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Heat Reservoir: It is a body of very high mass, so high that its temperature is not
affected by any heat Transfer. It can also be defined as a body of mass, which
can absorb or supply heat without any change in its temperature.
Heat Source : It is a heat reservoir of very high mass which can supply heat
without any change in its temperature.
Heat Sink : It is a heat reservoir of very high mass which absorbs heat without
any change in temperature.
4.
Heat Engine : A heat engine is defined as a device that produces net positive
work while absorbing heat from a source and dissipating heat to a sink.
5.
Heat Pump :
A heat pump is a device that operates in a cycle and transfers heat from a low
Temperature body (sink) to a high Temperature body (source) with the aid of external
work.
Difference between a Heater and a Refrigerator:
Essentially, both the , heater and the refrigerator are heat pumps. In case of heater ,
the purpose is to heat while in the case of the refrigerator, the purpose is to cool.
Performance parameters:
1. Efficiency: It is a term used to measure the performance of a heat engine. It is
defined as the ratio of the net +ve work output to the energy supplied. We may write.
= (W/Q1) = (Q1Q2/Q1)
2. Coefficient of performance: It is a term used to measure the performance of a heat
pump. COP of a heater is the ratio of heat supplied to the work input.
i.e. COPh = Q1/W = (Q1/Q1-Q2)
Q1/(Q1- Q2)
= W/Q3 = 0.3
COPr = Q2/W =5
Q1/Q3 = 1.5
Ans)
i)
= (Q1- Q2)/ Q1
= W/Q1
0.33 = (0.5/ Q1)6480 KJ
ii)
iii)
Q1 = 19440 KJ
1/3 = 1- 1/R
1/R = 2/3
R = 1.5 = Heat Supply/Heat rejected
Q2/W = 2/3
Therefore
(W/Q2) = 1.5
Proof:
Consider Heat Engine that violates Kelvin-Planck statement of 2nd law. Let it absorb
Q1 amount of heat from a source and perform an equivalent amount of work = Q1.
Consider a Heat Pump which would make use of the work delivered by this Heat
Engine .Let the Heat Pump extract Q2 amt of heat from the sink we realize that it
would deliver Q1 + Q2 amt of heat to the source. If we consider the HE and the HP
together as a single device, as shown, we notice that this combined device extracts a
net amt of heat = Q2 from the sink and delivers a net amt of heat = Q 2 to the source.
Such a device would obviously violate the Clausius, statement are equivalent.
ii)
Consider a block provided with a rope drawn over a pulley and provided with
weights at, the other end as shown. The block rests on a sliding surface. On increasing
the weights at one of the ends, the block may be moved up the sliding surface .As it
moves up, the sliding surface gets heated due to friction. If this process were to be
reversed, and the block brought, back to its original position. This would again heat
up the sliding surface . If the block and the sliding surface together are considered as
part of a system, then, in order to restore the system to its original state, same amount
of heat, say Q needs to be removed as indicated, on doing so, the system is restored to
its original state but the surroundings are not. Hence the process is irreversible. The
irreversibility is on account of friction.
2.Unrestrained expansions:
Consider a source at temp T1 and sink at, temp T2 (T 1>T2). Let Q1, amount of
heat be transferred from the source to the sink. If this process has to be reversed
we need to make use of a heat pump which would deliver Q 1 amount. of heat back
to the source with the aid of external work W=Q 1-Q2. Considering the source, sink
and heat pump together as part of a system, we notice that it is possible. To restore
the system to its original state but not be the state of the surrounding.
4.Mixing of substances:
Consider any two gases say N2 and O2, taken in a chamber, and separated by a thin
membrane as shown. If it ruptures, the 2 gases would expand and fill up the entire
volume. It is a case of unrestrained expansion for each of the gases considering
the gases to be a part of a system, we realize that if the system has to be restored
to its original states, some amount of work needs to be done as well as heat to be
transferred. In doing so, even though the system may be restored to its original
state, the surrounding is not.
5.Other factors:
a). Hysterisis and I2R losses in electrical circuits.
b) Combustion
c) Flow of water from a higher to a lower level, etc.,
Identify the factors in the following statements, which render process irreversible.
1. Automobile on road friction, combustion.
2. Man walking on road- friction.
3. Germination Heat transfer thru a finite temperature difference
4. Curing of cement Heat transfer thru a finite temperature difference
5. Throttling unrestrained expansion.
6. Sugar solution. Mixing of substances.
Internally and externally reversible processes:
Consider 2 cases of heat transfer:
i)
Involving heat transfer thru an infinitesimally temperature difference.
ii)
Thru a finite temperature difference T as shown is sketch.
R2
R1
R2
From this he arrived at the Thermodynamics temperature scale It is clear from the
form of F chosen by Lord Kelvin that Q1/Q2 = T1/T2
Hence, efficiency of a reversible engine operating between temp limits T1, T2 would
be given by the expression
R = 1 T2/T1
If we consider a reversible engine operating between the steam point and ice point we
would find that would be 0.268.
i.e. 1- Tice/Tsteam = 0.268
Or Tice /Tsteam = 0.732.
