Beruflich Dokumente
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WELDINGAND MECHANICAL
FORMING.
The application of
oxyacetylene powder cutting proccsses continued to receive
favorable attention as applied t o high-nickel alloys. Fleming
(29) described the application of powder cutting and scarfing
t o Monel and nickel, with an example of the shape cutting of
elliptical Monel fins for a pressure,vessel. Descriptions of the
Oxyarc process were given by Clauser ($0)and by Jefferson (44),
including applications to the cutting of Monel, nickel, and Hastelloy B. Description of a powder welding process for nickel-base
alloys was given by Clason (19). Chisholm (18) described the
welding characteristics of some of the high temperature alloys
including cobalt and cobalt-nickel and base, nickel-base, and
cobalt-nickel-iron base materials. The first group is more difficult t o weld than the other two. Weldability and welding
methods for nickel and high-nickel alloys were reviewed by West
(79).
I n a description of methods used in fabrication of sheet metal
parts for jet engines, Knight (46)described the procedure used in
drawing and annealing Inconel domes for the ends of combustion
chamber liners. A line of die-formed wrought fittings of Inconel,
nickel, and Monel is now available in eleven types of tees, elbows,
1801
1802
APPLICATIONS
HIGHTEMPERATURE.
As would be expected from the continued emphasis upon the high temperature properties of the
nickel alloys, many of the newer developments in uses of these
alloys are in the high temperature fields where both useful physical properties and corrosion resistance are required. Although
there is still accent on jet engine and gas turbine applications,
uses for heavy-duty engine valves and seats, furnace and heat
treating equipment, thermocouple protection tubes, instruments
and springs, and high temperature chemical process equipment
have been multiplying. Robertson (70) discussed some of the
fundamental considerations involved in the use of metals under
high temperature conditions. Gibb and Bowden (37) discussed
materials used in gas turbines and relationship of their properties
to turbine design with special reference to industrial applications.
Mochel ( 5 5 ) also discussed the general requirements for gas
turbine materials including temperatures involved or likely to
be involved, testing methods and equipment, and applications
of materials t o specific parts of gas turbines. Nimonic 80 was
used for the blades of a gas turbine developed for driving the
central shaft of a 100-foot triple-screw boat for the British Admiralty (6). Nickel-chromium alloy wire with diameter not
exceeding 0.05 mm. was used in forming the regenerator of the
Philips hot-air engine ( 1 ) .
A number of the high temperature nickel alloys have been
tried as valves and seats on heavy-duty engines in the work
described by Colwell @ I ) . Inconel X has shown particular
promise at temperatures u p to 1500" F. Nichrome and Stellite
are among the hard-facing materials used and the results of
endurance and corrosion tests for these materials are given.
Dike and Bradley (26) discussed materials, including nickel
alloys used in pyrometric instruments in the smelting, refining,
and melting of nonferrous alloys. Experience reported by
Murphy (61)showed Inconel t o be a suitable material for thermocouple protection tubes in industrial furnace applications below
2000" F. when sulfur content of gases is below 1%. Flexible
tubing with Inconel inner core and braid is supplied for temperatures up t o 1700" F. Applications include flexible exhaust
tubing for automotive power plants, fuel and oil lines for airplanes (Zone l),and chemical equipmcnt ( 2 ) . Inconel X appears
(23)to offer promise as a spring material at 900' F. or even higher.
It has given ( 5 5 ) good performance as bolting material a t
1200" F., with resistance to galling.
PETROLEUX
REFIXING. The continued expansion of petrochemical production has accounted for further uses of nickel
alloys, especially for handling mixtures including hydrochloric
acid, hydrofluoric acid, sulfuric acid, phosphoric acid, or sodium
hydroxide under elevated temperature conditions. Friend
(34) presented the results of plant and laboratory corrosion tests
in sulfuric acid solutions in petroleum refinery processes, many
of them at elevated temperatures. Friend and Mason (36)
published the results of corrosion tests in refinery distillation
equipment where corrosion is due either to dilute hydrochloric
acid or t o sulfur compounds a t elevated temperatures. Among
the high-nickel materials included in both of these summaries
were nickel, Monel, Inconel, Hastelloy alloys, and Illium. A
summary of uses of Hastelloy alloys in the petroleum industry,
given by Chisholm ( l 7 ) , included the use of Hastelloy B linings
for towers handling aluminum chloride, Hastelloy C for strong
oxidizing agents, and Hastelloy D for evaporation of sulfuric
acid. Inconel reaction tubes have been used in gas conversion
processes at temperatures up to about 1800" F. Morton ( 5 8 )
reviewed the steps taken by the production, transportation, and
refining divisions of the oil industry to counteract destruction of
equipment by both corrosion and abrasion. Considerations
involved in planning, conducting, and interpreting the results of
refinery corrosion tests were described by Wachter and Treseder
(78). Pray, Fink, and Peoples (67) published a literature review
October 1948
on corrosion of metals by flue gas condensate, in which some highnickel alloys were included.
