Beruflich Dokumente
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WORKSHEET FOR
JEE-ADVANCE/AIIMS
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
Gem-dibromide is
[RPMT 2000]
(a) CH3CH(Br)OH(Br) CH3
(b) CH3CBr2CH3
(c) CH2 (Br)CH2CH2Br
(d) CH2BrCH2Br
Ethylidene dibromide is
(a) CH3 CH2 Br
(b) Br CH2 CH2 Br
(c) CH3 CHBr2
(d) CH2 = CBr2
Benzylidene chloride is
(a) C6H5CH2Cl
(b) C6H5CHCl2
(c) C6H4ClCH2Cl
(d) C6H5CCl3
Haloforms are trihalogen derivatives of [CPMT 1985]
(a) Ethane
(b) Methane
(c) Propane
(d) Benzene
The general formula for alkyl halides is
(a) CnH2n+1 X
(b) CnH2n+2 X
(c) CnHn+1 X
(d) CnH2n X
The compound which contains all the four 10, 20, 30 and 40 carbon atoms is
[J & K 2005]
(a) 2, 3-dimethyl pentane
(b)3-chloro-2,3-dimethylpentane
(c) 2, 3, 4-trimethylpentane
(d) 3, 3- dimethylpentane
The following reaction is known as
Pyridine
C 2 H 5OH + SOCl2
C 2 H 5Cl + SO2 + HCl
[AIIMS 2002; MH CET 2004]
(a) Kharasch effect
(b) Darzens procedure
(c) Williamsons synthesis
(d) Hunsdiecker synthesis reaction
What is the main product of the reaction between 2- methyl propene
with HBr
[RPMT 2002]
(a) 1- bromo butane
(b) 1-bromo-2-methyl propane
(c) 2-bromo butane
(d) 2-bromo-2 methyl propane
Halogenation of alkanes is
[KCET 2002]
(a) A reductive process
(b) An oxidative process
(c) An isothermal process
(d) An endothermal process
+
N NBF4
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
Silver acetate
Cs2
+ Br2
hv
21.
22.
23.
24.
25.
26.
27.
28.
(a)
(c)
29.
CH 3
|
CH 3 C COOH
|
OH
(b)
(d)
H
|
CH 3 C COOH
|
Cl
CH 3
|
CH 3 C COOH
|
Cl
(a)
(c)
H
|
HO C COOH
|
H
CH 3
|
CH 3 CH COOH
NH 2
|
CH 3 CH CH 3
NH 2
|
CH 3 CH 2 CH CH 3
30.
31.
32.
33.
F
HOOC C OH
Me
C
Me
C
H
34.
35.
(a) R and E
(b) S and E
(c) R and Z
(d) S and Z
Which one of the following objects is achiral
(a) Letter P
(b) Letter F
(c) Ball
(d) A pair of hand
Which one of the following contains asymmetric carbon atom
[IIT JEE 1989; Roorkee 2000]
Cl Br
H
(a)
H
(c)
(b)
(d)
Cl
Cl
Br
OH
CH3
CH3 CHCl CH2 CH3 Has a chiral centre, which of the following represents
its R configurations
[CBSE PMT 2007]
36.
C2H5
H3C
C2H5
Cl
(a)
37.
38.
39.
40.
41.
42.
CH3
CH3
(c)
(d)
Cl
C2H5
(a)
CH 3
|
CH 3 CH CH 2COOH
(c)
CH 3
|
CH 3 CH CH 2OH
H
C=C
CH3
H
C
CH3
(a) Tautomerism
(c) Geometrical isomerism
5
CH3
Cl
(b)
C2H5
Cl
COOH
43.
44.
45.
46.
47.
HO2C
CO2H
48.
49.
(a) R, R
(c) S, R
Which is optically active...
(a) CH2Cl2
(c) Meso form of tartaric acid
An organic compound
OH
OH
(b) R, S
(d) S, S
[MH CET 2001]
(b) CHCl3
(d) Glyceraldehyde
50.
CH 3 2 CH 2 3 CH 2 4 CH 2 5 CH 2 6 CH 2 7 CH 3
To make it chiral compound the attack should be on which carbon atom?
[DEC 2001]
(a) 1
(b) 3
(c) 4
(d) 7
Which of the following molecules is expected to rotate the plane polarized
light
[AIEEE 2007]
CHO
(a)
HO
(b)
SH
CH2OH
H2N
(c)
(d)
H
Ph
6
COOH
NH2
Ph
H2N
H
H
51.