From the Celsius scale, we leave
Tsteam Tice = 100
i.e. Tsteam 0.732 Tsteam = 100.
Tsteam = 100/0.268 = 373. 13 K
Tice = 273.13 K
.
These values are assigned to the steam and ice- pts on the absolute Thermodynamic
scale with Celsius scale as reference. The units are named Kelvin after Lord Kelvin
i.e. Tice = 273.13 K
Tsteam = 373.13K
With F scale as reference, absolute Thermodynamic temperature scale takes the
form:
Tsteam Tice = 180
Tice = 0.732 Tsteam
Solving the above we get
Tice = 32F
Tsteam = 212F
The units for this scale are Rankines
Tice =491.64 R
Tsteam = 671.64 R
Corollary 3a:
It is impossible to reduce a system absolute zero, in a finite number, of operations.
Consider a no of reversible, engines:
R1, R2 , R3..,RN connected in series with the heat rejected by 1 becoming the
source for the next as indicated. Let the last reversible engine reject heat to a sink
which is at absolute zero by absolute Thermodynamics temperature scale, we
recognize that
TN/ T sink=QN/ QN+1
But T sink =0(absolute)
Therefore QN+1 = 0
But this would result in the last engine violating the Kelvin -Planck statement of 2 nd
law of Thermodynamics.
Hence, we conclude that absolute zero cannot be attained in actual practice, we may
say, if there are infinite engines connected in series, the last engine may reject heat to
a sink whose temperature tends to absolute zero. But, this is not possible in finite
number of operations.
Corollary 3b:
It is not possible to have negative values on the absolute. Thermodynamics
temperature scale:
A Carnot engine consists of an insulated cylinder provided with frictionless piston and
a perfectly conducting member at one end. Provision is made for an insulated cap,
which can for fitted at one end when required .The engine is provided with a source at
T1 and sink at T2.
Processes involved:
i) 41 Reversible Isothermal heat addition: The insulated cap removed. The source is
brought in contact with the membrane. Heat is conducted in the cylinder. In a
reversible Isothermal process.
ii)23 Reversible adiabatic expansion:
The source is removed, the insulated cap is inserted, and the piston is allowed to
expand in a reversible adiabatic process.
iii) 34 Reversible Isothermal heat rejection: The cap is removed and the sink is
brought in contact with the membrane. Heat is rejected from the cylinder in a
reversible Isothermal process.
iv) 41Reversible adiabatic compression: The sink is removed and the cap is inserted.
The piston compresses the working medium in a reverse adiabatic process.
Expression for :
QS = p1v1* ln (V2/V4)
QR = p2v2* ln (V3/V2)
It can be shown that
V1/V4 = V3/V2 for a Carnot cycle
P1V1 = RT1
P2V2 = RT2
Substituting the above
carnot engine = (Qs QR)/ Qs = RT1* ln (V1/V4) RT2* ln (V3/V2) = (T1T2)/T1
RT1* ln (V1/V4)
carnot =1T2/T1
Therefore efficiency of the Carnot cycle depends only on temperature involved and
not on the working medium.
Reasons for impracticality:
1.All processes are reversible and hence impractical.
2. Frictionless piston is impractical.
3.During 1 half stroke of the piston there is a reversible isothermal process while
during the other half stroke, there is a reversible adiabatic process. The reversible
isothermal process needs to be very slow while a reversible and adiabatic process
needs to be very fast. This means that the piston should move very slowly for half a
stroke and very rapidly for the other half stroke, this is highly impractical.
Reversed Carnot engine:
A Carnot engine works on the Carnot cycle, which is a reversible, cycle Hence it is
possible to reverse the direction of all the processes and run the engine as a Heat
pump.
PROBLEMS
1. A Heat engine works on the Carnot cycle between 900C & 200C. If the heat
received by the engine is 50 KW calculate the power developed.
Ans)
Q1/T1=Q2/T2
Therefore 50/(900+273) = Q2/(200+273)
Hence Q2=20.16KN
Power developed = W = Q1 Q2 = 5020.16 = 29.84KN
2. A Heat engine operates between a source at 300C and a sink at 30C. What is
the least possible heat that can be rejected when delivering 100 KW?
Ans) W = Q1Q2 (Engine rejecting least heat would have the maximum efficiency.
And maximum efficiency is for a reversible cycle)
W = 100KW
Q1/T1 = Q2/T2
Therefore W = Q2 *( T1/T21)
100 = Q2 *( 573/2431)
Q2=73.64KW
3. An engineer claims to have developed and engine producing power of 4.5 KW,
working between temperature limits of 1400C & 350C consuming 0.5kg. Of fuel /hr
with calorific value = 42000 kJ /kg. Comment on the claim.
Ans)W = 4.5KW
Q1=Mass flow rate Calorific value=0.5*(42000/3600)=5.833KW
= W/Q1 = 0.77
max = (1T1/T2) = (1623/1673) =0.628
Since is greater than max
The above claim is not valid.
