macroscopic or a microscopic observation?
microscopic observation
Mastering Problems 47. If your lab procedure instructs you to add two parts acid
to each one part of water and you start with 25 mL of water, how much acid will
you add and how will you add it?
2 25 mL 50 mL acid; Always add acid to the water very slowly.
51. Infer A newscaster reports, The air quality
Think Critically
48. Compare and Contrast Match each of the
today is poor. Visibility is only 1.7 km. Pollutants in the air are expected to
rise above 0.085 parts per million (ppm) in the next eighthour average. Spend as

little time outside today as possible if you suffer from asthma or other breath
ing problems. Which of these statements are qualitative and which are quantitativ
e?
The qualitative statements are that air quality is poor and that people should s
pend little time outside. Quantitative statements include that visibility is onl
y 1.7 km and that the pollutants will rise above 0.085 ppm in the next eight-hou
r average.
following research topics with the branch of chemistry that would study it: wate
r pollution, the digestion of food in the human body, the composition of a new t
extile fiber, metals to make new coins, and a treatment for AIDS.
Possible answers: water pollution, environmental chemistry; the digestion of foo
d, biochemistry; textile fibers, polymer chemistry; metal coins, inorganic chemi
stry; AIDS treatment, biochemistry.
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Additional Assessment
Writing in Chemistry
Arctic low-ozone area (million km2)
Annual Average Arctic Low-Ozone Area for February and March
12 11 10 9 8 7 6 5 4 3 2 1 0 0.2 1.9 1.3 0.5 0.2 0.9 0.0 1.4 0.0 6.1 6.4 5.8 4.3
5.8 11.8
52. Ozone Depletion Based on your knowledge
of chemistry, describe the research into depletion of the ozone layer by CFCs in
a time-line.
Answers will vary but should include increased use of CFCs and the decrease in t
he ozone layer, including the effects of the depletion of life on Earth.
53. CFC Reduction Research the most recent
measures taken by countries around the world to reduce CFCs in the atmosphere si
nce the Montreal Protocol. Write a short report describing the Montreal Protocol
and more recent environmental measures to reduce CFCs.
Answers will vary but should include the measures taken by the United States to
limit the use and control of the disposal of CFCs. Answers should also include t
he measures taken by several other countries.
91 92 93 94 95 96 97 98 99 00 01 02 03 04 05
Year
55. In what year or years was the low-ozone area
the largest? The smallest?
largest, 1996; smallest, 2002 and 2004
54. Technology Name a technological application
56. What is the average area from 20002005? How
Check student booklets for accuracy. Be sure students clearly explain how the ap
plication is related to chemistry.
(4.3 0.9 0.0 1.4 2.1 million sq. km; (5.8 11.8 6.4 4.8 million sq. km 0.5
0.0 0.2
5.8)/6 4.3)/6
Document-Based Questions
Ozone Depletion The area of low-ozone varies over the Arctic as well as over the
Antarctica. NOAA collects data and monitors low-ozone area at both poles. Figur
e 1.23 shows the average areas of unusually low ozone concentration in the north
pole region from February to March of each year from 1991 to 2005.
Data obtained from: http://www.cpc.ncep.noaa.gov/products/ stratosphere/winter_b
ulletins/nh_04-05

Standardized Test Practice


pages 2829
1. When working with chemicals in the laboratory,
which is something you should NOT do? a. Read the label of chemical bottles befo
re using their contents. b. Pour any unused chemicals back into their original b
ottles. c. Use lots of water to wash skin that has been splashed with chemicals.
d. Take only as much as you need of shared chemicals.
b
6
Chemistry: Matter and Change Chapter 1
Solutions Manual
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
of chemistry that you use every day. Prepare a booklet about its discovery and d
evelopment.
does that compare to the average area from 19952000?

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SOLUTIONS MANUAL
Use the table and graph below to answer Questions 25.
Page From a Students Laboratory Notebook
Step Observation Notes Carbonated beverages taste fizzier when they are warm tha
n when they are cold. (Carbonated beverages are fizzy because they contain disso
lved carbon dioxide gas.) At higher temperatures, greater amounts of carbon diox
ide gas will dissolve in a liquid. This is the same relationship between tempera
ture and solubility seen with solids. Measure the mass of carbon dioxide (CO2) i
n different samples of the same carbonated beverage at different temperatures. S
ee graph below.
3. Assuming that all of the experimental data are
Hypothesis
correct, what is a reasonable conclusion for this experiment? a. Greater amounts
of CO2 dissolve in a liquid at lower temperatures. b. The different samples of
beverage contained the same amount of CO2 at each temperature. c. The relationsh
ip between temperature and solubility seen with solids is the same as the one se
en with CO2. d. CO2 dissolves better at higher temperatures.
a
Experiment
4. The scientific method used by this student
Data Analysis Conclusion
showed that a. the hypothesis is supported by the experimental data. b. the obse
rvation accurately describes what occurs in nature. c. the experiment is poorly
planned. d. the hypothesis should be thrown out.
d
Mass of CO2 Dissolved in a Carbonated Beverage
0.30
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
5. The independent variable in this experiment is a. b. c. d.
d
0 5 10 15 20 25
Mass of CO2 (g)
0.25 0.20 0.15 0.10
the number of samples tested. the mass of CO2 measured. the type of beverage use
d. the temperature of the beverage.
6. Which is an example of pure research? a. creating synthetic elements to study
their
Temperature (C)
properties
2. What must be a constant during the experiment? a. b. c. d.

c
b. producing heat-resistant plastics for use in
temperature mass of CO2 dissolved in each sample amount of beverage in each samp
le independent variable
household ovens c. finding ways to slow down the rusting of iron ships d. search
ing for fuels other than gasoline to power cars
a
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7

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Use the table below to answer Question 7.
What is the effect of drinking soda on heart rate?
Student 1 2 3 4 Cans of Soda 0 1 2 4 Heart Rate (beats per minute) 73 84 89 96
ments. This student might be proposing a hypothesis.
11. Explain why scientists use mass for measuring the
amount of a substance instead of using weight.
Because weight is affected by gravity, it can change depending on its location o
n Earth. Mass measures the amount of matter in a substance regardless of the eff
ect of gravity on the substance, which makes it a more reliable measurement when
comparing measurements made in different parts of the world.
7. In this experiment testing the effects of soda on
students heart rates, which student serves as the control? a. Student 1 b. Studen
t 2 c. Student 3 d. Student 4
a
Consider the following experiment as you answer Questions 12 and 13. A chemistry
student is investigating how particle size affects the rate of dissolving. In h
er experiment, she adds a sugar cube, sugar crystals, or crushed sugar to each o
f three beakers of water, stirs the mixtures for 10 seconds, and records how lon
g it takes the sugar to dissolve in each beaker.
12. Identify the independent and dependent
Use the table below to answer Questions 8 and 9.
Physical Properties of Three Elements
Element Sodium Phosphorus Copper Symbol Na P Cu Melting Point (C) 897.4 44.2 1085
Color Grey White orange Density (g/cm3) 0.986 1.83 8.92
variables in this experiment. How can they be distinguished?
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
8. Give examples of qualitative data that are true
The dependent variable is the amount of time required for dissolving, while the
independent variable is how much the sugar is crushed before it is added. The in
dependent variable can be identified because it is the factor that the researche
r is changing, while the dependent variable is the outcome of the experiment tha
t is being measured.
for the element sodium.
Sodium is grey in color; it has the symbol Na, its density is low, its melting p
oint is between the other values.
13. Identify a feature of this experiment that
should be kept constant. Explain why it is important to
e constant.
Answers will vary but can include temperature of water,
of sugar added. It is important to keep these features
e different trials to be compared appropriately. If too

include keep this featur


volume of water, or mass
constant in order for th
many factors are changed

in an experiment, the researcher cannot identify what effect each individual fa


ctor has on the outcome of the experiment.
9. Give examples of quantitative data that are true
for the element copper.
Copper has a melting point of 1085C and a density of 8.92 g/cm3.
10. A student in your class announces that he has
a theory to explain why he scored poorly on a quiz. Is this a proper use of the
term theory? Explain your answer.
No; A theory is an explanation of how nature behaves and is based on many repeat
ed experi8
Chemistry: Matter and Change Chapter 1
Solutions Manual

