MSC Chemistry PDF

DR.
BHIM RAO AMBEDKAR UNIVERSITY, AGRA
Course Structure for M.SC. (CHEMISTRY) under

Semester System to come into force from Academic
Session 2013-14.
M.SC. (CHEMISTRY)
(SEMESTER-WISE)
PAGE 1
DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA
M.SC. (CHEMISTRY)
SEMESTER STRUCTURE
FIRST SEMESTER
400 MARKS
PAPER 101 - Computers for Chemistry
075 MARKS
PAPER 102 - Inorganic Chemistry
075 MARKS
PAPER 103 - Organic Chemistry
075 MARKS
PAPER 104 - Physical Chemistry I
075 MARKS
PAPER 105 PRACTICAL :-
100 MARKS
(A) Inorganic Chemistry
35 Marks
(B) Organic Chemistry
30 Marks
(C) Physical Chemistry
20 Marks
(D) Viva Voce & Record
15 Marks
PAGE 2
M.SC. (CHEMISTRY)
SEMESTER STRUCTURE
SECOND SEMESTER
400 MARKS
PAPER 201 - Group Theory and Spectroscopy
075 MARKS
PAPER 202 - Coordination Chemistry
075 MARKS
PAPER 203 - Bioorganic Chemistry
075 MARKS
PAPER 204 - Physical Chemistry II
075 MARKS
100 MARKS
30 Marks
20 Marks
20 Marks
15 Marks
(E) Seminar
15 Marks
PAGE 3
M.SC. (CHEMISTRY)
SEMESTER STRUCTURE
THIRD SEMESTER
400 MARKS
PAPER 301 - Organometallic Chemistry
075 MARKS
PAPER 302 - Stereochemistry and Photochemistry
075 MARKS
PAPER 303 - Physical Chemistry III
075 MARKS
PAPER 304 - Analytical Chemistry
075 MARKS
100 MARKS
35 Marks
30 Marks
20 Marks
15 Marks
PAGE 4
M.SC. (CHEMISTRY)
SEMESTER STRUCTURE
FOURTH SEMESTER
400 MARKS
PAPER 401 Selected topics in Inorganic Chemistry
075 MARKS
PAPER 402 Spectroscopy and Chromatographic technique
075 MARKS
PAPER 403 Physical Chemistry IV
075 MARKS
PAPER 404 OPTIONAL PAPER :-
075 MARKS
(A) Selected topics in Inorganic Chemistry

(B) Selected topics in Organic Chemistry
(C) Selected topics in Physical Chemistry
(D) Selected topics in Analytical Chemistry
100 MARKS
(A) Experiments of Paper 404
60 Marks
(B) Seminar
20 Marks
(C) Viva Voce & Record
20 Marks
PAGE 5
M.SC. (CHEMISTRY)
RULES & REGULATION
Each practical performance will be of 100 marks.

Passing marks in individual theory as well as practicals be 40%, overall the total
aggregate of the candidate should be 45% in each semester.
The entire course of M.Sc. (Chemistry) will be of 1600 marks. So every semester
will be of 400 marks.
Each theory paper will be of 075 Marks.
Practical Paper will be of 100 Marks.
PAGE 6
MASTER OF SCIENCE (CHEMISTRY)

FIRST SEMESTER
PAPER 101
COMPUTERS FOR CHEMISTRY
Unit-I :
History of development of computer, mainframe , mini, micro and super

computers, generations of computers, general awareness of computer
hardware- CPU and other peripheral devices, I/O and auxiliary storage
devices.
Unit-II:
Computer languages development and history, operating system single

and multi uses system.
Unit-III:
General awareness of popular commercial software packages like( DBASE,

WORDSTAR) FOXPRO, MS-Excel, MS-Word, MS Power Point & other
scientific applications packages.
Unit- IV:
Introduction to networking and searching study material using Internet
Unit - V:
Uses of computers in Chemistry
PAGE 7

FIRST SEMESTER
PAPER 102
INORGANIC CHEMISTRY
Unit-I:
Studies and Application of Lanthanides and Actinides: Spectral and

Magnetic properties, Modern methods of separation of Lanthanides and
Actinides, Organometallic Compounds of lanthanides, Application of
lanthanides and actinides compounds in Industries, Use of lanthanides
compounds as Shift reagents.
Unit-II :
Nuclear Chemistry : Radioactive decay and equilibrium, Nuclear Reactions Types, Q value, Cross Section of reactions, Chemical effects of nuclear
transformation, Nuclear Fission - Fission Products, Fission Yield and Nuclear
Reactors, Nuclear Fusion and stellar energy,
Radioactive techniques:
(i) Tracer techniques (neutron activation analysis),
(ii) Countering Techniques such as G.M Ionization and Proportional
counters.
Unit -III :
Inorganic Rings, Cages and Clusters : Polyhedral Boranes : Higher Boranes,

Carboranes,
Metallo-boranes
and
Metallocarboranes,
Classification,
PAGE 8
Nomenclature, preparation, Structure and Bonding, Wades rule, Metal

carbonyl hydrides and Metal carbonyl clusters, LNCC & HNCC, Capping rule.
Unit -IV :
Inorganic Polymers : Characteristic properties and Classification., Types of

Inorganic
Polymerization
(step-growth,
chain-growth,
ring-opening,
Reductive Coupling, Condensation synthesis ), Synthesis, properties and

applications of important inorganic polymers : Polyphosphazenes,
phosphonitrilic halides. Polysiloxanes (Silicones), polysilanes, Coordinate
Polymers,
Condensed
Phosphates,
Silicates,
and
sulphur-nitrogen
compounds, Isopoly and Hetropoly acid and Salts: Synthesis and structural
principles with reference to those of Mo and W.
Unit -V :
Nanoscience and Nanotechnology : Introduction to nanotechnology, scope

of applications, Techniques for synthesis of nanoparticles, Important nano
materials (nanooptics, nanomagnetics, nanoelectronics), Carbonnanotubes
- types, properties & applications.
BOOKS RECOMMENDED
Chris J. Jones, d- and f- Block Chemistry , (2002), Wiely Interscience & RSC
V.S. Sastri, J.C.G. Bunzli, V.R. Rao, G.V.S. Rayudu, J.R. Perumareddi, Modern
Aspects of
rare earths and their complexes, (2003) Elsevier publication.
H.J. Arnikar, Essentials of Nuclear Chemistry, 4th Edition (1995), Wiely-Eastern
Ltd., New Delhi.
PAGE 9
B. G. Harvey, Introduction to Nuclear Physics and Chemistry, (1969) Prentice Hall,

Inc.
Attila Vertes (editor), Handbook of Nuclear Chemistry, 2nd Edition, (2011),
Springer.
G. Fridlander, J.W. Kennedy, E. S. Macias, and J. M. Miller, Nuclear &
Radiochemistry, 3rd Edition (1981), John Wiley, New York.
Tristram Chivers, Ian Manners, Inorganic Rings and Polymers of the p-Block
Elements : From Fundamentals to Applications, (2009) Royal Society of Chemistry.
P. Braunstein, L. A. Oro, P. R. Raithby (editors), Metal Clusters in Chemistry, (1999),
Wiley-VCH.
J.D. Woollins, Non-Metal Rings, Cages and Clusters, (1988), John Wiley & Sons.
James E. Mark, Harry R. Allcock, Robert West, Inorganic Polymers - 2nd Edition,
(2005), Oxford University Press.
Mao-Chun Hong, Ling Chen (editors), Design and Construction of Coordination
Polymers
(2009), John Wiley & Sons
Chris Binns, Introduction to Nano-science and Nanotechnology (2010), John Wiley
& Sons, Inc.
C. N. R. Rao, A. Muller, A. K. Cheetham (Eds.), The Chemistry of Nano-materials,
(2004), Wiley-VCH Verlag.
PAGE 10

