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Effective date: 20/04/2015
Previous Date: 24/10/2014
CORRSHIELD MD4100
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name or designation of
the mixture
CORRSHIELD MD4100
Version number
8.1
Revision date
20/04/2015
Supersedes date
24/10/2014
1.2. Relevant identified uses of the substance or mixture and uses advised against
Water-based corrosion inhibitor
Identified uses
Uses advised against
None known.
T;R25, Xi;R36
Health hazards
Environmental hazards
Category 1
Health hazards
Acute toxicity, oral
Category 4
Skin corrosion/irritation
Category 2
Category 2
Version: 8.1
Effective date: 20/04/2015
Previous Date: 24/10/2014
CORRSHIELD MD4100
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended
Sodium nitrite
Contains:
Hazard pictograms
Warning
Signal word
Hazard statements
H290
H302
H315
H319
Precautionary statements
Prevention
P234
P280
Response
P301 + P312
P302 + P352
P305 + P351 + P338
Storage
P406
Not available.
Disposal
Supplemental label information
None.
None known.
Chemical description
Chemical name
Sodium molybdate
Classification:
DSD:
CLP:
Sodium nitrite
Classification:
CAS-No. / EC No.
INDEX No.
10 - < 20
7631-95-0
231-551-7
01-2119489495-21
5 - < 25
7632-00-0
231-555-9
01-2119471836-27
007-010-00-4
DSD:
CLP:
Ox. Sol. 3;H272, Acute Tox. 3;H301, Eye Irrit. 2;H319, Aquatic Acute 1;H400
Sodium hydroxide
Classification:
< 0,5
1310-73-2
215-185-5
DSD:
C;R35
CLP:
01-2119457892-27
Notes
011-002-00-6
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Effective date: 20/04/2015
Previous Date: 24/10/2014
CORRSHIELD MD4100
The classification of the above substance(s) is given, including the symbol letters, R-phrases, hazard class, category code and hazard
statements which are assigned in accordance with their physicochemical, health and environmental hazards. Please refer to section 16
where the full text of each relevant R-phrase and H-statement is listed.
Eye contact
Ingestion
Not available.
Contains an oxidiser.
Avoid all contact with reducing agents, oils, greases, organics and acids.
Do not allow to dry.
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Previous Date: 24/10/2014
CORRSHIELD MD4100
7.3. Specific end use(s)
Do not freeze.
If frozen, thaw completely and mix thoroughly prior to use.
Store containers closed when not in use.
Only for professional and industrial users
Shelf life
720 days
Type
STEL
Value
2 mg/m3
STEL
10 mg/m3
TWA
5 mg/m3
Recommended monitoring
procedures
Not available.
Type
Route
Value
Form
Workers
Workers
Dermal
Inhalation
Inhalation
Inhalation
2 mg/kg/day
2 mg/m3
1 mg/m3
11,17 mg/m3
Workers
Inhalation
2 mg/m3
Inhalation
2 mg/m3
Type
Route
Value
Aqua (freshwater)
Aqua (marine water)
Sediment (freshwater)
Sediment (marine
water)
Soil
STP
Aqua (freshwater)
Aqua (marine water)
Intermittent release
Sediment (freshwater)
Sediment (marine
water)
Soil
Not applicable
Not applicable
Not applicable
Not applicable
12,7 mg/l
1,9 mg/l
22,6 g/kg dwt
1,98 g/kg dwt
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
STP
Form
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CORRSHIELD MD4100
Skin protection
- Hand protection
- Other
Respiratory protection
Thermal hazards
Environmental exposure controls
Yellow
Not available.
Odour
Mild
Odour threshold
Not available.
pH (concentrated product)
12,8
-10 C
104 C
Flash point
Not applicable.
Evaporation rate
< 1 (Ether = 1)
Not applicable.
Not available.
Vapour pressure
18 mm Hg
21 C
Vapour density
< 1 (Air = 1)
Relative density
1,18
21 C
Solubility
Solubility (water)
100 %
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature
Not applicable.
Decomposition temperature
Not available.
Viscosity
4 cps
Viscosity temperature
21 C
Explosive properties
Not available.
Oxidizing properties
Not available.