52.
CH3
(a)
CH3
H
HO
H
and
OH
HO
HO
CH3
CH3
CH3
(b)
CH3
OH
HO
and
CH3
CH3
CH3
OH
HO
(d)
and
HO
HO
CH3
CH3
CH3
CH3
OH
H
HO
and
HO
HO
CH3
53.
HO
CH3
(c)
HO
CH3
Br
C
H3 C
54.
H
Cl
(a) R
(c) Z
Which of the following will be chiral
(a) CH3CHCl2
(c) CD2Cl2
(b) S
(d) E
[J & K 2005]
(b) CH3CHBrCl
(d) CH2CIBr
55.
HO
CHO
(a)
CHO
(b)
CHO
CHO
CH2OH
HO
CH2OH
(c)
OH
(d)
HO
CH2OH
HO
CHO
(e)
56.
A.
compound A is
57.
CCl3
CCl3
Br
(a)
(b)
CCl3
Br
(c)
CCl3
(d)
Br
Br
Br
58.
59.
60.
61.
62.
63.
64.
65.
66.
67.
68.
2 CHCl3
O2
2COCl2 + 2HCl
69.
70.
71.
72.
73.
74.
75.
76.
77.
78.
79.
10
80.
81.
82.
83.
84.
85.
86.
(a) C2H5Cl + Mg
(c) C2H5Cl + C2H5ONa
87.
88.
11
CH2Cl
Cl
(a)
(b)
Br
CH3
I
(c)
Cl
(d)
Br
89.
90.
91.
92.
93.
94.
95.
96.
97.
12
if
to
2-
in
98.
99.
100.
101.
102.
103.
104.
105.
106.
107.
108.
13
C3 H7 Cl + HCl
C3H8 + Cl2
is an example of which of the following
types of reactions
[AFMC 1997; CPMT 1999]
(a) Substitution
(b) Elimination
(c) Addition
(d) Rearrangement
In preparation of CHCl3 from ethanol and bleaching powder, the latter
[BHU 1986]
provides
(a) Ca(OH)2
(b) Cl2
(c) Both (a) and (b)
(d) None of these
Lucas reagent is
[AIIMS 1980; CPMT 1986,
89;MP PET 1992, 95; MP PMT
1996; Kurukshetra CEE 2002]
(a) Concentrated HCl + anhydrous ZnCl2
(b) Dilute HCl + hydrated ZnCl2
(c) Concentrated HNO3 +anhydrous ZnCl2
(d) Concentrated HCl + anhydrous MgCl2
Which compound does not form iodoform with alkali and iodine
[IIT JEE 1885]
(a) Acetone
(b) Ethanol
(c) Diethyl ketone
(d) Isopropyl alcohol
Acetone reacts with I2 in presence of NaOH to form
[MP PMT 1992]
(a) C2H5I
(b) C2H4I2
(c) CHI3
(d) CH3I
A Grignard reagent may be made by reacting magnesium with
[CPMT 1984]
(a) Methyl amine
(b) Diethyl ether
(c) Ethyl iodide
(d) Ethyl alcohol
Haloalkanes and Haloarenes -Worksheet JEE Advance/AIIMS
109.
110.
111.
112.
113.
114.
115.
116.
117.
118.
119.
14
X + KCN
CH3 CN
what is (X)
[DCE 2007]
(a) CH3CH2Cl
(b) CH3Cl
(c) CH3CH2CH2Cl
(d) (CH3)2 CHCl
In Nucleophilic aliphatic substitution, the nucleophiles are generally
(a) Acids
(b) Bases
(c) Salts
(d) Neutral molecules
120.
121.
122.
123.
124.
125.
126.
127.
CH3
128.
15
129.
130.
131.
132.
133.
134.
135.
136.
137.
138.
139.
140.
16
141.
142.
143.
144.
145.
146.
147.
C6 H5CH2Cl + KCN(aq.)