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SOLUTIONS MANUAL
14. A scientist from which field of chemistry
16. Use chemicals in rooms with proper ventilation
investigates a new form of packaging material that breaks down rapidly in the en
vironment? a. biochemistry b. theoretical chemistry c. environmental chemistry d
. inorganic chemistry e. physical chemistry
c
in case of strong fumes.
e
17. Wear proper protective clothing to prevent stains
and burns.
d
18. Objects may be extremely hot or extremely
cold; use hand protection.
b
Use the safety symbols below to answer Questions 1518. Some choices may be used m
ore than once; others will not be used at all.
a. b. c. d. e.
19. Which statement is NOT true about mass? a. It has the same value everywhere
on Earth. b. It is independent of gravitational forces. c. It becomes less in ou
ter space, farther
from Earth.
d. It is a constant measure of the amount of
Select the symbol for the safety rule being described in each case.
15. Safety goggles should be worn whenever you
matter.
e. It is found in all matter.
c
are working in the lab.
c
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
Solutions Manual
Chemistry: Matter and Change Chapter 1
9

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SOLUTIONS MANUAL
Analyzing Data
Section 2.1 Units and Measurement
pages 3239
6. Compare a base unit and a derived unit, and list
the derived units used for density and volume.
Base units are defined based on a physical object or process. Derived units are
defined based on a combination of base units. The derived units for density are
g/cm3 or g/mL. The derived units for volume are cm3 or m3.
Practice Problems
page 38
1. Is the cube pictured at right made of pure
aluminum? Explain your answer.
7. Define the relationships among the mass,
volume, and density of a material.
Density is the mass-to-volume ratio of a material.
8. Apply Why does oil float on water?
Mass = 20 g Volume = 5 cm3 No; the density of aluminum is 2.7 g/cm3; the density
of the cube is 20 g _ 5 cm3 4 g/cm3. Oil floats on top of water because the den
sity of oil is less than that of water.
9. Calculate Samples A, B, and C have masses
of 80 g, 12 g, and 33 g and volumes of 20 mL, 4 cm3, and 11 mL, respectively. Wh
ich of the samples have the same density?
density of A 80 g/20 mL 4 g/ml; density of B 12 g/4 cm3 3 g/cm3; density of C 33
g/11 mL 3.0 g/mL; B and C have the same density
2. What is the volume of a sample that has a mass
of 20 g and a density of 4 g/mL?
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
volume
20 g mass _ _ density
4 g/mL
5 mL
3. Challenge A 147-g piece of metal has a
10. Design a concept map that shows the relationdensity of 7.00 g/mL. A 50-mL graduated cylinder contains 20.0 mL of water. What
is the final volume after the metal is added to the graduated cylinder?

volume volume 147 g mass _ _ density 20.0 mL 7.00 g/mL 21.0 mL 21.0 mL 41.0 mL
ships among the following terms: volume, derived unit, mass, base unit, time, an
d length.
Student concepts maps will vary, but should show the following relationships: SI
units are divided into base units and derived units; volume and density are der
ived units; mass, time, and length are base units.
Section 2.1 Assessment
page 39
Section 2.2 Scientific Notation and Dimensional Analysis
pages 4046
4. Define the SI units for length, mass, time, and
temperature.
length: meter; mass: kilogram; time: second; temperature: kelvin
Practice Problems
pages 4146
11. Express each number in scientific notation. a. 700
7 102
5. Describe how adding the prefix mega- to a unit
affects the quantity being described.
It makes the quantity larger by a factor of 106. Solutions Manual
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11

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SOLUTIONS MANUAL
b. 38,000
3.8 104
d. (4
5
10
10
12
12)
(1
10
12)
c. 4,500,000
4.5 106
14. Challenge Express each answer in scientific
notation in the units indicated. a. (1.26 104 kg) (2.5 106 g) in kg
1.26 104 kg 0.25 104 kg
4
d. 685,000,000,000
6.85 1011
1.51
104 kg
b. (7.06 g) e. 0.0054
5.4 10
3
(1.2
10
kg) in kg
10
3
7.06 10 3 kg 0.12 7.18 10 3 kg
kg
f. 0.00000687
6.87 10
6

c. (4.39
4.39
105 kg)
105 kg
(2.8
107 g) in kg
4.11 105 kg
0.28
105 kg
g. 0.000000076
7.6 10
8
d. (5.36
10
1
kg)
(7.40
10
2
kg) in g
h. 0.0000000008
8 10
10
5.36 10 1 kg 0.740 10 1 kg 4.62 10 1 kg 4.62 102 g
15. Solve each problem, and express the answer in
12. Challenge Express each quantity in regular
scientific notation. a. (4 102) (1
(4 1) 102
8
108)
4 1010
notation along with its appropriate unit. a. 3.60 105 s
360,000 s
b. (2
5
10 4)
3) 10

(3
4 2
102)
6 10
2
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
b. 5.4
10
g/cm3
(2
0.000054 g/cm3
c. (6
(6
102)
2) 102
(2
1
101)
3 101
c. 5.060
103 km
5060 km (cannot express in regular notation with the correct number of significa
nt figures)
d. (8
(8
104)
4) 104
(4
1
101)
2 103
d. 8.9
1010 Hz
16. Challenge Calculate the areas and densities.
89,000,000,000 Hz
13. Solve each problem and express the answer in

scientific notation. a. (5 10 5) (2
7 10
5
Report the answers in correct units. a. area of a rectangle with sides measuring
3 101 cm and 3 10 2 cm
area (3 (3 3) 101 cm)(3 10 2 cm) 101 ( 2) 9 10 1 cm2
10 5)
b. area of a rectangle with sides measuring
b. (7
3
108)
108
(4
108)
1
area (1
103 cm and 5
(1 5)
10
1
cm
c. (9
2
102)
102
(7
102)
103 cm)(5 10 1 cm) 103 ( 1) 5 102 cm2
12
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SOLUTIONS MANUAL
c. density of a substance having a mass of
c. Convert 5600 dm to m.
5600 dm 1m _ 10 dm 560 m
9
105 g and a volume of 3
10
1
cm3
density mass/volume (9 105 g)/(3 10 1 cm3) (9 3) 105 ( 1) 3 106 g/cm3
d. Convert 72 g to mg.
72 g 1000 mg _ 1g 72,000 mg
d. density of a substance having a mass of
4
10
3
g and a volume of 2
10
2
cm3
e. Convert 2.45
2.45 102 ms
102 ms to s.
1s _ 1000 ms 0.245 s
density mass/volume (4 10 3 g)/(2 10 2 cm3) (4 2) 10 3 ( 2) 2 10 1 g/cm3
f. Convert 5
5 m
m to km.
9
17. Write two conversion factors for each of the
10 km _ 1 m

5
10
9
km
following. a. a 16% (by mass) salt solution
16 g salt 100 g solution __; __ 100 g solution 16 g salt
g. Convert 6.800
6800 cm
103 cm to km.
1000 m 0.068 km
1m 1 km _ _ 100 cm
b. a density of 1.25 g/mL
1.25 g 1 mL _; _ 1 mL 1.25 g
h. Convert 2.5
2.5 101 kg
101 kg to Mg.
1 Mg _ 1000 kg 0.025 Mg
c. a speed of 25 m/s
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
20. Challenge Write the conversion factors
25 m 1 s _; _ 1s 25 m
needed to determine the number of seconds in one year.
1 yr
18. Challenge What conversion factors are needed
to convert: a. nanometers to meters?
nanometers to meters: 10 m _
9
(_) (_) (_) (_)
365 d 1 yr 24 h 1d 60 min 1h 60 s 1 min
21. The speedometer below displays a cars speed
1 nm
in miles per hour. What is the cars speed in km/h? (1 km 0.62 mile)
b. density given in g/cm3 to a value in kg/m3?
g/cm3 to kg/m3: 1 kg 10 cm _ and _
6 3
1000 g
1

m3
Use Table 2.2 on page 33 to solve each of the following. 19. a. Convert 360 s to
ms.
360 s 1000 ms _ 1s 360,000 ms
65 mi 1 km (_) (_) 0.62 mi 1h
10
102 km/h
b. Convert 4800 g to kg.
4800 g 1 kg _ 1000 g 4.8 kg
(Note: because significant figures and rounding havent been covered yet, students
might generate a calculator answer of about 104.8 km/h.)
Solutions Manual
Chemistry: Matter and Change Chapter 2
13

