Beruflich Dokumente
Kultur Dokumente
CHEMF214
Instructor-in-charge
Inamur R. Laskar
Electronegativity
Topics to be covered
Robert S. Mulliken
(1896-1986); Noble prize in 1966
(for his fundamental work concerning
chemical bonds and the electronic
structure of molecules by the molecular
orbital method)
Mulliken-Jaffes Electronegativity
Mullikens EN equation (from Paulings EN)
M = 0.336[IEv + EAv/2 0.615] (where the energies are in electron
volts)
Plotting of ionization
energies electron
affinities results a
smooth curve and the
function can be described
accurately by the
following
quadratic formula,
E = q + q2 ; E is the
total energy of the ion
(IE or EA
What are the observations??
so Mulliken EN =