[BHU 1979]
(a) C6H6 + KCl
(b) C6H5 CH2 CN + KCl
(c) C6H5CH3 + KCl
(d) None of these
In presence of AlCl3, benzene and n-propyl bromide react in FriedalCrafts reaction to form
[MP PMT 1991]
(a) n propyl benzene
(b) 1, 2 dinormal propyl benzene
(c) 1, 4 dinormal propyl benzene
(d) Isopropyl benzene
Which of the following statements about chloroform is false
[Manipal MEE 1995]
(a) It is a colourless, sweet-smelling liquid
(b) It is almost insoluble in water
(c) It is highly inflammable
(d) It can be used as an inhalational anaesthetic agent
On heating CHCl3 with aq. NaOH, the product is
[BHU 1997; EAMCET 1998; JIPMER (Med.) 2002; Orissa JEE 2003]
(a) CH3COONa
(b) HCOONa
(c) Sodium oxalate
(d) CH3OH
Identify X and Y in the following sequence
x
y
C6H5Br
product
C3H7NH2
[Orissa JEE 2005]
(a) X = KCN, Y = LiAIH4
(b) X = KCN, Y = H3O+
(c) X = CH3Cl, Y = AlCl3/HCl
(d) X = CH3NH2, Y = HNO2
Which of the following statements is incorrect
[CPMT 1977]
(a) C2H5 Br reacts with alco. KOH to form C2H5 OH
(b) C2H5 Br when treated with metallic sodium gives ethane
(c) C2H5Br when treated with sodium ethoxide forms diethyl ether
(d) C2H5Br with AgCN froms ethyl isocyanide
Following equation illustrates
200 2500C
C6H5Cl + 2NaOH
148.
149.
17
200 atm
150.
151.
152.
153.
154.
155.
156.
157.
158.
COONa
(a)
(c)
18
COONa
Na
(b)
159.
160.
161.
162.
163.
164.
165.
166.
HBr
HBr
Hv
Br
19
Br
Br
(c) A is
Br
& B is
Br
167.
168.
169.
170.
171.
172.
173.
174.
20
(d) A is
Br & B is
(e) A is
Br & B is
Br
The correct increasing order of the reactivity of halides for SN1 reaction
[BHU 2006]
is
(a) CH3 CH3 X < (CH3 )2CH X < CH2 = CH CH2 X < PhCH2 X
(b) (CH3 )2 CH X < CH3 CH2 X < CH2 = CH CH2X < PhCH2 X
(c) PhCH2 X <(CH3 )2CH X <CH3 CH2 X < CH2 =CH CH2 X
(d) CH2 = CH CH2 X < Ph CH2 X < (CH3 )2 CH X < CH3 CH2 X
Number of isomers of molecular formula C2H2Br2 are
[CPMT 1987]
(a) 1
(b) 2
(c) 3
(d) 0
Lactic acid shows which type of isomerism
[CPMT 1987; MP PMT 1987; BHU 2003]
(a) Geometrical isomerism
(b) Tautomerism
(c) Optical isomerism
(d) Metamerism
Separating of d and I enantiomorphs from a racemic mixture is called
[CBSE PMT 1988; DPMT 1983; KCET 2002]
(a) Resolution
(b) Dehydration
(c) Rotation
(d) Dehydrohalogenation
Number of optical isomers of lactic acid are
(a) 1
(b) 2
(c) 3
(d) 4
Meso-trararic acid is optically is optically inactive due to the presence of
[AIIMS 1982; MP PMT 1987; BHU 2001]
(a)Molecular symmetry
(b) Molecular asymmetry
(c) External compensation
(d) Two asymmetric C-atoms
It is possible to distinguish between optical isomers by
[Manipal MEE 1995; AFMC 1995]
(a) Infrared spectroscopy
(b) Mass spectroetry
(c) Melting point determination
(d) Polarimetry
The number of enantiomers of the compound CH3CHBrCHBrCOOH is
[AIIMS 1997]
(a) 0
(b) 1
(c) 3
(d) 4
175.
176.
177.
178.
H
CL
179.
180.
181.
182.
183.
21
184.
COOH
OH
OH
OH
OH
COOH
COOCH3
(A)
185.
186.
187.
(B)
CH3
H
Br
F
They are
(a) Enantiomers
(c) Conformational isomers
188.
F
Br
[KCET 2006]
189.
(a) (CH3)2CHCHO
(b) CH3CH2CH2CHO
(d) CH3CH2CBr2CHO
Acyclic stereoisomers having the molecular formula C4H7Cl are classified and
tabulated. Find out the correct set of numbers
a
b
c
d
e
22
Geometrical Optical
6
2
4
2
6
0
4
0
5
2
190.
191.
192.
193.
