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LABORATORY REPORT
Name
Matrices No.
: SEW150091
: Heat of Neutralisation
Objective
Heat of neutralization
: Heat evolved during neutralization
: Heat of dilution of sodium hydroxide
Molar Heat of neutralization =
In this experiment, several acids would be neutralizing by small volume of concentrated of
sodium hydroxide, NaOH. Hydrochloric acid, nitric acid, acetic acid and monochloroacetic acid
are acid that been selected in this experiment to undergo neutralization process. Different
strength of acid would give different value of molar heat of neutralization.
Since no adiabatic calorimeter can be insulated perfectly from its surroundings, there will always
be some heat lost from the calorimeter. This loss of heat can be compensated for.
Procedure:
Calibration of the calorimeter
1.
2.
3.
4.
5.
Measured 120 cm3 of distilled water with graduated cylinder and poured in calorimeter.
Supplied 0.5 A to the calorimeter by power supply
Recorded time for each intervals until temperature rises 1oC
Plotted graph for Temperature vs. Time
Calculated heat capacity of calorimeter.
Neutralization of an acid
1. Measured and placed 120 cm3 of 0.5 mol dm-3 HCl solution into calorimeter.
2. Recorded the temperature at certain time interval until rate changes constant or
temperature become constant.
3. Added 3cm3 of the concentrated sodium hydroxide,NaOH solution.
4. Recorded the temperature changed with regular time interval until become constant or
rate change constant.
5. Plotted graph Temperature vs. Time.
6. Repeated step (1) by replacing position of HCL with the following acids:
Nitric acid, acetic acid and monochloroacetic acid.
7. Calculated heat of neutralization and molar heat of neutralization for each acid .
Heat of Dilution of Sodium Hydroxide
1. Repeated above procedure by replacing acid with 120 cm3 of distilled water.
Results:
iTime,t (s)
0
15
30
45
60
75
90
105
120
135
150
165
180
195
210
225
240
255
270
285
300
315
330
345
360
375
390
405
420
435
450
Time,t (s)
465
480
495
510
525
540
555
570
Cooling Process
Temperature,T
(oC)
27.96
27.96
27.97
27.98
27.98
28.00
28.00
28.00
Temperature, oC
27.6
27.4
27.2
27
26.8
26.6
26.4
0
50
100
150
200
250
300
350
400
450
Time, s
Calculations:
Uncertainty:
I = 0.50 A
Vp = 4.35
Range
t = 525 0
= 525 s
T = (27.98 + 273)
= 1.34 K
Cp =
=
= (852.146
= 1.36
0.1) JK-1
+ 273)
0.68
0.1
Coefficient
s
26.637820
51
0.0029406
21
Intercept
X Variable 1
ii-
Standard
Error
0.06277775
2
0.00018951
9
t Stat
P-value
424.3194
401
15.51622
462
7.95042E70
8.87751E18
Lower
95%
26.510620
71
0.0025566
19
Upper 95%
26.765020
32
0.0033246
23
Lower
95.0%
26.5106207
1
0.00255661
9
Temperature, oC
32.00
31.00
30.00
29.00
28.00
27.00
0
50
100
150
Time, s
200
250
Upper
95.0%
26.7650203
2
0.00332462
3
Calculations:
HCl + NaOH NaCl + H2O
q
=
Uncertainty:
Cp
(852.146 JK )
(4.5 K)
Range
= 5.06
3834.657 J or 3.834657 kJ
=
3.834657 kJ 1.840635 kJ
2.53
0.5
1.99402 kJ
Molar heat of neutralization =
= 33.23 kJmol-1
Thus,
Heat of neutralization of hydrochloric acid,HCl is 1.99 kJ
Molar heat of neutralization of hydrochloric acid,HCl is (33.23
Intercept
X
Variable
1
0.5) kJmol-1
Coefficient Standar
t Stat
P-value Lower
Upper
Lower
Upper
s
d Error
95%
95%
95.0%
95.0%
26.45152 0.54585 48.4589
4.87E- 25.3163 27.5866 25.3163 27.5866