FIRST SEMESTER
PAPER 103
ORGANIC CHEMISTRY
Unit-I:
(a) Nature of bonding in organic molecules: Delocalised chemical bondingconjugation, cross conjugation, resonance, hyperconjugation, inductive
effect, electromeric effect, mesomeric effect, steric effect tautomerism.
(b) Fullerenes, annulenes, aromaticity, anti- aromaticity.
Unit II:
Reaction mechanisms, structure and reactivity:Types of mechanisms, type

of reactions, reaction intermediates- carbocations, carbanions, free radicals,
carbenes, nitrenes and benzyne (generation, Structure, stability and
reactivity)
Unit III:
Substitution reactions:
(a) Electrophilic Substitution reaction: The SE1 and SE2 mechanisms, effect
of substrates, leaving group and the solvent polarity on the reactivity.
PAGE 11
(b) Nucleophilic Substitution reaction: The SN1, SN2 and SNi mechanisms,
effect of substrate structure, attacking nucleophile, leaving group and
reaction medium, ambedient nucleophile.
Unit IV:
Addition and elimination reactions:

(a) Addition to carbon carbon multiple bonds, addition to carbonheteromultiple bonds and hydrolysis of esters.
(b) The E1, E2, E1cB and orientation of double bond, reactivity effects of
substrate structures, attacking base and the leaving group and the
medium, pyrolytic elimination
Unit V:
Pericyclic reactions: Selection rules, classification of pericyclic reaction,

Woodward-Hoffman
correlation
diagram,
FMO,PMO
approach,
stereochemistry of electrocyclic reactions, cycloaddition and sigmatropic

shifts, Cope and Claisen rearrangements, Ene reaction
PAGE 12

FIRST SEMESTER
PAPER 104
PHYSICAL CHEMISTRY I
Unit-I:
QUANTUM CHEMISTRY: Introduction Operators and related theorems

postulates of wave mechanics, Schrodinger equation, Eigen value and Eigen
function, discussion of solutions of Schrodinger equation to some model
systems viz. particle in a box, the harmonic oscillator, the rigid rotator, the
hydrogen atom.
Unit-II:
CLASSICAL THERMODYNAMICS: Brief resumes of concepts of I and II law of

thermodynamics, Nernst heat theorem, III law of thermodynamics,
Calculation of absolute entropy partial molar properties and their methods
of determination, chemical potential, Gibbs Duhem Equation.
Unit-III:
NON-IDEAL SYSTEMS: Non-ideal systems, Excess functions for non-ideal

solutions, Concepts of fugacity and determination of fugacity, activity,
activity coefficients. Debye Huckle theory for activity coefficient of
electrolytic solution, Determination of activity and activity coefficient, ionic
Strength.
PAGE 13
Unit-IV:
ADSORPTION: Adsorption, Surface tension, Capillary Action, Pressure

difference across curved surface (Laplace Equation), Vapour Pressure of
droplets (Kelvin Equation), Gibbs adsorption isotherm, estimation of
Surface area (BET Equation), Surface films on liquid (electro kinetic
phenomenon), catalytic activity at surfaces.
Unit-V:
MICELLES: Surface active reagents, Classification of surface active agents,

micellization, hydrophobic interaction, Critical miceller concentration,
factors affecting the CMC of surfactants, thermodynamic of micellizationphase separation and mass action models solubilization, microemulsion,
reverse micelles.
PAGE 14

FIRST SEMESTER
PAPER 105
PRACTICAL
35 Marks
30 Marks
20 Marks
15 Marks
(A) INORGANIC PRACTICALS

A. Qualitative Analysis of Inorganic Mixture
(21 Marks)
Identification of seven radicals including insoluble residue and rare earth metal ions by
semi micro analysis.
(i) Rare elements: Tl, W, Se, Mo, Ti, Zr, Ce, Th, V, U, Li
PAGE 15
(ii) Insolubles: PbSO4, SrSO4, Al2O3, Cr2O3, Fe2O3, SnO2, AgX, TiO2, ThO2,
WO2.xH2O
B. Preparations of Inorganic Complex Compounds
(14 Marks)
1. Prussian Blue (Potassium Ferric Ferro cyanide)

2. Reineckes salt (Ammonium diammine tetra thio cyanato chromate (III))
3. Potassium tri oxalato ferrate (III) trihrdrate.
4. trans-potassium di aqua bis(oxalato) chromate (III)
5. cis-potassium di aqua bis(oxalato) chromate (III)
6. Sodium hexa nitrito cobaltate (III)
7. tris (acetylacetonato) manganese (III)
(B) ORGANIC PRACTICALS
Separation and identification of components of mixture of three organic
compounds.
(C) PHYSICAL PRACTICALS
1. To find out partition coefficient of l2 between CCl4 and H2O.
2. To find out the partition coefficient of benzoic Acid between C6H6 and water.
3. To find out the equilibrium constant for the tri-iodide formation, I2+I- =I-3.
4. To determine the partition coefficient of succinic with water and ether.
5. To determine the molecular weight of succinic Acid in benzene by determining its
partition coefficient with water
(D) VIVA VOCE & RECORD
PAGE 16

SECOND SEMESTER
PAPER 201
GROUP THEORY AND SPECTROSCOPY
Unit-I:
Symmetry elements and symmetry operation, point groups and their

classification with examples, sub groups. General methods of assigning
point groups to a molecules like water (C2v), ammonia (C3v), phosphorous
(D3h) and Xenon tetrafluoride (D4h).
Unit-II:
Application of group theory to chemical bonding, hybrid orbitals for

bonding in
different geometrics and hybrid orbitals for bonding,
symmetric of molecular orbitals in BF3, C2H4 and B2H6.
Unit-III:
Rotational and vibrational spectroscopy: Introduction, fundamental

principle and applications
Unit-IV:
Raman Spectroscopy- Classical and quantum theories of Raman effect, pure

rotational - vibrational and vibrational - rotational Raman spectra, Selection
rules, mutual exclusion principle, resonance Raman Spectroscopy.
PAGE 17
Unit-V:
Electronic spectroscopy: Introduction, theory involving electronic transition

and applications
PAGE 18

SECOND SEMESTER
PAPER 202
COORDINATION CHEMISTRY
Unit -I:
Theories of Metal Ligand Bonding : (CFT) Recapitulation of Crystal Field

