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Contents
16
32
38
FEATURES
FEATURE ARTICLE
20 MINUTES WITH
16
Paul A. Bessette
32
Maintenance 4.0
Condition monitoring moves into
its fourth decade with an
increased emphasis on risk
management maintenance.
By Rachel Fowler
46
MARKET REPORT
LUBRICATION FUNDAMENTALS
22
38
WEBINARS
24
22
W W W. ST L E .O RG
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
AUGUST 2016
Contents
DEPARTMENTS
8
EDITOR
Evan Zabawski, CLS
Reliability Specialist
Calgary, Alberta, Canada
evan.zabawski@gmail.com
Tech Beat
RoboBees learning to perch;
monitoring of chemical
reactions in real time;
acousticsa potential
diagnostic tool for lubricants.
PUBLISHER/
EDITOR-IN-CHIEF
Thomas T. Astrene
tastrene@stle.org
ASSOCIATE EDITOR
Rachel Fowler
rfowler@stle.org
56
66
New Products
SynPrime lubricant esters,
dimensional analysis system
and more.
68
72
74
Newsmakers
COLUMNS
4
78
Advertisers Index
80
Resources
Presidents Report
The passing of a legend
Patrick Brutto
ANGUS Chemical Co.
Buffalo Grove, Illinois
Michael N. Kotzalas
The Timken Co.
North Canton, Ohio
Vincent Gatto
Vanderbilt Chemicals, LLC
Norwalk, Connecticut
Coils in oils
David B. Gray
Evonik Oil Additives
Horsham, Pennsylvania
Shawn McCarthy
Ocean State Oil, Inc.
Riverside, Rhode Island
Automotive Tribology
Cutting Edge
Michael D. Holloway
ALS Tribology
Highland Village, Texas
Tyler Housel
INOLEX, Inc.
Philadelphia, Pennsylvania
Copyright 2016 Society of Tribologists and Lubrication Engineers. All Rights Reserved.
TLT magazine is owned and published in print and electronically by the Society of Tribologists and Lubrication Engineers (STLE).
The views set forth in this magazine are those of the authors and not necessarily the views of STLE. Material from TLT magazine
may be reproduced only with written permission from STLE. TLT magazine assumes no liability or responsibility for any
inaccurate, delayed or incomplete information. For more information, contact us at TLT@stle.org.
Subscription and Single Copies: Current volume single copies are $25 (not including shipping and handling). Annual subscription
rate is $225/U.S., $290/international. Prepayment is required before subscription is started. Remittances from foreign countries
must be by international money order or bank draft drawn on U.S. bank.
AUGUST 2016
ADVERTISING SALES
Tracy Nicholas VanEe
Phone: (630) 922-3459
Fax: (630) 904-4563
tnicholas@stle.org
TECHNICAL EDITORS
CONTRIBUTING EDITORS
Stuart F. Brown
Dr. Neil Canter
Dr. Robert M. Gresham
Dr. Nancy McGuire
Debbie Sniderman
DESIGN/PRODUCTION
Joe Ruck
Sounding Board
CIRCULATION
COORDINATORS
Myrna Scott
Judy Enblom
(847) 825-5536
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
Paula Vettel
Novvi, LLC
Emeryville, California
Andras Korenyi-Both
Tribologix, Inc.
Golden, Colorado
Jeff Walkup
Gram & Juhl
Englewood, Colorado
W W W. ST L E .O RG
Fresh air.
To learn more,
scan the QR code or visit
evonik.com/oil-additives.
PRESIDENTS REPORT
Dr. Ali Erdemir
From left to right: Peter Jost, Kenneth Holmberg and Ali Erdemir at the 50-year
celebration of the Jost Report held March 2 at Buckingham Palace.
4 Originally the sixth month and called Sextilis in Latin, August was changed to the eighth month and renamed after Augustus Caesar in 8 BC.
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August 1, 1944: Anne Frank pens her last journal entry. She dies at the Bergen-Belsen concentration camp March 15, 1945, at age 15.
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TECH BEAT
Dr. Neil Canter / Contributing Editor
KEY CONCEPTS
The limited endurance off micro
a rial vehicles reduces their
aerial
ability
b l ty to be used
edd in many
potential
t t l applications.
appl t .
A process
proocesss called
lled electrostatic
el t t t c
adhesion enables a micro
mi o
a rial vehicle called a RoboBee
aerial
too perch below a surface.
Perching enables a RoboBee to
reduce
edu
d cee power
po er consumption
cons
t n by
t eee orders
three
orde
d s of magnitude.
gn t de.
AUGUST 2016
ELECTROSTATIC ADHESION
Graule worked with colleagues including Robert J. Wood, Charles River
Professor of Engineering And Applied
Sciences at the Harvard John A. Paulson School of Engineering and Applied Sciences and the Wyss Institute
for Biologically Inspired Engineering
at Harvard University in Cambridge,
to develop a procedure for enabling
MAVs to perch underneath a surface.
The researchers used a process called
electrostatic adhesion that is similar
W W W. ST L E .O RG
Figure 1 | Electrostatic adhesion enables the RoboBee to perch underneath a leaf. (Figure courtesy of Harvard University.)
REFERENCES
1. Canter, N. (2016), Improving
the efciency of plug-in-hybrid
electric vehicles, TLT, 72 (5),
pp. 16-17.
2. Graule, M., Chirarattananon, P.,
Fuller, S., Jafferis, N., Ma, K.,
Spenko, M., Kornbluh, R. and
Wood, R. (2016), Perching and
takeoff of a robotic insect on
overhangs using switchable
electrostatic adhesion, Science,
352 (6288), pp. 978-982.
Available at http://science.
sciencemag.org/content/352/6288/978.
August 2, 1776: U.S. Continental Congress signs the parchment copy of the Declaration of Independence.
TECH BEAT
KEY CONCEPTS
A new technique for monitoringg real-time chemical
ing
che
h ical
all reac
react o s uses nanoparticles
ti
tions
nanop ticles
prepared from
ffrom perovskite and
cesium lead halides.
The nanoparticles exchange
halides causing a gradual color
change
h gee in the reaction
reactt n mixture
mi t e
t at can
that
c n be monitored to follow
the progress of
of the reaction.
Potentially this approach could
m nitor the detection and
monitor
a d
relati e concentration of
relative
conta
contaminants
nt ina
in ts in lubricant
lubric
ub ca t
systems.
10
Maye. He says, A certain degree of exdetermine the condition of the lubripertise is needed to do analytical techcant. In a previous TLT article, a sensor
niques such as NMR. The time needed
device was developed that can be used
to take a sample from a reaction vessel,
to determine the viscosity of a liquid
1
travel to the location of the NMR inin real time. The approach used by
strument and wait for instrument time
the researchers was to measure parameters that can then be
converted to viscosity
through a mathematiReal-time monitoring provides instant
cal relationship in a
data that enables the end-user to
process known as an
inverse method.
determine the progress of a chemical
A similar strategy
reaction.
for running chemical
reactions also would
prove to be benecial.
also can be problematic.
