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Article history:
Available online 17 March 2012
Synthetic ester transformer uid has the ability to substantially reduce the risk associated with operational on/off-shore transformers. In comparison to alternative dielectrics such as cast resin, silicone uid
and natural ester, synthetic ester has proven to be the most suitable transformer dielectric. This paper
presents evidence to support these claims.
2012 Published by Elsevier Ltd.
Keywords:
Ester
Transformer
Alternative uids
Synthetic ester
MIDEL 7131
Natural ester
1. Introduction
q World Renewable Energy Congress XI and Exhibition 2010, Abu Dhabi, 25e30
Sep10.
* Corresponding author.
E-mail address: HussamAl-Amin@mimaterials.com (H. Al-Amin).
0960-1481/$ e see front matter 2012 Published by Elsevier Ltd.
doi:10.1016/j.renene.2012.01.071
34
Cast resin
Fluid lled
Turbine
transformer
Fire point
Classication
Mineral oil
Synthetic ester (MIDEL)
Natural ester
Silicone uid
w170 C
>300 C
>300 C
>300 C
O
K
K
K
35
Table 3
OECD 301 biodegradation classications.
Type of uid
Mineral oil
Synthetic ester (MIDEL)
Natural ester
Silicone uid
Not biodegradable
Readily biodegradable
Readily biodegradable
Not biodegradable
Table 4
IEC 61039 biodegradation classications.
Type of uid
Mineral oil
Synthetic ester (MIDEL)
Natural ester
Silicone uid
Not biodegradable
Fully biodegradable
Fully biodegradable
Not biodegradable
Picture 1. Faults within a cast resin transformer taken from an offshore wind turbine [7].
As the wind load hits the offshore turbine it can cause dramatic
vibrations in the transformer especially when situated in, or under
the nacelle. To reduce the vibrations and resonance a liquid lled
transformer can incorporate a corrugated tank with vertical and
horizontal reinforcements. The active part of the transformer is also
highly clamped to the tank restricting movement in any of the
dimensions. The uid lled transformer has a much greater withstand to any generated movement than a cast resin transformer,
which is much more vulnerable at these low frequency stresses.
8. Risk assessment of transformer uid stability
8.1. High temperature operation
As space within a nacelle or tower is at a premium it is desirable
to have the turbine transformer build as small as possible. In this
instance the transformer will run hotter than a conventional
transformer. To allow for high temperature operations designers
opt for uid/aramid paper insulation. Top oil temperatures can
regularly reach 135 C and hot spot winding temperatures 180 C.
At these temperatures mineral oil would be very close to its ash
point and would be expected to experience uid degradation in the
form of sludging.
Silicone, natural and synthetic esters have the ability to operate
at these elevated temperatures and remain stable providing that
the transformer remains in a sealed form. However, as these
transformers are in an offshore location and with large mechanical
force exerted on them there is a small possibility that the seals of
the transformers could be compromised. Therefore, it is prudent to
consider the risk to each of these uids should air or moisture
ingress into the operating transformer.
8.2. Oxygen stability of each of the transformer uids
The rotating bomb test, according to ASTM D2112, subjects the
test uid to pressurised oxygen at elevated temperature in the
presence of common catalysts. Measuring the time for the oxygen
pressure to drop, to a predetermined level, gives understanding of
how oxygen stable the uids are.
The results presented in Graph 1 clearly show that synthetic ester
is a far more oxygen stable dielectric than mineral oil or natural ester.
As natural ester performed very poorly in this test further studies
36
where made with the uid to understand the chemical reactions that
occur during the oxidation process. Research performed at M&I
Materials internal laboratory shows that excessive oxidation of
a natural ester can result in gels forming as shown in Picture 2.
Natural ester represents a high risk should any of the seals
around the transformer be compromised. In contrast the risk of
oxidation when using a synthetic ester is low.
8.3. Moisture tolerance of each of the dielectric uids
Should a transformer seal be compromised as explained above it
is important to consider the effect of moisture on each of the
dielectrics.
Below are the moisture saturation curves for each of the uids.
Synthetic ester has the highest saturation limit of all the
transformer uids. As the uid is used primarily as a dielectric it is
important to understand how moisture affects the dielectric
rigidity. Results are shown in Graph 3.
When considering Graphs 2 and 3 it can be concluded that
synthetic ester is the most moisture tolerant of all the uids and
still remains dielectrically strong even in the presence of high
absolute values of moisture.
9. Offshore transformer substations
For offshore substation transformers, at voltages of greater than
100 kV and with ratings in excess of 100 MVA, the only commercially available option is a uid lled transformer. Cast resin
transformers are limited in rating to around 40 MVA at the time of
writing and this is unlikely to increase signicantly in the foreseeable future. Silicone liquid is not suitable for these high voltage
transformers as it more prone to electrical instability at voltages
above 36 kV [6].
Natural and synthetic esters offer a viable alternative to mineral
oil in this power range. Indeed synthetic ester has been used as the
dielectric medium inside a 238 kV power transformer since 2004
with exemplarily performance. However, as discussed earlier in the
paper natural ester will have to operate in a sealed transformer and
with the possibility of the seal being compromised and maintenance very difcult it would be advisable to insure against this with
the use of a synthetic ester.
10. Conclusion
With the evidence presented it is possible to use the following
scoring system to assess which dielectric uid will present the least
risk to the offshore windpark
37
It can be seen that cast resin dielectrics offer a greater operational risk in comparison to uid dielectrics. As such the following
graphs make risk comparisons of the uid only.
38
References
[1] www.wind-energy-the-facts.org.
[2] IEC 61039. Classication of insulating liquids.
[3] Ready biodegradation of MIDEL transformer uids. Cantest 2007 M&I archive
document.
[4] IEC 61039. Classication of insulating liquids; 2008.
[5] Transformers for offshore multi-megawatt turbines: discussions on specications, safety and environment e European Offshore Wind 2007.
[6] Volker Wasserberg. Step-up transformers for wind energy plants.
[7] Cracks in Siemens Geafol transformers used in Middelgrunden Windturbine
Park e Karsten Borch Gylding.
[8] M&I materials internal technical report TD3203.
[9] M&I materials internal technical report TD3255.
[10] Dumke et al. Fundamental investigations on the inuence of temperature and
water content on the electrical behavior of uid impregnated insulating
paper.
[11] Russell Martin. Ester transformer uids for environmental protection,
improved re safety, and operational reliability.