Theory including Splitting of d-orbitals in Octahedral, tetrahedral square
pyramidal, triogonal bipyramidal environments, Factors affecting the
magnitude of crystal field splitting, spectrochemical series, Structural
effects (ionic radii & John-Teller Effect) and Thermodynamic effects
(ligation, hydration, & lattice energies) of Crystal Field Theory, Applications
of CFSE and adoption of geometrical arrangements, Limitations of crystal
field theory.
Unit-II :
Theories of Metal Ligand Bonding : (ACFT and MOT): Experimental evidence

for Metal ligand orbital overlap in complexes, Nephelauxetic series,
Adjusted crystal field theory (ACFT) (also called Ligand Field Theory),
Molecular Orbital Theory for Octahedral, tetrahedral, and square planer
complexes (excluding mathematical treatment).
PAGE 19
Unit -III:
Metal Ligand Equilibria in Solutions: Stepwise and overall formation

constants and their interaction, trends in stepwise constants, Factors
affecting stability of metal complexes with reference to the nature of metal
ion and ligand, chelate effect and its thermodynamic origin, Determination
of binary formation constant by pH metry and spectrophotometry.
Unit -IV:
Reaction Mechanism of Transition Metal Complexes (I) : Energy profile of a

reaction, reactivity of metal complexes, inert and labile complexes, A,D and
I mechanism for metal complexes, Kinetics and mechanism of octahedral
substitution, Acid hydrolysis, factors affecting acid hydrolysis, Base
hydrolysis, conjugated base mechanism, direct and indirect evidence in
favor of conjugated mechanism, Anation reactions, reactions without metal
ligand bond cleavage.
Unit -V:
Reaction Mechanism of Transition Metal Complexes (II) :Substitution

reactions in square planer complexes, Mechanism of the substitution
reaction, the trans effect, Redox Reaction, Electron Transfer Reactions :
Mechanism of one electron transfer reactions, outer sphere type reactions.
Cross reactions and Marcus-Hush theory, Inner sphere types reactions.
BOOKS RECOMMENDED
Geoffrey A. Lawrance, Introduction to Coordination Chemistry, (2010), Wiley &
Sons.
PAGE 20
Rob Janes and Elaine Moore, Metal-Ligand Bonding (2004), RSC.

Yves Jean, Molecular Orbitals of Transition Metal Complexes, (2005), Oxford
University Press.
C H Langford & H B Gray, Ligand Substitutin Processes,(1965), W.A.Benjamin Inc.
Robert B. Jordan, Reaction Mechanisms of Inorganic and Organometallic System,
3rd edition (2007), Oxford University Press.
Fred Basolo, Ralph G Pearson, Mechanisms of Inorganic Reactions, 2nd Ed (1984),
Wiely Eastern Ltd.
PAGE 21

SECOND SEMESTER
PAPER 203
BIO-ORGANIC CHEMISTRY
Unit-I:
Enzymes: Introduction, classification and nomenclature, characteristics

mechanisms of enzyme Action, factors affecting enzyme activity,
Coenzymes NAD, NADP, applications and Clinical use of enzymes. Methods
of immobilization of enzymes, effect of immobilization on enzyme activity.
Applications of immobilized enzymes.
Unit II:
Vitamins: Introduction of fat soluble and water soluble vitamins, sources,

structure, requirements and functions of vitamin A,D,E and vitamin B1 and
C.
Unit III:
Antibiotics: - Lactumrings, structure and synthesis of penicillin G,

penicillin-V, Amoxycillin, cholamphenicol, streptomycin.
Unit IV:
Bio-energetics: Standard free energy change in biochemical reactions,

exogenic, endrogenic hydrolysis of ATP, synthesis of ATP from ADP
Unit V:
Thermodynamics of biopolymer solutions: Thermodynamics of biopolymer

solutions, osmotic pressure, membrane equilibrium, muscular contraction
and energy generation in mechano-chemical system.
PAGE 22

SECOND SEMESTER
PAPER 204
PHYSICAL CHEMISTRY II
UNIT I:
Quantum Chemistry
Approximate Method: The Variation Theorem, linear variation principle,
Perturbation theory (first order & non degenerate). Application of variation
method & perturbation theory to the Helium atom.
Unit II:
Statistical Thermodynamics: Partition functions, transitional rotation,

vibrational & electronic partition functions, calculation of thermodynamics
properties in terms of partition functions, applications of partition functions.
Heat capacity behavior of solids; chemical equilibria & equilibrium content
in terms of partition functions. Fermi-Dirac statistics, Bose-Einstein
statistics.
Unit III:
Chemical dynamics: Collision theory of reaction rates, steric factor,

activated complex theory, Arrehnius equation & activated complex theory,
ionic reaction, kinetic salt effect, steady state kinetics, kinetics and
thermodynamic control of reaction, treatment of unimolecular reactions.
PAGE 23
Dynamic Chain (Hydrogen-bromine reaction, pyrolysis of acetaldehyde,

decomposition
of
ethane),
photochemical
(hydrogen-bromine
and
hydrogen-chlorine reaction), homogenous catalysis, kinetics of enzyme

reaction, general features of fast reaction, Hach photolysis and nuclear
magnetic resonance method.
Unit IV:
Macromolecules: polymer-definition, types of polymers, electrically

conducting , fire resistant, liquid crystal polymer, kinetics of polymerization,
mechanism of polymerization, sedimentation, chain configuration of
macromolecules, calculation of average dimensions of various chain
structures.
Unit V:
Electrochemistry: electrochemistry of solutions, Debye- Huckel-Onsanger

treatment and its extension, ion solvent interaction, Debye-Huckel-Jerum
mode, Thermodynamics of electrified interface equation, Over potential,
exchange current density.
PAGE 24

SECOND SEMESTER
PAPER 205
PARCTICAL
30 Marks
20 Marks
20 Marks
15 Marks
(E) Seminar
15 Marks

A. Quantitative Analysis
(20 Marks)
Quantitative Separation and determination of two metal ions : Cu-Ni, Ni-Zn, Cu-Zn etc
using volumetric and gravimetric methods.
PAGE 25
B. Chromatography
(10 Marks)
1.
Paper chromatographic separation of Pb, Ag and Hg ions .
2.
Determination of the Rf value of Pb, Hg, Cu and Cd ions by using paper

chromatographic technique.
3.
Determination of the Rf value of Fe, Al, Cr ions by using paper chromatographic

technique.
4.
Determination of the Rf value of Ba, Sr, Ca ions by using paper chromatographic

technique.
5.
TLC separation and determination of the Rf values of Ni, Mn, Co and Zn ions.
6.
Radial paper chromatographic seperation of Cu, Cd ions.
7.
Radial paper chromatographic seperation of Ni, Cu ions.

1. Estimation of amines/phenols using bromated bromide solution / or acetylation
method.
2. Estimation of glucose by Fehling solution.
1.
To find the velocity constant of the hydrolysis of methyl acetate catalyzed by an

acid.
PAGE 26
2.
To determine the order of saponification of ethyl acetate with NaOH
3.
To compare the strength of two acids say hydrochloric acid and sulphuric acids
used in equal concentration for the hydrolysis of methyl acetate.
4.
To study the reaction Kinetics of decomposition of benzene diazonium chloride in

the temperature range 90oC to 60oC, calculate the rate constant also.