There are a large number of additive
A more desirable way to monitor
chemistries used in lubricants that
chemical reactions is a sensor that can
are prepared by different processes.
In many cases, specic parameters are
provide real-time data enabling the refollowed through a sampling technique
searcher to know how far the reaction
to determine when the reaction has
has progressed. One of the best ways to
reached its end point.
accomplish this goal is through sensing
Dr. Mathew Maye, associate profesa change in the color of the reaction
sor of chemistry at Syracuse Univermixture.
sity in Syracuse, N.Y., says, Chemical
Maye says, One of the areas of our
research deals with the examination
reactions are difcult to follow over
of inorganic nanomaterials like quantime. Samples need to be taken from a
tum dots. Recently in evaluating a new
reaction vessel and then evaluated by
an analytical method such as nuclear
nanomaterial known as a perovskite,
magnetic resonance (NMR) or mass
with a unique cesium lead halide comspectroscopy to give the researcher an
position, we found out by accident
that a color change occurred in an exindication of how close the reaction is
periment where chloride contaminants
to completion.
were present in a solvent. This result
There are challenges in monitoring
prompted us to determine if perovskite
reactions in this fashion according to
August 3, 1492: Christopher Columbus sets sail from Palos, Spain, with the Nina,
Figure 2 | Perovskite-based
nanoparticles can follow a halide
exchange reaction through a
gradual color change, taking
place over a 90-minute period in
the images shown on the right
side of the gure. Use of a nonhalide-starting material does not
cause a reaction leading to no
color change as shown on the left
side of the gure. (Figure courtesy
of Syracuse University.)
the Pinta and the Santa Maria in search of a westerly trade route to the Far East.
REFERENCES
1. Canter, N. (2012), Real-time
monitoring of viscosity, TLT, 68
(6), pp. 16-18.
2. Doane T., Ryan, K., Pathade, L.,
Cru, K., Zang, H., Cotlet, M. and
Maye, M. (2016), Using
perovskite nanoparticles as halide
reservoirs in catalysis and as
spectrochemical probes of ions in
solutions, ACS Nano. DOI:
10.1021/acsnano.6b00806.
11
TECH BEAT
KEY CO
CONCEPTS
C
S
Jet noise is an old problem
t at dates
that
d t s back
bac prior too th
the
development of jet aircraft.
A new study uses input-output
p t-output
analysis to enable researchers
to focus only on those bits of
tu bbulence
turbulence
e ce that
th t are
arre important
to noise
noi e production
p oduction in
subsonic jets.
The researchh suggests
ts that
t at
noise potentially
potentially could serve
as a diagnostic tool to analyze
anal e
lubrication problems.
proble .
12
AUGUST 2016
WERE NAVIGATING
THE TRENDS
SO YOU DONT
HAVE TO.
TECH BEAT
With the increasing demand for air travel globally, jet noise is becoming a bigger problem, particularly with airports near major population centers. A
new study is providing more insight into how noise is generated within a subsonic jet engine.
AUGUST 2016
noise can be used as a potential diagnostic tool for lubricant analysis. Nichols says, Jet engines produce their own
noise signature, which is representative
of performance. If that noise signature
changes, it may be an indication of an
engine problem.
Additional information on the jet
noise research can be found in a recent article1 or by contacting Nichols
at jwn@umn.edu.
REFERENCE
1. Jeun, J., Nichols, J. and Jovanovic,
M. (2016), Input-output analysis
of high-speed axisymmetric
isothermal jet noise, Physics of
Fluids, 28, 047101.
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20 MINUTES WITH
By Rachel Fowler / Associate Editor
Paul A. Bessette
This self-described chemical tribologist discusses
industry consolidation, education, economicsand his
favorite testing machine.
PAUL A. BESSETTE The Quick File
Paul A. Bessette is the president of
Triboscience & Engineering, Inc. (TS&E),
and lead tribologist for Tecsia Lubricants.
He has been involved with synthetic
lubricants for more than 39 years,
including 25 years at Nye Lubricants and
three years at Ciba-Geigy.
TS&E was established in 2000 and
initially provided consulting services. Since
Paul A. Bessette
2005 TS&E has gravitated toward manufacturing lubricants for both domestic and
foreign customers with an emphasis on peruorinated polyethers.
Paul was vice chairman of the NLGI Grease Education Course for
10 years and was honored with the NLGI Fellows Award, Meritorious
Service Award, Achievement Award, Clarence E. Earle Memorial
Award and Authors Award. He also was an associate editor for
Tribology Transactions, Journal of Synthetic Lubricants and a peer
reviewer for NLGI. He is a member of STLE and ASTM.
Paul earned a bachelors of science degree in chemistry from
Lowell Technological Institute. His graduate work included polymer
chemistry at Brooklyn Polytechnic Institute. He also has a masters
of business administration from University of Massachusetts
Dartmouth.
Clients have included Engineered Custom Lubricants, DuPont,
BP Castrol, Lubrication Technologies, Kyodo Yushi, Honeywell,
Hewlett-Packard and NASA.
Research interests include improving methods of grease
ltration, vapor pressure of synthetic lubricants, thermo-oxidative
stability, low-temperature rheology of oils and greases and
advanced rolling element bearings greases.
Paul has authored or co-authored chapters in Space Vehicle
Mechanisms: Elements of Successful Design, John Wiley & Sons,
Inc.; Handbook of Lubrication and Tribology, CRC Press; and
Synthetic Lubricants and High-Performance Functional Fluids,
Marcel Dekker.
16
August 4, 1962: Apartheid opponent Nelson Mandela is arrested by security police in South Africa and spends
Paul Bessette preparing to run a weight loss determination using the thermogravimetric analysis.
$1,000. Its the application and technology that dictates grease economics. Consider a conductive plastic potentiometer where the lubricant must
function from -40-100 C, be resistant
to fuel vapors and possess a viscosity
index sufciently high that contact
hydroplaning does not occur. A linear
peruoroether grease costing approximately $500 per pound is a viable candidate for this application, but the cost
of grease per potentiometer is marginal
since only milligrams of grease are used
per unit. Even expensive greases usually have a minor impact on the overall
economics of a component.
the next 27 years in prison on charges of treason and sabotage. He would win the Nobel Peace Prize in 1993.
17
AUGUST 2016
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any of these products, read and comply with the information contained in the MSDS, label and other product literature.
LUBRICATION FUNDAMENTALS
Dr. Robert M. Gresham / Contributing Editor
Which
came
first?