CHAPTER
2
SOLUTIONS MANUAL
22. How many seconds are in 24 h?
24 h 60 min 60 s _ _ 1h 1 min 86,400 s
30. Apply Concepts A classmate converts 68 km
into meters and gets 0.068 m as the answer. Explain why this answer is incorrect
and the likely source of the error.
Because meters are smaller than kilometers, there should be more meters than kil
ometers. The 68 km was divided by 1000, not multiplied by 1000.
23. Challenge Vinegar is 5.00% acetic acid by
mass and has a density of 1.02 g/mL. What mass of acetic acid, in grams, is pres
ent in 185 mL of vinegar?
mass (volume)(density) 189 g vinegar (189 g vinegar) (185 mL)(1.02 g/mL)
31. Organize Create a flow chart that outlines
5.00 g acetic acid 100 g vinegar 9.45 g acetic acid
( __ )
when to use dimensional analysis and when to use scientific notation. Does the g
iven value have trailing zeros or leading zeros? yes use scienti c notation no Is
the unit of the given value the desired unit? yes conversion is not required no
use dimensional analysis
Section 2.2 Assessment
page 46
24. Describe how scientific notation makes it easier
to work with very large or very small numbers.
When numbers are expressed in scientific notation, the space-wasting placeholder
zeros are eliminated, thus making it easier to perform arithmetic on the number
s.
25. Express the numbers 0.00087 and 54,200,000 in
8.7
10
4;
5.42
107
26. Write the measured distance quantities
3 1024 cm and 3 notation.
0.0003 cm; 30,000 km

104 km in regular
27. Write a conversion factor relating cubic centimeters and milliliters.
1 cm3/1 mL
28. Solve How many millimeters are there in
2.5
102 km?
1000 m 1000 mm (_)(_) 1m 1 km 2.5 108 mm
250 km
29. Explain how dimensional analysis is used to
solve problems.
It is a method of problem solving focusing on the units used to describe matter.
A given value is multiplied by a conversion factor that relates the given unit
to the desired unit.
14
Chemistry: Matter and Change Chapter 2
Solutions Manual
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
scientific notation.
Student flowchart should include the following yes/no decisions branches: 1) Doe
s the given value have trailing zeros or leading zeros? (If yes, use scientific
notation.); 2) Is the unit of the given value the desired unit? (If no, then use
dimensional analysis.)

CHAPTER
2
SOLUTIONS MANUAL
Student Density and Error Data (Unknown was sucrose; density = 1.59 g/cm 3)
Student A Density Trial 1 Trial 2 Trial 3 Average 1.54 g/cm 1.60 g/cm
3 3 3
Student B
3
Student C
3
Error (g/cm ) 0.05 0.01 0.02
Density 1.40 g/cm 1.68 g/cm 1.45 g/cm 1.51 g/cm
3 3 3 3
Error (g/cm ) 0.19 0.09 0.14
Density a. 1.70 g/cm 3 1.69 g/cm 1.71 g/cm 1.70 g/cm
3 3 3
Error (g/cm 3) 0.11 0.10 0.12
1.57 g/cm b. 1.57 g/cm 3
a. These trial values are the most precise. b. This average is the most accurate
.
Section 2.3 Uncertainty in Data
pages 4754
34. Challenge Based on percent error, which
students trial was the most accurate? The least accurate?
most accurate: Student B, trial 2; least accurate: Student B, trial 1
Practice Problems
page 49
Answer the following questions using data from Table 2.3. 32. Calculate the perc
ent errors for Students Bs trials.
0.19 _ 1.59 1.59 1.59 0.19 _
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
Problem-Solving Lab
page 50
100 100 100
11.9% 5.66% 8.80%
Think Critically 1. Calculate the volume and density for each sample and the ave
rage density of the six samples.
Volume: Sample 1, 60.3 mL 50.1 mL 10.2 mL; Sample 2, 62.5 mL 49.8 mL 12.7 mL; Sa
mple 3, 61.5 mL 50.2 mL 11.3 mL; Sample 4, 56.7 mL 45.6 mL 11.1 mL; Sample 5, 65

.3 mL 50.3 mL 15.0 mL; Sample 6, 60.8 mL 47.5 mL 13.3 mL Density: Sample 1, 50.2
5 g/10.2 mL 4.93 g/mL; Sample 2, 63.56 g/12.7 mL 5.00 g/mL; Sample 3, 57.65 g/11
.3 mL 5.10 g/mL; Sample 4, 55.35 g/11.1 mL 4.99 g/mL; Sample 5, 74.92 g/15.0 mL
4.99 g/mL; Sample 6, 67.78 g/13.3 mL 5.10 g/mL Average density (4.93 g/mL 5.00 g
/mL 5.10 g/mL 4.99 g/mL 4.99 g/mL 5.10 g/mL)/6 5.02 g/mL
0.14 _
Note: The answers are reported in three significant figures because student erro
r is the difference between the actual value (1.59 g/cm3) and the measured value
.
33. Calculate the percent errors for Student Cs
trials.
0.11 _ 1.59 1.59 1.59 0.10 _ 0.12 _ 100 100 100 6.92% 6.29% 7.55%
2. Apply The student hopes the samples are gold,
Note: The answers are reported in three significant figures because student erro
r is the difference between the actual value (1.59 g/cm3) and the measured value
.
which has a density of 19.3 g/cm3. A local geologist suggested the samples might
be pyrite, a mineral with a density of 5.01 g/cm3. What is the identity of the
unknown sample?
The average density of the samples was 5.02 g/mL which is very close to the acce
pted value of 5.01 g/cm3 for pyrite. The samples are probably pyrite. Chemistry:
Matter and Change Chapter 2
Solutions Manual
15

CHAPTER
2
SOLUTIONS MANUAL
3. Calculate the error and percent error of each
d. 0.0084 mL
2
sample. Use the appropriate density value given in Question 2 as the accepted va
lue.
Errors: Sample 1, 4.93 5.01 g/mL 0.08g/mL; Sample 2, 5.00 5.01 g/mL 0.01 g/mL; S
ample 3, 5.10 5.01 g/mL 0.09 g/mL; Sample 4, 4.99 5.01 g/mL 0.02 g/mL; Sample 5,
4.99 5.01 g/mL 0.02 g/mL; Sample 6, 5.10 5.01 g/mL 0.09 g/mL Percent errors: Sa
mple 1, 0.08 g/mL /5.01 g/mL 100 1.6%; Sample 2, 0.01 g/mL/5.01 g/mL 0.20%; Samp
le 3,0.09 g/mL/5.01 g/mL 1.8%; Sample 4, 0.02 g/mL/5.01 g/mL 0.40%; Sample 5, 0.
02 g/mL/5.01 g/mL 0.40%; Sample 6, 0.09 g/mL/5.01 g/mL 1.8%
37. Challenge Write the numbers 10, 100, and
1000 in scientific notation with two, three, and four significant figures, respe
ctively.
two significant figures: 1.0 1.0 103 three significant figures: 1.00 1.00 103 fo
ur significant figures: 1.000 1.000 103 101, 1.0 102, 102, 102,
101, 1.00 101, 1.000
38. Round each number to four significant figures. a. 84,791 kg
84,790 kg
4. Conclude Was the data collected by the
student accurate? Explain your answer.
The students values ranged from 0.20% error to 1.8% error. The average error was
1.03% error. The data is accurate.
b. 38.5432 g
38.54 g
c. 256.75 cm
Practice Problems
pages 5154
256.8 cm
4.936 m
39. Challenge Round each number to four signifi4
b. 820,400.0 L
7
cant figures, and write the answer in scientific notation. a. 0.00054818 g
5.482 10
4

g
c. 1.0200
5
105 kg
b. 136,758 kg
1.368 105 kg
d. 807,000 kg
3
c. 308,659,000 mm
3.087 108 mm
36. a. 0.049450 s
5
d. 2.0145 mL
2.014 100 mL, or 2.014 mL
b. 0.000482 mL
3
c. 3.1587
5
10
4
g
16
Chemistry: Matter and Change Chapter 2
Solutions Manual
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
Determine the number of significant figures in each measurement. 35. a. 508.0 L
d. 4.9356 m

CHAPTER
2
SOLUTIONS MANUAL
40. Add and subtract as indicated, and round when
44. Challenge (1.32
103 g)
(2.5
102 cm3)
necessary. a. 43.2 cm
142.9 cm
51.0 cm
48.7 cm
divide coefficients: 1.32/2.5 0.528; subtract exponents: 103 2 101; combine part
s and round: 0.528 101 g/cm3; 5.3 g/cm3
b. 258.3 kg
768 kg
257.11 kg
253 kg
Section 2.3 Assessment
page 54
41. Challenge Add and subtract as indicated, and
45. State how a measured value is reported in
round when necessary. a. 4.32 103 cm 1.6
4.32 104 mm 160 1.6 106 mm
terms of known and estimated digits.
A measured valued is reported with all of the known digits and one estimated dig
it.
106 mm
104 mm
46. Define accuracy and precision.
b. 2.12
107 mm
1.8
103 cm

