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+2; Fe3+ ion, +3; I- ion, -1; O2- ion, -2; and so on.]
3. In their compounds, the group 1 metals (Alkali) have an O.S. of +1 and the
group 2 metals (Alkaline) have an O.S. of +2.
[Examples: The O.S. of K is +1 in KCl and K2CO3; the O.S. og Mg is +2 in
MgBr2 and Mg(NO3)2]
4. In its compounds, the O.S. of fluorine is -1.
[Examples: The O.S. of F is -1 in HF, ClF3 and SF6 ]
5. In its compounds, hydrogen usually has an O.S. of +1.
[Examples: The O.S of H is +1 in HI, H2S, NH3, CH4]
Exceptions to rule 6 occur in compounds with O-F bonds, such as OF2, and in
compounds where O atoms are bonded to one another, as in H2O2, and KO2.
Source:
General Chemestry Petrucci, Chapter 3, page 85
Chang Chemestry, Chapter 4, page 138
2
EXERCISES
P4:
HNO3:
This is the formula for nitric acid, which yields a H+ ion and a
NO2 ion in solution. From rule 5 we see that H has an oxidation number of +1.
Thus the other group (the nitrate ion) must have a net oxidation number of -1.
Oxygen has an oxidation number of -2, and if we use x to represent the
oxidation number of nitrogen, then the nitrate ion can be written as:
H2O2:
This is hydrogen peroxide. Rule 5, stating that H has an O.S. of
+1, takes precedence over rule 6. The sum of the oxidation states of the two H
atoms is +2 and that of the two O atoms must be -2. The O.S. of O must be -1.
NaH:
This is a formula unit of the ionic compound sodium hydride.
Rule 3 states that the O.S. of Na is +1. Rule 5 indicates that H should also have
an O.S. of +1. If both atoms had a O.S. of +1, the total for the formula unit
would be +2. This violates the rule 2.
Na has an O.S. of +1; the total for the formula unit is 0; and the O.S. of H must
be -1.
Al2O3:
The total of the oxidation states of all the atoms in this formula
unit is 0. The O.S. of oxygen is -2. The total for three O atoms is -6. The total
for two Al atoms is +6. The O.S. of Al is +3.
MnO4-:
oxidation states of all the atoms in the ion is -1. The total for the four O atoms
is -4. The O.S. of Mn is +7.
PF3: Using algebra like in the other compounds I can calclulate the oxidation
states.
F= -1 Rule 4
P + 3(-1) = 0 Rule 2
P=0+3
P = +3