The age-old chicken or egg riddle has revealing lessons for those
interested in the causes of climate change.
KEY CONCEPTS
Individuals sometimes confuse the nature off cause
and effect for social or political purposes.
A closer examination of the full range
g of data might
suggest that man-made
de carbon dioxide might not be
the cause of climate change.
The tribology community should
shou d analyze th
these
situations closely before
befo e taking action.
22
August 5, 1962: Marilyn Monroe dies at age 36 from an overdose of sleeping pills.
When in 1999 Antarctic ice cores revealed high carbondioxide concentrations and temperature marching in lockstep
over 400,000 years ago, many found this a convincing argument for attributing past climate change to the emergence
of evil carbon dioxide. About 95% of carbon dioxide in the
atmosphere is natural, coming from normal biological processes. In the past, carbon-dioxide levels rose as the earth
warmed at the end of ice ages and fell as it cooled at the end
of interglacial periods.
However, a few years later more in-depth analysis of ice
cores showed that the temperature changes, in fact, preceded
the changes in carbon dioxide concentrations by about 800
years. The cause-and-effect mechanism is that as the oceans
begin to warm, the rate of the dissolved carbon dioxide begins to out-gas more into the atmosphere. Since the effect
cannot precede the cause, we have to change our thinking
about this particular chicken/egg conundrum.
Temperature changes caused the changes in carbon dioxide levels, not the opposite. Or, gods forbid, carbon dioxide does not really cause global warming! This is heresy of
the highest order. So the ever-clever climate scientists came
up with a novel rationalization (or, if you prefer, hypothesis): An initial change, probably caused by variations in the
earths orbit (really) that affected the warmth of the sun, was
then amplied by changes in carbon dioxide levels. But this
makes for a circular argument as the reversal of the trend after a period of warming (when amplication should be at its
strongest) still harder to explain. Did the earth shift again?
Or if carbon dioxide is still driving the temperature upward
but the temperature is falling, then something else must be
happening and is the more dominant process.
Alternatively, with increases in temperature caused by
Mankind and all of his heat-generating activities and machines, and/or this business of the earth shifting its orbit,
W W W. ST L E .O RG
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
TM
AUGUST 2016
23
WEBINARS
Jeanna Van Rensselar / Senior Feature Writer
Considerations for
thin section bearings
K CO
KE
KEY
CONCEPTS
CEP S
Thin section bearings have a cross section
se ion
that is constant
consta
nstantt regardless
reg rdle s of bore
b re size.
si .
They are used in specialty applications
applicatio such
as robotics that require smooth
s
th movements
mo e entss
andd an accurate,
curatt , stable
st ble axis
axiis off rotation.
tati .
They are very similar to conventional ball
bearings but thinnercreating many
many
advantages
dvant ges andd a few
e disadvantages.
di dvant ge .
24
AUGUST 2016
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
W W W. ST L E .O RG
LLes Mill
Miller
A technical examination of
these unique components,
their applications and
advantages.
An array of Kaydons thin section bearings. (Courtesy of Kaydon Bearings.)
THE FOCUS OF THIS ARTICLE IS THIN SECTION BALL BEARINGS. The difference between the inside and outside diameter
of the rings is much less than standard
bearings, but the cross section remains
constant as the bore diameter changes.
Generally a bearing is considered a
thin section when the bore diameter
is greater than four times the radial
cross section. The considerable advantage of the compact design is slightly
offset by a diminished load-carrying
capacity and temperature limitations
in some cases. The standard material
is high-chrome bearing steel, but they
are available in other materials such as
stainless steel.
Thin section bearings save weight,
create space, reduce friction, increase
design exibility and provide excellent running accuracy. These bearings
Light weight
Multiload capabilities
High stiffness
A small cross section (with a variety
of possible cross sections and sizes).
Thin section bearings were originally developed for applications with tight
space limitations. They continue to be
most advantageous where space limitations and combined loading and/or
August 6, 1962: To end the war in the Pacic, the U.S. drops the rst atomic bomb on Hiroshima at 8:15 a.m. 200,000 perish in the blast. 2 5
THE BASICS
A simple bearing is dened as a device
that supports and facilitates motion between xed and moving machine parts
(see Bearing Denitions and Terms). It
may have internal rolling elements, and
those rolling elements may consist of
balls, cylindrical rollers, tapered rollers
or spherical rollers. A thin section bearing, per ANSI/ABMA standard 26.2,
Thin Section Ball Bearings Inch Design,
is a bearing with a xed cross section so
that ...within a given series, the bearing cross section remains constant irrespective of the bore diameter. This includes ball bearings of (1.) single-row,
radial contact; (2.) single-row, angular
contact; and (3.) single-row, four-point
angular contact.
Single-row radial contact ball bearings
Handle radial loads
Have a zero-degree contact angle
Have a single ball path
Include a snap-over separator
Have a preload or clearance set
at the factory.
Single-row angular contact ball bearings
Are used in pairs
Handle radial, axial or moment
loads
Have a 30-degree contact angle
Have a single-ball path
Include a circular pocket separator
Have a t-up that can be adjusted at installation.
Four-point contact ball bearings
Handle radial, axial or moment
loads
Are used alone
Have 30-degree contact angles
Include a snap-over separator
Have a clearance set at the factory.
Common separator materials include:
Brass. Usually the standard option
for Kaydon catalog bearings.
300 series stainless steel/precipitation
hardened SST wire. Advantages include low outgassing, high-temperature and harsh-environment tolerance. Disadvantages include higher
friction than brass, more particle
26
AUGUST 2016
APPLICATIONS
Thin section bearings make the most
sense in applications that involve tight
spaces, low weight requirements, compact designs and precision. Primary applications are semiconductor mechanisms such as:
Atmospheric and vacuum robots
Wafer probers
Ion implantation
Sputtering equipment
W W W. ST L E .O RG
Test heads/manipulators
Rapid thermal processing (RTP)
Megasonic cleaning systems
Photolithography lens and counterbalance
Chemical mechanical polishers (CMP)
Die bonders
Lappers
Wafer steppers
Transfer systems (SMIF).
These semiconductors typically require a vacuum environment, low-particle generation and high accuracy.
Medical applications include:
Oncology treatment
Robotic surgery
Security scanners
Diagnostic equipment
CT scanners and baggage scanners used for
airport security.
Bearings for CT scanners in particular require quiet operation, long life and low friction (see Figure 1). They require a
large opening for scanning (people or baggage) for which a
large diameter thin section bearing system is key. The long
service life can be achieved with the addition of lithium or
polyurea grease.
August 9, 1974: U.S. President Richard M. Nixon resigns following the Watergate scandal.
