Pratita Triasalin (21030113130108)

13.11 A mixt of LiCl and BaI2 weighing 0.600 gr is treated with 45.15 ml of
0.2000 N AgNO3 soln., and the excess Ag+ is then titrated with 0.100 N KCNS
soln. (ferric alum indicator). If 25.00 ml is required, what is the percentage of I in
the sample?
Diketahui :

Campuran LiCl dan BaI2 = 0,6 gram

Misal BaI2 = x gram, maka LiCl = (0,6-x) gram
AgNO3 (excess) = 0,2 N ; 45,15 ml
KCNS (titrasi balik) =0,1 N ; 25 ml

Ditanya : % I dalam sample = ................?

Jawab :

AgNO3 (excess) = 0,2 N ; 45,15 ml

0,2 N 45,15 ml=9,03 mmol

Mol AgNO3 =

Sisa Ag+ dititrasi balik dengan KCNS = 0,1 N ; 25 ml

Mol KCNS =

0,1 N 25 ml=2,5mmol

Ag yang dibutuhkan untuk mengendapkan Cl dan I 2

9,032,5=6,53 mmol

( 0,6x )
x
+
=6,53
LiCl/1000 Ba I 2 /2000
(0,6x)
x
+
=6,53
(6,93+35,5)/ 1000 (137,3+(2 127))/2000
(0,6x)
x
+
=6,53
0,042 0,195
0,1170,195 x +0,042 x
=6,53
8,2173. 103
x=0,412 gram
I
Ba I 2
2
100 =44,6
0,6 gram

0,412 gram

Maka,

I=

13.13 A sample of feldspar weighing 2.000 gr yields a mixt. of NaCl and KCl
weighing 0.2558 gr. If 35.00 ml of 0.1000 N AgNO 3 is added to the dissolved
chlorides and the excess Ag+ requires 0.92 ml of 0.0200 N KCNS soln. for
titration, what is the percentage of K in the feldspar?
Diketahui :

Sample Feldspar = 2 gram

Terdiri dari NaCl dan KCl = 0,2558 gram
Misal NaCl = x gram, maka KCl = (0,2558-x) gram
AgNO3 (excess) = 0,1 N ; 35 ml
KCNS (titrasi balik) =0,02 N ; 0,92 ml

Ditanya : % K dalam feldspar = ................?

Jawab :

AgNO3 (excess) = 0,1 N ; 35 ml

Mol AgNO3 =

0,1 N 35 ml=3 ,5 mmol

Sisa Ag+ dititrasi balik dengan KCNS = 0,02 N ; 0,92 ml

Mol KCNS =

Ag yang dibutuhkan untuk mengendapkan Cl

0,02 N 0,92ml=0,0184 mmol

(0,2558x)
x
+
=3,4816
Na Cl /1000 KCl /1 000
(0,2558x)
x
+
=3 , 4816
(23+35,5)/1000 (39+ 35,5)/1 000
(0,2558x)
x
+
=3,4816
0,0585
0,0745
0,0745 x +0,01490,0585 x
=3,4816
4,36 .103
x=0,01875 gram

3,50,0184=3,4816 mmol

( 0,2558x ) =0,23705 gram

0,23705 gram
Maka,

K=

2 gram

K
KCl

100 =6,3