Beruflich Dokumente
Kultur Dokumente
2,094,711
COMPOSITION or MATTER
William Hale Charch', Buffalo, and Albert Hersh
berger, Kenmore, N. Y., assignors, by mesne as
'
(Cl. 134-79)
(4) Wax, cellulose derivativaresin or blend
This invention relates to moistureproof ma
terials and more particularly to a. composition ing agent, andsolvent.
As the- wax, a para?in wax having a melting
which will deposit a glass-clear, ?exible and
point between 50 C. and 60 C., and preferably
1 Claim.
moistureproof coating.
'
20 .
excess of the cellulose nitrate and/or 50% or ' thousand seconds or more, may be used. It is ad
more of wax.
, .
55
2,094,771
'
10.
of the wax. This solution is then allowed to cool ' range from approximately 0.00001 to 0.00010 of
gradually and the temperature at which the wax an inch, although, in certain special instances,
begins to crystallize is noted. If the tempera -it may be possible to use coatings of somewhat
20 ture at which the wax begins to crystallize lies greater thickness. When the solids oi the com
above 50 C. and solvent, in general will not be _ position consist of a mixture of wax and nitro 20
suitable for the herein described purpose. 0n cellulose, the coating thickness should generally
the other hand, if the temperature of crystalliza
be less than the coating thickness used when the
tion lies under 50 C. the solvent in general will composition also contains a blending agent and
be found to be suitable. By the same test it should generally approach the lower limits of
25
has also been found that the lower the tempera
the thickness range above set forth.
ture of crystallization of the wax from such a
The compositions herein described are particu
solution, the more e?ective will be the solvent for larly suitable for application to a transparent
the herein described purpose. For instance, cer
sheeting base, such'as regenerated cellulose,-gly
30 tain very effective solvents when submitted to the
col cellulose, casein, gelatin, cellulose acetate, etc. 30
above test retain the wax in solution at tempera
They may also be used onpapers, such as glass
tures as low as 40C. or even lower.
ine or other smooth, semi-transparent papers.
Several illustrative solvents which have given It is to be understood that the solvents of the
40
For the purposes of this speci?cation and '
However, they may be used with other suitable .claim, we de?ne moistureproof materials as those
solvents 'of similar nature or they may be used which, in the form of continuous, unbroken
with hydrocarbon diluents, such as toluol, benzol,
45 etc., provided such diluents are not present in ' sheets or ?lms, permit the passage of not more
than 690 grams of water vapor per 100 square 45
such large quantities as would cause the precipi
meters per hour, over a period of 24 hours, at
tation of thenitrocellulose during the'evapora
approximately 39.5" C.i0.5 C., the relative hu
tion of the solvent. In general, the use in any midity of the atmosphere at one side of the ?lm
solvent mixture of appreciable quantities of sol
being maintained at least at 98% and the rela
vents which are not active para?in solvents. such tive humidity of the atmosphere at the other side
as alcohol, acetone, etc., is to be avoided. Small being maintained at such a value as to give a
quantities of these materials, however, may be humidity differential of at least 95%.
> .
present without deleterious e?ect. For example,
Moistureproo?ng-coating compositions are de
alcohol should not'bepr'esent in an amount of
55 more than 15%. Generally, if alcohol is used, it ?ned as those which, when laid down in the form
a thin, continuous? unbroken ?lm applied uni
should be present in an amount less than 10%, of
formly as a coating with a total coating thick
and preferably 1% or less. A preferred solvent ness not exceeding 0.0005" to both sides of a
-mixture consists of pyroxylin solvent of the type sheet of regenerated cellulose of thickness ap
described, with or without small quantities of
60 alcohol, and a hydrocarbon diluent, preferably an proximately 0'.0009", will produce a coated prod
uct which is moistureproof.
aromatic hydrocarbon diluent or chlorinated ali
For the purposes of experimental tests, espe
phatic hydrocarbon solvent, and the said diluent cially
for those materials adaptable as coating
being present in quantities insu?lcient to cause compositions,
moistureproof materials include
the precipitation of the nitrocellulose during those substances,
compounds or compositions
evaporation of the solvent.
In- all cases the ingredients of the solvent are
of such a nature as to. maintain all the solid
. ingredients in solution until substantially all the
70
"
2,094,771
tial of 50455 mm. (preferably 534:0.7 mm.) of
mercury. For convenience, the number of grams
of water vapor passed under these conditions may
be referred to as the permeability value." An
uncoated sheet of regenerated cellulose having a
thickness of approximately 0.0009" will show a
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Parts by weight
8.0
2.0
123.5
20.0
4775
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15
Parts by weight
(a) Paramn wax (M. P. so" C.-62 c.)__-___ 7.5
Pyroxylin (283 seconds) .. ___________ __
2.5
Ethyl
1.11
alcohol....___\________________ __
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2,0.
25
Example II-Wax-pyro:cylin-resin
. Parts by weight 40
(a) Paramn; wax (M. P. 60 C.-62 C.)_...._ . 7.5
Pyroxylin
' 2.5.
1.0
20.0
123.5
19.0
0.00005-000006 of an inch.
'
non-tacky.-
Parts by weight
Spermaceti wax ______ -1 ___________ __
2.0
2.5 I
Alcnh'nl
9.0
1.0
1,7
3.0
'
Parts byweight
6.0
4.0 60
W Rosin
20.0
Parts by weight
Parts by weight
'
5.0
20.0
47.5
70
5.0
Alcohol-
as
55
'
45
Parts by weight
____
rosin _______________ __
m1 acetate
_____
Hydrogenated
2.0
' "
78.0
Alcohol ____________________________ __
2.0 30
4.0
Almmhnl
201)
Toluol
47.5 75
v4.
2,094,771
Example IV-Waz-mroxylimresin-plasticizer
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'
Parts by weight
2.5
A W
1,0.
L0
123.5
main
'
Alpnhn]
2'0
20-0
47.5
*\
to abrasion.
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'
7.5
Parts by weight
Example IIIWa:c-py'ro:cylin-plasticizer
2.5
2.0
Toluol ____________________________ __
78.0
2.0
30
Parts by weight
(b) Paramn wax (M. P. 60 C.-62 C.) ___
7.5
2.5
'
2.0
20.0
47.5
We
claim:
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'
"
4.0
3-8
7.5
Amyl acetate
25
6.0
20
Parts by weight
>
'
Parts by weight
- 7.5
Hydrogenated
Amyl
_/ 1.0
123.5
Alcohol _______ __
Tolunl
2.5
20.0
__'I._-..
V 47.5
tion.
WILLIAM HALE CHARCH.
ALBERT HERSHBERGER.