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REFERENCES
1. Excerpt from Kaydon Catalog, p.127.
2. From Lubrication and Maintenance of Reali-Slim Thin Section Bearings, Reali-Slim Bearings Catalog 300 Kaydon Bearings. Available
at www.kaydonbearings.com/downloads/catalog300/Kaydon_300_LubeMaintenance.pdf.
30
AUGUST 2016
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
W W W. ST L E .O RG
FEATURE ARTICLE
Dr. Robert M. Gresham / Contributing Editor
KEY CONCE
EPTS
EPTS
Asset man
ma agement
management
g
was a dom
d minant
miinant
m
ant
nt
th e at the
theme
thee LubMat
20 6 confe
2016
co erence
erence
e cee inn
Spai
Spain.
Risk managgement
gement
maintenannce
nce involves
an even
eeveen hi
h gher
higher
gh r use
see of
sensors onn critical
equip entt and big
equipment
bigg
data analyysis.
ysis.
In the futu
future
re robots
willll doo mo
more
re manufacmanuf ct ring whil
turing
whh le
le humans
huu a s
maintain the robots.
32 August 13, 1899: British lm director Alfred Hitchcock is born in London. Hed go on to direct Vertigo, Psycho, The Birds and North by Northwest.
I RECENTLY ATTENDED THE LUBMAT 2016 CONFERENCE IN BILBAO, SPAIN. This conference is
more industry focused than many conferences
in our eld and has a broad international attendanceprimarily greater Europe, the U.S., Central America and South America. At the last conference, LubMat 2014, I made a presentation on
STLEs Emerging Trends report which had come
out that year. It was well received and elicited
good questions and commentary in the halls. Interestingly, at this LubMat many of the plenary
speakers talked about and expanded on emerging trends from their various perspectives.
W W W. ST L E .O RG
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
AUGUST 2016
33
AUGUST 2016
BRASIL
2016
AUGUST 2016
Institution in 2004, the ISO 55000 series of asset management standards was
launched in January 2014. In a recent
article, in Norias Machinery Lubrication, Jim Fitch characterized the standard: Asset management involves the
balancing of costs, opportunities and
risks against the desired performance of
assets, to achieve the organizational objectives. An asset management system
provides a structured approach for the
development, coordination and control
of activities undertaken on assets by the
organization over different life cycle
stages and for aligning these activities
with its organizational objectives.
When one thinks of the enormous
capital investment and the equally enormous repair expense in large wind turbine farms, a Maintenance 4.0 approach
would seem the only logical method to
manage these assets. Manufacturing
robots also can be an expensive investment which is amenable to a Maintenance 4.0 approach. Interestingly, when
you think about manufacturing someT R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
W W W. ST L E .O RG
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$2
4XDOLW\<RX&DQ&RXQWRQ
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MARKET REPORT
Gabriel Tarle
Metalworking
uids:
Global
challenges,
trends and
opportunities
Can Stock Photo Inc. / sspopov
38
August 14, 1935: President Franklin Roosevelt signs the Social Security Act, guaranteeing pensions for Americans at age 65.
REGULATORY TRENDS
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
AUGUST 2016
39
NEW MATERIALS
New materials continue to penetrate
the global automotive and aerospace in-
WERE ADDING
TO OUR MIX
moval uids. Composites do not generally have metal components, and there
is no need for corrosion inhibitors. The
most preferred polymer material is carbon ber reinforced due to its durability
and superior mechanical performance.
However, any polymer-based composite
cannot safely operate at temperatures
above 150 C, well below the high pressure turbine operating temperatures.
The high costs associated with machining the high-temperature metal alloys,
as well as their heavy weight, make the
alloys candidates for future substitution. Currently ceramic-based composites are being researched to replace
metal alloys in some instances.
Non-ferrous metals, alloys, exotic
metals and composites will continue
to change MWF formulation. From the
beginning of the 2000s, the complexity
of automotive and aerospace manufacturing has demanded different types
of uids for ferrous and non-ferrous
metals. Nowadays, weight reduction
40
AUGUST 2016
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
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NEW OEMS
The competition in the passenger jet
industry intensifies as Chinas first
homemade plane just started service.
Japans Mitsubishi announced it also
is entering the market. This comes in
addition to Russias Sukhoi and Brazils
Embraer each launching a line of commercial aircraft.
MWF ADDITIVES
On the functional additive classes, regulatory drivers will have a major impact
on the future use of EP additives. In
the U.S. the transition to vLCCPs will
be more prominent in metal-forming
fluids due to their higher viscosity
compared to MCCPs and LCCPs. But
the vLCCP will be at disadvantage for
metal-removal uids where the sulfurized chemistries are easier to formulate. Both sulfurized olens and fats will
grow as a result. Phosphate esters are a
good substitute for chlorinated parafns
when the cost is justied. They provide
good antiwear and staining protection
for aluminum alloys. However, they are
used in less severe applications. From
the same class, phosphonates are good
for stain-free application.
The use of aluminum alloys have
been increasing and pushing formulators to reduce the uid pH to avoid
alkaline-driven staining. However, the
reduction of the pH generally results
in reducing the uid life when using
phosphate esters, which are food for
microorganisms. TEA could be a good
x due to its buffer abilities but only in
small volume to avoid staining. Amine
carboxylate and lactic acid have no
health and environmental issues, but
only the demand for lactic acid is growing. The demand for DCHA, a permitted secondary amine, has been growing
for a while but is subject to the hazard
label. DCHA, lactic acid and carboxylate are good alternatives to the boron
technology. Boron compounds are used
both in semisynthetic and synthetic
metalworking uids formulations and
42
AUGUST 2016
Preventol CMK Preservative and Preventol CMK 40 are approved by the FDA, EPA and NSF (HX-1) as
antimicrobial preservative for lubricants with incidental food contact. The approved use is up to 1% active
ingredient (p-chloro-m-cresol). PREVENTOL is a registered trademark of LANXESS Deutschland GmbH.
BIOCHEK and VERIGUARD are registered trademarks of LANXESS Corporation.
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
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VERSATILITY
Introducing SynPrime
Lubricant Esters
from PolyOne
Customizable chemistries.
Manufacturing agility.
Collaborative approach.
Gabriel T. Tarle
Gabriel T. Tarle is a senior consultant at Klines Petroleum and Energy practice. He is responsible for both ad-hoc and syndicated
studies across the entire supply chain of nished lubricants and related specialties, ranging from base stocks (virgin and re-rened),
waxes and additives to automotive and industrial lubricants, as well as various process oils.
His key contributions for Klines market studies include Metalworking Fluids: Global Market Analysis and Opportunities; Global
Lubricant Basestocks: Market Analysis and OpportunitiesEurope; Global Wax Industry: Market Analysis and OpportunitiesEurope;
Global Lubricants: Market Analysis and AssessmentDACH, Romania, and other Eastern European countries; Global Synthetic
Lubricants: Market Analysis and OpportunitiesDACH.