2.12 107 mm 0.0018 107 mm 2.1218 107 cm 2.12 107 cm


Accuracy is defined as how close a value is to the accepted value. Precision is
defined as how close a series of measurements are to one another.
47. Identify the number of significant figures
Perform the following calculations and round the answers. 42. a. 24 m 3.26 m
78 m2
in each of these measurements of an objects length: 76.48 cm, 76.47 cm, and 76.59
cm.
They each have four significant figures.
48. Apply The object in Question 47 has an actual
b. 120 m
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
0.10 m
length of 76.49 cm. Are the measurements in Question 47 accurate? Are they preci
se?
Answers may vary but might include the following. They are not precise for value
s recorded to four significant figures. The first and second values are close en
ough to the accepted value to be called accurate.
12 m2
c. 1.23 m
2.5 m2
2.0 m
d. 53.0 m
81.1 m2
1.53 m
49. Calculate the error and percent error for each
measurement in Question 47.
43. a. 4.84 m/2.4 s
2.0 m/s 76.48 76.47 76.59 76.49 76.49 76.49 20.01 cm 20.02 cm 0.10 cm 100 100 10
0 0.01307% 0.02615% 0.1307%
b. 60.2 m/20.1 s
3.00 m/s
|76.48 cm 76.49 cm| 76.49 cm |76.47 cm 76.49 cm| 76.49 cm |76.59 cm 76.49 cm| 76
.49 cm
__ __ __
c. 102.4 m/51.2 s
2.00 m/s
d. 168 m/58 s
2.9 m/s

50. Apply Write an expression for the quantity


506,000 cm in which it is clear that all the zeros are significant.
5.06000 Solutions Manual 105 cm
Chemistry: Matter and Change Chapter 2
17

CHAPTER
2
SOLUTIONS MANUAL
51. Analyze Data Students collected mass data
56. Construct a circle graph for the composition
for a group of coins. The mass of a single coin is 5.00 g. Determine the accurac
y and precision of the measurements.
Number of coins Mass (g) 5 23.2 10 54.5 20 105.9 30 154.5 50 246.2
of air: 78.08% N, 20.95% O2, 0.93% Ar, and 0.04% CO2 and other gases.
Student graphs should have four wedge-shaped areas that are sized proportionatel
y with the composition percentages given. Elements in Earths Atmosphere
The mass of an individual coin calculated for each trial are as follows: 5 coins
, 23.2 g/5 4.6 g; 10 coins, 54.5 g/10 5.45 g; 20 coins, 105.9 g/20 5.295 g; 30 c
oins, 154.5 g/30 5.150 g; and 50 coins, 246.2g/50 4.924 g. Knowing that the acce
pted value for the mass of the coin is 5.00 g, the data in the table is too vari
ed to be considered precise and differs too greatly from the accepted value to b
e considered accurate.
Argon 0.93%
CO2 and other
gases 0.93%
Oxygen 20.95%
Nitrogen 78.08%
Section 2.4 Representing Data
pages 5558
Section 2.4 Assessment
page 58
57. Infer from Figure 2.17 how long the ozone
hole lasts.
from September to November, approximately three months
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
52. Explain why graphing can be an important tool
for analyzing data.
Often, trends in data are not easily seen when the data is presented in a table.
Graphing the data allows patterns and trends to be more easily spotted and inte
rpreted. Graphing provides visual information about relationships between variab
les, relative amounts, or parts of a whole.
58. Apply Graph mass versus volume for the given
data. What is the slope of the line?
Volume (cm3) Mass (g) 7.5 24.1 12 38.5 15 48.0 22 70.1
53. Infer What type of data must be plotted on

a graph for the slope of the line to represent density?


Mass and volume data must be plotted; the y value must be mass and the x value m
ust be volume.
Student graphs should show mass on the y-axis and volume on the x-axis. Slope (y
y ) (70.1 g 38.5 g) _ __ (x x ) (22 cm 12 cm ) 31.6 g _ 3.16 g/cm 3.2 g/cm
2 1 2 1 3 3 3
3
10 cm3
54. Relate If a linear graph has a negative slope,
The slope of the line is 3.2 g/cm3.
what can you say about the dependent variable?
Volume (cm3) It decreases in value as the independent variable increases.
25 20 15 10 5 0 20 30
Mass v. Volume
55. Summarize What data are best displayed on a
circle graph? On a bar graph?
circle graph: parts of a whole; bar graph: how a quantity varies with a factor s
uch as location
40
50
60
70
80
Mass (g)
18
Chemistry: Matter and Change Chapter 2
Solutions Manual

CHAPTER
2
SOLUTIONS MANUAL
Chemistry and Health
page 59
Post-1982 Penny
Total mass of pennies (g) 12.50 25.03 37.55 50.04 62.55 Total Volume of water di
splaced (mL) 1.8 3.5 5.2 7.0 8.7 Density Mass Volume (g/mL) 6.9 7.2 7.2 7.1 7.2
Writing in Chemistry Research Access the MSDS for several chemicals used at home
. Compare the possible adverse health effects of exposure to the chemicals and l
ist the first aid requirements.
Answers will vary based on the students product selection. Sample answer: The MSD
S of an automatic dishwashing detergent indicates that it is an irritation to ey
es and skin. If swallowed, it will irritate the mouth, throat, and stomach. Firs
t aid is as follows: for the eyes, flush with water for 15 min; for the skin, wa
sh with soap and water; and if ingested give large amounts of milk or water. Do
not induce vomiting. Call a doctor if ingested or the eye and skin irritation co
ntinues.
2. Make and Use Graphs Graph total mass
versus total volume for the pre-1982 and post1982 pennies. Plot and label two li
nes on the graph, one for pre-1982 pennies and one for post-1982 pennies.
See graph below.
ChemLab
page 60
3. Make and Use Graphs Draw a best-fit line
Analyze and Conclude
1. Calculate Complete the Data Table for the
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
through each set of points. Use two points on each line to calculate the slope.
The slopes of the lines give you the density of the pre-1982 and post-1982 penni
es.
See graph below. The slope for pre-1982 penny is 7.1 g/mL. The slope for post-19
82 penny is 9.0 g/mL.
Density of a Penny by calculating the total mass and the total volume of water d
isplaced for each trial.
Pre-1982 Penny
Total mass of pennies (g) 15.50 31.02 46.53 62.12 77.54 Total Volume of water di
splaced (mL) 1.7 3.5 5.2 6.9 8.7 Density Mass Volume (g/mL) 9.1 8.9 8.9 9.0 8.9
Pennies
100 80 60 40 20 0 0 2 4 6 8 Pre 1982 Post 1982 10
Mass (g)
Volume (mL)
4. Apply Can you determine if a penny was minted

before or after 1982 if you only know its mass? Explain how volume, mass, and de
nsity support using a mass-only identification technique.
Both pennies have similar volume but the mass is different, therefore the densit
y is different. Mass can be used to identify both pre and post 1982 pennies.
Solutions Manual
Chemistry: Matter and Change Chapter 2
19

CHAPTER
2
SOLUTIONS MANUAL
5. Error Analysis Determine the percent error in
63. What is the relationship between the SI unit for
the density of each coin.
Pre 1982 pennies (9.0 Post 1982 pennies (7.1 8.8)/8.8 7.2)/7.2 100 100 2.3% erro
r 1.4% error
volume and the SI unit for length?
The SI unit for volume is the cubic meter, m3, which is equal to three SI measur
ements of length multiplied together.
(Note: accepted values for density were determined by calculating a weighted ave
rage of the accepted values of the densities of copper and zinc. Densities of th
ese metals are listed in the appendix.) Error could be reduced by using a more a
ccurate graduated cylinder so measurements could be made with more significance.
64. Explain how temperatures on the Celsius and
Kelvin scales are related.
The sizes of the units are equal; C 273 K.
65. Examine the density values for several common
Inquiry Extension Compare your results with those from the rest of the class. Ar
e they consistent? If not, explain how you could refine your investigation to en
sure more accurate results.
The results should be consistent. More accurate results could be achieved with a
graduated cylinder that read a more accurate volume. Make sure the pennies are
dry before they are massed.
liquids and solids given in Table 2.5. Sketch the results of an experiment that
layered each of the liquids and solids into a 1000-mL graduated cylinder.
Density Values
Liquids (g/mL) Ethyl alcohol Glycerin Isopropyl alcohol Corn syrup Motor oil Veg
etable oil Water at 4 C 0.789 1.26 0.870 1.37 0.860 0.910
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
Solids (g/cm3) Bone Cork Plastic Oak (wood) 1.85 0.24 0.91 0.84
Chapter 2 Assessment
pages 6265
1.000
Section 2.1
Mastering Concepts 59. Why must a measurement include both a number and a unit?
The number gives you the quantitative value, and the unit indicates what was mea
sured.
Student drawings should show the layers in the following order from top to botto
m: cork, ethyl alcohol, wood (oak), motor oil, isopropyl alcohol, vegetable oil
and plastic (at the same level), water, glycerin, corn syrup, and bone.