(E) SEMINAR
PAGE 27

THIRD SEMESTER
PAPER 301
ORGANOMETALLIC CHEMISTRY
Unit-I:
Metal Carbonyls: Preparation, structure and bonding, Vibration spectra of

metal carbonyls for structural elucidation, Important reactions of metal
carbonyls, Bonding synthesis and reaction of transitional metals with NO,
O2, N2, and tertiary Phosphine Ligands.
Unit-II:
Main Group Organometallics: Ligand hapticity, electron count for different

types of organometallic compounds,18 and 16 electron rule with
exceptions, Synthesis and Reactions of organo Lithium and organo
magnesium compounds. Organo metallics of zinc and cadmium.
Unit-III:
complexes of Unsaturated Molecules: Synthesis, structure, bonding and

reactivity of transitional metal complexes with alkenes, cyclo penta dienyl
(Metallocenes), Benzenoid, - allyl, and enyl systems, Transitional metalcarbon - bond, metal alkyls, metal carbenes, metal carbines.
Unit-IV:
Transition Metal Compounds in Homogenous catalysis: Reaction Steps of

Transition Metal Catalysed Reactions - Coordinative unsaturation, Oxidative
addition reactions, reductive elimination reactions, insertion (migration)
PAGE 28
reactions. Reactions of coordinative legands and activation by small

molecules, Catalytic reactions of Alkenes isomerisation, hydrogenation,
hydroformylation, hydrosilylation and polymerization.
Unit-V:
Supramolecular
Chemistry:
Definition,
supramolecule
host-guest
compounds, Macrocyclic effect, nature of supramolecular interactions,

Molecular recognition, Applications in Transport process and carrier design.
BOOKS RECOMMENDED
Didier Astruc, Organometallic Chemistry and Catalysis, (2007), Springer.
Robert H Crabtree, The Organometallic Chemistry of the Transition Metals, 4th Ed
(2005), Wiley Interscience.
Helmut Werner, Landmarks in Organo-Transition Metal Chemistry, (2009),
Springer.
R.C. Mehrotra and A. Singh, Organometallic chemistry: A unified approach, (1991),
Wiley, New York.
Ayodhya Singh, R. Singh, Organometallic Chemistry, (2006) Campus Books
International.
R.H. Crabtree, The Organometallic Chemistry of the Transition Metals, 1st
Edn.(1988), John-Wiley & Sons, New York.
J. P. Collman, L. S. Hegedus, J. R. Norton and Richard G. Finke, Principles and
Applications of Organotransition Metal Chemistry, 1st Edn.(1987), University
Science Books, Mill Valley, California.
PAGE 29
Ionel Haiduc, Frank Thomas Edelmann, Supramolecular organometallic chemistry,

(2000), Wiley-VCH
Peter J. Cragg, A Practical Guide to Supramolecular Chemistry, (2005), John Wiley
& Sons Ltd.
Katsuhiko Ariga,Toyoki Kunitake, Supramolecular Chemistry-Fundamentals &
Applications (2006), Springer-Verlag.
Jean-Marie Lehn, Supramolecular Chemistry, (1995) VCH, Weinheim.
PAGE 30

THIRD SEMESTER
PAPER 302
STEREOCHEMISTRY AND PHOTOCHEMISTRY
Unit-I:
(a) Concept of chirality, elements of symmetry, R-S nomenclature, E-Z

isomerism.
(b) Interconversion of Fischer, Newman and Sawhorse projections.
(c)Conformation and reactivity in acyclic compounds (upto four carbon
atoms) and cycloalkanes (upto six carbon atoms).
Unit II:
(a) Racemates and their classification, methods of resolution of racemates.

(b)Chemoselectivity, regioselectivity, steroselective, sterospecific reactions
and enatioselectivity with examples.
Unit III:
Molecular dissymmetry and chroptical properties, linear and circularly

polarized light, circular birefringences and circular dichroism, ORD and CD
curves. Plain and Cotton effect curves and their applications. The octant
rule and axial haloketone rule with applications.
Unit IV:
General principles- Photochemical energy, Frank Condon principle,

Jablonski diagram, singlet and triplet states, photosensitization, quenching,
PAGE 31
quantum efficiency and quantum yield, energy transfer process in

photochemistry, experimental methods of photochemistry.
Unit V:
Photochemistry of carbonyl compounds, Norrish type- I and Norrish type- II

cleavages, Paterno-Buchi reactions, photoreductions, photochemistry of
unsaturated systems like olefins, cis-trans isomerisation , dimerisations,
hydrogen abstractions, addition.
Photochemistry of enones rearrangement of unsaturated ketones and

cyclohexadienones.
PAGE 32

THIRD SEMESTER
PAPER 303
PHYSICAL CHEMISTRY III
Unit-I:
SOLID STATE REACTIONS: general principle, experimental procedures, coprecipitation as a precursor to solid state reactions. Crystal defects and
non-stoichiometry, perfect and imperfect crystals, intrinsic and extrinsic
defects-point defects, line and plane defects, vacancies-Schottky defects
and Frenkle defects. Thermodynamics of Schottky defects and Frenkle
defect formation, Color centres, non-stoichiometry and defects.
Unit-II:
THERMODYANAMICS OF BIOPOLYMER SOLUTIONS: Thermodynamics of

bio-polymer solutions, osmotic pressure, membrane equilibrium, macular
contraction and energy generation in mechano-chemical system
Evalaution of molecular weight, size, shape, molecular weight and extent of
hydration
of
biopolymers
by
various
Sedimentation
equilibrium,
hydro
experimental
dynamic
methods,
techniques.
diffusion,
sedimentation velocity, Viscosity, electrophoresis and rotational motions.

Diffraction Methods: Light Scattering, Low angle X-rays Scattering, X-ray
diffraction and photo correlation spectroscopy, ORD.
PAGE 33
Unit-III:
BIOENERGETICS: Standard free energy change in biochemical reactions,

exergonic and endergonic hydrolysis of ATP, synthesis of ATP from ADP.
Solid State- Unit cells, Bravis Lattice, Miller Indices, Differaction of X- rays
by crystalline solids, fundamental aspects of electron and neutron
differaction studies.
Unit-IV:
POLAROGRAPHY: Polarography, Ilkovic Equation, Half wave potential & its

significance, Introduction to corrosion homogenous theory, forms of
corrosion, corrosion monitoring and prevention methods.
Unit-V:
ORGANIC SOLIDS: Electrically conducting solids. Organic charge transfer

complex, organic metals, new super conductors.
PAGE 34

THIRD SEMESTER
PAPER 304
ANALYTICAL CHEMISTRY
Unit-I:
Conductometry: Introduction, principle, technique, electrolytic conductivity,

measurement of electrolytic conductivity, conductometric titration,
applications.
Unit-II:
Polarography and Voltammetry: (a) Introduction, principle, technique,

D.M.E., half-wave potential, residual current, migration current, diffusion
current, limiting current, applications.
(b)Cyclic voltammetry and anodic stripping voltammetry.
Unit-III:
Amperometry: Introduction, principle, types of current, technique,

amperometric titrations with DME, amperometric titrations with rotating
platinum micro electrode, biampero-metry, applications.
Unit-IV:
Coulometry: Introduction, constant current coulometry, controlled

potential coulometry (principle and technique), types of coulometer,
applications.
Unit-V:
Thermal methods of analysis: TGA and DTA (principle, instrumentation,

factors affecting TGA results, applications), a brief idea of DSC.
PAGE 35

THIRD SEMESTER
PAPER 305
PRACTICAL
35 Marks
30 Marks
20 Marks
15 Marks

A. Colorimetry / Spectrophotometry
(25 Marks)
(a) Determination of the wavelength of maximum absoption.

To carry out absorbance measurements for Chromium (VI) and Manganese (VII)
solutions on a spectrophotometer and draw its UV-VIS spectrum and determine the
wavelength of maximum absoption (l max) of Chromium (VI) and Manganese (VII) and
compute the corresponding molar absorption coefficient.
(b) Verification of Beer-Lambert law and Determination of Metal Ions (in ppm) in
supplied solution.
PAGE 36
1. Verification of the Beer-Lambert law and determination the concentration of

supplied KMnO4 solution.
2. To test the validity of the Beer-Lambert law and determine the concentration
of supplied K2Cr2O4 solution.
3. To analyse the validity of Beers law using colorimeter and determine the
concentration of supplied CuSO4.5H2O
4. Determination of the concentration of supplied NiSO4.7H2O solution as Ni-dmg
complex spectrophotometrically.
(c) Determination of Metal Ions (in ppm) in unknown sample.
1. Spectrophotometric Determination of Iron in Vitamin Tablets.
2. Spectrophotometric Determination of Manganese in Steel.
(d) Spectrophotometric Titration.
1.Determination of the concentration of the supplied FeCl3 solution by
spectrophotometric titration with EDTA.
2. Determination of Copper by EDTA
(e) Determination of composition of binary mixture.
1. To calculate the concentrations of Chromium (VI) and Manganese (VII) in a
mixture from the absorption measurements of the mixture at two different
wavelengths.
2. To calculate the concentrations of Cobalt (II) and Chromium (III) in a mixture
from the absorption measurements of the mixture at two different wavelengths.
(f) Spectrophotometric determination of anions.
1. To determine the concentration of given unknown phosphate solution by
Molybdophosphoric acid Method with the help of spectrophotometer.
PAGE 37
2. To determine the concentration of given unknown phosphate solution by