Tarle has worked on a number of studies for Klines consulting projects related to market entry, niche market assessment, new
products/services and material demand models.
44
AUGUST 2016
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
www.pilotchemical.com | 1.800.70.PILOT
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PEER-REVIEWED
46
KEY WORDS
Titanium; Oxides; Coatings; Friction Mechanisms
ABSTRACT
The principal goal of the experiments described in this article is to elucidate the effect of oxide layer formation during lubricated sliding on the frictional properties of Ti-coated silicon.
It was found that the TiO2 layer is the prime determinant of the frictional properties of sliding surfaces coated with Ti coating. At the initial stage of sliding, Ti coating showed a high
(0.55) and unstable frictional response. During this period, the Si substrates and Ti coating
were damaged simultaneously, indicating that the wearing of the coating and substrate is
attributed to the high and unstable friction. With the formation of the oxide layer, after a
few cycles of the onset of sliding, the friction coefcient became stable and decreased to 0.16.
By analyzing the oxide layer using scanning electron microscopy (SEM), energy-dispersive
spectroscopy (EDS), and Raman spectroscopy, it was found that the oxide layer (TiO 2
layer) was formed from the debris of the worn Ti coating. Adhesion tests using atomic force
microscopy (AFM) revealed that the adhesive component of the friction of sliding surfaces
was not lowered by the oxide layer. By comparing the SEM images and frictional response,
it was demonstrated that the oxide layer restrained the development of surface damage and
the frictional work was converted to the growth of the oxide layer instead of damaging the
sliding surfaces. From these results, it was conrmed that the deformation component of Ti
coating friction was suppressed by the oxide layer.
BACKGROUND
Generally, sliding components in mechanical systems require a low friction value except for some components such as brakes and clutches. To meet this requirement,
surface coatings have been widely used to tailor the frictional properties of sliding
surfaces (Holmberg and Matthews (1)). Among the surface coatings, Ti and its alloys
are considered as promising materials because of their outstanding properties such
as high resistance against fatigue, low density, corrosion resistance, formability, and
low modulus (Cheng, et al. (2);Rastkar and Shokri (3); Das, et al. (4); Cao, et al. (5)).
Although Ti and its alloys have been widely used, it is very difcult to make accurate
predictions about the frictional response on real components because the oxide layer
formed during sliding rather than the surface coatings dominates it (Bhushan (6); Savas
August 15, 1969: 300,000 young people go on down to Max Yasgurs
TABLE 1CHEMICAL PROPERTIES OF THE WHITE MINERAL OIL USED IN THE PRESENT STUDY (PROVIDED BY MICHANG CO.)
Property
Value
Specic
Gravity
pH
Vapor
Density
Vapor
Pressure
Viscosity
Solubility
in Water
Volatile
Characteristics
0.838
Not applicable
>1
<0.1 mmHg (@ 20 C)
8.2 cSt @ 40 C
Slightly volatile
EXPERIMENTAL DETAILS
During the main experiment, we used a typical ball-on-disk
type tribometer. Using a ball-on-disk sliding tester, we could
observe the formation of an oxide layer during sliding with
a gently applied load. The applied load can be controlled by
providing different dead weights on the steel ball straightway.
The signal transmitted from the strain gage for measuring friction force was transformed with a sampling frequency of 5 Hz.
Silicon wafers with a thickness of 675 m were used as a
substrate for the Ti coating. A 1-m-thick titanium (Ti) coating was deposited by physical vapor deposition using the DC
magnetron sputter method on <100> oriented silicon wafers
with a hardness of 12.4 GPa and surface roughness (Rq) of
300 nm. As the counterpart against the coated surfaces, an
AISI 52100 bearing steel ball with a diameter of 10.16 mm
was chosen. The disk sample rotated at a sliding speed of 0.02
m/s during test. All sliding tests were performed in a white
mineral oil (Michang Co.) environment in order to generate
mild sliding, allowing us to explore the relation between the
formation of the oxide layer and frictional properties. Table 1
provides the chemical properties provided by Michang. During the tests, room temperature and constant humidity of 15%
were maintained.
Two types of friction tests were performed with the experimental conditions mentioned above. Four different applied loads ranging from 2 to 6 N were used in order to make
comparisons of the effects of the oxide layer on the frictional
properties under diverse loads; additional sliding tests were
subsequently made with an applied load of 4 N. These tests
were paused at certain sliding cycles in order to clearly observe the process of oxide layer formation during sliding.
Herein, the latter type of test is designated as a stage-by-stage
test. The worn surfaces generated from the stage-by-stage tests
were analyzed to determine the effect of the formation of the
oxide layers using SEM, EDS, Raman spectroscopy, and AFM.
47
In particular, the tests results from EDS and Raman spectroscopy were used to conrm the type of oxide layer.
An SEM/EDS system manufactured by JEOL (JSM-7600F)
was used to observe the formation of the oxide layer. Raman
spectroscopy (Alpha300 M+, WITEC GMbH) was also employed to conrm the oxide species formed on the wear track.
The adhesion force of the unworn Ti coating, oxide layer,
and wear track without oxide were measured using an AFM
manufactured by Seiko Instruments (E-sweep). A sharp AFM
silicon tip, SI-AF01, fabricated by Seiko Instruments was used
and its normal spring constant was 0.22 N/m. The normal
spring constant was calculated using the following equation
(Palacio and Bhushan (18)):
KN =
Ewt3
,
4l3
[1]
AUGUST 2016
(d) 2 N.
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
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Lubrhophos LF800
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50
AUGUST 2016
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
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Figure 3 | SEM images of the wear under 4 N contact loads in different stages: (a) stage 1, (b) stage 2, (c) initial point of stage 3, (d)
stable point of stage 3. White arrows indicate the sliding direction.
Scale bar, 200 +m.
August 16, 1977: Elvis Presley dies from a heart attack reportedly brought about by years of abusing prescription drugs.
51
AUGUST 2016
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Grease Relief
ALUMINUM COMPLEX TAKES THE
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(Figures 2c, 2d, 3c, 3d). In addition, it can be seen that the
size and density of the crater on the worn surfaces did not
signicantly increase after the oxide layer formation (Figure
3). The fact that the craters are not generated more and hardly
grow after the onset of oxide lm formation imply that the
frictional work is converted to the formation of oxide lm
but damage to the surfaces. The oxide lm generated in front
of the crater also can be a factor restraining the development
of craters. Therefore, it can be speculated that the formation
of the oxide layer is highly relevant to the reduction in the
deformation component of friction rather than the adhesion
component. Further study is required to clearly determine
this mechanism.