60. Explain why standard units of measurement are


Mastering Problems 66. A 5-mL sample of water has a mass of 5 g. What is the den
sity of water?
density 5g mass _ _ volume 5 mL 1 g/mL
particularly important to scientists.
Scientists from different countries have different languages and cultures but mu
st be able to share and compare data.
67. The density of aluminum is 2.7 g/mL. What is
the volume of 8.1 g?
volume 8.1 g mass _ _ density 2.7 g/mL 3.0 mL
61. What role do prefixes play in the metric system?
Prefixes give the magnitude of the measurement.
62. How many meters are there in one kilometer?
In one decimeter?
1 km 1000 m; 1 dm 0.1 m
20
Chemistry: Matter and Change Chapter 2
Solutions Manual

CHAPTER
2
SOLUTIONS MANUAL
68. An object with a mass of 7.5 g raises the level
73. When dividing numbers in scientific notation,
of water in a graduated cylinder from 25.1 mL to 30.1 mL. What is the density of
the object?
volume density 30.1 mL volume 25.1 mL 5.0 mL 5.0 mL 1.5 g/mL 7.5 g mass _ _
what must you do with the exponents?
Subtract them.
74. When you convert from a small unit to a large
unit, what happens to the number of units?
It decreases.
69. Candy Making The directions in the candy
recipe for pralines instruct the cook to remove the pot containing the candy mix
ture from the heat when the candy mixture reaches the softball stage. The soft-b
all stage corresponds to a temperature of 236F. After the soft-ball stage is reac
hed, the pecans and vanilla are added. Can a Celsius thermometer with a range of
10C to 110C be used to determine when the soft-ball stage is reached in the candy
mixture?
C (F 32) 5 _ 9 (236 32) 5 _ 9 113C
75. When converting from meters to centimeters,
how do you decide which values to place in the numerator and denominator of the
conversion factor?
Meters will be in the denominator so that the units will cancel when the startin
g value is multiplied by the conversion factor.
No, the Celsius thermometer could not be used to make this candy because the tem
perature is out of the thermometers range.
Mastering Problems 76. Write the following numbers in scientific notation. a. 0.
0045834 mm
4.5834 10
3
mm
b. 0.03054 g
Section 2.2
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
3.054
10
2

g
Mastering Concepts 70. How does scientific notation differ from ordinary notatio
n?
Scientific notation uses a number between 1 and 10 times a power of ten to indic
ate the size of very large or small numbers.
c. 438,904 s
4.38904 105 s
d. 7,004,300,000 g
7.0043 109 g
77. Write the following numbers in ordinary
71. If you move the decimal place to the left to
convert a number into scientific notation, will the power of ten be positive or
negative?
positive
notation. a. 8.348
106 km 103 g
8,348,000 km
b. 3.402
3402 g
72. Two undefined numbers expressed in regular
notation are shown below along with the number of places the decimal must move t
o express each in scientific notation. If each X represents a significant figure
, write each number in scientific notation.
a. X.XXXX b. X.XX
10 102
7
c. 7.6352
10
5
3
kg
0.0076352 kg
d. 3.02
10
s
0.0000302 s
Solutions Manual

Chemistry: Matter and Change Chapter 2


21

CHAPTER
2
SOLUTIONS MANUAL
78. Complete the following addition and
d. (8.42
(8.42
108 kL)
4.21) 108
(4.21
3
103 kL)
105
3
subtraction problems in scientific notation. a. 6.23 106 kL 5.34 106 kL
(6.23 5.34) 106 kL 1.157 107 kL 11.57 106 kL
2.00
e. (8.4
(8.4
106 L)
2.4)
(2.4
10
3.5
L)
106 ( 3)
4
109
b. 3.1
(0.31
104 mm
4.87)
4.87
105 mm
105 mm
5.18 105 mm
f. (3.3
(3.3
10

1.1)
mL)
10
(1.1
3.0
10
6
mL)
4 ( 6)
102
c. 7.21
103 mg
43.8
102 mg
11.59 103 mg
80. Convert the following measurements. a. 5.70 g to milligrams
5.70 g 1000 mg _ 1g 5.70 103 mg
(7.21 4.38) 103 mg 1.159 104 mg
d. 9.15
10
4
cm
3
3.48
4
10
12.63
4
cm
10
4
(9.15 3.48) 1.263 10
10 cm
cm
cm

b. 4.37 cm to meters
4.37 cm 1m _ 100 cm 4.37 10
2
m
e. 4.68
(4.68
10
5
cg
10
3.5
5
10
5.03
6
cg
10
5
0.35)
cg
cg
c. 783 kg to grams
783 kg 1000 g _ 1 kg 7.83 105 g
f. 3.57
(3.57
102 mL
1.43)
1.43
102 mL
2.14 102 mL
102 mL
d. 45.3 mm to meters
45.3 mm 1m _ 1000 mm 4.53 10
2
g. 9.87
(9.87
104

g
6.2
104 g
103
9.25
g
104 g
m
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
0.62)
h. 7.52
(7.52
105 kg
5.43)
5.43
105 kg
105 kg
2.09 105 kg
e. 10 m to centimeters
10 m 100 cm _ 1m 1000 cm
i. 6.48
(6.48
10
3
mm
10
3
2.81
mm
10
3.67
3
mm
10
3
f. 37.5 g/mL to kg/L
mm 37.5 g 1 kg 1000 mL _ _ _ 1 mL 1000 g 1L 37.5 kg/L
2.81)
j. 5.72

(5.72
10
4
dg
10
2.3
4
10
5.49
5
dg
10
4
0.23)
dg
dg
81. Gold A troy ounce is equal to 480 grains, and
79. Complete the following multiplication and
division problems in scientific notation. a. (4.8 105 km) (2.0 103 km)
(4.8 2.0) 105 3
4
1
,
1
g
9

grain is equal to 64.8 milligrams. If the price of gold is $560 per troy ounce
what is the cost of 1 g of gold?
troy ounce 1 grain $560 __ __ _ 1 troy ounce 64.8 mg 480 grains 1000 mg _ $18/
0.125 g

km2
9.6
108
km2
b. (3.33
(3.33
10
3.00)
m)
10
(3.00
4 ( 5)

10
5
m)
10 m2
m2
9.99
7
c. (1.2
(1.2
106 m)
1.5) 106
(1.5
( 7)
10
m)
10
1
m2
1.8
m2
22
Chemistry: Matter and Change Chapter 2
Solutions Manual

CHAPTER
2
SOLUTIONS MANUAL
82. Popcorn The average mass of a kernel of pop88. Which number will produce the same number
corn is 0.125 g. If 1 pound 16 ounces, and 1 ounce 28.3 g, then how many kernels
of popcorn are there in 0.500 pound of popcorn?
0.500 lb. popcorn 1 kernel _ 0.125 g 28.3 g 16 ounces _ _ 1 pound 1 ounce
when rounded to three significant figures: 3.456, 3.450, or 3.448?
3.450 and 3.448
89. Record the measurement shown in Figure 2.18
1810 kernels popcorn
to the correct number of significant figures.
83. Blood You have 15 g of hemoglobin in every
100 mL of your blood. 10.0 mL of your blood can carry 2.01 mL of oxygen. How man
y milliliters of oxygen does each gram of hemoglobin carry?
2.01 mL oxygen 100 mL blood __ __ 10 mL blood 15 g hemoglobin 1.34 mL oxygen/g h
emoglobin 5.85 cm
5
INCHES
6
CENTIMETERS
2
90. When subtracting 61.45 g from 242.6 g, which 84. Nutrition The recommended c
alcium intake
for teenagers is 1300 mg per day. A glass of milk contains 305 mg of calcium. On
e glass contains a volume of 8 fluid ounces. How many
liters of milk should a teenager drink per day to get the recommended amount of
calcium? One fluid ounce equals 29.6 mL.
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
value determines the number of significant figures in the answer? Explain.
242.6 g; the number that has the fewest digits to the right of the decimal point
; it is less precise.
1 glass 1300 mgCa 8 fluid ounces __ _ __ 305 mgCa 1 day 1 glass 29.6 mL 0.001 L
1 L milk __ _ _ 1 fluid ounce 1 mL 1 day
Mastering Problems 91. Round each number to four significant figures. a. 431,801
kg
431,800 kg
b. 10,235.0 mg

