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1.
B + C. (non-equimolar counter
b. Adiabatic operation.
4. Derive the expression representing time variation of the reactant particle size, for the
general situation where external mass transfer, product layer diffusion, & reaction,
may all have resistances comparable in magnitude (Eqn. 33b in Levenspiel).
5. A plant is removing a trace of chlorine from a waste gas stream by passing it over a
solid absorbent in a Packed bed. 63.3% removal is being achieved right now. What is
the percentage removal expected when all of the following are done simultaneously?
Flow rate is increased by a factor of 4; particle diameter decreased by factor of 3;
packed tube length increased by 50%. Assume that the chlorine is removed by a
virtually instantaneous reaction at the surface of the absorbent. (Hint: dont forget the
dependence of mass transfer coefficient/specific surface area on the particle size)
6. The global rates of SO2 oxidation have been measured with a platinum catalyst
impregnated on the outer surface of 1/8 x 1/8 in cylindrical pellets of alumna. The
data were obtained in a differential reactor consisting of 1 inch ID tube packed with
catalyst pellets. The superficial mass velocity of the reaction mixture was 1460 kg/hr
m2. At constant conversion of 20% of a feed consisting of 6.5% (mol) SO 2 (and rest
air), the rates are as shown below. The toal pressure of 790 mm of Hg. Consider the
properties of mixture to be those of air. Sc for SO2 is 1.21.
a. If only the data at 4600C and 5000C are used and external diffusion is neglected,
what is the apparent activation energy?
b. By calculating (Cb-Cs) for SO2 at various temperatures and all the data above,
estimate the true activation energy for the combined adsorption and reaction
processes at the catalyst surface. Consider the reaction to be isothermal.
0
C
rp, gmol
SO2/h/
gcat
350
0.0049
360
0.0079
380
0.0142
400
0.024
420
0.0344
440
0.052
460
0.067
480
0.09
500
0.122