CONCLUSION
Herein, the effect of oxide layer formation on the frictional
properties of Ti coating was explored. During the few cycles
after the onset of sliding, the friction coefcient of Ti coating
was relatively high (0.55) and unstable. This is attributed to
the wear of the coating and the generation of a crater on the
Si substrate. After the formation of an oxide layer, the friction coefcient was approximately 0.16 and stably saturated.
The analysis of EDS and Raman signal reveals that the wear
debris of Ti coating reacted with oxygen and was transformed
to the TiO2 layer. By testing the adhesive force of the unworn
Ti coating and the worn surfaces, it was conrmed that the
adhesive component was not relevant to the reduced friction.
The SEM and EDS analysis of the worn surfaces showed that
August 18, 1920: The 19th Amendment to the U.S. Constitution is passed, giving women the right to vote.
REFERENCES
1. Holmberg, K. and Matthews, A. (2009), Coatings Tribology:
Properties, Mechanisms, Techniques and Applications in Surface
Engineering, Elsevier Science: Amsterdam.
2. Cheng, J., Yu, Y., Fu, L. C., Li, F., Qiao, Z. H., Li, J. S., Yang,
J., and Liu, W. M. (2013), Effect of TiB2 on Dry-Sliding Tribological Properties of TiAl Intermetallics, Tribology International, 62, pp 9199.
3. Rastkar, A. R. and Shokri, B. (2008), A Multi-Step Process
of Oxygen Diffusion to Improve the Wear Performance of a
Gamma-Based Titanium Aluminide, Wear, 264(1112), pp
973979.
4. Das, G., Kestler, H., Clemens, H., and Bartolotta, P. A. (2004),
Sheet Gamma TiAl: Status and Opportunities, JOM, 56(11),
pp 4245.
5. Cao, X., Shao, T., and Wen, S. (2004), Micro/Nanotribological and Mechanical Studies of TiN Thin-Film for MEMS Applications, Tribology Transactions, 47, 227232.
6. Bhushan, B. (2002), Introduction to Tribology, John Wiley &
Sons: New York.
7. Savas, S. and Danisman, S. (2014), Multipass Sliding Wear
Behavior of TiAlN Coatings Using a Spherical Indenter: Effect of Coating Parameters and Duplex Treatment, Tribology
Transactions, 57, 242255.
8. Egaa, A., Rech, J., and Arrazola, P. J. (2012), Characterization of Friction and Heat Partition Coefcients during Machining of a TiAl6V4 Titanium Alloy and a Cemented Carbide, Tribology Transactions, 55, 665676.
9. Blau, P. J., Erdman, D. L., III, Ohriner, E., and Jolly, B. C.
(2011), High-Temperature Galling Characteristics of Ti-6Al4V with and without Surface Treatments, Tribology Transactions, 54, 192200.
Ti6Al4V alloy (Molinari, et al. (24)) and TiN (Cho and Lee
(13), (19)). Therefore, this study not only provides useful
information for the lubrication engineer to utilize the Ti coating but also shows the fact that the frictional characteristics
of each Ti-based material should be understood based on the
formation of the oxide layer.
22. Melendres, C. A., Narayanasamy, A., Maroni, V. A., and Siegel, R. W. (1989), Raman-Spectroscopy of Nanophase TiO2,
Journal of Materials Research, 4(5), pp 12461250.
11. Cho, C. W., Hong, B., and Lee, Y. Z. (2005), Wear Life Evaluation of Diamond-Like carbon Films Deposited by Microwave
Plasma-Enhanced CVD and RF Plasma-Enhanced CVD Method, Wear, 259(16), pp 789794.
23. Feist, T. P. and Davies, P. K. (1992), The Soft Chemical Synthesis of TiO2 (B) from Layered Titanates, Journal of Solid
State Chemistry, 101(2), pp 275295.
12. Polcar, T., Kubart, T., Novak, R., Kopecky, L., and Siroky, P.
(2005), Comparison of Tribological Behaviour of TiN, TiCN
and CrN at Elevated Temperatures, Surface & Coatings Technology, 193(13), pp 192199.
W W W. ST L E .O RG
24. Molinari, A., Straffelini, G., Tesi, B., and Bacci, T. (1997),
Dry Sliding Wear Mechanisms of the Ti6Al4V Alloy, Wear,
208(12), pp 105112.
25. Bowden, F. P. and Tabor, D. (1964), The Friction and Lubrication of Solids, Part II, Clarendon Press: Oxford, UK.
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
AUGUST 2016
55
NEWSMAKERS
TOP STORIES
SKF PROVIDES LUBRICATION SOLUTIONS FOR ONE OF
WORLDS LARGEST COPPER MINES
Gothenburg, Sweden-based, SKF has secured a contract with
the Las Bambas mine in Peru to provide lubrication management services for all electric motors in the mines concentrator
plant.
Engineered specically for Las Bambas, the lubrication
solutions will contribute to increased equipment reliability
and cost effectiveness.
The two-year agreement with Las Bambas includes engineering, planning and scheduling, execution and management
of all lubrication-related activities for the electric motors. In
addition, SKF will supply lubrication system components and
tools to the mine.
As part of its reliability program, Las Bambas needed a
world-class lubrication system for its electric motors, says
service and upselling manager Carlos Lahura of SKF Peru.
Mine personnel contacted SKF to develop a series of integrated lubrication solutions for their rotating machinery and
were impressed by our expertise and commitment. As a result,
SKF was engaged to provide lubrication management services
as well.
The ultimate SKF three-barrier solution, consisting of
sealed SKF explorer spherical roller bearings, housings and
SKF taconite seals, also has been deployed for the mines
overland conveyor belts, with shafts measuring between
500-700 mm. The bearings and housings provided will have
integrated sensor positions for condition monitoring that offer the improved contamination protection needed in severe
weather conditions.
Biobased content*
77%
66%
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47%
100%
49%
68%
brother Wilbur achieve the rst sustained ight by a controlled motorized aircraft.
57
further validation that by working together with its customers, its DigitalClone software is making a huge impact on
the wind industry.
AUGUST 2016
Anthony Conti, NextEra Resources, and Edward Wagner, Sentient Science, accepted awards for industry excellence at the
Wind Energy Update Dallas O&M Show.
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
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STLE
PRESIDENTIAL
AWARDS
PROGRAM
AWARDS
The E. Richard Booser Scholarship
for Undergraduate Students
The E
E. Elme
Elmer Klaus Fellowship
for Graduate Students
Society of Tribologists and Lubrication Engineers, 840 Busse Highway, Park Ridge, IL 60068 (USA), P: (847) 825-5536, F: (847) 825-1456, www.stle.org.