Section 2.3
Mastering Concepts 85. Which zero is significant in the number 50,540? What is t
he other zero called?
the first one; placeholder
10,240 m
c. 1.0348 m
1.035 m
d. 0.004384010 cm
0.004384 cm
86. Why are percent error values never negative?
Because the percent error equation uses the absolute value of the error.
e. 0.00078100 mL
0.0007810 mL
87. If you report two measurements of mass, 7.42 g
f. 0.0098641 cg
0.009864 cg
and 7.56 g, are the measurements accurate? Are they precise? Explain your answer
s.
You must know the accepted value to know if the measurements are accurate. They
are fairly precise because there is only 0.14 g difference between the two measu
rements. Solutions Manual
Chemistry: Matter and Change Chapter 2
23

CHAPTER
2
SOLUTIONS MANUAL
92. Round the answer for each of the following
94. The accepted density for copper is 8.96 g/mL.
problems to the correct number of significant figures. a. 7.31 104 3.23 103
(7.31 0.323) 7.63 104 104 7.633 104
Calculate the percent error for each of these measurements. a. 8.86 g/mL
error 8.86 g/mL 8.96 g/mL 0.10 g/mL 100 1.12% | 0.10 g/mL | 8.96 g/mL
b. 8.54
10
3
3.41
10
3
10
4
percent error 10
3
__
8.96 g/mL
(8.54 0.341) 8.20 10 3
8.199
b. 8.92 g/mL
error 8.92 g/mL 0.04 g/mL 100 0.446%
c. 4.35 dm
(4.35 2.34 74.8 dm3
2.34 dm
7.35)
7.35 dm
74.81565 dm3 percent error
dm3
| 0.04 g/mL | 8.96 g/mL
__
8.96 g/mL
c. 9.00 g/mL

d. 4.78 cm
4.78 3.218
3.218 cm
5.82 cm
5.82 cm
13.818 cm 13.82 cm
error
9.00 g/mL
0.04 g/mL 100 0.446%
percent error
e. 45 m
(45 72
72 m
132 m
427,680 m3 430,000 m3
| 0.04 g/mL | 8.96 g/mL
__
8.96 g/mL
132) m3
d. 8.98 g/mL
error 8.98 g/mL 0.02 g/mL 100 0.223%
f. 38,736 km/4784 km
38,736 km 4784 km 8.0969899 8.097
percent error
| 0.02 g/mL | 8.96 g/mL
__
93. The accepted length of a steel pipe is 5.5 m.
Section 2.4
Mastering Concepts 95. Heating Fuels Which type of graph would you use to depict
how many households heat with gas, oil, or electricity? Explain.
A bar graph could be used with the method of heating on the x-axis and the numbe
r of households on the y-axis. If the data include all the households for a regi
on, relative numbers could be converted to a percentage and expressed as a circl
e graph.
error
5.2 m
5.5 m | 0.3 m _| 5.5 m

0.3 100 5.5%


percent error
b. 5.5 m
error 5.5 m 5.5 m |0 m _| 5.5 m 0m 100 0
percent error
c. 5.7 m
error 5.7 m 5.5 m | 0.2 m _| 5.5 m 0.2 m 100 3.6%
96. Gasoline Consumption Which type of graph
would you choose to depict gasoline consumption over a period of a 10-year perio
d? Explain.
line or bar graph because they can show how consumption varies with time
percent error
d. 5.1 m
error 5.1 m 5.5 m | 0.4 m _| 5.5 m 0.4 m 100 7.3%
97. How can you find the slope of a line graph?
Choose two points on the line. Divide the difference in the y values by the diff
erence in the x values.
percent error
24
Chemistry: Matter and Change Chapter 2
Solutions Manual
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
Calculate the percent error for each of these measurements. a. 5.2 m

CHAPTER
2
SOLUTIONS MANUAL
Mastering Problems 98. Use Figure 2.19 to answer the following questions.
Density Comparison
12.0
e. (4.42
(4.42 2.2
10
3
kg)
3 2
(2.0
2.21
102 kg)
10
5
2.0) 10 10 5
f. (6.42
(6.42
10
3.21)
2
g)
10
(3.21
2 ( 3)
10
2.00
3
g)
101
Density (cm3)
10.0 8.0 6.0 4.0 2.0 0 Wood Water Sugar Glass Iron Lead Mercury
100. Convert each quantity to the indicated units. a. 3.01 g 0 cg
3.01 g
(_)
1 cg 0.01 g 1 km (_) 1000 m

7g
7
301 cg
b. 6200 m 0 km
6200 m 6.2 km
Materials
a. Which substance has the greatest density?
mercury
c. 6.24
6.24
10
10
0 g
1 g
6
b. Which substance has the least density?
wood
g
(_ )
10 g 0.2 dm3
6.24
10
1
g
d. 0.2 L 0 dm3
c. Which substance has a density of 7.87
iron
g/cm3?
0.2 L
1 dm (_) 1L
3
d. Which substance has a density of
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
e. 0.13 cal/g 0 kcal/g
0.13 cal/g 1 kcal (_) 1000 cal 0.00013 kcal/g
11.4
Lead
g/cm3?

f. 3.21 mL 0 L
Mixed Review 99. Complete these problems in scientific notation. Round to the co
rrect number of significant figures. a. (5.31 10 2 cm) (2.46 105 cm)
(5.31 2.46) 10 2 5 cm2 103 cm2 1.31 104 cm2 13.0626
3.21 mL
1L (_) 1000 mL
0.00321 L
101. In the laboratory, students used a balance and
a graduated cylinder to collect the data shown in Table 2.6. Calculate the densi
ty of the sample. If the accepted value of this sample is 6.95 g/mL, calculate t
he percent error.
Volume and Mass Data
b. (3.78
103 m)
(7.21 102 m)
2
(3.78 7.21) 103 2.73 106 m2
m2
27.2538
105 m2
Mass of sample Volume of water Volume of water + sample volume of sample 43.0 mL
20.46 g 40.0 mL 43.0 mL 40.0 mL 3.0 mL
c. (8.12
10
3
m)
(1.14
3 ( 5)
10
8
5
m)
(8.12 1.14) 10 9.2568 10 8 m2
m2 9.26 10

m2
d. (9.33
(9.33
104 mm)
3.0) 104
2
(3.0
3.11
102 mm)
102 3.1 102
density mass/volume 20.46 g/3.0 mL 6.82 g/mL |___ 6.82 g/mL 6.95 g/mL | % error
(100) 1.87% 6.95 g/mL Chemistry: Matter and Change Chapter 2
Solutions Manual
25

CHAPTER
2
SOLUTIONS MANUAL
102. Evaluate the following conversion. Will the
107. Astronomy The black hole in the galaxy
answer be correct? Explain. 75 m 60 s 1h rate _ _ _ 1s 1 min 60 min
No, the conversion is not correct because the units of rate should be m/min. Thi
s expression yields the units m h/min2. The last conversion 60 min factor should
be . 1h
M82 has a mass about 500 times the mass of the Sun. It has about the same volume
as the Moon. What is the density of this black hole? mass of the Sun 1.9891 103
0 kg volume of the Moon 2.1968 1010 km3
massblack hole 500 masssun 500 (1.9891 1030 kg) 9.9455 1032 kg volumeblack hole
2.1968 1010 volumemoon km3 mass __
black hole
_
103. You have a 23-g sample of ethanol with a
density of 0.7893 g/mL. What volume of ethanol do you have?
volume 23 g mass _ __ density 0.7893 g/mL 29 mL
densityblack hole
32
volume
104. Two separate masses of zinc were measured
on a laboratory balance. The first zinc sample had a mass of 210.10 g, and the s
econd zinc sample had a mass 235.10 g. The two samples were combined. The volume
of the combined sample was found to be 62.3 mL. Express the mass and density of
the zinc sample in the correct number of significant figures.
mass density 210.10 g 235.10 g 62.3 mL 445.20 g 7.15 g/mL 445.10 g mass _ _ volu
me
9.9455 10 kg __ 2.1968 1010 km3 densityblack hole
black hole
4.5273
1022 kg/km3
( 4.5273
1022 kg/km3 )
(_)(_) (_)
1000 g 1 km 3 1 m 3 1000 m 100 cm 1 kg 4.5273 1022 3 9 6 4.5273
1010 g/cm3

