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MODULE 5: DISTILLATION
LECTURE NO. 7
Stepwise procedure to determine the number of theoretical trays:
Step 1: Draw the equilibrium curve and the enthalpy concentration diagram for
the mixture to be separated
Step 2: Calculate the compositions of the feed, distillate and bottom products.
Locate these compositions on the enthalpy-concentration diagram.
Step 3: Estimate the reflux rate for the separation and locate the rectifying
section difference point as R as shown in Figure 5.23. Point y1 is the intersection
point of line joining point xD and R and HV-y curve.
Step 4: Locate the stripping section difference point s. The point s is to be
located at a point where the line from R through xF intersects the xB composition
coordinate as shown in Figure 4.23.
Step 5: Step off the trays graphically for the rectifying section. Then the point of
composition x1 of liquid of top tray is to be determined from the equilibrium
relation with y1 of vapor which is leaving the tray and locate it to the HL-x curve.
Then the composition y2 is to be located at the point where the line of points R
and x1 intersects HV-y curve. This procedure is to be continued until the feed plate
is reached.
Step 6: Similarly follow the same rule for stripping section. In the stripping
section, the vapor composition yB leaving the reboiler is to be estimated from the
equilibrium relation. Then join the yB and S to find the xN. The vapor composition
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(5.51)
LD ( H D QC / D) H V ,1 R H V ,1
_________
D
H V ,1 H D
H V ,1 H D
________
(5.52)
________
Where R H V ,1 and H V ,1 H D are the lengths of lines between points R and HV,1
and HV,1 and HD. The internal reflux ratio between any two stages in rectifying
section can be expressed as:
_________
( H D QC / D) H V ,n 1 R H V ,n 1
Ln
_________
Vn 1
( H D QC / D) H L ,n
R H L ,n
(5.53)
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Vm
H L ,m1 ( H B QR / B)
(5.54)
FH F QR DH D BH B QC
(5.55)
xF S
D H F ( H B QR / B)
_________
B ( H D QC / D) H F
xF R
(5.56)
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(ii)
(iii)
The heat loads of the condenser and reboiler for the condition of
minimum reflux.
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(iv)
The quantities of the diustillate and bottom streams using the actual
reflux ratio.
(v)
(vi)
The heat load of the condenser for the actual reflux ratio
(vii)
The internal reflux ratio between the first and second stages from the
top of tower.
0
0
0.1
0.36
0.3
0.7
0.5
0.85
0.55
0.9
0.7
0.95
1
1
0.1
0.3
0.5
0.7
0.9
7000
6300
5000
4100
3400
3100
3000
Enthalpy-Concentration Data
Mole fraction,
Hexane
Enthalpy,
Cal/gm-mol
Sat.
Liquid
Sat.
Vapor
Solution 5.3:
(i) The minimum number of stages can be obtained by drawing vertical operating
lines that intersects as R tends to infinity. As shown in Figure E2, three stages
required.
(ii) Using Equation (5.52), the minimum reflux is
_________
LD ( H D QC / D) H V ,1 R H V ,1 19000 11500
_________
0.88
D
H V ,1 H D
11500 3000
H V ,1 H D
(iii) From the Figure E2, H B QR / B =-5000
QR / B = 5000+7000 = 12000
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H D QC / D = 19000
QC / D = 19000-11500 =7500
(iv) The distillate and bottom flowrates are obtained by solving the overall and
component material balances simultaneously
100 = D + B
0.4 (1000 = 0.92 D + 0.04 B
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Figure E2: Minimum reflux and minimum stages for example problem 4.3
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L
L
(v) D 1.5 D 1.5(0.88) 1.32
D act
D min
Using Equation (5.52) gives a new value for R :
1.32
( H D QC / D) 11500
11500 3000
Or, H D QC / D 22750
H D QC / D 22750
So QC / D 22750 11500 = 11250
(vii) Reading enthalpies for the points (a) and (b) and using Equation (5.53) gives
0.563
Vn 1
( H D QC / D) H L,n
22750 3750
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