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Chemical Structure

Chem

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Name (in ink)

Student Number (in ink)

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Summer 2016 SC/CHEM 1000

Quiz2
Calculators are permitted. Answer all questions in the space provided on thL
paper; additional paper for roui?;h work is not permitted. York University's
policies on academic honesty will be strictly enforced.

All final answers must be written in ink.

Time allowed: 50 minutes

Total Marks= 30

1) (3) A 1.6 Mg (megagram) Mazda Miata convertible was

left sitting in the sun and its largely aluminium body,
frame and engine rose to a temperature of 65C. It was
accidently allowed to roll into an insulated pool containing
3.0x103 liters of water at 23C. What is the temperature of
the car and water at equilibrium? (Assume the car 's mass is
l .6xlrl kg and only made of aluminium. There was no heat loss to
anything else. It is just heat exchanged between the car and the water
in the pool.)

Specific heat of water= 4.1855 J/gC

Specific heat of aluminium = 0.900 J/gC

Do

1n~e,

A, C~

IT( -Ti )
'.3

310xlD L ::= 3#0

Tt-

Z7, ~ 0 c_

; 27

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Chemical Structure

Chem

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2)(3) Glucose is the dominant fuel source for our bodies. Combined with 0 2, we burn this
simple sugar into carbon dioxide and water plus a lot of energy. Calculate the standard
enthalpy of combustion for the following reaction:

Here are some l1H 0 f values in kJ:

C6H1206(s)
02(g)
C02(g)
H20(t)

1275.0
0.0
-393.5
-285.8

3)(3) A chemical reaction that absorbs heat from the surroundings is said to be
and has a
L1H at constant pressure. {Circle one)

a ndothermic, positive
b) endothermic, negative
c) exothermic, negative
d) exothermic, positive
e) exothermic, neutral

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Chemical Structure

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4)(3) Assume that a particular reaction produces 244 kJ of heat and that 35 kJ of PV
(expansion/contraction) work is done on the system. What is the value of ~U for the
system? (Hint: Be careful)

5)(3) Calculate ~H for this reaction:

CHig) + NH3(g) --> HCN(g) + 3Hig) given:
N1(g) + 3 H2(g) -+ 2 NH3(g)

~H =

C(s) + 2 H2(g) -+ C!Li(g)

~H=-74.9

H2(g) + 2 C(s) + N1(g)-+ 2 HCN(g)

~H

-:::i

kJ

= +270.3 kJ

~ H :;. z ( --"\ t~.\L~)

+ 5h .l/a'.j)

NII&._3J + Vi. Nij'

ei~i..i('O

-91.8 kJ

~-=

~) + z.. Hz..t'7 l

Vi/..\~ciJ + C<~) + '1~Nz. _,,~Jc~

rt:. i-\ ~ +ts-:

74. q
~ )/.; (:

D ]

6)(3) Calculate the speed (v) of a neutron having a de Broglie wavelength of

2.6x10-10m. (Hint: A neutron has a mass of l.7x10-27 kg)

_bM

.i/

rv:.~ I~ l>O

,,,2.,2. X10_3 ..,::Ss

v -:: .h-

M
W\

l.s

1,

1 x1o- 2 7 K

z. . ,-,-x-,
. o- --;-;;'0 rv

7)(3) It takes 5.1 electron volts (eV) of energy to eject an electron from a piece of gold.
What frequency and wavelength does light with this energy have? "(J \
19

(n~e: 1ev= i.~10- n

Y-; I"'
-

,/

vXl.tKJo- ir.t ..JI< V/ -

(, ,(:. Z' Z ~10 -3 J ..s

A
= l,z.x10 I/~

-~______,!

(.

=/2,{" rio-7 VVI

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Chemical Structure

Chem

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8) (3) .From the previous question, what would happen if l were to shine a light of 6.5 e V
on the gold surface? How is this same or different from using light of 3.0 eV?
(Hint: I thinking the answer should be in light of the photoelectric effect - some of Einstein's best work)

el

c~rov

9) (3) lt is summertime and l'm going outside. With my complexion 1 need to worry
about sunburn. We tend to lump all UV electromagnetic radiation in to two categories:
UV A and UV B . UV A may not give me a bum but it stimulates tanning and is implicated
in skin cancer. UVB is higher energy and can cause nasty sunburns.
UVA radiation has a wavelength of about 360nm. How much energy, in Joules, does a
photon of UVA light transfer?

t--- -

h'

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3~

10

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10)(3) Which of the following are state variables or as the book says "state
fondions?"

f1H

Work (w)

yes~ noo
yes /

noo

yeso

no~

;< JO +.21111

lOOOA
Chemical Structure

Chem

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Appendix
q = mC~T

E=mc2

hc/J..

H'II= E'I/

I..= h/mv
~H=~U+P~V
~U = Q(added to the system) + W (done to the system)

h = 6.6262xlff34 Js

1~

PERIODIC TABLE OF THE ELEMENTS

,...----

VlllA

He

13
IJIA

14

1.003

2
ll A

IVA

Li

Be

6.9-1

9.ol

10.lll

12.01

M.I

16.00

19.00

20.13

ll

12

13

15

16

17

18

Al

Si

2698

28.09

'0.91

:.t2.06

'5.'IS

19.9:;

31

32

33

3'1

35

36

Na Mg

3
ll lB

IVB

VB

Vl8

VllB

21

22

23

K Ca Sc

Ti

22.99

200

19

20

21

25

JO

II

r - v1118 - - ,

18

26

27

28

29

1.00

10

F Ne

s Cl Ar
Br Kr

40.08

M.96

..7.90

50.91

;i.oo

'9.9 1

s:;.s;;

591

5&.69

6"l.;S

'57

38

39

IO

41

42

13

1'I

45

46

17

30

17
VllA

Cr Mn Fe Co Ni Cu Zn Ga Ge As Se

'.19 10

Rb Sr

12
118

VA

16
VIA

65.'.19

69.72

72!.!9

14 92

7896

79.90

19

50

51

52

53

54

Te

Xe

Zr Nb Mo Tc Ru Rh Pd Ag Cd In

Sn Sb

ICl.80

S5A7

81.62

&8.9 1

9 1. 22

92 .9 1

95.91

(93)

IOI.I

102.9 1

106.42

107$7

112. 11

IJ.1 "'2

113.7 1

121.75

127.60

126.9 1

111 .29

55

56

57

72

73

71

75

76

78

79

80

RI

82

83

84

85

86

200. S'J

20-1.38

201.2

208.98

(209)

(210)

(222)

66

67

68

69

70

71

Cs Ba *La Hf Ta

w Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn

132.9 1

137.JJ

133.91

17M9

lll0.9i

JIS3JJ5

136.2 1

190.2

192.2

19;.os

196.97

87

88

89

104

105

106

107

108

109

110

I ll

Fr Ra tAc Rf Db Sg Bh Hs Mt Ds Rg
(223)

226.02

2V.o1

*Lanthanide eries
tActinide Series

(26 1)

(262)

(266)

(26-1)

(V7)

(2611)

(VI)

1272)

58

59

60

61

62

63

61

65

Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
M0.12

11091

111.2 1

(115)

150.'I

1:)1.97

1:;7,25

158.93

162.50

164 .93

167.26

169.91

171.01

90

91

92

93

91

95

96

97

98

99

100

IOI

102

Th

Pa

232.04

23 1.0 1

u x Pu Am Cm Bk Cf Es
2)ll.03

(2.17)

(l-14)

(2-11)

(247)

(2-17)

'25H

(2;2)

11191

103

Fm Md No

Lr

(2.>~)

(262)

(2>7)

(239)