5
23
6
9
6
9
0.023067 0.00317 7.26277
3.74E- 0.01646 0.02967 0.01646 0.02967
6
8
07
2
3
2
3
iii-
Temperature, 0C
32
31
30
29
28
27
26
0
50
100
150
200
250
Time, s
Calculations:
HNO3 + NaOH NaNO3 + H2O
q
Cp
(852.146 JK-1)
(4.58 K)
3902.828 J or 3.902828 kJ
Uncertainty:
Average Temperature = 30.81 oC
Range
= 4.8
3.902828 1.840635
2.062194 kJ
= 34.36 kJmol-1
Thus,
Heat of Neutralization of nitric acid,HNO3 is 2.06 kJ
Molar heat of neutralization of nitric acid,HNO3 is (34.36
kJmol-1
2.4
0.4
Intercept
X
Variable
1
iv-
Coefficient
s
26.68199
0.027955
Standar
d Error
0.43800
8
0.00277
6
t Stat
60.9166
7
10.071
P-value
5.29E33
3.88E11
Lower
95%
25.7874
6
0.02228
6
Upper
95%
27.5765
2
0.03362
4
Lower
95.0%
25.7874
6
0.02228
6
Upper
95.0%
27.5765
2
0.03362
4
Temperature, oC
31.5
31
30.5
30
29.5
29
28.5
28
27.5
0
50
100
150
200
250
Time, s
Calculations:
CH3COOH + NaOH NaCH2COOH + H2O
q
Cp
(852.146 JK-1)
(4.07 K)
3468.234 J or 3.468234 kJ
Uncertainty:
Average Temperature = 30.98 oC
Range
= 4.3
3.468234 1.840635
1.627599 kJ
= 45.21 kJmol-1
Thus,
Heat of neutralization of acetic acid,CH3COOH is 1.62 kJ
Molar heat of neutralization of acetic acid,CH3COOH is (45.21
kJmol-1
2.15
0.4
Intercept
X
Variable
1
v-
Coefficient
s
27.04552
0.027608
Standar
d Error
0.46145
1
0.00301
7
t Stat
P-value
58.6097
9.15049
1
7.65E31
6.58E10
Lower
95%
26.1002
8
0.02142
8
Upper
95%
27.9907
6
0.03378
9
Lower
95.0%
26.1002
8
0.02142
8
Upper
95.0%
27.9907
6
0.03378
9
31.5
31
30.5
30
29.5
29
28.5
28
27.5
0
50
100
150
200
250
Time, s
Calculations:
q
Cp
(852.146 JK-1)
(3.58K)
3050.682 J or 3.050682 kJ
Uncertainty:
Average Temperature = 31.22 oC
Range
3.050682 1.840635
= 3.98
=
1.99
1.210047 kJ
=
= 20.91 kJmol-1
Thus,
Heat of Neutralization of monochloroacetic acid,ClCH2COOH is 1.21 kJ
Molar heat of neutralization of monochloroacetic acid,ClCH2COOH is (20.91
) kJmol-1
0.4
Intercept
X
Variable
1
vi-
Coefficient
s
27.72488
0.024487
Standar
d Error
0.40608
6
0.00265
5
t Stat
P-value
68.2734
3
9.22255
1
1.1E-32
5.57E10
Lower
95%
26.8930
6
0.01904
8
Upper
95%
28.5567
1
0.02992
6
Lower
95.0%
26.8930
6
0.01904
8
Upper
95.0%
28.5567
1
0.02992
6
Temperature, oC
27.5
27
26.5
26
25.5
25
0
50
100
150
200
250
Time, s
Calculations:
Uncertainty:
Range
-1
(852.146 JK )
= 2.17
(2.16 K)
=
1.08
1840.635 J or 1.840635 kJ
= (1.84
Intercept
X
Variable
1
0.2 ) kJ
Coefficient
s
25.00175
0.014285
Standar
d Error
0.19266
1
0.00126
t Stat
P-value
129.770
8
11.3401
5
0.2
1.8E-40
Lower
95%
24.6071
Upper
95%
25.3964
Lower
95.0%
24.6071
Upper
95.0%
25.3964
5.59E12
0.01170
5
0.01686
5
0.01170
5
0.01686
5
Discussion:
According to the theory, the order or an arrangement for the molar heat of neutralization for the
selected acids is:
HCl > HNO3 > ClCH2COOH > CH3COOH
Unfortunately, based on the result that is totally different from the theory where is;
CH3COOH > HNO3 > HCl > ClCH2COOH
Due to the result, acetic acid, CH3COOH has highest molar heat of neutralization followed by
nitric acid, HNO3, hydrochloric acid, HCl and monochloroacetic acid, ClCH2COOH. Acetic acid
is the weakest acid among others and the molar heat of neutralization should be the lowest due to
the partially dissociation. Hydrochloric acid is the strongest acid followed by nitric acid. The
molar heat of neutralization arrangement begins with hydrochloric acid followed by nitric acid.