Phosphovanadomo- ybdate method with the help of spectrophotometer.
(g) Determination of Dissociation Constants of an Indicator.
1. To determine the dissociation constant , pKa, of an acidbase indicator (methyl
red) by spectrophotometric method.
2. To determine the dissociation constant , pKa, of an acidbase indicator
(Bromothymol Blue or Phenol Red) by spectrophotometric method.
(h) Determination of Composition (formula) and Stability Constant of Complexs.
1. Fe(III) thiocynate complex by Job's method.
2. Fe(III) sulpho salicylic acid (SSA) complex by Job's method.
3. Copper-ethylene diamine complex by mole fraction or Slope ratio method.
B. Flame photometry
(10 Marks)
1. Determination of Na concentration in the given solution flame photometrically by

calibration curve method
2. Using a flame photometer, determine K in the given solution
3. Determination of calcium concentration flame photometrically
4. Determination of total Na, K & Ca concentration in a plant material
5. Determination of total sodium, potassium, calcium concentration in milk
6. Determination of total Na, K, Ca concentration in banana
7. Determination of Lithium concentration flame photometrically
A. Multi step synthesis of organic compounds
B. Benzaldehyde- benzoin-benzil-benzilic acid
PAGE 38
1.
Benzene-benzophenone-benzophenone oxime-benzilide
2.
Aniline-acetanilide-p-nitro acetanilide-p-Nitroaniline
3.
Aniline-acetanilide-p-bromo acetanilide-p-bromoaniline
4.
Phathilic anhydridr-phalimide-anthranilic acid-methyl red
5.
Nitrobenzene-m-dinitrobenzene-m-nitroaniline-m-nitrophenol.
C. Extraction of organic compounds from natural sources

1.
Isolation of caffeine from tea leaves.
2.
Isolation of casein from milk.
3.
Isolation of lactose from milk
4.
Isolation of carotene from carrot

1. Titration between a strong Acid and strong base conductometrically / Potentio
Nutrically.
2. Titration between a strong base and weak base conductometrically / Potentio
Nutrically.
3. Titration between a weak acid and weak base conductometrically / Potentio
Nutrically.
PAGE 39
4. Titration between a weak Acid and strong base conductometrically / Potentio

Nutrically.
5. To determination tha basicity of an acid and citric acid conductometrically.
6. To find the solubility and solubility product of a sparingly soluble salt and barium
suphate conductometrically.
PAGE 40

FOURTH SEMESTER
PAPER 401
SPECIAL TOPICS IN INORGANIC CHEMISTRY
Unit -I:
Electronic Spectra of Transition Metal Complexes : Types of electronic

transition, selection rule of d-d transition, Spectroscopic ground states,
correlation, Orgel energy level and Tanabe-Sugano diagrams for transition
metal complexes, Calculation of ligand-field parameters (Racah parameters),
Charge transfer spectra. Inter-valance charge transfer spectra.
Unit -II :
Magenetic properties of transitional metals: Different types of magnetic

behavior. Factors affecting observed magnetic moments, Origin of
magnetic moment, spin contribution, spin only formulas, orbital
contribution, spin-spin coupling. Derivation of Van-Vleck equation,
Methods of magnetic susceptibility measurement. Ferromagnetism,
Antiferromagnetism, Mechanism of Antiferromagnetism interaction, Spin
cross over and anomalous magnetic moments, Application of magnetic
measurements for structural elucidation.
Unit -III :
Environmental Chemistry - Soil & Water

(a) Lithosphere (Soils) : Nature and Composition of Soil, Micro and macro
nutrients in soil, Pollutants in Soil - Fertilizers, pesticides, plastics and
metals. Waste Treatment
PAGE 41
(b) Hydrosphere (Water) : Hydrosphere (Sources of water - oceans, lakes,

revers, glaciers and groundwater etc.) and Hydrological cycles. Chemical
composition of water and water quality standards. Aquatic pollutants Inorganic - metals, contents of chloride, sulphate, phosphate and nitrate.
Organic - Pesticide, agricultural, industrial & sewage detergents, oil spills &
oil - pollutants. Solid Waste, Micro organism. Water quality parameters dissolved oxygen, biochemical Oxygen demand . Purification and treatment
of water.
Unit -IV :
Environmental Chemistry - Atmosphere (Air ) Chemical composition of

atmosphere- particles, ions and radicals and their formation. Heat (energy
& radiation) budget of the Earth atmosphere systems. Vertical stability of
atmosphere. Chemical and photochemical reactions in atmosphere, smog
formation. Oxides of N,C,S,O and their effect, Green house effect, Acid rain.
Air pollution controls and their chemistry.
Unit -V:
Green Chemistry : Introduction to green chemistry. Principles of green

chemistry, Designing and chemical synthesis, examples of green synthesis/
reactions. Future trends in green chemistry.
BOOKS RECOMMENDED
Derek Sutton, Electronic spectra of transition metal complexes: An introductory
text (1968), McGraw-Hill.
R.L.Carlin, A. J. van Duyneveldt, Magenetic properties of transitional metals
Compounds (1979), Springer-Verlag.
PAGE 42
Rob Janes and Elaine Moore, Magnetism and the magnetic properties of
transition-metal complexes (2004), RSC.
G.W. Vanloon, S.J. Duffer, Environmental Chemistry - A Global Perspective, (2000)
Oxford University Press.
F.W. Fifield and W.P.J. Hairens, Environmental Analytical Chemistry, 2nd Edition
(2000), Black Well Science Ltd.
Colin Baird, Environmental Chemistry, (1995) W.H. Freeman and Company, New
York.
A.K. De, Environmental Chemistry, 4th Edition (2000), New Age International
Private Ltd., New Delhi.
Peter O. Warner, Analysis of Air Pollutants,1st Edition (1996), John Wiley, New
York.
S.M. Khopkar, Environmental Pollution Analysis, 1st Edition (1993), Wiley Estern
Ltd., New Delhi.
S.K. Banerji, Environmental Chemistry, 1st Edition (1993), Prentice-Hall of India,
New Delhi.
James H. Clark, Duncan J. Macquarrie, Handbook of Green Chemistry and
Technology, (2002) Wiley.
V. K. Ahluwalia, M. Kidwai, New Trends in Green Chemistry (2004), Springer.
R. L.Carlin, Magnetochemistry, Springer.
PAGE 43
D.N. Sathyanarayana, Electronic Absorption Spectroscopy and Related Techniques

(2001), Universities Press (India) Ltd., Hyderabad.
Oliver Kahn, Molecular Magnetism, (1993) VCH, Weinheim.
PAGE 44

FOURTH SEMESTER
PAPER 402
SPECTROSCOPIC METHODS & CHROMATOGRAPHIC TECHNIQUE
Unit-I:
Infra-red spectroscopy: Introduction, principle, fundamental vibration in

polyatomic molecules. Detailed studies of vibrational frequencies of >C=O
group compounds (ketone, aldehydes, esters, amides, anhydrides, lactone,
lactams and conjugated >C=O group)and metal complexes. Hydrogen
bonding and solvent effect on vibrational frequencies, overtones,
combination bonds and ermi resonances.
Unit II:
Nuclear Magnetic resonance spectroscopy (NMR): Introduction theory,

relaxation process and saturation, environmental effects on NMR spectra ,
chemical shift, spin-spin splitting , coupling constant.
13
C NMR, FT-NMR,
Medicinal applications of NMR spectroscopy applications.
Unit III:
Mass: Introduction, molecule ion peak, base peak, isotopic abudance,

metastable ions fragmentation mechanism of compounds containing
C,H,O,N and halogen. MacLaffery rearrangement, nitrogen rule and ring
rule and applications.
PAGE 45
Unit IV:
ESR: Introduction, principle, hyperfine splitting and significance of g-value.