Cl
(a)
Cl
Cl
(b)
Cl
Cl
Cl
Cl
Cl
Cl
(c)
Cl
C
Cl
Cl
Cl
Cl
Cl
Cl
Cl
(d)
Cl
194.
195.
196.
23
197.
198.
199.
200.
Match the list I and II and pick the correct matching from the codes
given below :
[Kerala PMT 2006]
A. Iodoform
1. CF4
B. BHC
2. antiseptic
C. Freon-14
3. month repellant
D. Halothanes
4. inhalative anesthetic
E. p-dichlorobenzene
5. termite pesticide
(a) A 2; B 4; C 5; D 3, E 1
(b) A 2; B 5; C 1; D 4, E 3
(c) A 3; B 4; C 2; D 1, E 5
(d) A 1; B 3; C 5; D 2, E 4
(e) A 5; B 4; C 3; D 2, E 1
Which of the following is used in fire extinguisheres
[AFMC 1993]
(a) CH4
(b) CHCl3
(c) CH2Cl2
(d) CCl4
Which of the following is an anaesthetic[AFMC 1989]
(a) C2H4
(b) CHCl3
(c) CH3Cl
(d) C2H5OH
What would be the product formed when 1-Bromo-3-chloro
cyclobutane reacts with two equivalents of metallic sodium in ether
[IIT JEE (Screening) 2005]
Cl
(a)
(b)
Br
(c)
201.
202.
203.
24
(d)
(b)
(c)
204.
205.
206.
207.
25
(d)
CH3 CH2 C Cl
CH3
CH3
A dihalogen derivative X of a hydrocarbon with three carbon atoms
reacts with alcoholic KOH and produces another hydrocarbon with
forms a red precipitate with Ammonia cal Cu2Cl2. X gives an aldehyde
on reaction with aqueous KOH. The compound X is
[Kerala PET 2008]
(a) 1, 3- Dichloropropane
(b) 1, 2- Dichloropropane
(c) 2, 2- Dichloropropane
(d) 1, 1- Dichloropropane
(e) 1, 3- Dichloropropane
ALKYL HALIDES
ANSWERSHEET
Que.no. Ans. Que.no. Ans. Que.no. Ans. Que.no. Ans. Que.no. Ans. Que.no. Ans. Que.no. Ans. Que.no. Ans.
1
b
27
a
53
a
79
d
105
a
131
d
157
b
183
a
2
b
28
b
54
a
80
a
106
c
132
c
158
b
184
c
3
c
29
d
55
c
81
c
107
c
133
d
159
a
185
e
4
b
30
c
56
a
82
a
108
c
134
a
160
c
186
c
5
a
31
b
57
a
83
b
109
d
135
c
161
b
187
d
6
b
32
a
58
c
84
a
110
c
136
c
162
c
188
c
7
b
33
c
59
c
85
a
111
c
137
b
163
a
189
a
8
d
34
c
60
c
86
b
112
b
138
c
164
a
190
b
9
d
35
d
61
c
87
a
113
c
139
d
165
d
191
b
10
a
36
c
62
d
88
c
114
b
140
b
166
c
192
d
11
a
37
d
63
a
89
b
115
a
141
b
167
a
193
a
12
b
38
a
64
a
90
b
116
d
142
d
168
c
194
c
13
a
39
b
65
b
91
c
117
d
143
c
169
c
195
c
14
a
40
c
66
c
92
c,d
118
b
144
b
170
a
196
a
15
a
41
b
67
b
93
a
119
b
145
a
171
b
197
b
16
a
42
b
68
a
94
b
120
a
146
a,b
172
a
198
d
17
a
43
b
69
a
95
c
121
b
147
a
173
d
199
b
18
c
44
d
70
a
96
a
122
d
148
b
174
d
200
d
19
a
45
b
71
d
97
c
123
a
149
b
175
a
201
d
20
b
46
c
72
a
98
a
124
b
150
c,d
176
a
202
a
21
d
47
a
73
c
99
c
125
d
151
c
177
a
203
a
22
a
48
d
74
b
100
d
126
b
152
a
178
a
204
b,c
23
b
49
b
75
b
101
a
127
b
153
d
179
d
205
c
24
c
50
a
76
b
102
a
128
a
154
b
180
a
206
d
25
c
51
d
77
b
103
a
129
a
155
d
181
d
207
d
26
b
52
b
78
a
104
c
130
d
156
b
182
d
26