108. The density of water is 1 g/cm3. Use your


answer from Question 107 to compare the densities of water and a black hole.
The density of the black hole is 4.5273 1010 g/cm3 (almost fifty billion) times
greater than that of water.
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
105. What mass of lead (density 11.4 g/cm3) would
have a volume identical to 15.0 g of mercury (density 13.6 g/cm3)?
volume of mercury mass of mersury __ density of mercury 1.10 cm3 mercury
109. When multiplying 602.4 m by 3.72 m, which
value determines the number of significant figures in the answer? Explain.
3.72 m determines the number of significant figures in the answer because it is
the original value having the fewest number of significant figures.
__
15.0 g mercury g/cm3 13.6 mercury
mass of lead (volume of lead) (density of lead) ( 1.10 cm3 ) ( 11.4 g/cm3 ) 12.5
g lead
106. Three students use a meterstick with milli110. Round each figure to three significant figures. a. 0.003210 g
0.00321 g
meter markings to measure a length of wire. Their measurements are 3 cm, 3.3 cm,
and 2.87 cm, respectively. Explain which answer was recorded correctly.
The third student (2.87 cm) is correct. A meterstick has markings to the millime
ter, so a third digit should be estimated.
b. 3.8754 kg
3.88 kg
c. 219,034 m
219,000 m
26
Chemistry: Matter and Change Chapter 2
Solutions Manual

CHAPTER
2
SOLUTIONS MANUAL
d. 25.38 L
25.4
112. Cough Syrup A common brand of cough
e. 0.08763 cm
0.0876 cm
f. 0.003109 mg
0.00311 mg
111. Graph the data in Table 2.7, with the volume
syrup comes in a 4-fluid ounce bottle. The active ingredient in the cough syrup
is dextromethorphan. For an adult, the standard dose is 2 teaspoons, and a singl
e dose contains 20.0 mg of dextromethorphan. Using the relationship, 1 fluid oun
ce 29.6 mL and 1 teaspoon 5.0 mL, determine how many grams of dextromethorphan a
re contained in the bottle.
1 teaspoon 4 fluid ounces 29.6 mL ( __ ) ( __ ) ( __ ) 5.0 mL 1 bottle fluid oun
ce 20 mg 0.001 g __ _
on the x-axis and the mass on the y-axis. Then calculate the slope of the line.
Density Data
Volume (mL) 2.0 mL 4.0 mL 6.0 mL 8.0 mL 10.0 mL Mass (g) 5.4 10.8 16.2 21.6 27.0
(
1 mg 2 teaspoons 0.24 g dextromethorphan/bottle
)(
)
Thinking Critically 113. Interpret Why does it make sense for the line in Figure
2.16a on page 57 to extend to (0, 0) even though this point was not measured?
Chlorine in the Stratosphere
The graph shows a direct relationship between mass and volume. slope
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
21.6 g 10.8 g __ 8.0 mL
4.0 mL
2.7 g/mL
CFC113 6% HCFC22 3% Methyl chloroform 10% CFC12 28%
Density Data
30 25
CFC11 23% Methyl chloride 15% Carbon tetrachloride 12%
Mass (g)

20 15 10 5 0 2.0 4.0 6.0 8.0 10.0


Hydrogen chloride 3%
Volume (mL)
Manufactured compounds Natural sources
Extrapolation of measured data extends the line to this point. The graph shows t
hat an object with no mass will have no volume.
114. Infer Which of these measurements was
made with the most precise measuring device: 8.1956 m, 8.20 m, or 8.196 m? Expla
in your answer.
8.1956 m because it has the greatest number of significant figures
Solutions Manual
Chemistry: Matter and Change Chapter 2
27

CHAPTER
2
SOLUTIONS MANUAL
115. Apply Concepts When subtracting or adding
two numbers in scientific notation, why do the exponents need to be the same?
Equal place values should be added to each other.
Nutrition Facts
Serving Size cup (29 g) Servings Per Container about 17
Amount Per Serving
Calories 120
Calories from Fat 10
116. Compare and Contrast What advantages
do SI units have over the units commonly used in the United States? Are there an
y disadvantage to using SI units?
Answers will vary but might include that units based on powers of ten are easy t
o convert from one to another. Most disadvantages involve the initial changing f
rom another system to SI.
% Daily Value * Total Fat 1g 2% Saturated Fat 1 g 5% Cholesterol 0 mg 0% Sodium
160 mg 7% Potassium 25 mg 1% Total Carbohydrate 25 g 9% Dietary Fiber less than
1 g 2% Sugars 13 g Protein 1 g Vitamin A 4%
117. Hypothesize Why do you think the SI standard for time was based on the distance light travels through a vacuum?
There is no chance for matter to interfere with the speed measurement in a vacuu
m.
( __ ) ( __ ) ( __ ) ( ) (_)
2.0 cups cereal 160 mg salt 1 serving 430 mg 7 percent 160 mg 19%
1 serving 0.75 cups cereal 0.001 g salt 0.43 g salt 1 mg
118. Infer Why does knowing the mass of an
object not help you identify what material the object is made from?
Mass itself has no meaning without a measurement of its volume. If the object is
a pure substance and its mass and volume are known, its density can help identi
fy it.
121. Predict Four graduated cylinders each
contain a different liquid: A, B, C, and D. Liquid A: mass Liquid B: mass Liquid
C: mass Liquid D: mass 18.5 g; volume 12.8 g; volume 20.5 g; volume 16.5 g; vol
ume 15.0 mL 10.0 mL 12.0 mL 8.0 mL
119. Conclude Why might property owners hire
a surveyor to determine property boundaries rather than measure the boundaries t
hemselves?
Surveyors use equipment that is not affected by terrain or obstacles.

Examine the information given for each liquid and predict the layering of the li
quids if they were carefully poured into a larger graduated cylinder.
Liquid A density Liquid B density 18.5 g /15.0 mL 12.8 g /10.0 mL 20.5 g /12.0 m
L 16.5 g /8.0 mL 1.23 g/ml 1.28 g/ml 1.71 g/mL 2.1 g/mL
120. Apply Dimensional Analysis Evaluate
the breakfast cereal nutritional label shown in Figure 2.20. This product contai
ns 160 mg of salt in each serving. If you eat 2.0 cups of cereal a day, how many
grams of salt are you ingesting? What percent of your daily recommended salt in
take does this represent?
Liquid C density Liquid D density
From top to bottom the liquids would be liquid A, liquid B, liquid C and liquid
D on the bottom.
28
Chemistry: Matter and Change Chapter 2
Solutions Manual
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

CHAPTER
2
SOLUTIONS MANUAL
Challenge Problem 122. Carboplatin (C6H12N2O4Pt) is a platinumcontaining compoun
d that is used to treat certain forms of cancer. This compound contains 52.5% pl
atinum. If the price for platinum is $1047/troy ounce, what is the cost of the p
latinum in 2.00 g of this compound? A troy ounce is equal to 480 grains, and one
grain is equal to 64.8 mg.
125. Units Research and report on unusual units of
measurement such as bushels, pecks, firkins, and frails.
Student answers will vary. For example, a firkin (a small wooden tub used for bu
tter and lard) is a unit of volume equal to barrel.
126. Product Volume Research the range of
(
(
1
g

__ ) ( _ ) ( _ ) (
2.00 g carboplatin
mg 1 grain 0.001 g
carboplatin 1 troy

__ ) ( ___ )
)
64.8 mg $1047.00 1 troy ounce platinum 52.2 g platinum 100
ounce 480 grains $35.3

volumes used for packaging liquids sold in supermarkets.