Determination of value. Rules for hyperfine splitting and application.
Unit V:
Chromatographic
techniques:
Introduction,
principle
types
of
chromatography. Applications of paper, column, thin layer, high

performance liquid chromatography (HPLC) and gas chromatography
PAGE 46

FOURTH SEMESTER
PAPER 403
PHYSICAL CHEMISTRY
Unit-I:
ANGULAR
MOMENTUM:
Angular
Momentum:
Ordinary
angular
momentum, generalized angular momentum, Eigen values of angular

momentum, operators using ladder operator, addition of angular
momentum, spin, antisymmetric and Pauli Exclusion principle.
Unit-II:
ELECTRONIC PROPERTIES AND BAND THEORY: Metals, insulators and

semiconductors, electronic structure of solids, band structure of metals,
band theory, intrinsic and extrinsic semiconductors, doping semiconductors,
p-n junction, super conductors, optical properties, optical reflectance.
Photoconduction-photoelectric effects, magnetic properties classification
of materials. Quantum theory of paramagnetic cooperative phenomenon.
Magnetic domains, hysteresis.
Unit-III:
CELL MEMBRANE AND TRANSPORT OF IONS: Structure and functions of cell

membrane,
ion
transport
through
cell
membrane,
irreversible
thermodynamic treatment of membrane transport, nerve conduction
PAGE 47
Unit-IV:
LIQUID CRYSTALLINE POLYMERS: Introduction, synthesis of an acrylate

based liquid crystal polymer, the hydrosilylation reaction, a useful
procedure for the preparation of variety of side chain polymers,
photochemical preparation of liquid crystalline elastomers with a memory
of the aligned cholesteric phase, defining permanent membrane of global
alignment of liquid crystal elastomers.
Unit-V:
NON_EQUILIBRIUM THERMODYNAMICS: Postulates and methodologies,

linear laws, Gibbs Equation, Onsager reciprocal theory
PAGE 48

FOURTH SEMESTER
PAPER 404
OPTIONAL PAPER
TO CHOOSE ANY ONE PAPER ONLY
A. Selected topics in Inorganic Chemistry

B.
Selected topics in Organic Chemistry
C.
Selected topics in Physical Chemistry
D. Selected topics in Analytical Chemistry
PAGE 49

FOURTH SEMESTER
PAPER 404 (A)
SELECTED TOPICS IN INORGANIC CHEMISTRY
Unit-I:
(a) Role of Metal ions in Biological Systems: Functions of metal ions in

biological systems. Transport of ions through cell membrane - Na+/K+
Pump.
(b) Oxygen carrier Systems: Structure and function of Hemoglobin,
Myoglobin, Hemerythrin & Hemocyanin. Mechanism of dioxygen binding
with heme proteins. Nature of Iron-dioxygen linkage in Hemoglobin, Model
system - Model Synthetic complexes of Iron and Cobalt as Oxygen carrier.
Unit-II:
(a) Photosynthetic Pigments : Complexes of Porphyrin. Redox mechanism in

Photosystems (PS-I and PS-II), Cleavage of Water in PS-II.
(b) Biological Nitrogen Fixation : Enzymetic reduction of Nitrogen to
Ammonia -
Nitrogenase Structure
and mechanism.
Molybdenum
Nitrogenase - Spectroscopic and other studies. Model Systems for

Nitrogenase.
Unit-III:
(a) Electron Transfer in Biology : Structure and Function of Metallic Proteins

in Electron Transport Process, Cytochrome, Iron-sulphur Proteins.
PAGE 50
(b) Metal Storage, Transport and Biomineralisation : Metal Storage and

Transport Structure and Function of Feritin, Transfrsin and Siderophores.
Biomineralisation.
Unit-IV:
(a) Calcium in Biology: Role of Calcium in living systems. Transport and

regulation of Calcium - pathways and mechanism, Calcium Channels and
pumps. Calcium binding proteins - Intracellular, Mediated membrane and
Extracellular.
(b) Metalloenzymes: Zinc enzymes - Carboxypeptidase and Carbonic
anhydrase. Iron enzyme - Catalase, Peroxidase and Cytochrome P-450.
Copper enzymes - Superoxides dismutase. Molybdenum enzymes Oxatransferase enzymes, Xanthine oxidase. Vitamin B12 Coenzyme
(Adenosyl Coenzyme).
Unit-V:
(a) Metal - Nuclic Acid Interactions : Metal ions and Nucleic Acids
Interactions (binding) - Types & suitable examples. Metal complexes (e.g.,
Cisplatin) interaction with DNA.
(b) Metals in Medicine: Metal Deficiency and disease. Toxic effects of
Metals. Metals used for diagnosis. Metals used in Chemotherapy with
particular reference to Anticancer drugs.
BOOKS RECOMMENDED
S. J. Lippard and J. M. Berg, Principles of Bioinorganic Chemistry, (1994),
University Science Books.
PAGE 51
Bertini, H. B. Grey, S. J. Lippard and J. S. Valentine, Bioinorganic Chemistry, (1998)

Viva Books Pvt. Ltd., New Delhi.
Harry B. Gray, Edward I. Stiefel, Joan Selverstone Valentine and Ivano Bertini,
Biological Inorganic Chemistry: Structure and Reactivity, (2006),University Science
Books.
Robert Crichton, Biological Inorganic Chemistry: An Introduction (2008), Elsevier
Science.
M. N. Hughes, Inorganic Chemistry of Biological Processes, 2nd Ed.(1981), JohnWiley & Sons, New York.
W. Kaim and B. Schwederski, Bioinorganic Chemistry: Inorganic Elements in the
Chemistry of Life, An Introduction and Guide, (1995) Wiley, New York.
Nicholas V. Hud, Nucleic Acid - Metal Ion Interactions, (2009), Royal Society of
Chemistry.
Ivano Bertini, A.Sigel, H.Sigel (Editors), Handbook on Metalloproteins (2001),
Marcell Dekker,Inc,
James C. Dabrowiak, Metals in Medicine (2009), John Wiley & Sons, Ltd.
Rosette M. Roat-Malone, Bioinorganic Chemistry - A Short Course, 2nd Edition,
(2007), Wiley.
H.B. Kraatz, N. Metzler-Nolte (Eds.), Concepts and Models in Bioinorganic
Chemistry (2006), Wiley-VCH.
L. Nelson and M.M. Cox, Lehninger Principles of Biochemistry, 3rd edition (2002)
McMillan North Publication.
PAGE 52

FOURTH SEMESTER
PAPER 404 (B)
SELECTED TOPICS IN ORGANIC CHEMISTRY
Unit-I:
Terpenoids: Introduction, classification of terpenoids, isolation of

terpenoids, isoprene rule. General methods of determination of structure .
Monoterpenoids- constitution of
-terpenol, pinene. Sesquiterpenoids-
constitution of farnesol and zinziberene.

