Beruflich Dokumente
Kultur Dokumente
xE
SS41Chem. (Supp.)
No. of Questions 30
No. of Printed Pages 15
=SS vE {E {I,
2013
x Yx
CHEMISTRY
1
4
Ph]
{hE : 56
x] : Eh E +E i i ii { JB*
{Il E B x xn :
GENERAL INSTRUCTIONS TO THE EXAMINEES :
1.
2.
|x Ex +x *
All the questions are compulsory.
3.
4.
Vx |x +xiE Jhb , =x E =k BE l J*
For questions having more than one part the answers to those parts
are to be written together in continuity.
5.
SS41Chem. (Supp.)
.SS441
[ Turn over
2
6.
7.
|x J
+E |iE |x
1-13
14-24
25-27
28-30
Q. Nos.
1-13
14-24
25-27
28-30
1.
reason ?
2.
n-
p-type semiconductors ?
SS41Chem. (Supp.)
. SS441.
3
3.
4.
5.
+G
A B
+G n nMx Vi V
E pi E S Mx
g Vi * < +G E E] i<B*
In reaction, A B rate of reaction is doubled when concentration of A
is increased four times. Give the order of reaction.
6.
+G
C12H22O11 + H2O
H+
C6H12O6 + C6H12O6
ME
<I-E
C]V
E M VE JB*
Write the rate expression for the reaction
C12H22O11 + H2O
Cane sugar
SS41Chem. (Supp.)
H+
C6H12O6 + C6H12O6
Fructose
Glucose
. SS441.
[ Turn over
4
7.
VE ( Z = 30 ) E Gh ii x x M * Eh nVB*
Zinc ( Z = 30 ) is not regarded as a transition element. Give reason.
8.
[ Co ( en ) 3 ] 3 +
Yi EVB
a)
Co
E +CEh +l
b)
Co
E x J*
Determine in [ Co ( en ) 3 ] 3 +
9.
a)
oxidation state of Co
b)
used ?
10.
SS41Chem. (Supp.)
. SS441.
5
11.
b<BVEh +G E Eh nVB*
Give the equation of diazotisation reaction.
12.
+E il +xE Bx + C +i ?
What is the difference between essential and non-essential amino
acids ?
13.
14.
a)
CHO
group in glucose
1
r E il BE x E { n B i{ E v +J JSx {
G: |{i G E Sj x<B*
b)
xEx V xi Jx { v EEB Ec Vi * Eh
nVB*
a)
b)
SS41Chem. (Supp.)
1+1
. SS441.
[ Turn over
6
15.
H2
16.
Na2SO4
E B
E Mhx EVB n
Calculate
for
Na + = 50 1 S cm2 mol 1
il
* < |H x E { JB*
Na2SO4
if
Na + = 50 1 S cm2 mol 1
17.
1++
and
1+1
18.
1+1
SS41Chem. (Supp.)
1+1
. SS441.
7
19.
20.
a)
Ti 3 + +x
b)
xlxb ESx C ?
a)
b)
Mx i VE
Ti 4 + +x
Mx* Eh nVB*
1+1
K 2 [ Zn ( OH )4 ]
b)
21.
a)
K 2 [ Zn ( OH )4 ]
b)
2-]x
E V
NaOH
il BEE
NaOH
1+1
E l xE
. SS441.
[ Turn over
8
Give the equations of chemical reactions of 2-Bromobutane with
4
aq. NaOH and alc. NaOH. Write the type of each reaction.
OR
wh PhE BE <b
+ 1
SN2
+G x E |ix E l {z
i * BE =nh u Z<B*
In optically active alkyl halides, SN2 reaction is completed with
inversion. Explain by an example.
23.
C4H10O
+hj S BE E +h+ E Sx j
1+1
I.U.P.A.C.
nVB*
Write structural formulae and I.U.P.A.C. names of four alcohol
molecules having molecular formula C4H10O.
24.
a)
b)
x <l h +G E Eh nVB*
a)
b)
SS41Chem. (Supp.)
. SS441.
1+1
1+1
9
25.
a)
( CH3 ) 3 N
b)
CH3CONH2 E LiAlH4 il
E IEi
CH3NH2
E * Z<B*
V G Ex { ME
l M Ex { nMxv ME
xi V
Y
xi *
il Y E j I.U.P.A.C. x nVB*
a)
b)
X and Y.
26.
a)
1++++
b)
x<x-6, 6 xx E +G E Eh nVB*
a)
b)
SS41Chem. (Supp.)
. SS441.
2+1
[ Turn over
10
27.
a)
b)
Ej vE E Ei ? <xE ={M v M u C E
Vi ?
+l
i A n +v E x i B nB MB =xE M EVB :
i A
a)
i B
B{x
|i]x
{xx
|iVxx Ii +v
Bm<x
|iE
xBlxbx
Vhx
Vhv
]xbx
{c*
b)
1 + 1
OR
SS41Chem. (Supp.)
. SS441.
11
Match the drugs given in Column A with their class given in
6
Column B :
Column A
28.
a)
Column B
Aspirin
Antihistamine
Penicillin
Anti-fertility drug
Erythromycin
Tranquilizers
Norethindrone
Bactericidal
Valium
Bacteriostatic
Terfenadine
Analgesic.
b)
+G
N2 ( g ) + 3H2 ( g )
Fe ( s )
Mo ( s )
2NH3 ( g )
Mo ( s )
={M Fe ( s ) E l C E M ? B {nl E C Ei ?
c)
SS41Chem. (Supp.)
. SS441.
[ Turn over
12
a)
b)
c)
x E vx G E Z<B*
a)
Write
two
differences
between
physiosorption
and
b)
In
reaction,
N2 ( g ) + 3H2 ( g )
Fe ( s )
Mo ( s )
2NH3 ( g ) , why
a)
b)
c)
SS41Chem. (Supp.)
. SS441.
(+++)+1+1
13
29.
a)
15
C i ? Z<B*
b)
BE i +vi ` X, V +v n{i i , E
CS2
x M ] {j Jx { i: V =`i i v
Y
c)
H2SO3
a)
M 18 E ii E =iE] M C Ei ?
b)
H2SO4 E
=i{nx E { |G E ix Sh x +G+ E
Eh nVB*
c)
XeF2
a)
b)
c)
SS41Chem. (Supp.)
. SS441.
[ Turn over
14
a)
b)
30.
c)
a)
i)
ii)
2CH3
O+
CHO
1+2+1
p KOH
A+B
ix NaOH
C
H 2O
b)
c)
Ex- n x E ={M M x xx i E Vi ?
+l
a)
OH
i)
CH3
ii)
C6H5COOCOCH3
CN
H2 O
H2O
H+
OH
C+D
b)
-b-VE +G Eh nE Z<B*
c)
R-COOH
E ClxE i +h BE =SS i *
Eh nVB*
SS41Chem. (Supp.)
. SS441.
15
a)
i)
ii)
2CH3
O + Conc. KOH
CHO
A+B
dil. NaOH
H2 O
b)
c)
a)
b)
c)
H+ or OH
i)
CH3
ii)
C6H5COOCOCH3
CN
H2 O
H+ or OH
H2O
C+D
SS41Chem. (Supp.)
. SS441.
(+++)+1+1
[ Turn over