Strong acid will dissociated completely when been neutralized and increase the heat of evolved,
HCl + NaOH NaCl + H2O
HNO3 + NaOH NaNO3 + H2O
Monochloroacetic acid is should slightly higher acidic than acetic acid due to the present of
chlorine atom in the structure. Chlorine atom has high electronegativity which tends to pull
electron density or electron cloud from CH3COO- ions. Based on Bronsted and Lowry theory
about an acid, acid is substance than easy to donate proton or H+ ions. In monochloroacetic acid,
chlorine atom with higher electronegativity pulls the electron cloud or density more towards it
causes the hydrogen atom less attraction and more easy to be donate or be release. Compare to
acetic acid, hydrogen ion much easy to donate which mean monochloroacetic acid become
slightly higher acidity than acetic acid and higher molar heat of neutralization.
Back to the result, it shown that errors were happened during the experiment which totally
change the final results. The most highlighted error is the heat loss to the surrounding from the
calorimeter. The heat loss gave higher significant different at the final calculation. It shows that
how heat play important role in this experiment. Heat produced needed to calculate the molar
heat of neutralization. Heat loss from the calorimeter cannot be avoid due to the calorimeter been
used is not really perfect but it can be minimize by certain step to increase the efficient of the
calorimeter.
Conclusion:
Calibration of calorimeter, Cp = (852.146
JK-1
kJ
Hm HCL
HmHNO3
HmCH3COOH
HmClCH2COOH
= (33.23
= (34.36
= (45.21
= (20.91
.5) kJ mol-1
kJmol-1
kJmol-1
) kJmol-1
Suggestion to improve:
Based on the results that completely different from the theory, can be concluded that many error
might happened during the experiment. Errors that can be emphasized are the heat losses to the
surrounding during each neutralization process take place. As the calorimeter that been used is
not really a perfect adiabatic system, heat can be loss to the surrounding and affect the reading
recorded. Heat evolved need to measure accurately due to heat is actually the main product. Final
results would be affected. Besides, during the addition of sodium hydroxide, NaOH to the
calorimeter, the cap must be open to pour the sodium hydroxide into it. From that, a lot of heat
could be loss to the surrounding. Step that suggested overcome this error is to use or put a cover
at the wall of the calorimeter especially at the caps part to ensure the heat losses as little as
possible
As we know, the neutralization process takes place in very short time after the addition of
sodium hydroxide and the temperature also will rises sharply and immediately. In that case, there
is a probability that we missed the exact reading of the thermometer. Recording a video of the
thermometer that used in the calorimeter could be the best way to detect the sharply rises of
temperature.
Last but not least, where the calorimeter that contains the mixture was not been shaken
consistency. The reaction cannot be undergo completely and causes the mixture do not reach the
equilibrium during the reading of temperature were recorded. Due to that the temperature reading
recorded could be not the exact ones. It can be overcome by decided only a person will shake the
calorimeter with consistent force and power for all the process and make time taken for the
thermometer reading recorded a little bit longer.
References:
3 ways to calculate uncertainty. Retrieved from http://www.wikihow.com/CalculateUncertainty
Neutralization.
Retrieved
from
http://chem.libretexts.org/Core/Physical_and_Theoretical_Chemistry/Acids_and_Bases/
Acid%2F%2FBase_Reactions/Neutralization
Neutralization Reaction: Definition, Equation & Example. Retrieved from
http://study.com/academy/lesson/neutralization-reaction-definition-equationexamples.html