0 (Estimated)
Shelf life
Material name: CORRSHIELD MD4100
720 days
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Version: 8.1
Effective date: 20/04/2015
Previous Date: 24/10/2014
CORRSHIELD MD4100
SECTION 10: Stability and reactivity
10.1. Reactivity
Not available.
Not applicable.
Test results
Components
Test results
Acute toxicity
Harmful if swallowed.
Skin corrosion/irritation
Not classified.
Respiratory sensitisation
Not classified.
Not classified.
Not classified.
Carcinogenicity
Not classified.
Not classified.
Reproductive toxicity
Not classified.
Skin contact
Eye contact
Symptoms
Not available.
None known.
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CORRSHIELD MD4100
Other information
Not available.
Species
Test results
Bluegill sunfish
Fathead minnow
Bluegill sunfish
Fathead minnow
LC50
Daphnia magna
NOEL
Daphnia magna
0% Mortality
Rainbow trout
Species
Test results
Fish
NOEL
Aquatic
Crustacea
Fish
Components
Sodium nitrite (CAS 7632-00-0)
Aquatic
Fish
LC50
0 (calculated data)
- BOD 28 (mgO2/g)
1 (calculated data)
5 (calculated data)
- Zahn-Wellens Test (%
Degradation in 28 days)
8 (calculated data)
6 (calculated data)
Not available.
Partition coefficient
n-octanol/water (log Kow)
Not available.
Not available.
Not available.
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Version: 8.1
Effective date: 20/04/2015
Previous Date: 24/10/2014
CORRSHIELD MD4100
Disposal methods/information
UN3266
Corrosive liquid, basic, inorganic, n.o.s. (Sodium hydroxide, Mixture)
8
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard
class(es)
Subsidiary class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for
user
UN3266
Corrosive liquid, basic, inorganic, n.o.s. (Sodium hydroxide, Mixture)
8
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard
class(es)
Subsidiary class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for
user
IATA
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard
class(es)
Subsidiary class(es)
14.4. Packing group
14.5. Environmental hazards
ERG Code
14.6. Special precautions for
user
IMDG
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard
class(es)
Subsidiary class(es)
14.4. Packing group
UN3266
Corrosive liquid, basic, inorganic, n.o.s. (Sodium hydroxide, Mixture)
8
III
No
(E)
Not available.
RID
III
No
Not available.
ADN
III
No
Not available.
UN3266
Corrosive liquid, basic, inorganic, n.o.s. (Sodium hydroxide, Mixture)
8
III
No
Not available.
Not available.
UN3266
Corrosive liquid, basic, inorganic, n.o.s. (Sodium hydroxide, Mixture)
8
III
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Version: 8.1
Effective date: 20/04/2015
Previous Date: 24/10/2014
CORRSHIELD MD4100
14.5. Environmental hazards
Marine pollutant
EmS No.
14.6. Special precautions for
user
14.7. Transport in bulk
according to Annex II of
MARPOL 73/78 and the IBC
Code
No
F-A, S-B
Not available.
This substance/mixture is not intended to be transported in bulk.
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Version: 8.1
Effective date: 20/04/2015
Previous Date: 24/10/2014
CORRSHIELD MD4100
Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding
Not regulated.
Other EU regulations
Directive 96/82/EC (Seveso II) on the control of major-accident hazards involving dangerous substances
Not regulated.
Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work
Sodium hydroxide (CAS 1310-73-2)
Sodium nitrite (CAS 7632-00-0)
Directive 94/33/EC on the protection of young people at work
Sodium hydroxide (CAS 1310-73-2)
Sodium nitrite (CAS 7632-00-0)
Not available.
National regulations
15.2. Chemical safety assessment
Not available.
Inventory status
Country(s) or region
Europe
Inventory name
European Inventory of Existing CommercialChemical Substances
(EINECS)
Europe
On inventory (yes/no)*
Yes
No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
References
Information on evaluation
method leading to the
classification of mixture
The physical, health and environmental hazards of this mixture are assessed by applying the
classification criteria for each hazard class or differentiation in Parts 2 to 5 of Annex I to Regulation (EC)
No 1272/2008 (CLP).
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Version: 8.1
Effective date: 20/04/2015
Previous Date: 24/10/2014
CORRSHIELD MD4100
Revision information
Training information
Provide training on safe handling while considering the type of application and exposure scenarios.
Based on EC Directive /
Regulations
Further information
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