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Problems for
Complex Systems
Solving Multiple-Equilibrium
Problems Using a Systematic Method
Mass-Balance Equations
Mass-balance equations relate the equilibrium concentrations of various
species in a solution to one another and to the analytical concentrations of
the various solutes.
Example
Write mass-balance expressions for a 0.0100 M solution of HCl that is in
equilibrium with an excess of solid BaSO4.
Example
Write mass-balance expressions for the system formed when a 0.010 M NH3
solution is saturated with the slightly soluble AgBr.
Charge-Balance Equation
no. moles/L positive charge = no. moles/L negative charge
This equation represents the charge-balance condition and is called the
charge-balance equation.
- Na+
- Mg2+
- PO43-
- 0.1 M NaCl
- 0.1 M MgCl2
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Step 2.
Step 3.
Step 4.
Practice problem
calculate the molar solubility of:
1. Calculate the molar solubility of Calcium oxalate in buffer
2. Calculate the molar solubility of Silver Bromide in Ammonia
3. Calculate the molar solubility of BaCO3 in water
4. Calculate the molar solubility of Calcium oxalate in water.
5. Calculate the molar solubility of lead carbonate in a solution
whose analytical concentrations are 0.05 M of benzoic acid and
0.08 M of sodium benzoate
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