CHEMICAL
PROCESSING.
The trend in chemical processing has
been toward the use of higher temperatures and pressures, coinciding with the increased availability of metals and alloys resistant to such conditions and expanded data on their high temperature physical properties. Some applications cited by Friend
(33) include the use of Inconel for reaction coils in continuous
hydrolysis of fats at 600" F. and 3500 pounds per square inch
pressure, clad and lined towers for continuous hydrolysis of
fats at 500' F. and 700 pounds per square inch pressure (also
referred to by Barnebey and Brown, 11), heaters and bubble
towers in fatty acid and tall oil distillation up to 625" F., heat
exchangers handling petroleum products of high-naphthenic
acid content at 700 F., reaction tubes handling sodium hydroxide
solutions at 800" F. and 4000 pounds per square inch pressure,
heaters for molten caustic soda baths at 900' F., and superheating coils heating steam to 1500" F. Other examples cited
include the use of L nickel for evaporation of sodium hydroxide
to 95 to 98% concentration at 700' t o 900" F. and for holding
and heating molten sodium nitrate baths at 920" F.
There was continued interest in processes involving the use of
hydrogen fluoride and fluorine at elevated temperatures. Myers
and D e Long (61)reported the results of corrosion tests in fluorine
at temperatures up t o 700" C., in hydrogen fluoride at temperatures up to 600" C., and in mixtures of hydrogen fluoride and
steam at temperatures u p to 750" C. Nickel was shown to be
the most resistant of the materials tested in fluorine. Nickel,
Monel, and Inconel showed suitable resistance to hydrogen fluoride at 600 O C.
In a series of published symposia describing the performance of
materials of chemical plant construction with various common
chemicals, Friend (82) dealt with the performance of nickel,
Monel, Inconel, and Ni-Resist, while Chisholm (16)dealt with
the performance of the Hastelloy alloys, and Staley (78), Traub
(77), and Luce (60) dealt with the Chlorimet alloys. The chemicals covered to date in these symposia include acetic acid,
phosphoric acid, chlorine, sulfur dioxide, nitric acid, sodium
chloride, and sulfuric acid. West (80) discussed performance of
nickel and nickel alloys in sulfur and sulfides at elevated temperatures.
Niakel, Monel, Hastelloy C, and Chlorimet 3 are among materials included by Fontana (30)in a discussion of construction
materials for making and handling acetic acid. Corrosion rates
of Chlorimet 2 (nickel-molybdenum) and Chlorimet 3 (nickelmolybdenum-chromium) alloys in sulfuric acid and hydrochloric
acid solutions and of Chlorimet 3 in ferric chloride solutions were
given in a recently issued booklet (27). I n a plant producing a
variety of fatty acids, drying oils, and other organics, uses of
Monel for Twitchell fat splitting tanks and of Inconel fatty
acid and oil heating were described (3). Applications of Monel
in the storage and piping of frit, and of nickel-chromium alloys for
heating elements and furnace tooling, in a porcelain enameling
plant, were described by O'Donnell (64). Nickel-clad steel is
applied to the construction of newly developed hydropulpers
in the pulp and paper industry (8). Nickel and nickel-clad
steel are used for tanks, tank cars, and drums in the storage and
shipment of liquid bromine and ethylene dibromide.
I n a discussion of equipment design, Brown (11)referred to the
uses of nickel and Monel for chlorine condensers, Monel heating
tubes in salt evaporators, and nickel for caustic soda evaporators.
MISCELLANEOUS.