Unit II:
Alkaloids: Introduction, classification of alkaloids, general
methods of
determination of structure of alkaloids. Isolationmorphine, reserpine and

quinine.
Unit III:
Steroids:
Introduction,occurance,
classification,
biological
role
and
important structural and stereochemical features of : Throxine, Cholestrol,

testosterone, oestrone and cortisone and plant harmones Auxins and
Gibberellins.
Unit IV:
Natural Pigments: General structural features, occurance, isolation,

biological importance and application of carotenoids, anthocyanins and
flavones. Structure determination and synthesis of carotene.
Unit V:
Heterocycles: Introduction, classification, IUPAC names of mono and

bicyclic hetero aromatic compounds. Criteria of aromaticity in heterocycles.
PAGE 53
Synthesis and reaction of benzo[b] and benzo [C], benzodiazoles, and

acridines. Heterocycles as drug and drug intermediates- caffeine, diazepam,
phenophiazines. Heterocycles in the preparation of flavours and perfumery
chemicals-indole and pyrazines.
PAGE 54

FOURTH SEMESTER
PAPER 404 (C)
SELECTED TOPICS IN PHYSICAL CHEMISTRY
Unit-I:
Thin Films and Langmuir- Blodgett

Preparation
techniques,
evaporation/sputtering,
chemical
prcesses,
MOCVD, Sol-gel, etc. Langmuir Blodgett (LB) Films, Growth Techniques,

Photolithography, Properties and application of thin and LB films.
Liquid Crystals: Mesmorphic behavior, thermo tropic liquid crystals,
positional order, bond orientational order, nematic and smetic mesophates,
smetic-nematic, transition and clearing temperature, hometropic, planar
and schlieren textures, twisted nematics, chiral nematics, molecular
arrangement in smetic A and Smetic C phases, Optical properties of liquid
crystals, Dielectric susceptibility and dielectric constants. Lyotropic phases
and their description of ordering in liquid crystals.
Unit-II:
Polymeric Materials: Molecular shape, structure and configuration,

crystanility, stress-strain behavior,thermal behavior, polymer types and
their application, conducting and feno-electric polymers.
Ionic Conductors: Types of Ionic conductors, mechanism of Ionic
conduction, interstial Jumps (Frenkle); Vacancy, Mechanism diffusion
PAGE 55
superionic conductor, phase transitions and mechanism of conduction in

super ionic conductors, examples and application of ionic conductors.
Unit-III:
Theortical and computational treatment of atoms and molecules, hartreeFock theory, Review of the principles of quantum mechanics, Born-oppen
heimer approximation, staler condon rules, Hartree Fock equation,
Koopmans and Brilloning theories, Roothan Equation, Gaussian basis sets.
Unit-IV:
General Properties of Liquids:

(a) Liquids
as
dense
gases,
liquids
as
disordered
solids,
some
thermodynamic reation, internal pressures and its significance in liquids

equation of state, critical constants. Different types of intermolecular
forces in liquids, different potential function for liquids, additivity of pair
potential approximation.
(b) A classical partition function for liquids, correspondence principle,
configuration integral, configuration properties.
Unit-V: Polymer Processing:

Plastic elastomers and fibres, compounding, processing techniques,
calendaring die casting, rotational casting injection moulding, Blow
moulding, extrusion moulding, thermoforming, foaming, reinforcing and
fibre spinning.
PAGE 56

FOURTH SEMESTER
PAPER 404 (D)
SELECTED TOPICS IN ANALYTICAL CHEMISTRY
Unit-I:
Unit operations of analytical chemistry: Role of analytical chemistry,

classification of analytical methods- classical and instrumentatal. Type of
instrumental analysis, selecting an analytical method, laboratory operations
and practices. Analytical balance, volumetric glassware- cleaning and
calibration of glassware, sample preparations dissolution and
decompositions.
Gravimetric techniques, selecting and handling of
reagents, laboratory notebooks. Safety in the analytical laboratory.
Unit-II:
Errors and Evaluation: Definition of terms in mean and median. Precision

standard deviation, relative standard deviation, accuracy- absolute error,
relative error. Types of error in experimental data determination
(systematic), indeterminate (or random) and gross. Sources of errors and
the effects upon the analytical results, methods for reporting analytical
data, statistical evaluation of data indeterminate error. The uses of
statistics.
PAGE 57
Unit-III:
Seperation Techniques: Distillation under reduced pressure, flash

evaporator, solvent extraction and ion exchange methods. Adsorption,
partition, exclusion, electro chromatography.
Unit-IV:
Radiochemical
methods: Radioactive emissions, detectors, X-
ray
spectrometry, X- ray absorption, X-ray fluorescence, X-ray diffraction,

photoelectron
spectrometry,
radiochemistry,
isotope
dilution,
radioimmuno assay, neutron activation analysis.
Unit-V:
Automated methods of analysis: An overview of automatic instruments and

instrumentation, advantage and disadvantage, types of automatic
analytical systems, flow injection analysis discrete automatic systems,
robotics, automatic organic elemental analyzers.
PAGE 58

FOURTH SEMESTER
PAPER 405
PRACTICAL
(A) Experiments of Paper 404
60 Marks
(B) Seminar
20 Marks
(C) Viva Voce & Record
20 Marks
(A) INORGANIC CHEMISTRY

A. Water Analysis
(10 Marks)
1. Determination of alkalinity of the given water sample

2. To determine temporary hardness of water by the HCl method
3. Determination of total hardness of water by complexometric titration method
4. Determination of temporary hardness of water by EDTA method
5. Determination of calcium and magnesium in water by EDTA method
6. To determine chloride content of the given water sample by Mohrs method
7. Determination of COD of the water sample
8. Determination of DO in water by iodometric method
PAGE 59
9. Determination of percentage of available chlorine in the supplied sample of

bleaching powder
10.To determine the residual chlorine
11.Determination of pH & electrical conductivity
12.Determination of dissolved carbon dioxide
13.Determination of Inorganic P, total P & Sulphate spectrophotometrically.
B. Soil Analysis
(10 Marks)
1. Determination of pH
2. Determination of conductivity
3. Determination of total alkalinity
4. Determination of chloride & sulphate
5. Determination of organic matter
6. Determination of phosphorus & total phosphorus
7. Determination of Na, K, Ca, Mg
C. Quantitative analysis of minerals/alloys/coins
(25 Marks)
1. Analysis the given brass (50-70% Cu+20-40%Zn+0-6%Sn+0-2%Pb+0-1%Fe) sample

for its Cu and Zn contents colorimetrically. Alternatively,Cu by iodometry and Zn
by EDTA method.
2. Analysis of the given sample of gun metal (90% Cu+10%Sn) for its Cu content by
iodometry.
3. To determine ferrous content in the supplied sample of iron ore/rust/steel
volumetrically against standard potassium dichromate solution using potassium
ferricyanide as external indicator.
PAGE 60
4. Analysis of the given sample of dolomite (equimolar CaCO3+MgCO3) for its volatile
matter, insoluble matter, and its Ca & Mg contents by EDTA method.
5. Analyse the given five-rupee coin for its Cu content iodometrically, and Ni content
as Nidmg complex colorimetrically or gravimetrically.
D. Potentiometry and pH-metry
(15 Marks)
(a) Determination of Concentration of Metal ions by potentiometric titration.