Student answers will likely include fluid ounces, quarts, half-gallons, gallons,
liters, and milliliters.
127. Dosing Error In hospitals, medicines are
given by dose. Find out what amount of error in the administered dose is accepta
ble for various medicines.
Student answers will vary. For definitive information on the subject, encourage
students to contact the U.S. National Institute of Standards and Technology (NIS
T), manufacturers, pharmacists, or hospital pharmacies.
Cumulative Review 123. You record the following in your lab book: a liquid is th
ick and has a density of 4.58 g/mL. Which data is qualitative? Which is quantita
tive? (Chapter 1)
Thick is qualitative; a density of 4.58 g/mL is quantitative.
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
Document-Based Questions
Ocean Water The density of pure water is 1.00 g/cm3 at 4C. Ocean water is denser
because it contains salt and other dissolved substances.The graph in Figure 2.21
shows the relationships among temperature, density, and salinity versus depth f
or ocean water.
1.023 1.024 1.025 1.026 1.027 1.028 1.029 34.0 0 500 0 34.5 4 35.0 8 12 35.5 18 36.0
20 36.5
Additional Assessment
Writing in Chemistry
124. Kilogram Standard Although the standard
Ocean depth (m)
kilogram is stored at constant temperature and humidity, unwanted matter can bui
ld up on its surface. Scientists have been looking for a more reliable standard
for mass. Research and describe alternative standards that have been proposed. F

ind out why no alternative standard has been chosen.


Two alternative methods of defining the standard kilogram would base the unit on
the Avogadro constant, which is the number of atoms in 12 grams of pure carbon12. One method would depend in part on X-ray measurements in silicon crystals. A
nother method would depend on electrical measurements that determine the ratio o
f the mechanical watt to the electrical watt. At this time, scientists have not
gained universal acceptance for either alternative method.
Density (g/cm3)
Salinity ()
24 Temperature ( C)
1000 1500 2000
Temperature Density
Salinity
2500 3000
Data obtained from Windows to the Universe, at the University Corporation for At
mospheric Research (UCAR).
Solutions Manual
Chemistry: Matter and Change Chapter 2
29

CHAPTER
2
SOLUTIONS MANUAL
128. How is temperature related to the density of
Use the table below to answer questions 4 and 5.
Measured Values for a Stamps Length
Student 1 Trial 1 Trial 2 Trial 3 Average 2.60 cm 2.72 cm 2.65 cm 2.66 cm Studen
t 2 2.70 cm 2.69 cm 2.71 cm 2.70 cm Student 3 2.75 cm 2.74 cm 2.64 cm 2.71 cm
ocean water at depths less than 1000 m?
The temperature is fairly stable through the first 200 meters then decreased rap
idly to a depth of 1000m. As the temperature decreases the density of the ocean
increases. Below 1000 m the density of the ocean remains constant with a slight
decrease in temperature.
129. Describe the effect depth has on salinity.
The salinity rapidly decreases through the first 500 m, then increases with an i
ncrease in depth.
4. Three students measured the length of a stamp
130. Describe how salinity changes as the ocean
water cools.
As the ocean water cools below 1000 m the salinity increases.
whose accepted length is 2.71 cm. Based on the table, which statement is true? a
. Student 2 is both precise and accurate. b. Student 1 is more accurate than Stu
dent 3. c. Student 2 is less precise than Student 1. d. Student 3 is both precis
e and accurate.
a
Standardized Test Practice
pages 6667
5. What is Student 1s percent error? a. b. c. d.
b error Percent Error accept value 0.05 cm 100 1.85% 2.71 cm
__
_
100
c
2. Which value is NOT equivalent to the others? a. b. c. d.
c
6. Solve the problem with the correct number of
500 m 0.5 km 5000 cm 5 1011 nm
significant figures. 5.31 8.4 a. 22 b. 21.64 c. 21.642 d. 21.6
d

7.932
3. What is the correct representation of 702.0 g in
scientific notation? a. 7.02 103 g b. 70.20 101 g c. 7.020 102 g d. 70.20 102 g
c
30
Chemistry: Matter and Change Chapter 2
Solutions Manual
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.
Multiple Choice 1. Which is NOT an SI base unit? a. second b. kilogram c. degree
s Celsius d. meter
1.48% 1.85% 3.70% 4.51%

CHAPTER
2
SOLUTIONS MANUAL
7. Chemists found that a complex reaction
10. At what temperature will Gas B have a volume
occurred in three steps. The first step takes 2.5731 102 s to complete, the seco
nd step takes 3.60 101 s, and the third step takes 7.482 101 s. What is the total
amount of time elapsed during the reaction? a. 3.68 101 s b. 7.78 101 s c. 1.37
101 s d. 3.3249 102 s
d
of 30L? a. 170 K b. 350 K c. 443 K d. 623 K
b
11. Which is NOT a quantitative measurement of a
8. How many significant figures are there in a
distance measurement of 20.070 km? a. 2 b. 3 c. 4 d. 5
d 257.31 s 0.36 s 74.12 s 332.49 s The answer should have two digits to the righ
t of the decimal for the correct number of significant digits.
pencil? a. length b. mass c. color d. diameter
c
Short Answer Use the diagram below to answer Questions 12 and 13.
0 mm 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
0 cm
1
2
3
4
5
6
7
8
9
10
11
12
13

14
15
Copyright Glencoe/McGrawHill, a division of The McGrawHill Companies, Inc.
Use the graph below to answer questions 9 and 10.
12. Explain which ruler you would use to make the
Volume v. Temperature for Three Gases
100
more precise measurement. Explain which is more accurate.
The top ruler allows more precise measurements because it has more divisions.
Volume (L)
80 60 40 20 0 0
Gas A
Gas B Gas C 100 200 300 400 500
13. What is the length of the rod using significant
digits?
9.50 mm (accept from 9.48 mm through 9.52 mm due to estimation)
Temperature (K)
9. What volume will Gas A have at 450 K? a. b. c. d.
d
23 L 31 L 38 L 80 L
Solutions Manual
Chemistry: Matter and Change Chapter 2
31

CHAPTER
2
SOLUTIONS MANUAL
Extended Response Use the table below to answer Questions 1416.
Temperature of a Solution While Heating
Time (s) 0 30 60 90 120 150 180 Temperature (C) 22 35 48 61 74 87 100
16. Choose and explain two safety precautions the
student should use with this experiment.
Acceptable answers include wearing safety goggles, tying hair back, using hand p
rotection, keeping flammable chemicals away, knowing the location of fire safety
equipment.
SAT Subject Test: Chemistry
Use the graph below to answer questions 1721.
Age of Ice Layers in an Ice Sheet
650
Age of ice layer (years)
14. A student recorded the temperature of a solution
600 550 500 450 400 350 300 250 200 50 55 60 65 70 75 80 85 90 95 100
Copyright Glencoe/McGrawHill, a division of The McGrawHill Companies, Inc.
every 30 s for 3 min while the solution was heating on a Bunsen burner. Graph th
e data.
The graph should show a constant linear positive slope.
Temperature of Solution While Heating
120
Temperature (C)
100 80 60 40 20 0 100 30 60 90 120 150 180 210
Depth of ice layer below surface (m)
17. A student reported the age of an ice layer at
Time (s)
15. Show the setup to calculate the slope of the
graph.
Slope equals the change in temperature over the change in time. Divide the diffe
rence in two temperature readings by the difference in the corresponding time re
adings. slope change in temp 87 74 __ _ 150 120 change in time 13 _ .43 C/s 30
70 m as 425 years. The accepted value is 427 years. What is the percent error of
the students value? a. 0.4683% b. 0.471% c. 1.00% d. 49.9% e. 99.5%
a percent error | error | __ accepted value 425 years 427 years ___ 100 427 year
s 100 0.468%
32

Chemistry: Matter and Change Chapter 2


Solutions Manual

CHAPTER
2
SOLUTIONS MANUAL
18. What is the approximate slope of the line? a. b. c. d. e.
e Solution: slope (500 350 y) y _ __ x
( 80
20. What is the relationship between ice depth and
0.00 m/y 0.13 m/y 0.13 y/m 7.5 m/y 7.5 y/m
age? a. Linear, positive slope b. Linear, negative slope c. linear, slope 0 d. N
onlinear, positive slope e. Nonlinear, negative slope
60 ) m 7.5 y/m a
19. What is the depth of an ice layer 450 years old? a. b. c. d. e.
a
74 years 75 years 76 years 77 years 78 m
Copyright Glencoe/McGrawHill, a division of The McGrawHill Companies, Inc.
Solutions Manual
Chemistry: Matter and Change Chapter 2
33

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