LEADING EDGE
I SpectraSyn Plus Base Oils Group IV I Pure Performance Base Oils Group II
I SpectraSyn Polyalphaolefin
I ConoPure Process Oils
Base Oils Group IV
I Esterex Esters Group V
60
August 21, 1959: President Dwight Eisenhower signs a proclamation admitting Hawaii into the U.S. as the 50th state.
2016 STLE
Tribology
Frontiers
Conference
The Drake Hotel Chicago
Nov. 13-15, 2016
Places of Interest The Art Institute of Chicago Museum of Science and Industry
Field Museum Shedd Aquarium Willis Tower Lincoln Park Zoo
John Hancock Building Navy Pier Millennium Park Michigan Avenue shopping
Follow us on:
Society of Tribologists and Lubrication Engineers, 840 Busse Highway, Park Ridge, IL 60068 info@stle.org www.stle.org 847-825-5536
TLT
T R I B O LO G Y &
LU B R I C AT I O N
T E C H N O LO G Y
62
AUGUST 2016
IN MEMORIAM
MIKE RYTERSKI
With great sadness TLT reports that
Mike Ryterski passed away in May at
the age of 96.
Admired and respected by his coworkers, Ryterski was known for his
wry sense of humor and dedication to
Schaeffer Manufacturing Co. Ryterski
was one of the few master blenders
of lubricants in the world; his exper-
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
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Biotribology
Condition Monitoring
Engine & Drive Train
Environmentally Friendly Fluids
Fluid Film Bearings
Gears
Grease
Lubrication Fundamentals
Materials Tribology (includes
Ceramics and Composites)
Metalworking Fluids
Nanotribology
Nonferrous Metals
Power Generation
Rolling Element Bearings
Seals
Surface Engineering
Synthetic and Hydraulic Lubricants
Tribotesting
Wear
Wind Turbine Tribology
Abstract Submission
If you are interested in presenting at STLEs 2017 Annual Meeting & Exhibition, submit a 100-150-word abstract at
www.stle.org. Abstracts are due Oct. 1, 2016. Notication of acceptance will be sent in December 2016. While you do
not need to prepare a full manuscript to be included on the meeting technical program, you are invited and encouraged
to submit a manuscript for review and possible publication in STLEs peer-reviewed journal, Tribology Transactions.
For more information, please contact:
Merle Hedland mhedland@stle.org 630-428-2133
Follow us on
#STLE2017
Society of Tribologists and Lubrication Engineers, 840 Busse Highway, Park Ridge, IL 60068, info@stle.org, www.stle.org.
-IN MEMORIAM-
H. Peter Jost
(1921-2016)
Father of modern tribology
lived to see 50th anniversary
of his world-changing
research report.
Professor H. Peter Jost
With deep sadness TLT reports the
death of a tribology legend, professor H.
Peter Jost, CBE. He died peacefully at
the age of 95.
Professor Jost was regarded as the
founding father of tribology and was
trained as an engineer. On March 9,
1966, his report titled the Lubrication
(Tribology) Education and Research: A
Report on the Present Position and Industrys Needsalso known as the Jost
Reportwas published. It was acclaimed
worldwide and changed the way our industry and science approach the question
of friction and wear. This is when the
word and concept of tribology rst entered the public domain. This report was
the key to the development of tribology.
The Jost Report was published 50
years ago. In March 2016, Peter Jost,
STLE Immediate Past President Martin
Webster and President Ali Erdemir were
invited to a celebration that included a
reception at Buckingham Palace hosted
by His Royal Highness Prince Philip,
the Duke of Edinburgh. In Martins
May 2016 Presidents Report column,
he wrote about his experience at the
celebration. He stated, Professor Peter
Jost responded and thanked the Prince
for hosting the event. He also reminded
us that tribology is critical to life on this
planet and that indeed without friction
we would never be able to leave the
room. I think many of us would have
been happy with that, at least for a few
extra hours! He also noted that tribology is undergoing a signicant expansion as we see a greater emphasis on the
64
AUGUST 2016
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
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66
August 24, 79 A.D.: Vesuvius, an active volcano in Southern Italy, erupts destroying the cities of Pompeii, Stabiae and Herculaneum.
Send us your new product news with color photos to: TLT Magazine, Attn: Rachel Fowler, 840 Busse Highway, Park Ridge, IL 60068, rfowler@stle.org
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SOUNDING BOARD
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3 %
35%
No
65%
65%
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
Altered States by Paddy Chayefsky. I read the book before seeing the
movie. The idea of sensory deprivation leading to an altered state of
consciousness was pretty interesting.
Fantastic Voyage. Intriguing
because of the scientic nature of
the plot and applicability to human
physiology and health.
The Riverworld books by Philip
Jos Farmer.
I, Robot by Isaac Asimov.
The classic books by Jules Verne,
Ray Bradbury and H.G. Wells.
The Twilight Zone, Rod Serlings
TV series.
The Lensman series by E.E. Smith.
AUGUST 2016
69
SOUNDING BOARD
The Doc Savage book series. I
read them when I was an early teen.
The stories are mysteries and were
written in the 1930s to 1940s. Many
of the tools and gadgets used in the
stories were unheard of and considered fantastic at the time but have
come into use today.
Songs of Distant Earth by
Arthur C. Clarke. Its a story of
the meeting of two human cultures:
one for which Earth is only a
distant legend, and the other the
nal group of people who left
Earth before its nal destruction.
I found it both uplifting and
poignant. Or maybe Asimovs
Robot/Foundation series.
The Time Machine by H.G. Wells.
When it was published in the late
1890s it was way ahead of its time
and genre.
KRISTIN REDMAN
Enterprise
Account Manager
49%
No
5%
51%
Editors Note: Reprinted from another issue of TLT. Sounding Board is based on an email survey of 13,000 TLT readers. Views expressed are those of the respondents
and do not reect the opinions of the Society of Tribologists and Lubrication Engineers. STLE does not vouch for the technical accuracy of opinions expressed in
Sounding Board, nor does inclusion of a comment represent an endorsement of the technology by STLE.
Were on the
job even when
were off the clock
Its not that we dont take time off, its that
we never waste time on. We invest in your
success. Were proactive in your prosperity.
And we approach our workdays with your
best interests front and center. Were ready
to show why Palmer Holland is more than
just a simple extension of your business.
Want to
Heighten
Your
Industry
Prole?
Include TLT in your
marketing strategy.
Your ad message
will reach 13,000
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decision makers in its
print and digital editions.
For information on how to customize
a multimedia marketing program that
ts your budget, contact:
National Sales Manager
Tracy Nicholas VanEe
(630) 922-3459
tnicholas@stle.org
Page
Acme-Hardesty Co.
40
IFC
BASF
OBC
77
23
50
Chemtura
13
75
31
El Corp.