4. A Heat engine works on Carnot cycle between temperature limits 800 K, 300K the
engine develops a power of 5KW .If the fuel used has a calorific value 4200 KJ/kg .
Determine the fuel consumption in kg/hr. Relative = 0.5
Relative efficiency = (Actual /Ideal )
Ans) Since
Q1 = (R*42000/3600)
R = 1.371 kg/hr
5. A Carnot engine works between 2 reservoirs at T1 and T2 Kelvin. The work output
the engine is 0.6 times heat rejected If the difference in temperature between the
source and the sink is 200C, Determine
a. Source temperature.
b. Sink temperature.
c.
Ans) W = 0.6*Q2
W = Q1Q2
Therefore Q1=1.6Q2
= W/Q1 = (0.6Q2/1.6Q2) = 0.375
T1 T2 = 200
= (1T1/T2) = 0.375
Therefore T1=0.625 T2
Hence T1 = 533.33 K
T2 = 333.33 K
6. A domestic food freezer maintains a temperature of 15C .The ambient air
temperature is 30C. If heat leakage into the freezer is 1.75 KW, What is the least
power necessary to pump out the heat continuously?
Ans)
Q2 = 1.75 KW
Q1/T1=Q2/T2
W = Q1Q2 = Q2 *(T1/T2 1)
= 1.75 *(303/258 1)
Therefore,
W = 0.305 KW
Q2 = 420*20 = 8400kJ/day
COPR = T2/(T1T2) = 275/(303 275) = 9.82
Actual COP = 0.15*9.82 = 1.47
Therefore Actual COP = Q2/W
1.47 = (8400/W)
Therefore W = 5714.28 KW/day
Net bill = 5714.28*0.32*30/3600 = Rs 15.24
8. A heat pump is used to heat a house in winter to cool and reversed in summer .The
interior temperature is to be maintained at 20C. Heat leakage through, the walls and
the roof is estimated to be 0.525 KJ/s perC difference in temperature between the
inside and outside.
A) If the outside temperature is 5C. What is the min power required to drive the
pump.
B) For the same power input in summer what is the maximum outside temperature
for which the inside temperature can be maintained at 20C .
Ans)
Case A) (Winter) Room = Source.
T2=5C=278K
T1=20C=293K
293/(T20) = 0.523(T20)/0.403
(T 20)*(T20) = (293*0.403)/(0.525)
By solving the above quadratic equation
we get T = 35 C and 5C
5C is not possible
Therefore we get T=35C
9. Three Carnot engines A, B and C work in series between temperature limits 1000K
& 300 K. Work output is in the proportion.
WA : WB: WC:: 3:2:1
i)
ii)
Ans)
Let Wc = k
Therefore Wb=2k and Wa=3k
a = Wa/Qa
Therefore (1T2/1000) = 3k/1000
Q1/T1 = Q2/T2 = Q3/T3 = Q4/T4
Therefore1000/1000 = Q4/300
Hence Q4=300KW
(1T3/ T2) = 2k/ T2
(1T4/ T3) = k / T3
(1 300/ T 3) = (k / T 3)
T 3 = 300+k
T 2 = T 3+2k = 300+3k
1000 = T 2+3k
Therefore 1000 = 300 + 3k
k= 700/6 =116.67 KW
T 2 = 650K
T 3 = 416.67 K
Therefore
Wc=116.67KW
Wb=233.3KW
Wa=350KW
10. Two reversible engines R1 & R2 operate in series between a high temperature
reservoir at 800K and a low temperature reservoir at 300K. Determine the
intermediate temperature if both the engine have same efficiency
Ans)
W1/Q1 = W2/Q2
(1T2/T1) = (1T3/T2)
Therefore T2=(T1.T3) = 489.9 K
11. A refrigerator produces 2 tones of ice / day at 0C from water maintained at 0C.
It rejects heat to the atmosphere at 27C. The power to rum the refrigerator is supplied
by an engine, which is, supplied heat from a source maintained at 227C by burning a
fuel of calorific. Value. = 20,000 kJ/kg . Find the consumption per hour and power
developed by the engine assuming both the devices to be rum on Carnot cycle take L
fusion = 333.3 KJ/kg.
Ans)
Q3 = 333.3*(2000/24) = 27775kJ/hr
COPR = Q3/W = (27775/W) = 273/(300 273)
Therefore W = 2746.9 KJ/hr = 0.763 KW
Q1= m* CV = m*20000
(W/Q1) = (1300/500)
m = 0.3434 kg/hr
12. A Heat engine operates between two reservoirs at 1000K & 300K is used for
running a Heat pump, which extracts heat from reservoir at 300K at a rate twice that
at which the engine reject heat to it. If engine = 40% of maximum possible & COP
of Heat pump is 50% of maximum possible COP. What is temperature of reservoir to
which the HP rejects heat? What is the rate of heat rejection from the heat pump if
heat supplied to engine is 50 KW.
Ans)