Beruflich Dokumente
Kultur Dokumente
Carbon Formation
C2H6
+H2O
2 CO + 5 H2
Reforming
2 C + 3 H2
Carbon
CARBON FORMATION
Two types of carbon formation:
Catalytic cracking
(on Ni crystals)
Thermal cracking
(on hot surfaces)
Steam to higher
hydrocarbon radio
14
12
10
8
Carbon formation
6
4
2
0
2
3
m from inlet
nH
m
C nH m
500C
C nH m
nH
m
CnHm
C nH m
Hm
Cn
C nH m
C nH m
C nH m
850C
High
activity
Low
activity
Reformer design
Radiant Wall
Top Fired
Bottom Fired
Terrace Wall
Topse
MW Kellogg
Chemico
Foster Wheeler
Selas
KTI
Girdler
UHDE
Impact of Alkali
Relative Activity
0
400
500
600
Catalyst Temperature
700
Sulphur Poisoning
Temperature dependence
Sulphur Coverage
1
0.8
ppbv=10
ppbv=50
ppbv=100
0.6
0.4
500 550 600 650 700 750 800 850 900
Temperature, C
Dynamics of poisoning
Sulphur Coverage
Year 1
Year 2
Year 3
Equilibrium
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0
20
40
60
Tube Length, %
80
100
Desorption of sulphur
S-Nisurface + H2 Nisurface + H2S
Sulphur Coverage
1.0
0.8
0.6
0.4
0.2
0.0
1
10
700 C
100
Time, hr
1000
800 C
10000
Sulphur Regeneration
S-Nisurface + H2O NiO + H2S
H2S + 2 H2O SO2 + 2 H2
TWT's
980
300
Before
After
960
200
940
920
100
SO2
900
0
0
6
Time
10
PPM SO2
Temperature C
1000
4
%
2
0
8
10
Time
11
12
Sintering
Decreased C tolerance
Decreased S tolerance
Decreased activity
Used
Fresh
Fresh
550C
0.8
0.6
700C
0.4
0.2
800C
0
1
10
100
Time/hours
1000
Triple Decker
Temperature
900
Sintering
Carbon
Sulphur
850
TWT
Catalyst
800
750
RK-211
RK-201
R-67-7H
700
0
10
R-67-7H :
Carrier:
Ni content:
MgAl2O4 (spinel)
14 %
RK-201:
Carrier:
Ni content:
K content:
CaAl2O4 + MgAl2O4
12 %
0.4 %
RK211:
As RK-201 except :
Doped with noble metal
Prereduced
Unidense
SpiraLoad
30-40
15-20
15-20
Tubes unloaded, %
~2
~2
0.01
Manpower
Demanding
Normal
Normal
Automised
Low
Low
High
END
CHALLENGES IN STEAM REFORMING
QUESTIONS?