41
Emery Oleochemicals
27
Federal Process
53
INOLEX, Inc.
35
60
45
LANXESS Corp.
42
79
69
37
65
70, 71
Pilot Chemical
44
PolyOne Corp.
43
Royal Manufacturing
76
67
Soltex, Inc.
19
Solvay Novecare
49
63
STLE Certication
73
59
61
15
57
IBC
29
21
72 August 27, 1910: Mother Teresa is born in Skopje, Yugoslavia, and devotes her life to helping the poor of India. She is slated to become a saint next month.
S T L E C E R T I F I C AT I O N
Invest in your greatest
assetyourself.
Credibility. Respect. Integrity.
Those are the qualities immediately conferred upon you
when you attain one of STLEs technical certications.
Becoming STLE certied not only veries your technical
expertise, it demonstrates your professional dedication
to your employer, customers and peers.
STLE offers four technical certications:
Certied Lubrication Specialist
STLEs signature certication is held by more than
1,500 lubrication professionals and remains the industrys
standard for technical excellence. Independent studies
show that CLS-certied professionals earn more money,
supervise larger staffs and are more likely to receive raises.
Designed for technical specialists, CLS also is held by
hundreds of sales and marketing reps.
Certied Oil Monitoring Analyst I & II
STLEs OMA certication is for the predictive maintenance
professional and demonstrates prociency in sampling and
analyzing oil properties. OMA I is for the individual taking
the oil sample on the shop oor. OMA II is for the person
responsible for running the proper tests, interpreting data
and managing the lubrication program.
Certied Metalworking Fluids Specialist
STLEs CMFS certication veries knowledge, experience
and education in this growing and specialized eld. CMFS
is for individuals with responsibility for metal-removal
or forming management, application and handling of
metalworking uids and related materials.
Invest in your greatest assetyourself. Plan now to attain
your STLE certication.
For more information or to schedule an exam, contact
STLE Certication Program Manager Alicia Skulemowski
at certication@stle.org, 847-825-5536.
Society of Tribologists and Lubrication Engineers, 840 Busse Highway, Park Ridge, IL 60068, info@stle.org, www.stle.org.
RESOURCES
TECHNICAL BOOKS
SURFACE CHEMISTRY OF NANOBIOMATERIALS
Publisher: Elsevier
Surface Chemistry of Nanobiomaterials brings
together the most recent ndings regarding the
surface modication of currently used nanomaterials, a eld that has become increasingly
important in the last decade. This book enables
the results of current research to reach those
who wish to use this knowledge in an applied
setting. Leading researchers from around the
world present various types of nanobiomaterials such as quantum dots (QDs), carbon nanotubes, silver nanoparticles, copper oxide, zinc oxide, magnesium oxide,
magnetite, hydroxyapatite and graphene, and discuss their related functionalization strategies. This book will be of interest to postdoctoral
researchers, professors and students engaged in the elds of materials
science, biotechnology and applied chemistry. It also is highly valuable
to those working in the industry, including pharmaceutics and biotechnology companies, medical researchers, biomedical engineers and advanced clinicians. Available at www.elsevier.com. List Price: $165.75
(USD).
AUGUST 2016
STLE Cleveland Golf Outing Fundraiser, Aug.
8, 10:30 a.m. (check in), 11:30 a.m. (cookout), 1 p.m. (modied shotgun start), 5:30
p.m. (putting contest), 6 p.m. (dinner),
Shale Creek Golf Club, 5420 Wolff Rd.,
Medina, Ohio. Contact: Leah Morris,
lmorris@elcocorp.com, or Buck Evans,
buck.evans@sealandchem.com.
SEPTEMBER 2016
STLE Northern California Section: Topic and
Speaker TBD, Sept. 28. Time and location
TBD. Contact: stle.norcal@gmail.com.
AUGUST 2016
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
W W W. ST L E .O RG
www.crcpress.com
RESOURCES
43RD LEEDS-LYON
SYMPOSIUM ON TRIBOLOGY
Since the delivery of the landmark
Jost Report in 1966, which high-
ROYAL 876
heavy duty lithium complex
ND
ER
* AM
NSF
ON
ROYAL 865HD
calcium sulfonate complex
A L A L F OU
TI
IC
ER
TIFIED HAL
AL
76
AUGUST 2016
www.royalmfg.com
Schertz, TX 78154
210-651-7322
T R I B O LO GY & LU B R I CAT I O N T EC H N O LO GY
W W W. ST L E .O RG
Turbine oils
Grease, an introduction
Solid lm lubricants
Aftermarket additives
Bearing lubrication
Engine oils
Pneumatics
Filtration
Introduction to seals
Wear types
CUTTING EDGE
Drs. Wilfred T. Tysoe &
Nicholas D. Spencer
Coils in oils
It is widely believed that polymeric viscosity index improvers
work by expanding their coil size at higher temperatures.
MD simulations show that life is not so simple.
VISCOSITY-INDEX (VI) IMPROVERS ARE
ADDED TO LUBRICANTS to resist the tendency of oils to lower their viscosity upon
increasing temperature. This, in turn, improves energy efciency in engines at lower
temperatures because lower-viscosity oils can
be used without the fear that the viscosity will
then be too low to maintain uid-lm lubrication at higher temperatures. These additives
are typically high-molecular-weight polymers,
such as olen copolymers (OCPs) or polyalkylmethacrylates (PMAs).
Selby put forward a potential mechanism
for the functioning of VI improvers in 1958,1
Figure 1 | Frequency histograms of Rg and typical molecular congurations for PMA (left) and OCP (right) at 40 C and 100 C.
78
August 31, 1997: Princess Diana dies at age 36 in Paris of massive internal injuries
REFERENCES
1. Selby, T.W. (1958), The non-Newtonian characteristics of lubricating
oils, ASLE Trans, 1, pp. 68-81.
2. Covitch, M.J. and Trickett, K.J. (2015), How polymers behave as
viscosity-index improvers in lubricating oils, Adv. Chem. Eng. Sci., 5,
pp. 134-151.
3. Ramasamy, U.S., Lichter, S. and Martini, A. (2016), Effect of molecularscale features on the polymer coil size of model viscosity index
improvers, Trib. Lett., 62, p. 23.
Consult us for:
Preservation Technologies
Metal Treatment
Platforms for Corrosion Inhibition
Contact us to learn more about our specialty products for your needs.
E: materialsprotection@lonza.com
www.lonza.com
following a high-speed car crash, reportedly while being pursued by car loads of paparazzi.
79
AUTOMOTIVE TRIBOLOGY
Dr. Edward P. Becker
AUGUST 2016
Although the
Mazda RX-3
climbed to sales
of 90,000 units
in the U.S. by
1973, Wankel
fever was short
lived.
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