1. Determination of Fe(II) with potassium dichromate.
2. Cu(II) by iodometric method.
(b) Determination of Dissociation Constants, pK values of 1. Glycine
2. Sulpho salicylic Acid
3. ortho-Phosphoric Acid
(c) Determination of Stability Constant of Complexs.
1. The stepwise and the overall stability constants of Cu(II)-Sulpho salicylic Acid
Complexs.
2. The stepwise and the overall stability constants of Mn(II)-Amino Acid (eg Glycine)
Complexs.
SEMINAR
20
RECORD AND VIVA
20
PAGE 61
OR
1.
Chromatographic separation of amino acids, carbohydrates, pigments and

dyes and determination of RF values.
2.
3.
20
Spectrophotometeric estimation of aminoacids, ascorbic acid, aspirin, proteins

and carbohydrate.
30
Extraction and separation of plant pigments
10
SEMINAR
20
RECORD AND VIVA
20
OR
(C) PHYSICAL PRACTICALS :

Polarimetry:
Determination of rate constant for hydrolysis/inversion of sugar using a polarimeter.
Thermodynamics:
PAGE 62
(i) Determination of partial molar volume of solute (KCl) and solvent in a binary
mixture.
(ii) Determination of temperature dependence of the solubility of a compound in to
solvents having inter molecular intraction (Benzoic acid in water and in DMSO
water mixture) and calculate the partial molar heat of solution.
Spectroscopy:
(i) Determination of pka of an indicator (e.g. Methyl Red) in (a) aqueous and (b)
micellar media.
(ii) Detremination of stoichometry and stability constant of inorganic (e.g. Ferricsalicylin acid) and organic (e.g. amine iodine) complexes.
(iii)
Characterization of the complexes by electronic and IR Spectra Data.
Polarography:
(i) Estimation of Pb+2 and Cd+2/Zn+2 and Ni+2 ions in a mixture of Pb+2 and Cd+2/Zn+2
and Ni+2 by Polarography.
(ii) Determination of dissolved oxygen in aqueous solution of organic solvents.
Electronics:
(i) Basic electronic experiments.
OR
PAGE 63

RECOMMEND BOOKS
ANALYTICAL CHEMISTRY
1.
Modern spectroscopy, J.M.Hollas, John Eiley
2.
Applied Electron Spectroscopy for Chemical Analysis Ed.H. Windai and F.L.Ho
Wiley Interscience
3.
NMR, NQR, EPR and Mossbauer Spectroscopy in Inorganic Chemistry, R.V. Parish,
Ellis Harwood.
4.
Physical Methods in Chemistry, R.S. Drago, Saunders College
5.
Chemical application of Group Theory, F.A. Cotton
6.
Introduction to Molecular Spectroscopy, G.M.Borrow, McGraw Hill
7.
Basic Principles of spectroscopy, R. Chang, McGrawHill
8.
Theory and Applications of UV spectroscopy, P.K.Ghosh, John Wiley
9.
Introduction to Magnetic Resonance, A. Carrington and A.D. Maclachalan, Harper

& Row.
PAGE 73

RECOMMEND BOOKS
COMPUTERS
1. Computers and common sense, R. Hunt and J. Wiley, Prentice Hall.
2. Computational Chemistry, A.C. Norris
PAGE 74

STANDARD TEXT BOOKS
F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 3rd Edn. (1972), Wiley
Eastern Ltd.,New Delhi.
F.A. Cotton and G. Wilkinson, Carlos A. Murillo, Monfred Bochmann, Advanced
Inorganic Chemistry, 6th Edn. (1999), John Wiley & Sons, Inc.
James E. Huheey, Inorganic Chemistry, 3rd Edn. (1983), Harper & Row Publisher.
James E.Huheey, Ellen A. Keiter, Richard L.Keiter, Inorganic Chemistry: Principles of
structure and reactivity, 4th ed. (1993), Addison-Wesley Pub. Co., New York.
R. Bruce King (Editor), Encyclopedia of Inorganic Chemistry (10 Vol), 2nd Ed (2005),
Wiley.
Duward Shriver, Peter Atkins, Tina Overton, Jonathan Rourke, Inorganic Chemistry,
5th edition (2010), Oxford University Press.
Catherine Housecroft, Alan G. Sharpe, Inorganic Chemistry, 3rd Edition, (2007),
Prentice Hall.
William W. Porterfield, Inorganic Chemistry: A Unified Approach, (1983), Longman.
Gary Wulfsberg, Inorganic Chemistry (2000), University Science Books.
PAGE 75
Gary L. Miessler, Donald A. Tarr, Inorganic Chemistry, 4th Ed. (2011), Prentice Hall,
Pearson.
PAGE 76

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DR.

BHIM RAO AMBEDKAR UNIVERSITY, AGRA

Course Structure for M.SC. (CHEMISTRY) under

DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA

PAPER 101 - Computers for Chemistry

PAPER 102 - Inorganic Chemistry

PAPER 103 - Organic Chemistry

PAPER 104 - Physical Chemistry I

PAPER 105 PRACTICAL :-

(A) Inorganic Chemistry

(B) Organic Chemistry

(C) Physical Chemistry

(D) Viva Voce & Record

DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA

PAPER 201 - Group Theory and Spectroscopy

PAPER 202 - Coordination Chemistry

PAPER 203 - Bioorganic Chemistry

PAPER 204 - Physical Chemistry II

PAPER 205 PRACTICAL :-

(A) Inorganic Chemistry

(B) Organic Chemistry

(C) Physical Chemistry

(D) Viva Voce & Record

DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA

PAPER 301 - Organometallic Chemistry

PAPER 302 - Stereochemistry and Photochemistry

PAPER 303 - Physical Chemistry III

PAPER 304 - Analytical Chemistry

PAPER 305 PRACTICAL :-

(A) Inorganic Chemistry

(B) Organic Chemistry

(C) Physical Chemistry

(D) Viva Voce & Record

DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA

PAPER 401 Selected topics in Inorganic Chemistry

PAPER 402 Spectroscopy and Chromatographic technique

PAPER 403 Physical Chemistry IV

PAPER 404 OPTIONAL PAPER :-

(A) Selected topics in Inorganic Chemistry

(A) Experiments of Paper 404

(C) Viva Voce & Record

DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA

Each practical performance will be of 100 marks.

DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA

MASTER OF SCIENCE (CHEMISTRY)

History of development of computer, mainframe , mini, micro and super

Computer languages development and history, operating system single

General awareness of popular commercial software packages like( DBASE,

Introduction to networking and searching study material using Internet

Uses of computers in Chemistry

DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA

MASTER OF SCIENCE (CHEMISTRY)

Studies and Application of Lanthanides and Actinides: Spectral and

Inorganic Rings, Cages and Clusters : Polyhedral Boranes : Higher Boranes,

DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA

Nomenclature, preparation, Structure and Bonding, Wades rule, Metal

Inorganic Polymers : Characteristic properties and Classification., Types of

Reductive Coupling, Condensation synthesis ), Synthesis, properties and

Nanoscience and Nanotechnology : Introduction to nanotechnology, scope

DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA

B. G. Harvey, Introduction to Nuclear Physics and Chemistry, (1969) Prentice Hall,

DR. BHIM RAO AMBEDKAR UNIVERSITY, AGRA