The uses of some high-nickel alloys in tho
handling of milk were described by Pattison (66). Mason (61)
gave the results of corrosion tests of a number of metals, including
nickel, Monel, Inconel, and Hastelloy alloys B and C in the production and handling of food products including fruit juices and
sirups, pectin, gelatin, salad dressing, vinegar, canning brines,
oleomargarine, monosodium glutamate, baker's yeast, and carbonated beverages. I n a study by Roberts (69) of corrosion and
O
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(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
Brown, C. O . , IND.
ENG.GHEM.,39, No. 10.89 A, 90 A (1947).
Brown, I., Phys. Rev., 72, No. 4, 348 (1947).
Carling, B., ProductEng., 18, No. 10, 169 (1947).
Chambaud, D., M t h n i q u e , 30, 285-9 (1946).
Chisholm, C. G., Chem. Eng., 53, No. 7, 222-6, No. 12, 206-8
(1946); 54, NO. 2, 228-31, NO. 9, 230-2 (1947); 55, NO. 1,
1804
of
VO!.
40, No. 10
(59) Mudge, W. A., Am. Inst. Mining Met. Engrs., Inst. Metals Div.?
Symposium on Non-Ferrous Melting Practice, 74-8 (1946)
(60) Mudge, 1%. A., Znd. Heating, 14, 1282 (1947).
(61) Murphy, E. A . , Materials & Methods, 25, No. 133 (1947).
8~
(62) Myers, W. R., and De Long, 1%.B., Chem. Eng. P r o g ~ e ~44,
359-62 (1948).
(63) Neuhaus, C. J . , Iron A g e , 161, No. 4,62-5 (1948).
(64) ODonnell, D. S., Can. Chem. & Process Inds., 31, 527-9, 536
(1947).
(65) Orbaugh, M. H., Monthly Rev., Am. Electropleters Soc., 34, No.
7, 810-15 (1947).
(66) Pattison, F. R., Dairuznds., 12, 329-37 (1947).
(67) Pray, H. A., Fink, F. W., and Peoples, R. S., Am. Cas Assoc.,
Rept. 1, Project DGR-4-CM (February 1947).
(68) Raymond, W. A , , Metal Finishing, 46, No. 1,56-60 (1948).
(69) Roberts, D., Wine Rw.,15, No. 5, 16, 18 (1947).
(70) Robertson, J. M., Iron and Coal Trades Rev., 154, 1135-42
(1947).
(71) Roehl, E. J., Metal Finishing, 45, No. 6,56-9, 71 (1947).
(72) Roehl, E. J., Monthly Rev., Am, Electroplaters Soc., 34, No. 10,
1129-40 (1947).
(73) Staley, W. D., Chem. Eng., 53, No. 11,256-60 (1946).
(74) Stout, W. W., Secret, Chrysler Corp., 1947.
(75) Sturm, R. G., and OBrien,
L.,
I.
Trans. Am. &c. Mech. Engrs.,
69, 353-8 (1947).
(76) Sullivan, G. F., Iron Aye, 160, No. 124, 137-9 (1947).
(77) Traub, J. L., Chem. Eng., 54, No. 3,240 (1947).
(78) Wachter, A., and Treseder, R. S., Chem. Eng. I3.ogres8, 43, 31526 (1947).
(79) West, E. G . , Sheet Metal Ind., 24, 2265-71 (1947) ; 25, 147-54,
360 (1948).
(80) West, J. R., Chem. Eng., 53, No. 10,226-38 (1946).
(81) Williams, W. L., Trans. Am. SOC.Metals, Preprint 11 (1947).
(82) Yamaguchi, S., Bull. Chem. Soc. J a p a n , 18,53-91 (1943).
(83) Zimmerli, 3. P., SOC.Automotive Engrs., Preprint ($Jun~
1947).
RECEIVBD
August
19, 1918.
Standards, Washington, D . @,
HREE full years have gone by since the end of World War
11. During the war period, 1939 to 1945, the plastics industry quadrupled in size, and many wondered whether it could
maintain this high level of production in peacetime. The years
1046 and 1947 have supplied the answer. Each of these years
has seen the establishment of new production records, new materials, and new applications. Developments in this field in
recent months are reviexed in this article.
VINYL RESINS
POLYVINYLIDENE CHLORIDE